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Home My WebLink AboutApplication APPLICANT 4/9/2010 . .City of Springfield ' Development Services Department 225 Fifth Street Springfield, OR 97477 Drinking Water Protection Overlay District Development . r~~&'1,\.iI;~:;;,,?i'^::~~~X~"\}rq!';;;'~4--:''4!%;-~fr-~~:;:-~€~") w:r:;;-~(~-~-\;- ~~. ~-T~c." ~u~d~Pr~je_~t~~~l1Wati?&i~~ L:.~ ;:.~~ : "f~fimJsaift;';f.i!!PJ!/*:t~ !11!'!!~~!!!!jj A Iicant Name: Jackie Mikalonis Volunteers In Medicine 3321 West 11th Avenue Eu ene OR 97402 Phone Fax: 541-685-1820 541-868-3577 Address: A licant's Re .. Phone Fax: Address: Owner: PeaceHealth PeaceHealth Phone 541-686-3660 541-686- 3699 Fax: ASSESSOR'S MAP NO: 17 03 25 13 P.O. Box 1479 Eu ene, OR 97440 TAX LOT 1700 Address: 2260 Marcola Road S rin field OR 97477 Size of Pro 1.89 Acres x S uare Feet 0 Zonin : Existin Use: Description of Pro osal: CC Communit Commercial Medical Clinic If you are filling in this form by hand, please attach your proposal description to this application. See Attached Associated Cases: (!5)IV\ 2010'- 8:f2kCJ Case No.: ~ Reviewed b : Date: A lication Fee: $ I OJ-D. 0 Technical Fee: 51.QD Posta TOTAL FEES: I D7l.ctJ PROJECT NUMBER: Date Received: APR -,9 2010 Original Submittal Revised 1/15/09 ddk 1 of 5 Signatures . . The undersigned acknowledges that the information in this application is correct and accurate. Applicant: tf:&r ~ Jacqlyn Mikalonis Print Date: April 8, 2010 If the applicant is not the owner, the owner hereby grants permission for the applicant to act in his/her behalf. Owner: s;gn/Jt1}NV Jim Weston Print Date: April 8, 2010 Date Received: APR -,9 2010 Original Submittal Revised 1/15/09 ddk 2 of 5 DWP Overlay District !velopment Submittal Requ!ments Checklist NOTE: If you feel an item does not apply, please state the reason why and attach the explanation to this form. o Submitted Concurrently with Site Plan Review or Minimum Development Standards applications, where applicable. o Application Fee - refer to the Development Code Fee Schedule for the appropriate fee calculation formula. A copy of the fee schedule is available at the Development Services Department. The applicable application, technology, and postage fees are collected at the time of complete application submittal. o DWP Overlay District Development Application Form o Copy of the Deed o Copy of a Preliminary Title Report issued within the past 30 days documenting ownership and listing all encumbrances. o Narrative explaining the proposal and any additional information that may have a bearing in determining the action to be taken, including findings demonstrating compliance with the Standards for Hazardous Materials within Time of Travel Zones (TOTZ) listed in SDC 3.3-235. NOTE: Before the Director can approve a DWP Overlay District Development request, information submitted by the applicant must adequately support the request. All of the Standards for Hazardous Materials within TOTZ must be addressed. Incomplete applications, as well as insufficient or unclear data, will delay the application review process and may result in denial. In certain circumstances, it is advisable to hire a professional planner or land use attorney to prepare the required findings. o Three (3) Copies of a Plot Plan reduced to 8 112" by 11" outlining the applicable TOTZ boundaries in relationship to the property boundaries o Three (3) Copies of the Following: H }kfl Use of hazardous materials that pose a risk to groundwater that existed on the IJ'V!'- ~operty prior to May 15, 2000, if applicable !SdHazardous Material Inventory Statement and Material Safety Data Sheet for all materials entered on the Statement. Hazardous material weights shall be converted to volume measurement for purposes of determining amounts (i.e. 10 pounds shall be considered equal to one gallon) -..Nfr/f List of chemicals to be monitored through the analysis of groundwater samples and a monitoring schedule if groundwater monitoring is anticipated to be .required .IT1oetailed description of the activities conducted at the facility that involve the storage, l'Jjf\handling, treatment, use, or production of hazardous materials in aggregate quantities . ., 0 ~:::~~t~:~nO:~hOe g;:ii:naSry and any secondary containment devices proposed, and, if ~ .'-"" ~~plicable, clearly identified as to whether the devices will drain to the sanitary sewer ;of stormwater system Date Received: '0 Proposed Hazardous Material Management Plan for the facility that indicates procedures to be followed to prevent, control, collect, and disposAAA ariY l!010uthorized release of a hazardous material Revised 1/15/09 ddk Original Submittal 4 'of-5- "J- \I'~~ ~J;C'IV . . ','l' *'0 Description of the procedures for inspection and mairirenance of containment devices ~d emergency equipment . ~ \ Description of the plan for disposition of unused hazardous materials or hazardous . I" material waste products over the maximum allowable amounts, including the type of transportation and proposed routes Date Received: APR -9 2010 Original Submittal Revised 1/15/09 ddk 5 of 5 . . April 8, 2010 City of Springfield Development Services Department 225 Fifth Street Springfield, OR 97477 Applicant: Volunteers In Medicine Clinic 3321 W. 11th Avenue Eugene, OR 97402 Subject Property: Map & TL 2260 Marcola Road, Springfield, OR 97477 17 03 25 13 1700 RE: Drinking Water Protection Overlay District Permit / Narrative V olunteers In Medicine is requesting review for compliance with the 1-5 year Time of Travel Zone regulations in accordance with the Springfield Development Code. Approval is requested for remodeling and renovation of a 9100 square foot medical clinic. The subject property is part of the larger Mohawk Marketplace. The improvements are on an 82,328-square-foot site zoned CC, Community Commercial by the City of Springfield. The subject property is improved with a single-story, 9,084 square foot medical office building built in 1994. The improvements consist of a wood framed building with a reception area, waiting rooms, exam rooms, three restrooms, break rooms and lab areas. The property is located at 2260 Marcola Road, Springfield (Assessor's Map 1703 13, TL 1700), and the site is zone CC Community Commercial. The 1-5 year Time of Travel zone (TOTZ) -a reference contour on the City of Springfield's wellhead protection, is adjacent to the subject building. Therefore, the subject building is located within the boundary of the 1-5 year TOTZ for the MAlA wellhead. o VOLUNTEERS INMEDICINE CliNIC Duncan McDonald Chair Jackie Mikalonis Prt'9id,'nt/cwcutiw Dired"r Doug Walker, M. D. Vice Chair Douglas G. Wl,ile S\'cn'lary Stevcn Ritcbie, C.P.A. Trea,;Ufl"r Liz Cawood Jack Eberly Sister ~lonica Heeran Sleven ~\ark5, M.D. Sandra Mattson Ciay Skurdal Jim Torrey Sarab Zacbem Date Received: APR - 9 2010 3321 WI t 1111 A E 0 97402;;41/686-6361 Original Submittal "eS 1 vellue, ~ugellc, regoll v v.'WW. vim-clinic.org - - -- - - 1 Il .t - I. L .. -.. f, I , . - - . . l ~ \ L - "' ................................ ............................... .............................. .......................... ......................... .' .:.:.:.:.:.:.:.:.:.:.:.:.:. 1.:.:-:.:.:-:.:.:.:-:.' . ................. .'. . . . .. -- ---- . . . \'I' " ~:MA .... lo ~~ ,J] '1 1 ~ J -- MAlA . . . . , . . . .'..~.!... I.' ........ . ......... ......... ......... .......... .......... .......... ....:.:.:. ...... . \ :.:.:.:.:.:.............. . . . . . .:.:.:.:.:.:.:.:.:.........:.:.:.. . ................. . ........... a,.. ......... .', . ...~...... ~................. . ...... ...... :.' * Volunteers In Medicine 2260 Marcola Road Springfield, OR Entire property is located within the 1-5 year Time of Travel Zone "0 Q) c:::> > <5 04) "" ai u en :=: Q) I 'e 0::: 0:: .c Q) 0... ~ - <( en 11l (ij 0 c '0, 'C 0 rOI< Assr5S\~CNl SW1/4 NE1/4 SEC. 25 T.17S. R,3W. W.M. _ _ ==- ;\~JD TAi.A. TI:;~; lANE COUNTY ~~jij; ONl': sc.ou:l".l00' ~,..,,_._..,; sa _" Q.J 2~ 12 I ! IL-------------------------------_______________:tf._ r-llll, 1~ 'JO:I 1'<<lO' ' -.-. - 'ri -i II ~. . . I~' r : I I' ;1 ~ ~ .'F.: i,{\ "1 III. "'- ! ~. t~\*f~j \, , I o)~0: i . :r..".:'1l".;';-~~. '00'.- S f 10 --;;'--=---LJ:" ~~. I : r 11;! - 'll~_J .1- ---" ,... <. : I 4~1 -;r- -.; ) 'i ,~" ""'17 ':"~ I i ~il' ,. .:11 -;:;'T/t~il 1 i 'I' 'j\'l -1- I' ~ 'l~~~.:~;;- --:::. --,----__. __'___ ________ _.____ -___.._~t.!..._~_ 1Wi.!.-- 1-....___1 _~_~_IlO<oO_ --~----_. -.- <:~.,,2~m-IWO_'"'_..-...... ..lr'-.....- /" .-"-~~"":"'-' .. . I .~.-..-,,- .~.-.. '[ ..fOe, _ F .\lOk. ~aooc. I .~.. j ! 1300 <<H>_~~__.__ i ~ ..,~. ~].-- ~,. 1- ! ~I ,#>{I' ...\"1.. :1 .. --""..:,-----~~_ L ' '",.: ---'- . ''\It'L; .P' "\I;-'Ij ,..1 " " ., . . o ~ ; .lI". ....r. u"n I - -$:-;:._:c~.;;;::.------ ----- .~ .~';;;.. "= -" ---.- --- -. ----- D.Il;OI(~"""""l'l-lllll ------ -~ RI_1703U.Z [ ] Plat Map 17 03 25 13 SPRINGFIELD ICAD. Sys.1 f"m :; ~ :J :: ~ , . . o ~ ; ~ ,,- ;::;: ....."'. . .. ..... ~~, 1~S~ ..~;;: ;=::-.: . ....'l,:' ..-' ,......... .~~'". .-. ..~.::. 17032513 SPRINGFIELO Date Received: APR - 9 2010 Original Submittal . . Volunteers In Medicine Clinic 2260 Marcola Road Springfield, Oregon 97477 Drinking Water Overlay Protection District Application April '2010 Proposed Primary and Secondary Containment Devices Hazardous materials will be stored, handled and used with precautions to avoid spills. Primary containment devices will be original containers. Secondary containment for storage of hazardous materials that pose a risk to the groundwater will e provided in accordance with the applicable regulatory requirements, Article 17.070 (2)(b) ofthe DWP Program. This requirement specifically states that: "Except those exempted, all hazardous materials that pose a risk to groundwater shall be stored in areas with approved secondary containment in place (Uniform Fire Code Articles 2 and 8003.1.3.3)". Secondary containment may be provided by one ofthe following means: Secondary containment devices, such as spill trays, leak proof plastic bags, tubs or trays for containers. Secondary containment will be sized to accommodate a spill from the largest container. In addition, the sizing needs to accommodate fire -protection water (20 minutes discharge volume). The materials of construction of the secondary containment system must be compatible with the hazardous material to be stored. The secondary containment system will have a monitoring method, such as visual observation. The secondary containment devices, such as plastic tubs, will allow easy access and quick inspection. The secondary containment tubs or trays will have sufficient depth to contain at least 110% volume of the largest container. In hazardous material use areas where products are used frequently and easily visible, individual containers of products that are not highly hazardous or toxic do not need to be kept in secondary containment. Examples would be a quart bottle of isopropyl alcohol in an exam room or dish detergent or hand soap at or under a sink. Materials not in current use should be returned to storage in secondary containment. Date Received: APR - 9 2010 Original Submittal - .-. CASCAoe TlTUi ca. . RETURN TO CASCADE TITLE CO. (b) TITLE NO. 227/418 ESCROW NO. EUOl-3430 TAX ACCT. NO. 1517638~N\ 11-03-1.5. \~-O'1'" Division of L.ne County ( C~l~epUlY Clerk D..d. end Records $31.00 03:49:00 PM WARRANTY DEED -- STATUTORY FORM SACRED HEART MEDICAL CBNTER POUNDATION, a nonprofit Oregon Corporation, Grantor, conveys and warrants to PEACEHBALTH, A WASHINGTON NON-PROFIT CORPORATION, Grantee, the following described real property free of encumbrances except as specifically set forth herein: SEE EXHIBIT A WHICH IS MADE A PART HEREOF BY THIS REFERENCE THIS INSTRUMENT WILL NOT ALLOW USE OF THE PROPERTY DESCRIBED IN THIS INSTRUMENT IN VIOLATION OF APPLICABLE LAND USE LAWS AND REGULATIONS. BEFORB SIGNING OR ACCEPTING THIS INSTRUMENT, THE PBRSON ACQUIRING PEE TITLE TO THE PROPERTY SHOULD CHECK WITH THE APPROPRIATE CITY OR COUNTY PLANNING DBPARMENT TO VERIFY APPROVED USES AND TO DBTBRMINE ANY LIMITS ON LAWS~TS AGAINST FARMING OR FORBST PRACTICES AS DEFINED IN ORS 30.930. Except the following encumbrances: 2001/2002 taxes which are a lien but not yet due and payable. COVENANTS, CONDITIONS, RESTRICTIONS AND EASEMENTS OF RECORD. The true consideration for this conveyance is $1,450,000.00. Dated this ~ day of -Ar!J1J.,St ,'200 \ . PRESIDENT SACRED HEAR BY: WILLIAM S. STATE OF OREGON, county of LMle... ) ss, This instrument was acknowledged before me on AtAaJcl"'3~, 20JLL, by WILLIAM S. ANDERSON, as PRESIDENT, of SACRED HEAR~ICAL CENTER FOUNDATION, on behalf of the grantor. ~ A/'-/ Notary ~ub~ic for.oregon v1 1~/f)6'~ My commlSSlon explres: ~J SACRED HEART MEDICAL CENTER FOUNDATION 1255 HILYARD ST, EUGENE. OR 97401 GRANTOR'S NAME AND ADDRESS Until a change is requested all tax statements shall be sent to the following address: *** SAME AS GRANTEE *** PEACEHEALTH P.O. BOX 1479 EUGENE. OR 97440 GRANTEE'S NAME AND ADDRESS After recording return CASCADE TITLE CO. 811 WILLAMETTE EUGENE, OR 97401 to: Date Received: APR -, 9 2010 cooZ'so ::>;0 S3~JdX3 NOISSlrMOO ~ c~!:6zt 'ON NOISSIYiWOO (I).. , N093'tiO"On8Od AM'I"lON :" ': H31111'l3VllVWVl .' W3S1VIOI&:fO I> OFFICIAL SEAL TAMARA E MILLER NOTARY PUBUc-oREGON , ,/i COMMISSIONNO.329313 MY' COtR.lISSION EXPIRES DEC 05,2003 al Submittal . . ~ r CD f:'j.I\.'o: 't "p.," PROPERTY DESCRIPTION A parcel of land in the Northeast one-quarter of Section 25, Township 17 South, Range 3 West, Willamette Meridian, said parcel more particularly described as follows: Beginning at a point on the Northerly margin of Marcola Road, said point being the Southeast corner of that tract of land described in Deed to Pay Less Drug Stores Northwest, Inc., recorded May 10, 1991, Reel No. 1695, Reception No. 9121697, Lane County Official Records, being North 89. 57' 3011 East, 887.38 feet and North 00 02' 00" West, 45.00 feet from a Brass Cap monument marking the Southwest corner of Felix Scott Donation Land Claim No. 51, in Section 25, Township 17 South, Range 3 West, Willamette Meridian; thence along the East line of said Pay Less tract, North 00 021 00" West, 269.90 feet; thence North 890 57' 3011 Eastl 305.00 feet; thence South 00 02' 3011 East, 269.90 feet, to the Northerly margin of Marcola Road; thence along said margin, South 890 57' 30" West, 305.04 feet to the Point of Beginning, all in Springfield, Lane County, Oregon. Dat~ Received: APR -'. 9 2010 Original Submittal . . -- == CASCADE TITLE CO. IIIII~ III! 1!111~III~il ~IIIII~ 1!lllllm STATUS OF RECORD TITLE REPORT VOLUNTEER'S FOR MEDICINE ATTN: JACKIE MlKALONIS 3321 WEST 11TH AVENUE EUGENE, OR 97401 Our No: CT-0265984 Date: APRIL 7, 2010 Charge: . $200.00 Government service Fee: $35.00 As requested, Cascade Title Co. has searched our tract indices as to the following described real property: A parcel of land in the Northeast one-quarter of Section 25, Township 17 South, Range 3 West, Willamette Meridian, said parcel more particularly described as follows: Beginning at a point on the Northerly margin of Marcola Road, said point being the southeast corner of that tract of land described in Deed to Pay Less Drug Stores Northwest, Inc., recorded May 10, 1991, Reel No. 1695, Reception No. 9121697, Lane County Official Records, being North 89' 571 3011 East, 887.38 feet and North O' 021 DOli West, 45.00 feet from a Brass Cap monument marking the Southwest corner of Felix. Scott Donation Land Claim No. 51, in Section 25, Township 17 South, Range 3 West, Willamette Meridian; thence along the East line of said Pay Less tract. North O' 021 00" West, 269.90 feet; thence North 89" 571 30" East, 305.00 feet; thence south O' 02' 30" East, 269.90 feet, to the Northerly margin of Marcola Road; thence along said margin, South 89' 571 3011 West, 305.04 feet to the Point of Beginning, all in springfield, Lane County, Oregon. and as of: APRIL 02, 2010 at 8:00 A.M., we find the following: Vestee: PEACEHEALTH a Washington non-profit corporation Said property is subject to the following on record matters: 1. Right of way, including the terms and provisions thereof, granted the City of Eugene, Oregon, a Municipal corporation, by and through the Eugene Water Board, recorded March 16, 1925, in Book 142, Page 450, Lane County Oregon Deed Records. (Along the North line of county Road No. 278) 2. permanent Slope Easement, including the terms and provisions thereof, granted Lane County, recorded August 11, 1982, Reception No. 8223699, Lane County Official Records. Date Received: continued- APR -' 9 2010 Original Submittal MAIN OFFICE' 811 WILLAMETTE ST. . EUGENE, OREGON 97401' PH: (541) 687-2233 FLORENCE' 1901 HWY 101 _ S. 2 . FLORENCE, OREGON 97439 . PH: (541) 997-8417 EUGENE FAX: 485-0307' E-MAIL: info@caacadetitle.com . FLORENCE FAX: 997-8246 ,4" '. .. . . 3. Covenants, conditions, restrictions and easements, including the terms and provisions thereof, (but omitting any covenant condition or restriction based on race, color, religion, sex, handicap, familial status or national origin unless and only to the extent that said covenant (a) ~s exempt under Chapter 42, Section 3607 of the United states Code or (b) relates to handicap but does not discriminate against handicapped persons) in Declaration of Restrictions and Grant of Easements, recorded March 17, 1989, Reel No. 1563, Reception" No. 8911762, and amendment recorded October 31, 1989, Reel No. 1600, Reception No. 8949055, and amendment recorded May 10, 1991, Reel No. 1695, Reception No. 9121698, Lane County Official Records, and as incorporated by instrument recorded May 10, 1991, Reel No. 1695, Reception No. 9121696, Lane County official Records. 4. Easement, including the terms and provisions thereof, granted Hayden Corporation, dba Hillman Properties Northwest, by instrument recorded May 10, ~991, Reel No. 1695, Reception No. 91216941 Lane County official Records. 5. Easement, including the terms and provisions thereof, as set forth in Option and Restrictions Agreement, recorded May 10, 1991, Reel No. 1695, Reception No. 9121696, Lane County Official Records. 6. Conditions and Restrictions, (but omitting any covenant condition or restriction based, on race, color, religion, sex, handicap, familial status or national origin unless and only to the extent that said covenant (a) is. exempt under Chapter 42, Section 3607 of the united States Code or (b) relates to handicap but does not discriminate against handicapped persons) in Option and Restrictions Agreement, recorded May 10, 1991, Reel No. 1695, Reception No. 9121696, and amendment recorded October 1, 1993, Reel No. l883, Reception No. 9362649, and amendment recorded October 12, 1993, Reel No. 1886, Reception No. 9365168, Lane County Official Records. 7. Easement, including the terms and provisions thereof, granted the City of springfield, by instrument recorded March 25, 1994, Reel No. 1935, Reception No. 9421981, Lane county Official Records. 8. Easements, conditions and restrictions, including the terms and provisions thereof, in Reciprocal Easement Agreement, recorded April 22, 1994, Reception No. 9429763, Lane County Official Records. NOTE: Taxes, Account No. 15176381 Assessor's Map No. l7 03 25 1 3, #17QO. Code 19-00, 2009-2010, in the amount of $18,684.54, PAID IN FULL. This report is to be utilized for information only. 'This report is not to be used as a basis for transferring, encumbering or foreclosing the real property described. The liability of Cascade Title Co. is limited to the addressee and shall not exceed the premium paid hereunder. CASCADE TITLE CO., by: ../~. Date Received: Officer: JIM HIGGINS APR -,9 2010 Original Submittal JQS.ou' ~ ~ N . 1800 .1.72 AC. PCL. 2 " \ ',-0'3 -z. 5"-1'3 THIS MAP IS. TO ASSIST LOcA ING PROPERTY, THE COMPANY ASS ES NO i.IAllIUTY ~OR INAGCURA IES. ~ "17 ~ .1700 1.89 AG. PCL. 1 ,. 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Vlln 59,93' 5l.B&' 52.DO' 5~.00' Vl43.90' -- 58S'0 '19' I: C!61.9' SBll'03'\9"( 32 '37' "0,00' . 3200 . ::! 0.12 AC. . g ,.. 'IJIlW-rt. r.: ., 72. .., SB9'03'19'( 9o.110' -.:-.:nn APR -' 9 2010 o 10:5.00' . '..3700 . c 0.14 AC, ,.: "lIo_san. .' n . =- Sl,ia"03'19"t 10'1.113' . ~ 3600 90.00' 3100 0.12 AC. 'I]IlSO.rT. 71 S 69'03'19" [ 9tl.OO' ..,..,..,.. ~ 2600 ". 0.16 AG. . , 67BO SI;I, 1'1. ~.. 7 N as.03'19' v Z B <Jfo.B6' 2500 .w ~'. 0.15 AC. ~. . 6(17 SO. n. ~~ 6 r;7 6 ate Received: 8.0b' 1I"(6'll" V ~~L' o al Submittal . . VOLUNTEERS IN MEDICINE 2260 Marcola Road SprinQfield. OR 97447 HAZARDOUS MATERIALS MANAGEMENT PLAN March 1, 2010 VOLUNTEERS INMEDICINE CliNIC Date Received: APR -,9 2010 Original Submittal Hazardous materials are substances, as defined in the City of Springfield Land Use Development Code Article 17 for the Drinking Water Protection (DWP) Overlay District that may be stored, handled, treated, used or produced at the Facility. As the Facility is located in areas specified to be a drinking water wellhead Time of Travel Zone of 1-5 years, restrictions apply to hazardous materiais to protect groundwater. The Springfield Development Code defines Hazardous Materials as those substances (liquid or solid) which pose a risk to groundwater quality (Article 17.020 (1) (a) a class of liquid chemicals or substances which are physical or health hazards to groundwater). The class of hazardous materials is based on Article 80 of the Uniform Fire Code (UFC) which has been as adopted and amended by the City, including materials in both useable or waste conditions. VIM HMMP 2010 Page I of 18 . . VOLUNTEERS IN MEDICINE 2260 Marcola Road Sorinqfield. OR 97447 HAZARDOUS MATERIALS MANAGEMENT PLAN Table of Contents Section Section II Section III Section IV Section V Section VI Section VII Section VIII Section IX Section X Facility Description Hazardous Material Inventory Statement Separation, Secondary Containment and Monitoring Waste Disposal Record Keeping Spill Prevention Emergency Response Plan Emergency Response Training Plan Process for Updating Hazardous Materials Mgt Plan Notes Date Received: APR -, 9 2010 Original Submittal VIM HMMP 2010 Page 2 of 18 . . VOLUNTEERS IN MEDICINE 2260 Marcola Road Sorinofield. OR 97447 HAZARDOUS MATERIALS MANAGEMENT PLAN March 1, 2010 Volunteers In Medicine is located in the 1-5 time-of-travel zone to one of Springfield's municipal drinking water wells This means that chemicals that spill or leak onto the ground surface have the potential to contaminate the well in less one to five years time. Volunteers In Medicine is a committed partner in the effort to protect Springfield's drinking water supply. Our hazardous materials management program emphasizes the importance of preventing chemicals leaks and spills and responding promptly and effectively should a release occur. We strive to increase awareness that the property lies within a sensitive drinking water protection area among both our employees and the public who visit our business. This hazardous materials management plan outlines Volunteers In Medicine's protocol for preventing, controlling, collecting, and disposing of any unauthorized releases of hazardous materials. The plan also identifies the greatest areas of risk within our facility and outlines the steps we take to reduce the risk. Any questions about this plan or how Volunteers In Medicine manages its hazardous materials should be directed to DeLeesa Meashintubby, VIM Senior Operations Officer at 541-686-3797. Date Received: APR - 9 2010 Original Submittal VIM HMMP 2010 Page 3 of 18 . . Section I: Facility Description Part A-General Information 1. Business Name: Volunteers In Medicine Address: 2260 Marcola Road Springfield, OR 97477 Phone: 541-686-3797 2. Person Responsible for the Business Name Jackie Mikalonis Title Executive Director Phone 541-242-5389 3. Emergency Contacts: Name Title Work Phone Lois Garner Medical Director 541-521-3689 541-685-1922 n.s. .u's"J.e'fl"'o....s.s..i!liIn,'.iBiiis... ',"e' 's"s"hM' 'a" .'n"'a'g'e' 'r' t:'iinlni:...itE!i"....,"'ii~i5i4i1i"'2.85'8.7.9.6 'iO"". 5'4.1"685 '1'820>: ; ';." ".... +p, . .r{0JJl,f-:~f., .,,\:.I,I!I..__3L _.__1- _;fAr!h++;i~t;-;f4siiLHbt,,-l!J0!>\ .._ .0;;;~___. _.,j,j,L....:ii:'ii#i;;H._"j,;;,;;,<.i, --;~-' 4. Person Responsible for the HMMP: Name DeLeesa Meashintubby Title Sr. Operations Officer Phone 541-098-7654 5. Property Owner: Name PeaceHealth Address P.O.Box 1479 Eugene, OR 97440 Phone 541-686-3660 6. Principle Business Activity: Medical Clinic/Health Care 7. Number of Employees (maximum number expected): 20 Date Received: 8. Number of Shifts: N/A APR -.9 2010 9. Hours of Operation: M 9 -9; T 1-9; W 9-1; Th 9-5; F 9-1 Original Submittal 10. Declaration: I certify that the information above and on the following parts is true and correct to the best of my knowledge. Signatur~ clA>5- {.-S- Print Name: I t/ Director! VIM HMMP 2010 Page 4 of 18 , ~. , cJ;~ J C-;I~ Mikalonis Date: ~ t.f. :20/0 'Title: Executive . . Part B -- General Facility Description/Site Plan Plat Map is attached. The property is located at 2260 Marcola Road. Sprinqfield. OR 97477 (Assessor's Map 17 03 25 13 TL 1700. The subject property is part of the larger Mohawk Marketplace. The improvements are on an 82,328-square-foot site zoned CC, Community Commercial by the City of Springfield. The subject property is improved with a single-story, 9,084 square foot medical office building built in 1994. The improvements consist of a wood framed building. with a reception area, waiting rooms, exam rooms, three restrooms, break rooms and lab areas. The interior finishes consist of commercial grade carpet, vinyl flooring, and HVAC units. The subject has a land to building ratio of 9.06 to 1, which is larger than typical in the market place; however, the site is subject to joint access/parking agreements typical of shared area in improved commercial centers. Part C -- Facility Map/Hazardous Material Storage Locations See Floor Plan Storage locations: Janitor Closet, Medical Storage, Dispensary, Patient Assistance Program room. VIM HMMP 2010 Page 5 ofl8 . ;..;~ a ;; ~~' ..,," . . . . . ~~ b- 1.----- IIQI I I I I I I I : I N WI I I _____..J ltI (;;;J IR IQI IQI BICYCLE AIOEA Entrance PLANTING: AREA LJ , L ,~" ". = 1/T{ C I Eligibility. J o I L066Tl \ = II II II I . , ,"\...,'~... .. Scheduling. ---,L I ~~J o ID\. ,.- r- _~';'t-. ReferralS/e Diabetes ~ -..."....-- , I~- '.;-~' I C"ART,': Iloce I = ~>"'-"~' ,-. r----J./ T r ;? ~:' ........1'-, I y- CoPl.~:;- I 7 \ I IlvA~~1 r- r- ~ I III I I I I I c~ .j1 T C EXAM RCOW' ~''''''' ~ I"~ VI >. 1../ I ". V" I "-. I I L rSJ IQI ---nm----mTIi .. L e ~ I--lALL ElWl ROOM' ~f- f- f- Irftfrh EX.... """"3 ~ I, Future EXPilinsion / .. ;..?-- &-- ( A::i~~:~ce WailinvRoorn F~- OFFICE ~ f- 'I I I ~ "T~ 1111~Cl , t IV~ ) ] TOI"E YI _~ IOCq., , - Dispensary EllA" ROOM' ~ f- ~ EX>><'. ~I """'" 81 l:'k IU~~~ g U III 'II . NURSE AI T TRI~E I MOA 2 DeC. """'" ...... ~ c L ~" .,., ~prog~ 1 I f~ I rFA~ ..2010! 1.i< SUR'&'" t H f coo,iAg ~'u ure orne 0 V olunteers In Medicine Clinic 2260 Marcola Road' Springfield, Oregon Current Location 4400 Square Feet . 7 Exam Rooms . Dispensary & Patient Assistance Program in m'o Separate Locations . Nurse's Station in Hallway . Cramped Quarters for Volunteering Providers . Phlebotomy Station In Hallway . Lease - $12/year New Location wlRemodel .9100 Square Feet . 13 Exam Rooms . Dispensary/P AP together . Large Nurses' Station . Dedicated Providers' Office . Lab & Draw Station Area . Privacy for Eligibility Screeninl . Spacious Medical Records . Expanded Counseling Area . Lease. $12/year Volunteer Break , /I _ :::J Room :;. ~ALL .\<;O;ii1 f1 r- -m I ==tl "\ I ~ (0 \.J][;T , H ---[!J%- ~ ~" I ~ ~r-- i~~~ ltQl F' II.A61 t lidl lhl 1!mOO:1 EX.... RDON' ...J\ HALL :J Di'.fJ~ RI f- f- l Copier EX>>< """". l€lli~;' ~ ~III.~ .x.... ROOI.ll0, . OJ I[j I I.~. .-or-: r- F !::::J I I' - -11 Ii~TIQ)~ 11 Q)~ .,1= ~8~~E III r\S~f\ ill~~ ~'71 r\" Medical Records "'C T I i I' In1 / "-.... ._ ~ _If'" .\-'1 II,.\., 11111111111:1:1 Illm\lh!~I......\ ....' ~ s~ EX.... EX.... f """", 'f- """'" J f- ~ IQI \ ----- i F-J L ~., . DRPlW I\RcPl Conference Room ~ALL ~ '=7 Senior Operating Officer o ~~[ [ I I I I I ,____:..J ~ -~-,~ . IQI I ..---~ I it:- I i r'lJ ~ C]f; __ I i I I I I I I I I .0...- 1 ., 1: ~ Date Received: APR - 9 2010 I 1 1 : CM~ Re~~l 1 @fill :51',11 ~;t C!) " F;(t~ fxt'~,^"5\oe.dc,*,w.t E::J ~ ':>~'"fJ e.. QreAS . . .fet 1ow<Z.niD1.I. -; II1c4u.",I... Section II: Hazardous Materials Inventory Statement If hazardous material inventory changes, this HMIS shall be updated to reflect those changes and provided to SUB for review for compliance with SDC 3.3-200 on an annual basis. Products containing DNAPLS are prohibited. Any new materials proposed for use or storage on-site shall be evaluated for DNAPLS by the Springfield Utility Board Water Quality Protection Coordinator (541-744-3745) prior to purchase, No DNAPLS are used by VIM and all vendors will be notified that DNAPLS are prohibited on site. VIM does not use hazardous materials in quantities that exceed 500 gallons. No more than 500 gallons of hazardous materials can be kept on the premises. The maximum allowed container size is 5 gallons. No more than 150 gallons of hazardous materials that pose a risk to groundwater may be on the premises in opened containers for handling, treatment, use, production, or dispensing on site. . 0 . ::!. ea ::r 0 !!!. C/l l> III - c: " <l> 0- ::0 ::0 3 I ;::;: <l> - .<a 0 !!!. ......, <l> = <' 2S <l> a. VIM HMMP 2010 Page 6 or 18 Hazard ous Ch . Storage CI T emlc aSSl1 I Approx. Conditions Open NFPA Manufacturer's cation Ab at Maximum Location of Name & Product Hazardous s rac . Range of (Survey State of or 704 Chemical Ingredients and Concentration Codes t Quantity Containe Table Material Closed Classifica Name (Surve S . Unit Noted Stored y Table ervlce r Sizes IV&V) Use tion VI) s No. (1) (1) Grafco H1 Silver Nitrate Silver Nitrate 37.5 15 ml 15 ml Liquid C F1 Exam Applicator - mg/Potassium Nitrate-12.5 mg tube R1 room . SOX H1 lIegiance Povidone Povidone 1 bottle x4 40z L C F1 Exam topical solution paint oz =4 QZ R1 room S 25 bottles, H3 Allegiance F3 preservative fluid cytorich 10 ml each 10ml L C RO pap =250 ml S 9 bottles, H2 F1 Exam Meridian BioScience, Buffered Neutral Formalin 10% 15ml each 15ml L C RO =135 ml room 9 bottles, H1 Meridian BioScience F1 Exam LV-PVA Fixative 15ml each 15ml L C R1 room =135 ml . H2 Amerisource Bergen Hydrogen Peroxide 12 bottles 32 oz to L C FO pap .) Solution =1840z 1040z R1 .::. , 0 H2 .- ~ Ge&uer Company 1 bottle F4 .) Ethyl Chloride - Spray x3.5 oz 3.50z L C RO pap r :;0 AI l ! ;: CD H2 + <D 0 1100 50 to 400 .:!.. PA~ Pharmaceutical Silver Sulfadiazine Cream L C F1 pap I'-) Grams Grams = <' R1 - = Go~ Neighbor Carbamide Peroxide 6.5% - Ear 3 bottles H3 Exam x 0.5 oz 0.50z L C F1 Pharmacy Wash =1.50z RO room 21 bottles H1 Safetex Cytology Fixative (1 to 4 oz) 4.00z L C F1 pap () ..., 6:5" S" ~;. ("::; !:~: 5:.,. ~t r[ - ""0 ~..:J 32 H3 Pathology Consultant Formalin Solution 10% containers 30 ml L C F2 pap x 30 ml = 960 ml R2 NW Pharmaceutical 1 bottle x H3 Potassium Hydroxide 10% 30 ml = 30 30ml L C FO pap Compounding solution ml RO 1 container H3 Polar Cryogenics, Inc Liquid Nitrogen x 18 Liters 18 L L C FO pap =18 liters RO 2 bottles x H2 Exam Aaron Brands Rubbing Alcohol-Isopropyl 16 oz = 32 160z L C F3 room oz R2 MedChoice 2 bottles x H1 8 oz = 16 80z L C F1 pap Biological Odor Elimin oz RO 2 bottles x H3 Virex 256 - Germicida 25 oz = 50 250z L C F1 pap Deodorant oz RO Allegiance 1 bottle x . H2 Janitor Cardinal Health 0.5 gal = 0.5 gal L C F1 closet Dual Enzy-Clean 0.5 gal RO 1 bottle x H2 Janitor Bleach - sodium Hypochlorite 6 96oz=96 960z L C FO closet oz RO Coastwide Labs 1 bottle x 1 H1 Janitor 1 qt L C F1 Orange Oil Polish qt = 1 qt R1 closet 1 bottle x H1 Janitor Water & Clorox soluli 32 oz = 32 320z L C F1 closet oz R1 Johnson Wax 1 bottle x HO Janitor ;;rofessionals 32 oz = 32 320z L C FO ~Iass Cleaner RO closet oz eorgia Pacificl 1 bottle x H1 Janitor atural Concepts 78 oz = 78 780z L C F3 closet and Sanitizer oz RO 3eorgia Pacificl 30 bottles x H1 Janitor I ~atural Concepts 8 oz = 240 80z L C F3 closet . ~and Sanitizer oz RO . . '. U~ ,.., -':",) c:3 2000 H1 Webcol Prep pads - 70% alcohol packets x 1 1 packet S C F3 pap ea = 2000 RO S HO POI 900 packets 1 packet C FO Exam room Cleansing Towelettes- x 1 ea = 900 RO SO Alcohol 40 BID 400 packets S H1 Sterile Alcohol Swabs 1 packet C F1 pap Ultilet x 1 ea = 400 RO 3M Cavil on 2 bottles x L H2 15 ml = 30 15 ml C F3 pap No sting barrier film ml RO Miltexl S H2 Fougera 1 gross 1 packet C F1 Exam room Surgical Lubricant Steril packet RO Miltexl S H2 Fougera 1 gross 1 packet C F1 pap Double Antibiotic Ointm packet RO 50 1 swab S H1 Allegiance Swabsticks C FO pap Providone Iodine swabsticks stick RO i?:RODilic'!ts'iUSEDl'oNQSimliN.ANi!lls'f:0REf);0@iSITE;lro<'affiifleSkilidi1ict"~lj'ali(j~dlifiEft-cHe'rfijcrais';niiio~4fertiilf~SlantlilanmStiai~RBlje&l'\~.,;t'i;~.'I"ifu~ w_",,';"~'--~ . ," ,~~1;'~;";';,". ,-,-,,<," """w':"'~.w"""~"'" .. ...~"",-,~~ "'i"",,,""""~"" '''''''''---.. w' _.-~ - none 0 . . (Q 3' 0 !!!. III CIJ )> ... <: -0 CD tT :::0 ;;0 3 ! ;::;: CD ~ u:> ~ !!!. "" = <' - = CD a. . . Section III: Separation, Secondary Containment, and Monitoring Above Ground Storage Areas (no underground storage areas on site). All hazardous materials and wastes, regardless of container size, must be kept in secondary containment. All hazardous materials shall be properly labeled. Storage Area Identification Areas (as shown on Floor Plan): Janitor Closet. Medical Storaqe. Dispensary. Patient Assistance Proqram. 1) Janitor Closet: 1. Storage Type: X Original Containers Inside Machinery 55-Gallon Drums Pressurized Vessel Safety Cans Bulk Tank Outside Barrels Other: 2. Storage Location: X Inside Building Outside Building Secured 3. Separation: All Materials X Compatible Separated by 20 feet One-Hour Separation Wall Approved Cabinets Other: 4. Secondary Containment': Approved Cabinet Secondary Drums Tray Bermed, Coated Floor Vaulted Tank Double-Wall Tank x Other: Plastic Storace bins and plastic bacs 5. Monitoring: X Visual Continuous Other: 6. Monitoring Frequency: _Daily x Other: Monthly Weekly 2) Medical Storage: 1. Storage Type: X Original Containers Inside Machinery 55-Gallon Drums Pressurized Vessel Safety Cans Bulk Tank Outside Barrels Other: Date Received: APR -. 9 2010 2. Storage Location: X Inside Building VIM HMMP 2010 Page 7 ofl8 Outside Building Original Submittal . Secured . 3. Separation: One-Hour Separation Wall Approved Cabinets Other: x All Materials Compatible Separated by 20 feet 5. Secondary Containment': Approved Cabinet Secondary Drums x Tray Bermed, Coated Floor Vaulted Tank Double-Wall Tank x Other: Plastic Storaqe bins and plastic baqs 6. Monitoring: --L Visual Continuous Other: 7. Monitoring Frequency: _Daily x Weekly Other: 3) Dispensary: 1. Storage Type: X Original Containers Inside Machinery 55-Gallon Drums Pressurized Vessel Safety Cans Bulk Tank Outside Barrels Other: 2. Storage Location: X Inside Building Outside Building Secured 3. Separation: X All Materials Compatibie Separated by 20 feet One-Hour Separation Wall Approved Cabinets Other: 6. Secondary Containment': Approved Cabinet Secondary Drums x Tray Bermed, Coated Floor Vaulted Tank Double-Wall Tank x Other: Plastic Storace bins and plastic baqs 7. Monitoring: X Visual Continuous Other: 8. Monitoring Frequency: _Daily x Weekly Other: Date Received: 4) Patient Assistance Program: APR -, 9 2010 1 Storage Type: X Original Containers Inside Machinery Safety Cans Bulk Tank Original Submittal VIM HMMP 2010 Page 8 of 18 . 55-Gallon Drums Pressurized Vessel Outside Barrels Other: . 2. Storage Location: X Inside Building Outside Building Secured 3. Separation: All Materials X Compatible Separated by 20 feet One-Hour Separation Wall Approved Cabinets Other: 7. Secondary Containment': Approved Cabinet Secondary Drums' x Tray Bermed, Coated Floor Vaulted Tank Double-Wall Tank x Other: Plastic Storaqe bins and piastic baqs 8. Monitoring: X Visual Continuous Other: 9. Monitoring Frequency: _Daily x Weekly Other: Section IV: Waste Disposal Hazardous waste kept on site will be disposed of in appropriate hazardous waste containers and hauled away weekly by Sanipac, the vendor contracted with to discard hazardous waste from the clinic. Soiled linens are stored in secondary containers and removed by ALSCO weekly. Hazardous waste and containers are inspected weekly. Discharge to Sanitary Sewer Wastes: Pretreatment Wastes: x Licensed Waste Hauler Wastes: Medicines, druqs, biomedical waste Recycle Wastes: Date Received: APR - 9 2010 Other OriDinl'l1 Submittal VIM HMMP 2010 Page 9 of 18 . . Describe Method: Wastes: No Waste Section V: Record Keeping (Inspection and Maintenance) Description of our Inspection Program: >- Visual inspections of containment and emergency equipment will take place monthly. >- The Sr. Operations Officer will conduct the inspections. . >- Written inspection forms will be recorded and filed monthly. >- The Sr. Operations Officer will sign off on the completed inspection forms. >- In the Sr. Operations Officer's absence, the Medical Director will sign off on the completed inspection forms. >- Completed inspection forms will be filed electronically with the Business Manager and kept in the Business Manager's file and the Sr. Operations Officer's office for seven years. . Visual inspection of the secondary containment devices will be conducted to ensure their integrity. Any secondary containment device that does not meet the standards necessary to adequately contain the materials and prevent them from spilling will be replaced within 24 hours. All areas and containers with hazardous materials will be inspected for leaks and/or spills. . Secondary containment devices will be inspected to make sure they are intact and secured if necessary. . Original containers will be inspected to make sure they are not leaking, rusted, bulging, or otherwise damaged . Ensure Warning signs properly displayed. . Ensure existing hazardous waste properly contained. Section VI: Spill Prevention >- All hazardous materials are stored in secondary containers no more than half full. >- Containers are stored at eye level or below and in secure cabinets and on secure shelves. >- Incompatible materials are not stored together. >- All secondary containers are monitored monthly and maintained in good condition. >- Employees are regularly trained in medication storage, spill clean-up, and disposal. Date Received: . No back up generators exist on-site. . There are no loading docks in the facility. APR - 9 2010 VIM HMMP 2010 Page 10 of 18 Orir.'....,~ q, '''mittal... . Storm and sani~ drains are protected via signage ! no concentrated liquid chemicals. Section VII: Emergency Response Plan 1. In the event of an emergency, the following shall be notified: A. On-Site Responders: Name Title Phone B. Method of Notification to Responders: Automatic Alarm Manual Alarm Other: X Telephone X Verbal c. Oregon Emergency Response S stem The standard procedure for notification of a hazardous material release in Springfield is to call 911. The first responder will dispatch information to Springfield Utility Board, which must be notified as soon as possible if a chemical release has the potential to contaminate municipal wells. 2. Designated Local Emergency Medical Facility: Name Address Phone 3. Mitigation Equipment: A. Monitoring Devices: Toxic or flammable gas detection Date Received: APR - 9 2010 VIM HMMP 2010 Page 11 ofl8 Original Submittal . Fluid detection Other: . B. Spill Containment: X Absorbents x Other: Secondary containment C. Spill Control and Treatment: Vapor Scrubber PumpsNacuums Neutralizer Mechanical Ventilation X Secondary Containment Other: 4. Evacuation: X Immediate area evacuation routes posted Entire building evacuation procedures developed Assembly areas pre-planned Evacuation maps posted Other: X 5. Supplemental Hazardous Materials Emergency Response Plan on Site: Location: Spill instructions posted with spill kits/see floor plan Responsible Person: DeLeesa Meashintubbv Phone: 541-686-3797 6. Spill Response The spill response will be physical. Dry materials will be swept with a broom and disposed of in a hazardous material secondary container clearly marked. Sanipac will haul hazardous materials away from site to be disposed of properly with Lane County, Public Works Department, Waste Management Division. Wet spills response will be physical using materials in the spill kit containers. Paper towels will be disposed of in a hazardous material secondary container clearly marked as hazardous material for Sanipac. Sanipac will haul hazardous materials away from site to be disposed of properly with Lane County, Public Works Department, Waste Management Division. Specific Instructions Included with each Spill Kit: 1. Attend to people who may be contaminated. Contaminated clothing must be removed immediately and the skin flushed with water for no less than fifteen minutes. 2. Wear personal protective equipment, as appropriate to the hazards. Refer to the MSD Sheets for appropriate personal protective equipment 3. Consider the need for respiratory protection. Protect floor drains or other means of environmental release. Floor drain mats may be placed around drains. 4. Setup up the box from the sill kit for disposal. Empty out the contents, fold the box back in with the top open, line with one of the biohazard bags., Date Received: VIM HMMP 2010 Page I2 of 18 APR - 9 2010 Original Submittal . . 5. Congeal the spill. Shake the powder directly on to the spill. Note: If the spill has coagulated and thickened, dilute the spill with the disinfectant solution, then shake the powder on. 6. Pick up the spill. When the liquid has solidified to a rubbery texture, use scoop and plastic square to gather material and place into the box. 7. Disinfect the area. When spill has been picked up, pour disinfectant directly on to affected area, let stand. Soak up with paper towels. Discard towels in the biohazard bag in the biohazard box. Secure for disposal. Section XIII: Emergency-Response Training Plan 1. Person Responsible for the Emergency-Response Training Plan: Name Title Phone 2. Training Requirements: A All employees trained in the following as indicated: X Procedures for internal alarm/notification X Procedures for notification of external emergency-response organizations X Location and content of the emergency-response plan X Awareness of the facility's proximity to sensitive drinking water protection area X Drinking water protection presentation (contact SUB Water Quality Protection Coordinator, Amy Chinitz, at 541-744-3745) B. Chemical handlers are trained in the following as indicated: X Safe methods for handling and storage of hazardous materials X Proper use of personal protective equipment X Locations and proper use of fire- and spill-control equipment Specific hazards of each chemical to which they may be exposed C. Emergency-response team members are trained in the following: Procedures for shutdown of operations _ Procedures for using, maintaining and replacing facility emergency and monitoring equipment 3. The Following Records are Maintained for All Employees: X Verification that training was completed by the employee Description of the type and amount of introductory and continuing training Documentation on and description of emergency-response drills conducted at the facility 4. A more comprehensive and detailed emergency-response training plan is maintained on site. Location: Sr. Operations Officer Office Date Received: Responsible Person: DeLeesa Meashintubbv Phone: 541- 686-3797 APR - 9 2010 VIM HMMP 2010 Page 13 oflS Original Submittal . . Spill instructions are posted throughout clinic for staff and volunteers: Problem Description F II Primary Response Secondary Response o oW-UP Hazardous Incidental Spill Trained user cleans up spill with Contact Senior Ops Officer and Nurse Complete report of the Materials Spill Small spill presenting appropriate personal protective Coordinator. Appropriately dispose of incident or Release NO hazard to trained equipment, decontamination materials. employee or the materials and places material in environment. appropriately marked secondary containers. Use spill kit Emeraencv.Soill Complete report of the Any spill which may Isolate the spill area (evacuate), incident. contaminate wells or Deny entry to others, Notify your present a hazard to Supervisor. ground water or people or the effects Assist contaminated victims in are unknown. decontamination process if you can do 50 safelY. Section IX: Process for Updating HMMP The HMMP will be updated on an annual basis. The Sr. Operations Officer will be responsible for keeping the document current. Copies of the HMMP will be kept in the Business Office and in the Sr. Operations Officer's office. Section X: Notes I. Hazardous materials wiJl be stored, handled and used with precautions to avoid spiJls. 2. Primary containment devices wiJI be original containers. 3. Secondary containment for storage of hazardous materials that pose a risk to the groundwater wiJl e provided in accordance with the applicable regulatory requirements, Article 17.070 (2)(b) of the DWP Program. This requirement specificaJly states that: "Except those exempted, aJl hazardous materials that pose a risk to groundwater shaJl be stored in areas with approved secondary containment in place (Uniform Fire Code Articles 2 and 8003.1.3.3)". Secondary containment may be provided by one of the following means: Secondary containment devices, such as spiJI trays, leak proof plastic bags, tubs or trays for containers. 4. Secondary containment wiJI be sized to accommodate a spiJI from the largest container. In addition, the sizing needs to accommodate fire -protection water (20 minutes discharge volume). The materials of construction ofthe secondary containment system must be compatible with the hazardous material to be stored. The secondary containment system wiJI have a monitoring method, such as visual observation. 5. The secondary containment devices, such as plastic tubs, wiJl aJlow easy access and quick inspection. The secondary containment tubs or trays wiJl have sufficient depth to contain at least 110% volume of the largest container. 6. In hazardous material use areas where products are used frequently and easily visible, individual containers of products that are not highly hazardous or toxic do not need to be kept in secondary containment. Examples would be a quart bottle of isopropyl alcohol in an eX~$IReoa~\l8l;,i!:rgent VIM HMMP 2010 Page 14 of 18 APR -, 9 2010 Original Submittal . . or hand soap at or under a sink. Materials not in current use should be returned to storage in secondary containment. 7. Wellhead protection signs are installed on-site to inform staff and visitors of the importance of reporting and cleaning up spills. These signs are located in visible areas of the clinic. Damaged or missing signs will be replaced. 8. A private service contractor will manage all outdoor landscaping chemicals. The contractor will not store any landscaping chemicals at the facility. To ensure that no DNAPL chemicals are used for landscaping, Volunteers In Medicine will inform the landscaping vendor of the policy of not using DNAPLES and preventing and containing any spills during their course of work. Landscaping vendors do not store materials or equipment on site. 9. Hazardous materials are substances, as defined in the City of Springfield Land Use Development Code Article 17 for the Drinking Water Protection (DWP) Overlay District that may be stored, handled, treated, used or produced at the Facility. As the Facility is located in areas specified to be a drinking water wellhead Time of Travel Zone of 1-5 years, restrictions apply to hazardous materials to protect groundwater. The Springfield Development Code defines Hazardous Materials as those substances (liquid or solid) which pose a risk to groundwater quality (Article 17.020 (1) (a) a class of liquid chemicals or substances which are physical or health hazards to groundwater). The class of hazardous materials is based on Article 80 of the Uniform Fire Code (UFe) which has been as adopted and amended by the City, including materials in both useable or waste conditions. 10. City of Springfield Land Use Development Code, Article 17 exempts several types ofUFC hazardous materials because they do not pose a risk to groundwater, these exemptions include (1) Hazardous materials in fuel tanks and fluid reservoirs attached to (i) a private or commercial motor vehicle and used directly in the motoring operation of that vehicle, or (ii) machinery, including by not limited to fuel, engine oil and coolant; (2) Fuel oil used in existing heating systems; (3) Hazardous materials contained in properly operating sealed units (transformers, refrigeration units, etc.) that are not opened as part of routine use: (4) Local natural gas distribution lines; (5) Fuel for emergency generators located at facilities that provide essential community services; (6) Any commonly used office supply-such as correcting fluid for typewriters, toner or computer printers or cleaners for windows and bathrooms - where the supplies are purchased off-site of use on-site. Date Received: APR - 9 2010 Original Submittal VIM HMMP 2010 Page 15 ofl8 Storage Area Date & Time Inspector Name Reviewed bv Instructions: To be completed weekly. Signed off by SOO or Medical Director Keep on file. INSPECTION TOPIC OK COMMENTS PROBLEMS DETECTED RESOLUTION (Include dates and times corrective actions taken) Area is free of leaks and/or soills Secondary containment devices intact and secured to shelves Original containers not leaking, rusted, bulging, or damaaed Hazardous material containers are oroperlv labeled Containers closed and sealed Spill kit accessible with sionaae and instructions Incompatible materials are stored separatelv Floor free of cracks and other S damaae ' Warning Signs properly :' disolaved 0 Existing hazardous waste ; g ~ prooerlv stored CD I ...u HAZARDOUS MATERIAL STORAGE MONTHLY INSPECTION FORM Completed inspection sheets are to be maintained in the inspection log for at least three years ;:;: iii <0 '" = C5 CD o CD <' CD c. VIM HMMP 2010 Page 16 of 18 . PRODUCT REVIEW LOG . All prospective new chemical products must be reviewed prior to purchase to determine whether or not they contain DNAPL chemicals. Use this log to ensure that no DNAPL-containing products are reintroduced into the inventory. (No new chemical products are planned to be purchased and used at this time.) CRC also makes a non- chlorinated brake cleaner Para dichlorobenzene volatizes in this formulation o ., 19: !!!. en c: Contains methyl ethyl ketone, which is not DNAPL l> -0 III - (I) :::0 (I) o <' (I) a. 3 ::: Q) I c.o '" = S VIM HMMP 2010 Page 17 of18 . . Date Received: APR -.9 2010 Original submittal ~ - o ~ . " " 0- <:> ;; N 0- :; :; :I: ! .. Hazard ous Ch . Storage CI "f emlc assll I Approx. Conditions Open NFPA Location of Manufacturer's cation Ab at Maximum Name & Product Hazardous Cds rac Quantity Range of (Survey State of or 704 Chemical Ingredients and Concentration o es t Containe Table Material Closed Classifica Name (Surve . Unit Noted Stored y Table Service r Sizes IV&V) Use tion VI) s No. (1) (1) Grafco H1 Silver Nitrate Silver Nitrate 37.5 15 ml 15 ml Liquid C F1 Exam Applicator - mg/Potassium Nitrate- 12.5 mg tube R1 room . SOX H1 Allegiance Povidone Povidone 1 bottle x 4 40z L C F1 Exam topical solution paint oz =4 oz R1 room S 25 bottles, H3 Allegiance F3 preservative fluid cytorich 10 ml each 10 ml L C RO pap =250 ml S 9 bottles, H2 Meridian BioScience, Buffered Neutral Formalin 10% 15ml each 15ml L C F1 Exam =135 ml RO room 9 bottles, H1 Meridian BioScience F1 Exam LV-PVA Fixative 15ml each 15ml L C R1 =135 ml room . H2 Amerisource Bergen Hydrogen Peroxide 12 bottles 32 oz to L C FO Solution =184 oz 1040z R1 pap H2 Gebauer Company Ethyl Chloride - Spray 1 bottle 3.50z L C F4 x3.50z RO pap 1100 50 to 400 H2 PAR Pharmaceutical Silver Sulfadiazine Cream Grams Grams L C F1 pap R1D ived: 3 bottles H3 Good Neighbor Carbamide Peroxide 6.5% - Ear x 0.5 oz 0.50z L C F1 Pharmacy Wash =1.50z RO 010 21 bottles H1 Safetex Cytology Fixative (1 to 4 oz) 4.00z L C Original 32 of' containers H3 Pathology Consultant Formalin Solution 10% x 30 ml = 30 ml L C F2 pap 960 ml R2 NW Pharmaceutical Potassium Hydroxide 10% 1 bottle x H3 Compounding solution 30 ml = 30 30 ml L C FO pap ml RO 1 container H3 Polar Cryogenics, Inc Liquid Nitrogen x 18 Liters 18 L L C FO pap =18 liters RO 2 bottles x H2 Exam Aaron Brands Rubbing Alcohol-Isopropyl 16 oz = 32 160z L C F3 oz R2 room MedChoice 2 bottles x H1 8 oz = 16 80z L C F1 pap Biological Odor Elimin oz RO Virex 256 - Germicida 2 bottles x H3 Deodorant 25 oz = 50 250z L C F1 pap oz RO Allegiance 1 bottle x H2 Janitor Cardinal Health 0.5 gal = 0.5 gal L C F1 Dual Enzy-Clean 0.5 gal RO closet .1 bottle x H2 Janitor Bleach - sodium Hypochlorite 6 960z=96 960z L C FO closet oz RO Coastwide Labs 1 bottle x 1 H1 Janitor Orange Oil Polish qt = 1 qt 1 qt L C F1 closet R1 1 bottle x H1 Janitor Water & Clorox sol uti 32 oz = 32 320z L C F1 oz R1 closet Johnson Wax 1 bottle x HO Professionals 32 oz = 32 320z L C FO Janitor Glass Cleaner oz RO closet Georgia Pacific/ 1 bottle x Oe\t~ R 3Gi8wed Natural Concepts 78 oz = 78 780z L C Hand Sanitizer oz RO closet Georgia Pacific/ 30 bottles x lArK . 9~ Natural Concepts 8 oz = 240 80z L C F3 Hand Sanitizer oz . . ,oRO closet ~ ",., . . 2000 H1 Webcol Prep pads - 70% alcohol packets x 1 1 packet S C F3 pap ea = 2000 RO S HO POI 900 packets 1 packet C FO Exam Cleansing Towelettes- 1 900 room x ea = RO SO Alcohol 40 BID 400 packets S H1 Ultilet Sterile Alcohol Swabs 1 = 400 1 packet C F1 pap x ea RO 3M Cavilon 2 bottles x L H2 15 ml = 30 15 ml C F3 pap No sting barrier film ml RO Miltexl 1 S H2 Fougera gross 1 packet C F1 Exam packet room Surgical Lubricant Steril RO Miltexl 1 S H2 Fougera gross 1 packet C F1 pap Double Antibiotic Ointm packet RO Allegiance 50 1 swab S H1 Providone Iodine Swabsticks swabsticks stick C FO pap RO i?R0DU0it.S']jSEDloNFSlmE~AND1Sffi0REDI0EE~SI;f;E!7~amvillSlihbfUi:I~I~'n~ds(2"a~'eral\'emj"C1nsTanCfloiThfertiIitefS1'an'{jrahiforiajTIsU'M5iiirs ',"'ili!!!','l;~~\1lI1 .a"x:*",j_~""_ '''''~..._ ~~"""~",""M'h'~;.;;;,0~,,,,~,""",,~""=""~;"''-'"~'''''(''"''_'';0,~f:!,,,_,~~-',,;;.'_"_'"' .~_, ",_.",,,.__,,,~,,J!, __~_.,__~0"M _""_,~,::!d"~"~,,..,,.,,,o.,"=, _"",,_.~~_,_,,~;i{;~ . %_)JM"~=W~W'- _~""",;P.l!w".",~.,~);&:i. 5!11mh:.,__~UiJj none Date Received: APR - 9 2010 Original Submittal . . . . MATERIAL SAFETY DATA SHEET' 1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product: Grafco@SILVER NITRATE APPLICATORS General Use: Cauterization of wounds and ulcers. Manufacturers Name: GF Health Products, Inc. Emergency Telephone Number: 800-347-5678 (Normal business hours) Address: 2935 Northcast Parkway Atianta, GA30360 Telephone Number for Information: 800-347-5678 (Normal busincss bours) Date Issued: 08/1 3/03 Datc Revised: 08/1 3/03 CHEMTREC CHEMICAL TRANSPORTATION 24- HOUR EMERGENCY TELEPHONE DOMESTIC/NORTH AMERICA 800-424-9300 INTERNATIONAL 703-527-3887 (CALL COLLECT) 2.0 COMPOSITION/INFORMATION ON INGREDIENTS OSHA Airborne Particulate ACGIH Airborne CAS 0;;1 Permissible Exposure Limit Particulate Threshold Ingredient Number Weight (PEL, TW A I) Limit Value (TLV, TWA') Silver 7761-88-8 75 0.01 mg/m3 0.1 mg/mJ, as Ag metal Nitrate2 Potassium 7757-79-1 25 not established3 not establishedJ Nitrate Note: The chemicals above are impregnated into the tip of a wooden applicator. The weight percentages indicated above represent the relative proportions of the active ingredients and do not take into account the weight of the applicator. I ITW A - Valucs2 given are 8-hour time-weighted averages: unless otherwise specified. 'Denoted ingredient is a SARA Title Ill, Section 313 listed toxic chemical (silver compounds). 'Not cstablished - Substance not assigned a specific PEL or TL V. Substance regulated by OSHA as particulalcs not otherwise regulated (PNOR,PELs - IS mg/m' total dust. 5 mg/m' respirable Iraction) and by ACGIH as particulates not otherwise classified (PNOC, TL V - ] 0 mg/m', total dust containing no asbestos and less than 1% crystaliine silica) and is considered nuisance dust. Date Received: APR - 9 2010 Grafco@ Silver Nitrate Applicators Rev. A Page I of6 Original Submittal . . II 3.0 HEALTH HAZARDS IDENTIFICATION II EMERGENCY OVERVIEW: Silver nitrate/potassium nitrate solid impregnated on tip of wooden applicator is a strong irritant to skin and tissue. Toxic if ingested. Primary Route(s) of I,ntry (for product): Inhalatinn:Nn Skin:Yes Ingestion:Nn Other:No POTENTIAL HEAL TII EFFECTS: Note: Since the product has not been tested as a whole, the health effects below are based on the health effects of individual ingredients which arc in signiticant concentrations in product. When appropriate, health effects ofthe individuai ingredients are given in order to provide adequate warning to persons using the silver nitrate applicators. Siiver nitrate applicators, in their final form for use, are not believed to pose high risk to the user, due to the small amount ofaetive ingredients on the tip of the applicator, and the highiy remote iikelihood of inadvertent or accidental exposures to toxic concentrations. Acute Effects of Overexposure: Eye contact: Contact with silver nitrate/potassium nitrate solid impregnated on tip of wooden applicator may cause irritation, the degree of which depends on the concentration and period of contact. Symptoms may include burning, tearing, and redness. Skin contact: Contact with silver nitrate/potassium nitrate solid impregnated on tip of wooden applicator may cause irritation, the degree of which depends on the concentration and period of contact. Symptoms may ineiude redness and burning. Inhalation: Inhaiation of airborne silver nitrate particles may cause irritation of the respiratory tract. " Ingestion: Poisonous. If swallowed, can cause severe gastroenteritis and can be tatal. Due to its causticity, large doses of ingested silver nitrate may cause a burning sensation in the throat, violent abdominal pain, vomiting, collapse, and death. Chronic Effects of Overexposure: It is rcported in the literature that chronic introduction ofsignitieant amounts of silver compounds into the blood stream and subsequent deposition of the reduced silver in various tissues' of the body may result in the production of a generalized permanent grayish pigmentation of the skin and mucous membranes - a condition known as argyria, with no constitutionai symptoms and no physieai disability. The introduction oftine partieies of silver through breaks in the skin produces a local pigmentation t the site of the injury. Locaiized argyria ofthe skin is rare. It has been concluded that on the average, 3.8 grams of oraiiy administered siiver nitrate causes argyria. The inhaiation of siiver powder over long periods has been concluded to cause pulmonary changes. Chronic exposure to potassium nitrate can cause anemia, nephritis and methemoglobinemia. Carcinogenicity: NTP:No IARC Monographs:No OSHA:No Medical Conditio'ns Generally Aggravated by Exposnre (to silver nitrate): Preexisting diseases of the iungs, skin, eyes, and other mucous membranes. Grafco@ Silver Nitrate Applicators Rev. A Page 2 of6 Date Received: APR - 9 2010 " Original Submittal . . II 4.0 FIRST AID MEASURES ~ Inhalation: This is not a probable routc ofcxposure duc to the product form. Ifacute overexposurc to product occurs, immediatciy rcmovc victim tram thc adverse cnvironment to Ircsh air. Ifbreathing is diflicult, administer oxygen. Ifbrcathing has stopped, give a11iticial respiration. Seek medicai attcntion immediately. Eye Contact: Wash out eye with lukcwarm water lor at least tifteen (is) minutcs. Seek prompt mcdical attention. Skin Contact: Immediately tlush with copious amounts of water, then with a sa it solution. Cali a physician or local Poison Control Center. Ingestion: Givc Copious amounts of salt water and follow with an emetic. Then administer a dosc of Epsom saits and follow with milk. Call a physician or the ioeal Poison Control Center. II 5.0 FIRE FIGHTING MEASURES II Flash Point (Method Used): For product, not appiicable. Flammable limits: Not applicable lor product LEL: Not applicable UEL: Not applicable Autoignition Temperature: Not applicable lor product General Hazard: The impregnated solid is an oxidizer. May release toxic or irritating vapors under lire conditions. Firc Fighting Instructions: As appropriate for surrounding tire. It is not beiieved that the product wouid be a significant hinderance to extinguishing methods used lor the surrounding tire, due to the small amount of impregnated chemical solid and product form. Fire Fighting Equipmcut: Fire tighters and others who may be exposed to combustion products during tire should wear fuli protective clothing, ineiuding positive pressure self-contained breathing apparatus (SCBA). Wear SCBA with a full face-picce, operated in the positive pressure mode when fighting tires. Hazardous Combustion Product: Acrid/irritating smoke, oxides of nitrogen, potassium oxide, and oxides of carbon. NFPA Rating: Health: I Flammability: f Reactivity:O Special: OX (oxidizer) II 6.0 ACCIDENTAL RELEASE MEASURES II Grafco@ Silver Nitrate Applicators Rev. A Page 3 of6 Date Received: APR - 9 2010 Original Submittal . . Steps to he Taken in Case Material is Released of Spilled: Not applicable for product in finai form (soiid silvcr nitrate/potassium nitrate impregnated on tip of wooden applicator). Dispose ofspcnt applicators in accordancc with appiicable CederaL state, and iocal regulations. II 7.0 HANDLING AND STORAGE Storage Temperatnre and Pressure: Ambient temperature and pressure are adequate. General: Store product in a dark, dry location, away I[om organic or other readily oxidizahle materials. Keep container closed when not in use. Do not use in eyes. Keep away hom children. II 8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Local and/or gcncral ventiiation, as needed, to reduce empioyce exposures to below applicable OSHA PELs and ACGIH TL Ys (see SECTION -2.0 COMPOSITION INFORMATION ON INGREDIENTTS, FOR PELs and TL Vs), or other industry standards or guidelines on exposure. I f respiratory protcction is required, all appropriate requirements as set forth in 29 CFR 1910. I 34 must be met. A competent health profcssionai should be consulted for respirator selection. Due to final product IDrm and usc. it is not believed that PELs or TLYs will be exceeded. Protective Gloves: Latex, vinyl or rubber examination gioves in order to prevent unnecessary or accidental skin contact. Eye Protection: Safety glasses to prevent accidental contact. Other Protective Clothing or Equipment: No speciai clothing ncccssary. II 9.0 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Decomposes @4440C, for" silvcr nitrate Vapor Pressure (mm Hg): Not appiicabie Vapor Density (AIR = 1): Not applicable Melting Point: 41401' (2120C), fDr silver nitrate 66301' (3340C), for Potassium Nitrate Appearance and Odor: Grayish soiid impregnated on tip of wooden appiicator, practically odorless Freezing Point: Not applicable Specific Gravity (H20 = I): > L for silver nitrate Evaporation Rate: Not applicable Solubility in water: Soluble, fi)!" siiver nitrate II 10.0 STABILITY AND REACTIVITY Grafco@ Silver Nitrate Applicators Rev. A Page 4 of 6 Date Received: APR - 9 2010 Original Submittal II II II II . . Stability: Product is stable at ambient temperature and pressure. Exposure of product to light may cause oxidation and discoioration orthe impregnated applicator. Conditions to avoid: Contact orproduct with easily oxidizabie materials and other incompatible materiais. Heat or high temperature may cause solid in tip ofjJroduct to decompose, possibiy releasing smail amount of toxic or irritating vapors. Incompatible Materials: Easily oxidizabie materials. Silver nitrate is incompatible with alkalies, antimony salts, arsenites, bromides, carbonates, cblorides, iodides, vegetable decoctions and extracts; acetylene, acetylene -I- ammonium hydroxide, acetyl ides, ammonium hydroxide, arsenic, chloride phosphine, phosphonium iodide, phosphorous isocyanate, and plastics. Potassium nitrate is incompatibie with antimony, antimony trisuilide. arsenic, arsenic disulfide, barium sulllde, boron, boron phosphide, calcium sulfide, chargoaL copper phosphide, lluorinc, germanium, germanium sulnde, sodium acetate, sodium hypophospite, sodium peroxide -I- dextrose, suifur -I- arsenic trisultide, titanium, titanium disuinde, trichloroethylene, zinc, zirconium. Hazardous Decomposition: When heated to decomposition, will emit small amounts of toxic NO, fumes and potassium oxide. Hazardous Polymerization: Will Not Occur. II 11.0 TOXICOLOGICAL INFORMATION II For silver nitrate: L050 oral mouse - 50 mg/kg LDLo unknown route, man - 29 mg/kg Eye rabbit - I mg, severe irritation For potassium nitrate: LDSO orai rabbit - 1901 mg/kg Other toxicity data exists in the literature. II No data was avaiiabie. 12.0 ECOLOGICAL INFORMATION II Grafcn@ Silver Nitrate Applicators Rev. A Page 5 of6 Date Received: APR - 9 2010 Original Submittal . . ~ 13.0 DISPOSAL CONSIDERATIONS II Waste Disflosal Method: Dispose of in accordance with applicable federal, statc, and local reguiations. Consult an expert on the disposal of spent or recovered material. A quaiified professionai should perform a solid waste determination. II 14.0 TRANSPORT INFORMATION II DOT hazard classification: OXIDIZER POTASSIUM Nitrate: UN 1486 Silver Nitrate: UNI493 Regulatory Rcferenee: 49CFR 172.101; 173.182 lATA: Nitrates, inorganic. n.o.s. UN# 1477 II 15.0 REGULATORY INFORMATION II ErA SARA Title III Hazard Categorization: Based on the components ofthe tip ofthe silver nitrate applicators, the product is categorized as an immcdiate (acute) health hazard and deiayed (chronic) hcalth hazard. FEr A SARA Title III Section 302 Extremelv Hazardous Snbstanees (EHSs): Noingredients in this product arc iisted as an EHS under Section 302 of SARA Titlc III. II 16.0 OTHER INFORMATION II Ali information, recommendations, and suggestions appearing herein concerning the product is based upon data believed to be reliable. It is the user's responsibility to dctcrmine the safety, toxicity, and suitability for their own use of the product described herein, and to comply with all applicable regulations. Since the actual use by others is beyond the MSDS developer's control, no guarantee, expressed or implied is made by GF Health Products Inc., as to the effects of such use, the results to be obtained or the safety and toxicity of the product nor does GF Health Products Inc. assume any liability arising out of use by others of the product referred to herein. This MSDS is not intended as a license to operate under, or recommendation to inti'inge on, any patents. Appropriate warnings and safe handling procedures shouid bc provided handlers and users. Notc: CHEMTREC and NATIONAL RESPONSE CENTER emergency teicflhone numbers are to be used oniy in the evcnt of CHEMICAL EMERGENCIES involving a spill, leak, fire, exposure, or accident involving chemicais. All non-emergency questions should be directed to GF I-leaith Products Inc. for assistance. PREPARED BY: GF Health Products, Inc. Revision No.: A Date: 08/13/03 SUPERSEDES MSDS DATED: N/A Date Received: Grafco@ Silver Nitrate Applicators Re\". A Page 6 of 6 APR - 9 2010 Original Submittal POVIDONE-IODINE TOPICAL.LUTTON, USP . Pagelof4 Material Safety Data Sheet SECTION I - Material Identity SECTION II - Manufacturer's Information SECTION III - Physical/Chemical Characteristics SECTION IV - Fire and Explosion Hazard Data SECTION V - Reactivity Data SECTION VI - Health Hazard Data SECrrON VII - Precautions for Safe Handling and Use SECTION VIII - Control Measures SECTION IX - Label Data SECTION X - Transportation Data SECTION Xl - Site Specific/Reporting lnformation SECTION XII - Ingredients/ldentity Information SECTION I - Material Identity Item Name Part Number/Trade Name National Stock Nurnber PODIODINE ANTISEPTIC 65050075<10374 60632 A 6654 B CAGE Code Part Number Indicator MSDS Number HAZ Code SECTION II - Manufacturer's Information Manufacturer Name Street LARSON'S LABORATORIES, INC 2101 PENINSULA DRIVE ERIE PA US 16506-2952 81<1-452-6815 City State Country Zip Code Emergency Phone MSDS Preparer's Information Date MSDS Prepared/Revised Date of Techni.cal Review Active Indicator Item Manager UNDATED 090C'1'8-; N KX Date Received: APR - 9 2010 Alternate Vendors OriQinal Submittal Vendor 115. CAGE BFNl,J httn./lnru.Tn.! <;;:ptnnrF'<:()llrrprpnfpr rnn, In' c:..-lC'h S1'u'nn' Ih+..-lnrc Ilrn1\A1\AIYl\.T IUT rTl()()()'7,!UT("T1()') il/Q!'){\l {\ POVIDONE-IODINE TOeAL SOLUTION, USP . Page 2 of4 SECTION III - Physical/Chemical Characteristics _m____~.___~m~m~..m__""'______ m"__'_""_~________~~m"~_._..,,,., _ .__.m.M_.__.____mm_.___._m____.'.."_~,_. Specification Number Hazard Storage Compatibility Code Appearance/Odor Boiling Point Vapor Pr:essure Vapor Density Specific Gravity E:vaporation Rate Solubility in Water Percent Volatiles by Volume Container Pressure Code' TemperatlJre Code Product State Code N/R N}-Ll REDDISH BROWN LIQUID HAVING A CHARl'-ICTERISTIC ODOR 212F, lOOe <. I N/K 1. 03 N/R COMPLETE o 4 8 U --~~--'---'----"--~~._,", ....__.-.__~_._______'__m_ SECTION IV - Fire and Explosion Hazard Data Flash Point !'lethod UNK Lower E:.:plosi.on Limit Upper Explosion Limit E~tinguishing Media Special FLre Fighting Pr.ocedures Unusual Fi,re/E:xplosion Hazards N/R N/R NOT APPLICABLE NOT APPLICABLE NONE SECTION V - Reactivity Data Stabili ty Stability Conditions to Avoid Materials to Avoid Hazardous Decomposition Products YES EXCESSIVE HEAT ABOVE l04f NONE NONE Hazardous Polymerization NO Polymerization Conditions to Avoid N/R SECTION VI - Health Hazard Data ...".......~_.._.-,.....~...~--~-"'.>--~-'...'...-.---.... ...-----,~ .........-..._~..._,~._...____.___..__._._..__________._.__.~w" _ ."m.__.__m...._._..___." .__.___....__ Symptoms of Overexposure Emergency/First Aid Procedures NONE EYE:IMMED FLUSH W/WATER FOR 15 ATTN f'--lINUTES.. GET MED Date Received: -----.--------..--- - --.------.----...--~-----._-----------------..-------.-APR--9 SECTION VII - Precautions for Safe Handling and Use -. 2010 BOTH "DRY" & "WET" MOP PROCEOUREPr~lnal Submittal RECOt1MENDED Steps if Material Released/Spilled Waste Disposal Method Handling and Storage Precautions FLUSH WITH WATER. FOLLOW ALL LOCAL, STATE & FEDERAL REGULATIONS RE IN COOL AREA BELOW l04F. DO NOT FREEZE. httD ://www.setonresollrcecenter.com/msdsha7.com/htdoc.sllr:OMM 0 N/WCfl()()n? 7/Wrfln7 L1/~/7nt n POVIDONE-IODINE TOPICAL.~UTION, USP . Page 3 0 f 4 Other Precautions PROTECT CONTAINERS FM DAI'JAGE. NO NONE SECTION VIII - Control Measures Respi. ca tOl:Y Protection Ventilation Protcctiv0 Gloves Eye Protection Other: Protective Equipment Supplemental Health/Safety Data Disposal Code NONE NONE OPTIONAL Sl\FETY GLASSES NONE t1SDS UNDATED o SECTION IX - Label Data React Code NO NO NO UNKNOtoJN UNKNOVIN UNKNOVIN UNKNOWN UNKNOWN Protect Eye ProtEct .'31:io Protec~ Respiratory Chronic Indicator Cop.tact Code Fire Code Health Code SECTION X - Transportation Data ContaiIler Quantity Unit of Measure 1 GL SECTION XI - Site Specific/Reporting Information SECTION XII - Ingredients/Identity Information Ingredient # Ingl"edient Name NIOSH Number Proprietary Percent 01 POLYVINYLPYRROLIDONE-IODINE USP l002999PI NO N/K N/K N/K N/K 02 SOLVENT (TYPE 67990276 100009255 Date Received: OSHA PEL ACGIH TLV Recomrnended Limit Ingredient # Ingredient Name CAS Number NIOSH Number Proprietat:y pet:cent NOT SPECIFIED) APR - 9 2010 Original Submittal NO N/K httn: //www .,dnnrte.""] rcteetent ter..cnm/m,r1,h"7c.nm/htrlncs//rOMMON /wrn()()()) 7/Wrn()) .1.1gl701 () POVIDONE-IODINE TOeAL SOLUTION, USP . Page 4 of 4 OSHA PEL N/K NIl< N/K ACGIH TLV Recormnended Lind. t Date Received: APR -, 9 2010 Original Submittal httn' / !YUUJur ~p.t(lnrp:o;:nllrr.pr,p.ntp.r r,()m/m,r1o;;:h~7r()t11/htrlnr.s/ jrn MM nN Iw('nonn? 7/Wrnn7 J./R17m n . . Page 1/7 Material Safet.)) Data Sheet ace. to ISOIDIS 11014 Date Prepared. U//07/2UIO Reviewed 011.- 09/25/2()()9 iJll Identification oifsubstallce: .J',V '; - "';' ,,' t- 'I';, '..; :;:..., "J'~':'" ;:\"::';:-~~H~~~~r-".v" J;.":~;'';';!'''I'_l'".':~bJl.i!'';-;''~' ': '}~', ~ .' , , . ..... ,...; . .' . ~, "'. .' " .,r.;, . !o~"'".... .. ,<., J' _." . Product name: BD (vtoR;clr TTlI Red Prescrl'ative . Catalog number: 490j08 lI~f()r11lafi()1l department: Technical Services . Emergency ;UfOI"JUllt;OU: III case ofa chemical emergency, spill, fire. exposure, or aceidellt cOlltacl BlJ Diagnostic ,)~v:.;te!l1s - TriPath at (336) 2VU-83UU or (866)-7/-i1'lIIh (option # I), or Chell/7lw; at (800) 424-9300. '(.'2 Comp'ositioll/Data 011 compollellts: . .' :". ; . Chemical characterization . Description: MiX/lire consisting of the [of/owing components. . Dangerolls compollenl.\': 67~63-0 isopropanol 67-56-1 methol/ol 107-21-1 ethylene glycol 50-()O-() formaldehyde 20JJ - 25JJ% IU(}% 5.0-10.0% < 1.0% ""'U""d"" ifi t' . " .,,'. '. - .' ..,.......' , '~?'o}Jnazar S'luelltl ca IOI,.(,7r'l'of>. ~ a 'f' '. r... ',J ,I~ ..' ...."'J:::r' !" :'''' "l~;_'" ,a.$:~~," '~f f, .'..u..,,~..t"~!'1it""''r, /Fer.:., . I . ~...'T " '. T . .' _ .' ..,,,,, , . ." ..,. .,., ..~ . '. ~ II'" . Hazard description: ~.~'.~'I . [~.~ f!.. P::, T TOXIC M*'" '41 ""..':;:' Ai;. :< . lt~rormati()1I pertaining to purticulur dangers for mall and envirollment R 10 Flammahle, R 20/21/22 Harmfid bJ! inhalatioll, in contact with skin and {(swallowed. R ]0 Irritating to eyes. H 39/23/24/25 Toxic: danger olvery serious irreversible effects through inhalation, il/ contact 11.'ith swa/lolvcd. R 40 Limited evidence ola carcinogenic effect. R 43 /vlay cause sensitization by skin contact. . NFPA ratings (scale 0-4) ..:)\ ~I~:l~;] ~.th-~: Reactivity = () skin and {( Date Received: . HilliS ratings ('1eall! 0-4) .3 ~ . .. 3 i '^~~~~C~VI~,X~'@;~ APR - 9 2010 Health = 3 Fire = 3 Reactivity = 0 Original Submittal .4 First'9id meas/lres ! . General information Immediately remove contaminated clothing. S)1/I1iJ/oms of poisoning may even occur afier severa/ hours; hOllrs after the accident. therefore provide medical observatio!l for at least 48 (Conld. on page 2) USA . . Page 217 Material Safety Data Sheet acc. /0 ISOIDIS II 0 I4 Date Prepared: 0/10712010 Rev/elved On: O<J/25/2009 ProdUd name: BD C.)'loRichnIRed Preservative (Conld. of page J) . Afier inltalatioll Supply Fesh air ([fld seek medica! advice. In case O/UIICOllSclousness place pallen! on side positionfiJr transportalion. . Ajier skin CO/ltact Immediately wash with water and soap and rinse thOroligh~v. . After eye cOli/act Rinse opened ere j(Jl' J 5 lIIillutes under running water. Theil consul, a dodoI'. . /~fter swallowing Seek medical treatment. . ft~f(Jrll1ati()ll.ror doctor 5'11011' this pmducllabe/ or this MSDS iw.5~r"""~fi 'to . ,I ~.~~.~,p.,~("",:..".:..:~;^ .-'_- ,,; "":i,,,,~Ar ,....,<<>~t;!j..,.t<.:l:~.I-'j.!) ."'.t".-.,..,..:,..;.....;:' ~'-...<..~:{:W\Io..;;~.. ~ ,~lreJ.g" '!'g J1leasuresJ.j~~"" '- ,.";'t,~ 1't~ -"..:;'.;,:,,, h '7,J~rl.'...,,-;{j::,rt;....l-j~,if(~.~~J~h-, ;;-";'~,i,'fl,,~ .\: j'.i1-,' .,.~f,,~~ifjj',t.:l.~(;ft~, "'~;'J,/i . Suitahle extinguishing agents C02, A 1/C multipurpose dry chemical or water spray. Fight larger fires with water spray or alcohol resistallt foam. . For safety reasons unsuitable extinguishing agellfs Water withflllljet. . .\pedal hazards cau.\'ed by tlte material. its products of combustion or resulting,gases: During heating o/' ill case of/ire toxic gases may be produc(id. , Protective equipment: IYca/, self-contailled rcspiratOl)i protective device. Wearjidly protcclive suit. ""'6-F.....:.>:..tJ,., ["'I 1 .""/ ~t,;l:( ,)1'I...:::r.....'.I"""..""."......",.. ,.,.~.....,.,''J'->"..'.-;'~1'..".''''....,~, ~' "nee' ellta re ease'nleasureS?ii..:',I:.'<':j~... j~ ,t l,.' ~...; ,.{~~:..,jI4'''~ \.. f :,5}~!1"~.r:{;:"t::.,:~{~;: ~.t~>:' h<'~ ~~:J.:i~;<-~"~:I:?,I ~~llf!:1;l:{ i1t~.~-. . Pasoll-related safe(1' precautions: Ensure adequate vel/tilaliOIl Keep alvayfrom ignition sources Use respimto/J' protective device. Wear protective clothing. . /l1easuresfol' em1il'OIlmelltal protectioll: IFipe up with damp sponge or 1I10p. . !tleaslll'e.\'for dealliug/collectiug: Absorb with liquid-binding material (.land, diatomite, acid bindcl:<;, lIlIive/^sal binden). Dispose contaminated materia! as waste according to item 13. Ellsure adequate vel/tilation. . A{Mitioflal information: S'ce S^ec/ioll 7 fur information 011 safe handling. See Section 8 for iI!fiJrmatiol1 01/ personal protectioll equipment. See Sectioll 13/or disposal il?(ormatioll. f.7 nil/idling and, storage I - . r .' . . Handling . l1~f(}rlJl{ltion for safe /ulIldlillg: Ellsure good ventilation/exhaustion at the workplace, Prevent formation a/aerosols. . "~f{)rmati{)1I about protectioll against explosions ami fires: Keep ignition sources away - Do not smoke. fJrotect against electrostatic charges. . Storage . Requiremellls to be met by storeroolJls aud receptacles: 15 - 30 C . !J~t.'ol'l1lati()Jl about storage ill one common stOJ'{lge facility: Store awayfrom oxidizing agents. nRte R . d (tc7nw. 011 pagc~P Ive : US,\ APR -, 9 2010 Original Submittal . . Page 3/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Date Prepared: 01107/2010 Reviewed 011: OY/25/2009 Product flame: BD Cy(oRich TI\1 Red Preservatil,c (C0f1td.ofpage2) . Further ill/ormation about storage cOllditiolls: Store in cool. dl] conditiolls ill well scaled containers. "'8E-" , I d I . . . j '~..,' xpo~ur~,contl'o s all persolla protectIOltl:F!:':t~...:.~.~.:; ....~:/:;~.) ':'; ":; '.:~ : ~ . . :~. . ;-:. :.'.;.' ~~~:~ . ....,:;,l~.~ ):";, . Additional ilIformation about design (Jffecl111h'al.~jwtel1ls: No further data; see item 7. . Components witlt limit values thaI require mouitoring allhe workplace: 67-63-0 isopropanol PEL 980 mg/mJ, 4()() ppm REL Short-IeI'm vallie: /225mg/1Il3, 500I)pm Long-term value: 980 mg/mJ, 400 ppm TL V /)'hort-term value: 984 mg/mJ, 400 PIJ//J Long-term value: 492 mg/mJ, 200 PfJlI1 HE! 67-56-/ methallol PEL 260 l71g/mJ, 200 ppm REL Shorr-terlll value: 325 mg/1I13, 25U ppm Long-term value: 260 mg/m3, 2UO ppm Skill TLV Short-term value: 328 mg/mJ, 250 pplll LOIlg-tenn value: 262 mg/m.1, 200 ppm Skill; HEI 107-2/-1 ethyleneg(rcol TLV Short-terlll value: C I()O mg/mJ II 5()-(}O-() formaldehyde PEL Short-term value: 2 ppm Long-term value: 0.75 ppm see 29 CPR 1910.1048 REL Short-IeI'm value: C 0. J * ppm Long-term value: 0.016 ppm * 15-mill TLV Shorl-term value: C 0.37 II1g/IIl.l, C 0.3 ppm SEN . Additiollal information: The lists thatll'ere ralid during the creation were IIsed as basis . Personal Protective Equipment . General protective and hygienic measures Keep away/i'om foodstl~fJs, beverages amlfeed. Immediately remove all.';oiled ([lid contaminated clothing. Wash hands before break<,. and at the end of work. A void contact with the eyes and skill. . Breathing equipment: In case ofhrief exposure, use a chemica! fume hood or a NIOS/-I/M,')'l-IA-approved respirator, . Protectioll of hamls: o I> Chemical resistant gloves (i.e. nitrile. or equivalent). . ~ye protection: Tightly sealed goggles'. DatfR~~j~~ lJSA APR - 9 2010 Original Submittal . . F{rae 4/7 o Material Safety Data Sheet ace. 10 ISO/DIS 11014 Dale Prepared: 01107/2010 Reviewed Oil.' 09/25/2009 Prodflct "lime: I/O Cy{oRic:/"'"!'>1 Red PresenQt;ve (Collld. of page 3) . B(J{~r protection: Protcctive work clothing (fah coat). ?fJJPl1ysicalalldclremicalproperties: .:.. .~ -:',..j ...... '-:: I".:' :,. :U:",;~.;,.,_\r,c;:":;;/;;;":' . GCllcral/llformatilm Form: Color: Odor: Liquid Clear Light red Characteristic . Change ill conditio/l Meltillg poillt!JWeltillg range: Boiling paim/Boiling range: . Flash point: Not determined 81"C: (1800F) 25"C: (77"F) 410.0"C (7700!) . fgllit;oll temperature: . Auto (glllfi",!:: Product is lint sc{j'igl/iting. Product is /lor explosive. 1-lo\1'c1'el. formation of explosive air/vapor mixtures (lrc possible. . Danger of explosion: . Et:plosioll limits: LOlller: Upper: 2.0/!o!% 44.0 Vol % . Vapor pressure at 200C (680F): 128.0 hPa (96/11111 Hg) . /)ellsi(l': NOI dctcrmined . Soluhili(v ill / Miscibili(JI with 1Vater: Soluh/e . pH-value: 7. 5 . Solvellt cOlltent: Or,--~an;c soh'eltts: 33.8 % tJ O"Stabilii,';:and reactiv;tu.m::.I_l.. ~;.\'~~,\t "':/."'; r- ,.:",'::tt:i,'/J,,\J.,;:';":,", i;.;~~,24l1"t'~t~~j ".~ ~.".;-:; iJ'I~' -,..d,;.:~,S,l';"",1.~ ~~';~.!;~~,-.:!IL~d ':'f.", > .--.1" -.1" >..:.: , , ',",,' . '.' . 'fl-'"" . . Thermal decomposition / l:owlitioJls to be ai'oided: No decompositioll/fused according to speqficatiolls. . !l1aterials to be at'oided: Incompatible material: strong oxidi:!ers. . Dangerolls reactiolls No dangerous reactions knolVn . Dallgerolls produos (~f decomposit;olt: No dangerous decomposition products known. 11.... . l . l'.j";' t' 1 .0.... .. ;," , :.l. OX1CO oglca InJornla Ion ~ . I . ". . j..1 _" _ .=. .j ;' .', ,'~"""fo,~!!:q:,_~ ,...."~tf....::'). . Anite toxicity: . LD/LC50 values that are re/evantfor classijicaf;olt: 67-56-1 melhallol Oral L!)50 5628111g/kg (rat) 50~(/(/-(/ jor(naldehyde Oral LD50 42'l11g/kg (rat) ,"j Original Submittal . . Page 5/7 Material Safety Data Sheet ace. 10 ISO/DIS 11014 Date Prepared." OJ/07/20IU Hevielved On: OY/25/2009 Product Ilame: BD CytoRich TJ\f Red Presen'atil'e . Primm}' irritfllll effect: . 011 fl1(~ skill: No irritating (freel. . (III the ~l'e: /rri{(Jtillg ejj(_'ct. . Sells;rizllt;oll: No scnsilizing efj(!Cfs knowl1. . Suhacute to dlrouic t{)xid~r: Target organ: !il'er . Additiollalloxic%gical in!or11l1llioll: The product shows the fill/owing dangers according to illtcrnally approved ca/culation methods for prepar(lliofls: Harmful Irritant (Colllu.orpage4) -~"E"l'--l'fi . . '"';'t . ,],"' .~' J"'-''''' ,"'r~.-"~'i"""""'Jo.~J~>tt~,w"~o!:~'~~;jt". 1~" co oDica III OrI11atlOIl.;<):i.~;t.;......J:. ~tr" ":. ~'t.';;l'r' "':r.jr.'>~l ::',~1r.~J;:";\!it:,t~y'.)l~~1H.('~i"~"'/_ ,""4~'~"'J6"'.il" 'j;.r.ttP,~~.u:;,~"~,,,!.f "'-- ,,0. ",' .-., I. ..1"'....',... !,,,/. "".~ .~., .....-.f'li'...".'/!. r'".fti t".~.::~ " Efotoxh'a[ effects: " ACqflllfh: t(}xid~r: This material is 1/01 expected to he toxic to aquatic life. " Otlter i1~formatioll: The ecological (1J(Y'!S have no! b(,(!/I thoroughly il/vestigated b1ll clIrrel/fly /lone have been idclltified. il'>D;~no'sa'I'cOI1SI'derations .". . , . .... ..,',' , ... . ", '. " ' -,"'.""..,"," .~' ""'r" ' ". ~ . "..,.' :"J,!t:' ., , i::' ~ i-'\;' .... ~l-<;'." -~: ' . Product: " Hecommcndatiou Mus! !lot be disposed o.(11'i!11 solid Il'as!c. Dispose (~{lIIateri(l1 in accordance 'l'ithfcderal (40 CFR 261 3). stale alld lor.al requirement.'."" RCRA hazardous waste. RCRA # DOOI (ignilable). " Uucleaued paclwginlJs: . Recol1lmendation: Disposal must be made acr.ording to Slate alldfederal regulatiolls. . Recol1lmeuded cleansiu,!; agem: WaleI', {( llecessm)l \1'ilh cleal/sing agel/ts. '1.'4'Tril/~~portillformatioll ,'. '" ;" . ." ....'. " ,/,"~''''''> 'j.,":'" . /JOT regulations: . " Ilazard class: 3 "Idellt~'fication number: UN/VS7 " Packiug group: III . Proper ,"hippillg lIallle: ALCOIiOLS. N.o.s. (ISOPROPANOL. METHANOL) " Label 3 . Laud traflsport ADR/RID (cross-border} . ADR/RlD class: 3 (Fl) Flommable liquids Date Received: USA Original Submittal . . Page 6/7 Material Safety Data Sheet ace. to ISO/I)[S 11014 Date Prepared: 0//07/2010 Reviewed all: 09/25/2009 Product flame: BD CytoRich™ Red PreserMlive (Contd. of page 5) . Danger code (Kemler): 30 . UN-Number: /987 . Packaging grollI': I! [ Descriplion o{goods: 1987 ALCOHOLS. NUS (ISOPROPANOL METHANOL) . Maritime transport IfltIDG: . UN Numher: 1987 . Label 3 . Packaging group: III ,Harine polluUl1lt: No . Pro[lC/" s!lipping name: ALCOHOLS. NUS. (ISOPROPANOL, METILINOI) . Ail' transport ICAO-Tllllld IATA-DGR: . ICA O/IA lA CllIss: 3 . UN/ID Numher: /987 . Label 3 . Padwging group: II! . Proper shipping ""me: ALCOHOLS, NOS. (ISOPROPANOL. METHANOL) ~'5 R" t.... I ..' ,<. , . '1 . - .. ". '.1 eon aIIOllS."!" " . ' >' . . ...., 't _:N."... . ."r., . .r','.:-,::~"J"'-1;' (,'''l.''''''''i~ ,~. b '" " , 'r ',.."....,',...,~.,.~~..."~,,1;:l.1I. SARA .~~ectioll 3-"5 (exlrel11e~I' hazardous sllbstanceJ) 50-()()-() formaldehyde . oS';1RA Section 313 (''jJecific toxic chemical listing.') u/-63-() isopropanol 67-56-/ methanol 10;-2/-/ ethylene glycol 50-()()-() formaldehyde . T...\'CA (Toxic Substallces Control Act) A/I ingredients are J;sted . California Proposition 65 - Chemicals known to calise cancer Pormaldehyde is toxic. allergenic, and is knowl1 to the state of Califhrnia to cause cancer. Note: Formaldehyde poses a cancer threat through inhalatioll Grthe gas or vapor. 50-00-0Iformaldehyde . CaNfornia Proposition 65 - Chemicals known to cause reproductive toxicity for females: None rf the ingredients is Iisled. . C.a/~forl1ia Proposition 65 - Chemicals kllown to cause reproductive toxici(r for males: None Cj(the ingredients is listed a e " California Proposition 65 - Chemicals kllown to cause del'elopmelltal toxicity: None Cj(lhe ingredients is listed. Original SubmiUa USA . Material Safety Data Sheet acc. to ISO/DIS I/O 14 . Page 7/7 Dale PreparcrL 0//07/20/0 Reviewed 0,1: 09/25/2009 Product flame: RD ()'{oRic!t TI\1 Red Preservative (Comu_ uf page 6) . Can:iuogcuic categories . NTP (Natio11al Toxicology Program) 5O-()()-Olji-Jrfllaldchyde IR . TL V (Threshold Limit Value established by ACG/II) 67-63-0 isopropanol .44 /07-2/-1 ethylene g~vcol .44 50-00-0 formaldehyde .42 . Produa related hazard illformation: The product has been class{fied and marked ill accordance with regula/iolls Oil hazardous materials. o Hazard .'J1f1tbo/s: T 7(1.yic . Hazard-determining cOlIIl'ouell(S (~l{aheliflg: I/lethal/ol fhrll1a/dclly(/e . Risk phrases: /0 Flammable. 2012/ln f-!annjid hy inha/mioJ1. i/1 COl/tact with skill olld i(swallower!. 36 Irritating to eyes. 39/23/24/25 Toxic: dallger of vel}' serious irreversihle effects through iI/halation, ill contact with .';kin and if swallowed. 40 Limited evidence of n carcinogenic e.ffect. 43 Ala)' calise sellsitization b)' skill COlltact. . Sllfe(r phrases: 719 Keep container tight(), closed and ill (I we/l-vemilated place. /6 Keep awayji.o//1 sources oJignition - No smoking. 20 TYhenllsillg do not eat OJ" drink. 36/37/39 Wear suitable protective clothing. gloves and c)'c/facc protection, 45 hI case of accident or if you feel unwell, seek medical advice ill/mediately. 60 This material and its container /IIust be disposed of as hazardous waste. 160tltefr.illformatioll:'. . . .' .,....'-~.".,. . ..,.,..".,..;..- ''':''.;.,...1,'"<'"', To the hest of our knowledge, the injormation COll/aillcd herein is accurate. However, neither Bectoll, Dickinsun and Company or any o.fits subsidiaries assumes any liabilities whatsoeverfor the accuracy or compleleness of the informatioll contaillcd hereill. Fina! determination (?fsuitahility (?lany material is the sole responsibiliZY of the user. Alllnateria!s !/IO)' present ul/known hazards and ,s'hould be used with cautiol/. Although certain hazards are described herein, we cal/1/ot guarantee thar these are the on~}' hazards that exist. . [Jeplll'tmellf issuing ~fSDS: ,')'{ifety and Environment Department ^,f,)~DS created by Michael J. Spinazzola . COfltact: Technical S'ervice Representative USA Date Received: APR - 9 2010 Original Submittal . . Page i 0 f 6 Material Safety Data Sheet 10% Neutral buffered formalin ACC# 88082 Section 1 - Chemical Product and Company Identification MSDS Name: 10% Neutral buffered formalin Catalog Numbers: NC9638612, NC9638613, 023-798, 027-274, 028-866, 032-059, 032-060, 032-067, 032-069, 035- 159,037-238,037-239,038-528,045-112, 23-005-155, 23-005-193, 23-005-500, 23-011-120, 23-111-114, 23-111-123, 23011112,23023798,23027274,23028866,23032059, 23032060, 23032067, 23032069, 23035159, 23037238, 23037239,23038528,23045111,23045112,23245684, 23245685, 23253998, 23286200, 23305510, 23314028, 23314029, 23314033, 23314034, 23314035, 23314036, 23314037, 23314038, 23314039, 23314040, 23316154, 23316155,23316156,23426796,23426797,23427098, 245-684, 245-685, 253-998, 286-200, 305-510, 314-025, 314- 026,314-028,314-029,314-030,314-033,314-034, 314-035, 314-038, 316-154, 316-155, 316-156, 316154, 316155, 316156,426-796,426-797,427-098,57011,57011-16, 57011-GA, 57011A, 59001-20 Synonyms: None. . Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796~7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECSjELINCS 50-00-0 Formaldehyde 3.7 200-001-8 67-56-1 Methyl alcohol 1.5 200-659-6 7558-79-4 Sodium phosphate dibasic <1.0 231-448-7 7558-80-7 Sodium phosphate monobasic <1.0 231-449-2 7732-18-5 Deionized Water Balance 231-791-2 II Section 3 - Hazards Identification II EMERGENCY OVERVIEW Appearance: colorless liquid. Flash Point: > 200 deg F. Warning! Harmful if inhaled. Harmful if absorbed through the skin. Contains formaldehyde whictl can cause cancer. May cause severe skin irritation. May cause allergic r~spiratory and skin reaction. May cause respiratory tractr+\'1t.i;l.J;.l.obCJ.~_' d' cause eye irritation and transient injury. May cause lung damage. May cause pulmonary edema. May ca~~~IVe . and fetal effects. Target Organs: Lungs, respiratory system, eyes, skin. APR - 9 2010 Potential Health Effects Eye: May cause severe eye irritation. May result in corneal injury. Original Submittal Skin: May cause skin irritation. May cause severe skin irritation. Harmful if absorbed through the skin. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. In severe cases may produce blistering, scaling and cracking. . Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Ingestion may cause violent vomiting and diarrhea leading to collapse.'May cause systemic toxicity including central nervous system depression, convulsions, coma, and possible death due to respiratory Inhalation: Harmful if inhaled. ~-1ay cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May cause pulmonary edema and severe respiratory disturbances. Chronic: Contains formaldehyde which can cause cancer in humans. There is sufficient evidence that formaldehyde causes httn./lfc:.r.lm:lGP. fidlP.rc:.r,l r,nm/m.c:.(k/RR()R? htm JIROO 1 0 . . Page 2 of6 nasopharyngeal cancer in hUn1ans, a rare cancer in developed countries. There is limited evidence that formaldehyde causes cancer of the nasa! cavity and paranasal sinuses and strong but not sufficient evidence for leukemia. II Section 4 - First Aid Measures II Eves: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air Immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. II Section 5 - Fire Fighting Measures II General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Use water spray to keep fire-exposed containers cool. Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Flash Point: > 200e deg F (> 93.33 deg C) Autoignition Temperature: Not applicable. Explosion limits, lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Urea based materials are available which can be used to bind the formaldehyde forming a polymer. II Section 7 - Handling and Storage II Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not ingest or inhale. Use only with adequate ventilation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incomlRtible strb.stances. d Uale ~ecelve : Section 8 - Exposure Controls, Personal Protection APR -9 201Q Oriainal Submittal Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewaS'M facrlity and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. See 29CFR 1910.1048 for regulatory requirements pertaining to all occupational exposures to formaldehyde, i.e., from formaldehyde gas, its solutions, and materials that release formaldehyde. EXDosure limits Chemical Name ACGIH NIOSH OSHA - Final PELs 0.75 ppm TWA; 2 ppm 0.016 ppm TWA 20 ppm STEL; 0.5 ppm Action hlto:/ /fseimas>e. Ii shersci .com/msds/88082. htm A!Q/'")f\lf\ . . Page 3 0 f 6 IDLH Level (Irritant and Formaldehyde 0.3 ppm Ceiiing potential cancer ha zard - see 29 CFR 1910.1048) 200 ppm TWA; 250 ppm 200 ppm TWA; 260 200 ppm TWA; 260 Methyl alcohol STEL; skin - potential for mg/m3 TW A 6000 pprn mg/m3 TWA cutaneous absorption IDLH Sodium phosphate dibasic none listed none iisted none listed Sodium phosphate none iisted none listed none listed monobasic Deionized Water none listed none listed none listed OSHA Vacated PELs: Formaldehyde: 3 ppm TWA (unless specified in 1910.1048) Methyl alcohol: 200 ppm TWA; 260 1119/m3 TWA Sodium phosphate dibasic: No OSHA Vacated PELs are listed for this chemical. Sodium phosphate monobasic: No OSHA Vacated PELs are listed for this chemical. Deionized Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: colorless Odor: Characteristic odor_ pH: 7.0 +/-0.1@25C Vapor Pressure: Not available. Vapor Density: >1 (Air= 1) Evaporation Rate:Similar to water. Viscosity: Not available. Boiling Point: 102 deg C Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Completely soluble in water. Specific Gravity/Density:1.0 (Water=1) Molecular Formula:Not applicable. Molecular Weight:Not available. II Section 10 - Stability and Reactivity II Chemical Stability: Stable under norm'al temperatures and pressures. Conditions to Avoid: Ignition sources, confined spaces. Incompatibilities with 'Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - Toxicological Information RTECS#: CAS# 50-00-0: LP8925000 CAS# 67-56-1: PC1400000 CAS# 7558-79-4: WC4500000 CAS# 7558-80-7: WA1900000 CAS# 7732-18-5: ZCOI10000 LDSO/LC50: Date Received: APR -, 9 2010 Original Submittal h1fn-//fcf';nv.llTp fichprN,j f'''m/n'lcrlclQQn5D htm A/Q/'1()1() . . Page 4 01"6 CAS# 50-00-0: Draize test, rabbit, eye: 750 ugj24H Severe; Draize test, rabbit, eye: 750 ug Severe; Draize test, rabbit, eye: 10 mg Severe; Draize test, rabbit, eye: 37% Severe; Draize test, rabbit, skin: 2 mg/24H Severe; Draize test, rabbit, skin: 50 mg/24H Moderate; Inhalation, mouse: LC50 ~ 454 mg/m3/4H; Inhalation, mouse: LC50 ~ 505 I1lg/m3/2H; Inhalation, rat: LC50 ~ 203 mg/m3; Inhalation, rat: LC50 ~ 578 mg/m3/2H; Inhalation, rat: LC50 ~ 250 ppm/2H; Oral, mouse: LD50 = 42 mg/kg; Oral, mouse: LOSO CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mgj24H Moderate; Draize test, rabbit, skin: 20 mgj24H Moderate; Inhalation, rabbit: LC50 ~ 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg; CA5# 7558-79-4: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 ~ 17 gm/kg; CAS# 7558-80-7: Draize test, rabbit, eye: 150 mg Mild; Oral, rat: LD50 = 8290 mg/k9; CAS# 7732-18-5: Orai, rat: LD50 = >90 mL/kg; Carcinogenicity: CA5# 50-00-0: ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 1/1/88 (gas) NTP: Suspect carcinogen IARC: Group 1 carcinogen CAS# 67-56-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7558-79-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CA5# 7558-80-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CA5# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: In June 2004 an expert '1ARC group determined that there is now sufficient evidence thU~~I"lJyde. d' causes nasopharyngeal cancer in humans, a rare cancer in developed countries. Lt: r\t:celve . Teratogenicity: No information available. Reproductive Effects: No information available. Neurotoxicity: No information available. Mutagenicity: No information available. Other Studies: No data available. APR - 9 2010 Original Submittal II Section 12 - Ecological Information II Ecotoxicity: No data available. No information available. Environmental: Persistence/Degradation: Substance is biodegradable in aerobic and anaerobic conditions. Bioconcentration: Studies on various fish have shown little potential for bioconcentration of substance. Soil Adsorption: log octanol/water partition coefficient=O.35 (indicates low potential for soil adsorption). Substance has a high biological oxygen demand. Physical: Substance photolyzes and reacts with hydroxyl radicals. The half-life (in sunlight) is a few hours. Without light, substance reacts with nitrate radicals. Other: No information available. l~.H_.lfr.~~~'~~~F~~ r;~1~~_~~; ~~.~~f~~~,..1~fOono") t...~...~ ..Inl,....n. n . . Page 5 of6 I[ Section 13 - Disposal Considerations [I Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification deterrnination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: CAS# 50-00-0: waste number U122. CAS# 67-56-1: waste number U154 (Ignitable waste). II Section 14 - Transport Information II US DOT Canada TOG Shipping Name: AVIATION REGULATED LIQUID, N.O.S. No information available. (10% FORMALIN) Hazard Class: 9 UN Number: UN3334 Packing Group: II Section 15 - Regulatory Information II US FEDERAL TSCA CAS# 50-00-0 is listed on the TSCA inventory. CAS# 67-56-1 is listed on the TSCA inventory. CAS# 7558-79-4 is listed on tfle TSCA inventory. CAS# 7558-80-7 is listed on tile TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 50-00-0: 100 Ib final RQ; 45.4 kg final RQ CAS# 67-56-1: 5000 Ib final RQ; 2270 kg final RQ CA5# 7558- 79-4: 5000 ib final RQ; 2270 kg final RQ SARA Section 302 Extremely Hazardous Substances CA5# 50-00-0: 500 Ib TPQ SARA Codes CAS # 50-00~0: acute, chronic. CAS # 67-56-1: acute, flammable. Section 313 This material contains Formaldehyde (CAS# 50-00-0, 3.7%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. This material contains Methyl alcohol (CAS# 67-56-1, 1.5%),which is subject to the reporting fli9...ulrente.nts of SectifVJ 313 of SARA Title III and 40 CFR Part 373. uare l"'\eCelVea: Clean Air Act: CAS# 50-00-0 is listed as a hazardoLls air pollutant (HAP). CA5# 67-56-1 is listed as a hazardous air pollutant (HAP). APR -, 9 2010 This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 50-00-0 Jslisted as a Hazardous Substance under the CWA. CAS# 7558-79-4 is listed as a Hazardous Substance Original Submittal http://fseimage.fishersei.eom/msds/88082.htm 4/8/20 I 0 . . Page 6 of6 under the CWA. None of the chemicals in this product are listed as Priority Pollutants under ttle CWA. None of the chemicals in this product are listed as TOXIC Pollutants under the CWA. OSHA: CASt 50-00-0 is considered highly hazardous by OSHA. STATE CAS# 50-00-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 67-56-1 can be found on the following state right to know fists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 7558-79-4 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts. CAS# 7558-80-7 is not present on state lists from CAT PA, MN, MA, FL, or NJ. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 The following statement(s) is(a.-e) made in o.-der to comply with the California Safe Drinking Water Act: WARNING: This product contains Formaldehyde, a chemical known to the state of California to cause cancer. California No Significant Risk Level: CAS# 50-00-0: 40 ceg/day NSRL European/International Regulations European Labeling in Accordance with EC Directives Haza.-d Symbols: T Risk Phrases: R 45 May cause cancer. Safety Ph.-ases: 5 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 5 36/37 Wear suitable protective clothing and gloves. S 51 Use only in well-ventilated areas. WGK (Water Danger/P.-otection) CAS# 50-00-0: 2 CAS# 67-56-1: 1 CAS# 7558-79-4: 1 CAS# 7558-80-7: 1 CAS# 7732-18-5: No information available. Canada - D5L/ND5L CAS# 50-00-0 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. CAS# 7558-79-4 is listed on Canada's DSL list. CAS# 7558-80-7 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of 028. Canadian Ingredient Oisclosure list CAS# 50-00-0 is listed on the Canadian Ingredient Disclosure List. CASt 67-56-1 is listed on the Canadian Ingredient Disclosure List. II Section 16 - Additional Information II MSD5 Creation Date: 6/07/1999 Revision #5 Date: 9/16/2002 Tile information above is believed to be accurate and represents the best information currently available to us. However, we make no warTantv of merclJ.'lntability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should mtfke their own investigations to determine the suitability of the information for their particular purposes. In no event shail Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages. Date Received: APR -9 20\0 Original submittal http://fscimage.fishersci . com/msds/88082 .hlm 4/8/2010 . . Para-Pak@ L V-PV A/I 0% Formalin MSDS Sheet .....-.--,.......--..... , f-..._-""-~,."'""""'".."".."."._.-""-"-,.,,-_._'--""".'"'.,,~'.__"""~"'~~"_."."._."".,.~.__<'O__<,,~'.,_'"",.~_.,",."_,~,"'''"'_'''''''''''_''_;'''_'_'"'_"'''='''~_"=>_'''''~'~__",".'''''''''''''=''; EroducLCalalog > E'ara:E'ak(J!H)arasitQlog)~..l.\odlLcts > E'am:E'ak\!!L.:[wo,,-YiaLStoDIJranspO!:l ! :Systcms> LisLQ!J'mducls > Para-Pak@ LV -PV A1i 0'% Formalin> MSDS5hcels > MSDS SilCCI . ! "'"=.".,....."..'""...",.'"'".....".,..'m'...'~'"'..~m..".....'"=.'"=."..,..."'"~.===''''''"'.~.........."'''''''''''''''''.''''''....'''.".''''.l-~''''=_.'"'''''''~''''''~'-=:''.,,-''' MA TERIAL SAFETY DATA SHEET 'Additional Product info i : [!~}fBIIj;:I~1I!QK=::::=:=~~:=:~:~:::~:=~~::=:-.=::=~=::~:=~::.::=::::~Pt"2r.Pr~Qa~~~~~t98..:J Manufactured for: Meridian Bioscience. Inc. iRevision Date: 7/i2/05 ! !_.........._......._......_......_..,.._............_j._..._c.,_..._..._m___.._...~,/.~._'__.............."".>"......+-- _ ~ Name: p'ara-Pak@ LV-PVA Fixative I ~~_i l(Low Viscosity !'olyviny! Alcohol ~den!ification i ".""_~."._,.."_ ..,......"...... !Ei!i!..~iy.~t....._'""_..,_,.,~,_,..__..,..,_,__"......i!i~~~ rd o..!!.li. C 2!!!P_q,!!,~I1.!L-_i ,Calaiog#: 1900112, 300112,300312, 380112, iE.!!ysical and Chemical Data [ L.............-..............-.. ...__......12.2.~.!1?.l..2}.Q..1.ii:'o.1}..QL~jo..:!.Q.QJJL.._j!i'ire "-lid eX)1losion data ' Fonnula .. ... .....jMixture .. .... .... ... ..... ... ..... I ~AS'1r-'.'.".'.'.' .. ....'.....'....fi7A..._............._._,.-...._...~'..-'1 'EPA.-ii;;~;~:d~;;~W;;st~..r"....",..."..,.,._._,.._.,..,......._.. ......, 1!2.ft......."........._....~..._.....t~:.~:~..~~~:..~~~.:...........................,,,...,,..............., tp A Hazardous Waste [Mercuric Chloride; EP Toxic waste I ;~J~:.~S,.,_.,..........,...."..,',.,....,...,.,...."k!~2........,..,......,.....--...,...........,..,-.............-...-1 ;........,'m"..............,,~...,......"'..""..,...."",.....<"'........._,,_...~.,....'.....H..._..,....>......_.......,...__,..._.~._..>.._,.~ HAZARDOUS COMPONENTS i ............'............."....,.-..-,..................,.....".....".......'-r....'................"..."..-'''''.'''......-., i !,! ACGm . , I Component! oy., ! CAS# i TL V ! CLASSIFICATION I i :i 1 I! j . !.'i.~~;;I~';;;~;;i--r28..F7~6.3~.1"4~~~~~..[..".__..;:i:~;;';;~;";bi.~.'---.."".I i_..."'__..._.....~._l.---I-_.~......._j__"..........._ -""-"'''''"''-'~''--.._.........i I Acetic Acid I 5 164-19-1 i Oppm 1 Corrosive I i I I 7 I TWA I I i .; ~ I ~ J j , I! I I)ppm i i I I STEL i "'"...................,.....",."H.......,,,.... ~._L."'..:.....""""......""".L,.""."""",""""_.~_...._._ "<......".......~ : Poly VlI1yl ! 5 i 9002-1 ND I Irritant ~ :.. .~:~:~~;~~. ',i 3 4 'h?8-~- t.l"oom~/m l'" . ..c~;;~;I~e- ! C.hlorIde. I 94-7 I 3 (skin) . I I TWA ' :...""~....,"_,.."~""."."~"""~=.""'L*",_."."",~,,L,,,_c,=.._"_~.._~l..'"'"_~_"'^.~,'~m=......"".">.".".....,,...",......""".,.",.;".,'~'"',..,.u..~1 1....(~I~.~.~I.:I.....LI..j..~.~.~~.I.J.......:.~.c..J......_,~r~.:.~~~~_'".,............I '. Hydrochloricll.4 II' 7647- I' 250mllin 'I' Corrosive . j ACid I '01-0., i i...,="=."".""~...."."".~'""..t..,"".___,J_..,,;==,~,~._,,J_..".;;~"__.~~;'''_._...J.''"''''.."''~"..,,~"'.."~~''~,,. ,..;._;.~.."'."...,,"....,.";f L,........".................._......_.....___....____....m.........,........._....................,._............_......._,.__....j PHYSICAL AND CHEMICAL DA T A i ........"..............._...~......_..,................._......"........,..-...............-............................".,..._.J bfP.s!.t'3.A..l;lS:.JO' ..._.,....:<,::'i'1'i'!1"s.~..!i5l!:!9,..,.,........._............_1 .pH: ND -.. i ""="""~,.~,"".,_==.."-""'".,"" """'''''"..."..,=~~""..,_~,'u''''''"''''".-"'"."..,",.._'"~".,,~"~..;,''~""'=."..~"",'......''''''..~....",,,...."'._;,....._"._._~."=;, .,._ """ .;, .ODOR. . [Alcohol. ... . .. Hm . ..: f~t~.~~f~~:~~QI~I::::!f.IfL:~::::::::.:::.:=::....:::::.::::::::=:::~'=:::':::::1 ;COMPONENTS: iND : ~'"'.,"'~'"'","^;"',..;,~...;;;=,=;"~,~'"..".,"~,~'".,.,,'; "",'""';"..."'""'=;~'"=,,~..,,~.",.,,.......~._""'=...."""""...."=""',,"''-"-"'',",,'''''.- """'I FVAPOHATTON l. i Date R~ceived: : APR ~. 9 2010 t Original Submittal Page I . Para-Pak@ L V-PV All 0% Formalin MSDS Sheet __..u___ INIJ ! !3"611?;.~",",~.~,",",,"._,.",_,",~.~!..~",..",,.",,",,_._,,._,,,...__._._......_~,....,..........'"..""'..1 SOLUBILITY IN ! I !Unlimited & A.IS.!3........ . ............._.............. n.'''''....W"1 , :........"...""'...._...,........._.m,..._."..,...,.~_......,...."..~....__...,....,....,..__,_".._.~._M..'''.. FIRE AND EXPLOSION HAZARD DATA i i'y~A.SY:i..po.iNT.............!66-,;..f.(T9.-oCJ:"B~ir~g.p~;i~;"t1"83..~..F'1 1_....................."._."m........__...._...!(8..~...~.f.L......................................,................._...........1 .EXTINGUISHING IMedia appropriate for surrounding llrd, 'MEDIA !conditions. i ;"'~".."""'<.."'"..",..."".""'"..,.=~....",,."<""_"'"""""l,;""."~."'".,,"'~_._=.="'w.......""'.,'=.<,'""."..='_m.."'",."..,...."n..=_..: FIRE FIGHTING IWear self.contained breathing . !eg9~1;:I?!dJ~J;:.~."."'._..J!!J2P..!l1:e!!;!~_i~I~.9_l?!:!?1'::~.~Ly.!.~1.2.tbjl}K,.....J [FIRE HAZARDS: [May produce hazardous ! i"'.....".."."..........._"...""..........J(j~.'::2.!]m.2.?l!L'2.!]..l?!:'2(j.~.~h~;..__........... ''''',."'_,_'''"''.".,,"_,~''",_'''~~,~W_~"'''O"~~~'''''','''<N,"'',"._w._..'~._~_._"'~._~"''"''''''''"'_,~_"~_,'''''',,,.."..~.'''.___'''',,.,'''''' REACTIVITY DATA , ',."""".c,,,",,"..,.,.,",,",,=,,,,o.,,,,",,",,,".,..,,,,,..,,,,,,",,."""'''''''""',","",'"'''",.,,,,,,''.'"'U''"''~'.'"',''',,,""""'''''''''"''''~''''"''''''''''"'''~'"''';''''"'''''P''''''''"~''''"~'I STABILITY: IStabic i ~""""M""_.""'''~,'''''~'''''''"""",_""""\,,,,,,,,__...,_,m.,......~."...."......c,... .....,_......m'..._......,..,...,.,...,.~ 1!.t!f:..Q.r~:'1J~.6I.I!3,.r.hII.Y,I.J? tl"2Dg_S~l.s!i~i!lg..~g~.!ll.?;..?!LS.!]g.!?~;?,S:?c! HAZARDOUS Nonc . l~Q.r;;YlYl'2.E!.?;.6.ILQJI:Lj......................... ..........._..._........................................., i i i.."~..m~."m...>m..~..H._.......,.,__....".......u>.,.,^......."..............._......._~........._.H'._'_.~..,."....................,..l HEAL TH HAZARD .. j j2IEQIgEg:hjMIfE]i\!~Q=:.~~:::.::=:~~~:~::.::::~~::~:~:::::'::~=:':.!::::~!~:; EXPOSURE EFFECTS: : ""'o.."....."".~"......,""..~,,..,.....~,.~.~~,.,.,,"'''_.._.."'"..*.~.."~."..~,,,.".._"~"'~._.."M.""..."".,,"..,'",,'"^"".~..."""_""..~m....._...".,,~'"',) !EYE: Irritant, burning sensation ! .S..j<:.iN...-........'...... I~;:it~;i-;;~..........................................................""'! "".,','"..."'''mmm...."...~...."".",''".." "" ...~,,",,~,.....'..=M'.."~."....._.'"~=,...~''''''~,,"."....._,=.."'""",_..'"'m'"'m".~....""._,._~.~,,_",.c_'''',....,r.,"; ! INHALATION: .Coughing, wheezing, laryngitis, shortness of i i Ibreath, headache ! ,.....................................1.............................................._....................~.................................., i.!~.9..I~.~Tlg!.:l.:....I.~.".~s:.~'..:v.?'.~.~i.~~:..E.~.il.l:.~:~~I.'.....................................I :""'."="==.........""'""",..,..,"'.",.,,,,,,,,,,,,='"',..,,,,,,"',,,,.,..,,""""",,,,,""''''',..,,.....,,,'"''''-,..,,..,,,,,,..,,.,,,,,,..,,,''',,......,j :FIRST AID DATA ' :FI'Rs~T...ATD~-~~="'6'bi;I~.~~;~dfZ;Tatt.e-ntjo~~'.""..."'...."'m'~__.._...,~.._ ......... ._,.."...~ .........~~~"""m""....N''"'=.'''"'"_''"~__~~~~'".._~_,,_.."~~"=,=""...."'~~.._..~,.,""=_,~~"=~.""...."..""~''',.__,,.,~,,."'".."..~~.."....1 EYE: :Fiush with water for 15 minutes. i ,..""..."......"'..""'''........''''m...''....._...........................,........._."_...._..".._'"..~..^...,....._.,._.".....,."._.',.,,,..>_.,_ SKIN: iFlush with water for 15 minutes. i "'."......".....""""...,."...."..,,""",=.,,=."'..-.........-"""..........._,..=....=.~_........._'"...,..."_.."......~_.._~.""",..;l INHALA nON \Rcmove to fresh air immediately. If breathing i '. ___......_....._....>...!:g!:?l?:~i.g,\Y.~-'IEEifl.siEL.!!~JI!.\@!.i2.~,..-.-..........................--1 ING ESTJON: . ,L:ontact a physician immcdiately to obtain the ! ~."''""''<~..."''=''"'".,"...,,,",,,."'2np.XQE!:!.~g,~.,E!!l.~!g~.!!g):"9~~,~"!~D~m:.=,,,",..,,.,"~.,,"'"'~,.,""~""""~ : ! L..,=......_"-.-",..""'_."...,."..,,,...,'",..,,'<.""""'~"'.~,.,,'"'"'~,."'""'""'c.,,"O'".~_,.O.c,~'O_.""",.""'''_..''".'",.,,'''.,,,<-T",,"'."";,.,.'",""."~.".,.;._,.,,,,...; HANDLING AND STORAGE ! __="-'..,"""""...n'.......""_,"".,.",",,,,,,..,,,"".........=.....,".,,~"n""."..........."".,~.'''".=n'"=".'..".""...""..,'".~'.,,""..,,.'''''''."'''''''''''''''.''".'''O<ffi,"''"'''< !Wear chemical safety goggles, chemical resistant gloves and i 'protective clothing. Use OSHA approved respirator ifTLV I=xcecdcd. General meehanicai ventilation is lIsuaiiy adequate 'under normal use. Do not exceed TL V. Containers potentiaiiy , b.~!?o~.!!d.2gs..~yl).~n.~!.'lRDi...P.!:?D.'21E.~!.!?..<:..._..._..............,.......-.....-.....J 'SPILr.AND-oi"sp.Os.AL-PROCEDURES........._.......__..."...........! "'."..,,,.,_...>>_._....~"..."M",.~_.......__ .~~.._""__~,~...~.___"_,,~,__,~ .?,~.!h.h:_.......................i4-~~L~.2!}_~12~r,.~nlli~!.!.Et~.,...~!.s......_,_....._~j 'W ASTE ",.,Consult federal, state. and local reguiations. I I ~ " t Page 2 . Dat~ Received: , AP~ -,9 2010 Original Submittal . . Para-Pak@ L V-l'V A/I 0",1" formalin MSDS Sheet DISPOSAL: I ! :'"".."..m......_......_......"'...,...",'''''~'"'_"'.",..,".'''.''''''''-',....="''''''''"'''''.",.-""""""''''...."~~-="-.,.'''''''''''''.._.'''''''''''''=~'"-'''"''''''-''"'''i ?rii'ANS'P'ORTATi"O'N'iNFOR:1\1ATioN""''''''''''''''''''''"''1 i5oT.............lFG;;;-;;;;;T;rz:-rTq;;rJ:-c"~TT;:;;;~~.~~~._.._..._, ! IUN2924, Hazard Class 3. Pkg. Group II, ! i (echnical Name: (Contains Isopropanol, ! jAyA...........-r~-G;,;i~,~J~~<!{iqU id~C~;~~T~e, ,;:0.5.:-......--1 \UN2924, Hazard Class 3, Pkg. Group II, i l"echtllcal Name' (Contains Isopropanol, . ._..._.......... .. _....A~~lic 1~.ts!L.. ..... _ . .._____.. ".._._..! ! N;.i~..i-:.p~~:49.cloR.=.~~i;..~.;;~.i;i.i;i;;;;g.J(i~;r-;;;:"T~~~~i;~~..;;;,;~;....! 'packaging and the gross weight does not exceed 641bs. use the i Ji 73.4 small quantity exception. 1 I 'Note 2 - Pcr catalou #400212 - 5 liters is the maximum voJum~ t ~ i ~hat can be shipped per package 011 a cargo aircrail. ~ NA =Not Applicahle , [NO = Not Determined [rhc above information is believcd to he correct but does not ]JurPOlt to be all inclusive and shall be used only as a guide. 'Meridian Bioscience, Inc. shall not be held liahic tor any I 'damage resulting li'om handling or li'olll conlacl with the above i 'Rr~.9.~!.SL...._....._........._......................,.~............,:...,,,....__...................,,................L.....,......,............ .'.........,...........,.,..,....... ,..,..,."....; !..........._.._._...._~..._._Q-C;p);;;gr;i .2004..rvl~~jdi~;;_B;~.;:i~;;.~~~J~""c~........._.....,"..........."..-"'i 1.....}\:Igidhlt:r....E1i'.'~,,~nce,J11,,;}EL~i~el~Ei~Qr:i~e"'._<::jI1cj..ntla.ti,..Q!i..1?2..4j_(m)nl~lZQ.lL.t Date Received: APR - 9 2010 Original Submittal Page 3 HYDROGEN PEROXIDE SOUe)N 3% . Page 1 of6 MSDS Number: H4070 * * * * * Effixlil'c Datc' Ol//5/0S * * * * * Supercedes: 04/22/05 24 Hour Emergency TeleptlOne: Material Safety Data Sheet /,7 CHEMTREC: 1.800-424.9300 "," ; National Response in Canada ~ ~~:~::~~6~~~:~:~,:6d6; ~_ ." Chemtrec:703-527-3887 JIBaker ~ ~',S' '.li1 S, ' "~".o;., ' ..t ::f>~, c ~ .' , ~ 90S.859.2151 From: M~llinckrodt Baker/Inc. 222 Red Schoolla"e Phillipsburg. NJ 08865 NOTE:CHEMTREC, CANUTEC and National Respon~e Center emergency numbersto be used only in the event of chemical emergencies. involving n spilt, leak, fire, exposure or accident involving chemlcals. l.,lfj r,r;n-p.m~r;;e!)cy f1~~~:;:fDn::; :;hou!ri' hp. dlr~(je:i :n Cli'st.'1mer Servic::.!;! (i-;:';OO-!;B2-~S0~'~) tor ."J:;dBt.'l.:ir:e. HYDROGEN PEROXIDE SOLUTION 301.1 J. Product Identification Synonyms: Hydrogen Dioxide Solution, 3%; Hydrogen Peroxide Topical Solution U.S.P CAS No.: 7722-84-1 j\lolecular \"eight: 34.01 Chemic:ll Formula: 1-1202 in aqueous solution (3%) Product Codes: 2180,2-182 2. Composition/Information on Ingredients Ingredic:nt CAS No Percent Hazardous Hydrogen Peroxide Phenacetin I'later 7722-84-1 62-44-2 7732-18-5 2 - 4% < 0.05% 96 - 98% Yes No No 3. Hazards Identification Emergenc~' Overview WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. Date Received: SAF- T -r>A TA(tm) Ratings (Provided here for YOllr convenience) APR - 9 2010 Health Rating: 2 - Moderate Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Original Submittal httn' //n,.nr\u ~t'V;>t.-Ol. rron.../n...crlc/onnllchhh-nl/hl1()7r\ ht......... /lfO!'1{\l {\ HYDROGEN PEROXIDe:>LUTION 3% . Page 2 ofG Lab Prolcelive EquIp: GOGGLES; LAB COA T; VENT HOOD; PROPER GLOVES Storage Color Code: Green (General Storage) u____n_________________________~__ ____________________________________________ _________________________ Potenthll Health Effects Inhal:ttion: Not expected to be a health hazard under normal conditions. Ingestion: Large oral doses may cause irritation and blistering to the mOllth, throat, and abdomen. May also calise :Jbdominal pain, vomiting, unci diarrhea. Skin Contact: No adverse effects expected on intact skin. Contact on burn or open skin may cause stinging pain or irrltatioll. Eye Contact: ClUscsirritation, redness, and pain. Chronic Exposure: No information found. Aggnn"::ltioll of Pre-existing Conditions: No information found. ^-^^.~^^---~,._---~~--_._--^._~----~^ 4. First Aid Measures Inhalation: Not expected to require first aid measures. Ingestion: Give sever:J.1 glasses of water to drink to dilute. If large amoLlnts were swallowed, get medical advice. Skin Contllct: Not expected to require first aid measures. Wash exposed area with soap alld \Val cr. Gel medical advice if irritation develops. Eve Contact: 1I~1Il1ediately /lush eyes with plenty of water for at least 15 minutes. lifting lower and upper eyelids occasionally. (jet medical attention immediately. ".-*...----~-~-**.*--~.-.--.-.*-*--.------*-~~-.___....^_ --.*__~.~~.__"^no__._._._.__.._.._*_.~__h_._m ^~__"..____..._.__..".,~__ 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Concentrated hydrogen peroxide (30%) is a strong oxidizer, but this dilute product docs not present that hazard. Explosion: Not considered to be an explosion hazard. Drying of concentrated hydrogen peroxide on clothing or other combustible materials may cuuse fire or explosion. Fire Exlinguishing Media: Use any means suitable for extinguishing surrounding fire. Sptciallnfonnation: In the event ora fire, wear full protective clothing and NIOSH~approved self-contained breathing apparutlls with full facepiece operated in the pressure demand or other positive pressure mode. ~~_____~._._._"'''..~'''__m_..._.W"...___.___.._.._~"_____.__._~.._.__." _______~_~._._w....,,__ __.+__.~.."_____"_____.__.._ ".. _ "________________...u _ .__~_~_.__ 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. CO'Nin i~l . d' recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (c. g~aLtit:l~~CeIVe . dry sand, earth), and place in a chemical waste container. Do not use combustible Inu(erials, such 3S saw dust. Small umounts of residue may be flushed to sewer with plenty of water. APR - 9 2010 Original Submittal hlto:! /www.itbaker.com/msds/enQlishhtml/h4070 htm A IQ !'1{")1 (l HYDROGEN PEROXIDE SOLl.N 3% . Pagc30fG 7. Handling and Storage Store in a cool, well-ventilated dark area. Protect from freezing. !soble frum incompatible 5ubst.:lnccs_ Protect container frol11 physical damage. Containers of this materiallllay be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): I ppm(TWA). -ACGIH Threshold Limit Value (TLV): ] pp11l (TWA), A3: Animal carcinogen_ Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it call control the emissions of the cont<llllinant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Velltilotio/l, A Malluot oJ ReCOil/mended I'raclir:cs, most recent edition, lor details. Personal H.espirators (NIOSH Appl"oYed): Not expected to require personal respirator usage. J f the exposure limit is exceeded, \vear a suppl ied air, full-faccpiccc respIrator, airlined hood, or full-faccpiece self-col1tJincd breathing Jpparatlls. This substance has unknown warning propertIes. Skin Protection: Wear protective gloves and clean body' covering clothing. Eye Protection: Use chcmical safcty goggles and/or a futl face shield where splashing IS possible. Maintain eye wash fountain and quick- drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear, colorless solution. Odor: Odorless. Solubility: Infinitely soluble. Specific Gravity: ca. 1.0 pH: No information fOLlnd. IXI Volatiles by volume @ 21 C (.70F): 100 Boiling Point: ca. 100C (ca. 212F) Melting Point:' ca. OC (ca. 32F) Vapor Density (Air=I): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=I): No information found. Date Received: APR - 9 2010 Original Submittal 10_ Stability and Reactivity htt......I/",,,,,,' ;t\..."l,-o... ""r\~....,/n.-......,-1.-,/C>...-........1~C'I...ht.........l/h;l()7() 1...+....... 11/0/'1(\1 (\ HYDROGEN PEROXID~LUTION J'x, . Page 4 of6 Stability: Stable under ordinary conditions of use and slor3ge. Haz:lrdolls Decomposition Products: Decomposes 10 water and oxygen. Hazardous Polymerization: \Vill not occur. Incompatibilities: I-kat, rcduc1l1g dgcnts, organic materials, dirt, alkalis, fust and many Illetals. CondiHolIs to Avoid: Light, heat, incompatibles. II. Toxicological Information --------\Cancer Lists\----------------------~------------___________________ ---t1TP CaI:cinogen--- Ingredient Known Anticipated IARe Category Hydrogen Peroxide (7722-84-1) Phenacetin (62-44-2) Water (7732-18-5) no No No No Yes No 3 2A None 12. Ecological Information Environmental F:ltC: No information found. En\'ironmcnt:1I Toxicity No information found. 13. Disposal Considerations Dilute with watcr and flush to sewcr if local ordimmces allow. othclwisc, whatever cannot be savcd for recovery or recycling should bc managed in an appropriate and approved waste disposal facility. Processing, llse or contamination of tl1is product may change the waste managemcnt options. State and local disposal regulations may differ fro111 federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requiremcnts. 14. Transport Information Not regulated. -___V__"'~m.~w_._,__~~.,~.~_ ...~_.._._',~___~,_.__~,_~._ ....~~__~,~__. 15. Regulatory Information Date Received: --------\Chemical Inventory Status - Part 1\-----------------________________ Ingredient TSCA EC Japan Australia APR - 9 2010 ---------~------------------------------------- Hydrogen Peroxide (7722-84-1) Phenacetin (62-44-2) Water (7732-18-5) Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Original Submittal --------\Chemical IIlverltory Status - Part 2\------------_____________________ --Canada-- Ingredient Korea DSL NDSL Phil. http://www.jtbaker.com/msds/englishhtml/h4070.htm 4/8/20] 0 HYDROGEN PEROXIDE SOLljON 3% . Page 5 of6 HydL"ogen PeJ:m:ide (7722-84-1) Phenacetin (G2-44-21 Water (7732-18-5) Ye, Yes Ye, Ye, Yes Yes No No No Ye, Yes YeS -----~--\Federal, State & Intenwtiop.i11 Regulations - -SARA 302- RQ TPQ rart 1\---------------- ------SARA 313------ List Chemical Catg. Ingredient Hydrogen Peroxide (7722-84-1) Phenacetin (G2-44-2,\ Water (7732-18-5) No No No No No No No No No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCA- Ingredi.ent CERCL.r.. 261.33 8 (dl IIydrogen Peroxide (7722-84-1) Phenacetin (62-44-2) Water (7732-18-5) No 100 . No No U187 Ho No No No Chemical weapons Cow,rention: No TSCA 12 (b): No COrA: No SARA 3Jl/312: Acute: Yes Chronic: No Fire: No Pressure: No ReactivitY': Yes (['.1ixture / Liquid) 'VARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOIVN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. Allstr:llian Ilazf!lelll Code: None aJJoc:Jlccl. Poison Schedule: S5 WH~IIS, This tvlSDS has been prepared Jccording to the hazard criteria of the Controlled Products Regulations (CPR) and the ivlSDS contains all of the jnfonmllion required by the CPR. ,._..._.._.".~-~..__.~~."'.._"'--,, "----'---'_.*------_..~~-_._~_.~~-"'_."- .__.--~--._.._---~~--~._~.._-~.._.,,~--~-~_._-~,--- 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 1 Label H::lzard Warning: WARNING! MA Y BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. Label Precautions: A void contact with eyes. Keep container closed. Wash thoroughly after handling. Label First Aid: In case of eye contact, immediately flush eyes with plenty of water for lit least 15 minutes. Get medical attention. If swallowed, give large amounts of water to drink. Never give anything by mouth to an unconscious person. If large amounts were swallowed, get medical advice. Product Use: Laboratory Reagent. Revision Information: No Changes. Ilisclaimer: ************************************************************************************************ Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes nu representation as to its comprehensiveness or .lccuracy. This document is intended only as a guide to the apprOI)riate precautionary handling of the material by a properly trained I}erson using this product. Individuals rcc{',iving the infOl'mation mIlst exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS 'OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCIIANTABlLlTY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTlIHEREIN OR THE PRODUCT TO WIIICH THE INFORMATION REFERS. ACCORDINGL Y, MALLlNCKROq,J;. . BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR REIlLIrate: Received: UPON THIS INFORMATION. ************************************************************************************************ Prepared by: Environmental Health & Safety APR -': 9 2010 http://www.jlbaker.com/msds/englishhtml/h4070 .hlm Original Submittal 4/8/2010 HYDROGEN PEROXm.LUTION 3% . Phone Number: (314) ()54-1600 (U.S_A.) http://www.itbakcr.com/msds/englishhtml/h4070.htm Page 6 of 6 Date Received: APR .c.9 2010 Original Submittal 4mnOlO . . GEBAUER COMPANY 9410 ST. CATHERINE AVE. CLEVELAND,OH 44104 1-800-321.9348 toll free or (216) 271.5252 FAX (216) 271-5335; WEBSITE: www.gebauerco.com AFTER HOURS EMERGENCY: CHEMTREC (BOO) 424.9300 MATERIAL SAFETY DATA SHEET GEBAUER'S ETHYL CHLORIDE@ TRAm; NA~IE SnmNY~1 , I ! i I REVISION DATE NOVEMBER, 2002 BY AMY PAUKOVITS GEBAUER'S ETHYL CHLORIDE@ CIlE:\IIC,\L NA~H, SYNONYMS FORMULA C2H~C1 ETHYL CHLORIDE, CHLOROETHANE, HYDROCHLORIC ETHER MOLECULAR WEIGHT 6452 Chemical Family. Halogenated Hydrocarbon Inhalation Ingestion Skin Contact Eye Contact Chronic Exposure Aggravation of Preexisting Conditions Health Rating 2-Moderate Flammability Rating 4.Acute ReaclivilyRating O-None Special Rating None Lab Protective EquipmC!nl Neopren(! or Vilon gloves, labeO'll, goggles or face shield, vent hood Slorage Color Code Red (Flammable) Headache, diu.iness, nausea, vomiting, loss of coordination and disorientation may produce narcotic and anesthetic effects. May produce central nervous system depression, respiratory paralysis, or fatal coma with respiratory or cardiac arrest. May sensitize then1yocardium to endogenous epinephrine, c.3using dan erousdvsrtwthmias, Alllwu tl,lhsor1Jedthrou hluIlQsandsf:ir1.i!alsoisra idlv i'lenolllllfOUQhlhelull 5 Unlikely route of exposure due to gaseous nature. RapId evaporation of liquid may cause frostbite. Symptoms of frostbite are blanching of the skin, cold feeling numbness. Cutaneous sensitization may occur, but is extremely rare. Freezing can occasional alter pigmentation. A single prolonged skin exposure is not likely to result in absorption of harmful amounts Is 0 slight irlitont to mucosa! tissu..s Long term Exposure to high levels may produce the following: loss of muscle coordination, involuntary eye movements, tremors, speech disturbance, slu ish reflexes and hallucinations. Theses m toms are all..viated when the overex osureisended. The defatting properties of Ethyl Chlorld~ may aggravate existing dermatitis. , I! IV. FIRST AID MEASURES I I Inhalation Ingestion Skin Contact Eye Contact Immediately remove to fresh air. If not breathing, give artificial respiration. If breathing Is difficult, qualified personnel may give oxygen. Call a physician. Unlikely route of exposure due to gaseous nature. For exposure to liquid, immediately warm frostbite area with warm water not to exceed 10S.F (41.C). In case of massive exposure, remove contaminated clothing while showering with warm water. Call a physician. . For contact with the liquid, immediately flush eyes thoroughly with warm waler for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. See a physician, preferably an ophthalmologist, Immediately. Special Fire Fighting Procedures DANGER! Flammable liquid and gas. Evacuate all personnel from danger area. Use water spray to cool fire-exposed conlainers, structures and equipment. Use water spray, carbon dioxide or dry chemicals as extinguishing media. Remove sources of ignition if without risk. Remove all containers from fire area if wi thou I risk; continue cooling water spray while moving containers. Do not extinguish any flames ell1itted from containers, stop flow of material if without risk, or allow flames to burn out. Self contained breathing apparatus may be required by rescue workers. Unusual Fire and Explosion Hazards Flammable liquid and gas. Very dangerous fire hazard when exposed to heat, flame or powerful oxiditers. Ethyl chloride is heavier Ihan air and the vapors may hug the ground, making distant ignilion and flashback possible. During a fire, toxic gases (hydrogen chloride, chlorine and phosgene) may be produced. Direct exposure 10 flameS may cause container explosion. Static discharge may ignite ethyl Chloride. : I! VI. ACCIDENTAL RELEASE MEASURES I I Spill and leak Response Flammable liquid and Gas. Eliminate all sources of ignition. Allow spilled ethyl chloride 10 evaporate, ventilate enClosed areas. In case of large spill, evacuate all personnel from area. f2L Entrv Into Unknown Concentrations That Could Be IOlH ( '! 3800 ppm): Full Face Self Contoined Breothing Apparotu, Waste Disposal Melhod . " .. . . .. . I! VII. HANDLING AND STORAGE i I d tiH 1Gb b ,. II , drr "" Storage Precautions Store in cool, dry well ventilated area.. Protect against physical damage. 00 not subject to temperatures above 120.F (50.C). Do not store near high frequency ultrasound equipment or non. ex losion roofelectricale ui menl. Usage and Handling Precautions . .. . . . , I : VIII. EXPOSURE CONTROLS - PERSONAL PROTECTION I I Ventilation/Engineering Controls Respiratory Protection Skin Protection EyaProtection Exposure limits Usewithadequateventllallon. For clinical sening: minimiza inhalation. ,?fvapors by patient, esp.eciaUy whe~ applying to head and neck. For large spills (,! 1000 fp'm twa and? 3800 ppm instantaneous exposure): full face, posltrve pressure, self-contarned breathing apparatus should be available for emergency useAPR _. 9 2010 Wear nooprllm.~ orviton gloves for exposures =1000 ppmTWA and =3800 ppm Instantaneous exposure. Splash goggles or safety glasses. OSHA -1000ppm, PELACGlIH -100 ppm TLV, A3 IDHL,-3800ppmLEL, Original Submittal . . : IX. PHYSICAL AND CHEMICAL PRO~ERTlES Boiling Point 54,1"F(12.30C) FreezingPoinl _213.S0F(.136.4"C) Evaporation Rate (Butyl Acetale" 1) Greater than 1 VilporDensity(Air=1@70'F)) 2,23 VaporPrcssure{@68'F) 20.1 psia (5,4 psig) SpecificGravity(@6S0F) pH Solubility in Water Odor Appearance 0.8939 Essentially neutral Slighl by slow hydrolysis Ethereal Clear and colorless liqujd orgas I X. STABILITY AND REACTIVITY, Stability Hazardous Decomposition Products Incompatible Materials Hazardous Polymerization Conditions to Avoid Normally stable in air. In presence 01 moisture, slowly hydrolyses forming hydrochloric acid. Carbon monoxide, hydrogen Chloride gas, phosgene gas, and carbon dioxide. Alkali metals such as sodium, and potassium, powdered met.als such as aluminum, zinc and magnesium and strong oxidizers. Not expected to occur. Contact with incompatible materials and exposure to heat, sparks and other sources of ignition and exposure to high heal. Acute Inhalation LC50 Skin Irritation Eye Irritation Chronic Effects: Effects of overexposure: Acute: Subchronic Carcinogenicity: Mutagenesis 60,632 ppm (rat) (2 hr.) Anesthetic effects. Produces frostbite. Produces frostbite. Is not listed as a carcinogen or suspected carcinogen by NTP or OSHA. Listed under IARC as a 3. Inhalation: Can produce varying degrees of intoxication; i.e. loss of coordination, drunkenness, possible convulsions, abdominal cramps, nausea and coma. It has been reported that concentrated vapors can produce narcotic and anesthetic effects in humans and may produce deep or even fatal anesthesia. Inhalation may also be irritating to the respiratory tract. EyelSkin: Liquid spilled on skin may cause possible frostbite, For eye contact, there are no specific known effects., but the effects may be the same as contact with skin. Increased liver weights were observed in rats and mice after exposure to 2500,5000,10,000 and 19,000 ppm for 6 hrslday, 5 dyslweek for 13 weeks. No other effects were observed in the study. Carcinomas of the uterus were observed in female mice exposed to 15,000 pppm during the course of a 2-year inhalation study. f-tas been shown to be mutagenic in bacteria, with and without activation. A2-year study in mice did not yield increases In bone marrow micronuclei. No teratogenic effects were observed in mice exposed to 500, 1500 or 5000 ppm during organogenesis. No effects on reproductive organs were observed after 13 weeks ex osuretova ors. Europe EINECS: SARA TiUell1 Proper Shipping Name Hazard Class Identification Number Packing Group Reportable Quantity DOT Label(s) Required Canada TOG Description Ethyl Chloride 2.1 (Flammable Gas) UN 1037 '(49 CFR.173.322) 100 LBS.l45.4 Kg Flammable Gas Ethyl Chloride, Class 2.1, UN1037 **Special Commodity** Section 302: not listed. Sections 311, 312: acute health hazard. Section 313: listed. Listed CERCLA Listed with a reportablequantityof100 Ibs. State Regulatory Information: Ethyl Chloride IS covered under The specific State regulations listed. AlaSka Designated Toxic and Hazardous Subsl.3nces California Permissible Exposure Umits for Chnmical Contaminants Florida SubstanceUst Illinois Toxic Substance List Massachusetts SubstanceUst Michigan Critical Materials Register Minnesota Ust of Hazardous Substances Missouri Employer Informationrroxic Substance List New Jersey Right to Know Hazardous Substance Ust Rhode Island Hazardous Substance Texas f-tazardous Substance Ust West Virginia Hazardous Substance Ust Wisconsin Toxic and Hazardous Substances Ethyl Chloride is on the California Proposition 65 lists. This product contains a chemical known to the State of California to cause cancer. CANADA Regulations (Wf-tMIS): Class A - Compressed Gas Class 81 - Flammable Gas Class 02A - Other Toxic Effects EUROPEAN UNION CLASSIFICATION: H'wdSymbo" F.;xn"'te Rece',ved Risk Phrases: R12-40bli~ Safety Phrases: S{2-) 9-16-33-36137_61 APR -, 9 2010 . . Science Chemicals & Laboratory Equipment Personal E Protection Material Safety Data Sheet Silver sulfadiazine MSDS Section 1: Chemical Product and Company Identification Product Name: Silver sulfadiazine Contact Information: RTECS: WP1950000 Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901.7247 International Sales: 1-281-441-4400 Catalog Codes: SLS4525. SLS2311 CAS#: 22199-08-2 TSCA: TSCA 8(b) inventory: No products were found. Order Online: ScienceLab.com CI#: Not available. CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 Synonym: Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887 Chemical Formula: C10H9AgN402S For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS# % by Weight Silver sulfadiazine 22199-08-2 100 -- Toxicological Data on Ingredients: Silver sulfadiazine: ORAL (LD50): Acute: 10001 mg/kg [Rat]. Section 3: Hazards.ldentification Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of inhalation. Inflammation of the eye is characterized by redness, watering. and itching. Skin inflammation is characterized by itching, scaling. reddening, or, occasionally, blistering. Potential Chronic Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. Date Received: APR - 9 2010 Original Submittal p.1 . . Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention. Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover Ihe irritated skin with an emollient. If irritation persists. seek medical attention. Wash contaminated clothing before reusing. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention. Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation: Not available. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-ta-mouth resuscitation. Seek immediate medical attention. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: May be combustible at high temperature. Auto-Ignition Temperature: Not available. Flash Points: Not available. Flammable Limits: Not available. Products of Combustion: These products are carbon oxides (CO, C02), nitrogen oxides (NO, N02 ..). Some metallic oxides. Fire Hazards in Presence of Various Substances: Not available. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: SMALL FIRE: Use' DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available. Section 6: Accidental Release Measures ~ ~ .... Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by APR - 9 2010 spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not Original Submittal p. 2 . . I Science . Chemicals & Laboratory Equipment Personal Protection J . Material Safety Data Sheet Carbamide peroxide MSDS Section 1: Chemical Product and Company Identification Product Name: Carbamide peroxide Contact Information: RTECS: Not available. Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281.441-4400 Catalog Codes: SLU1123 CAS#: 124-43-6 TSCA: TSCA 8(b) inventory: Urea peroxide Order Online: ScienceLab.com CI#: Not available. CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 Synonym: Oxygel; Peroxigel; Urea peroxide; Urea Hydrogen Peroxide; Carbamide Peroxide. USP International CHEMTREC, call: 1-703-527-3887 Chemical Name: Carbamide Peroxide For non-emergency assistance, call: 1-281-441-4400 Chemical Formula: CH4N20.H202 Section 2: Composition and Information on Ingredients Composition: Name CAS# % by Weight Urea peroxide 124-43-6 100 Toxicological Data on Ingredients: Urea peroxide LD50: Not available. LC50: Not available. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive). of eye contact (corrosive). The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness, watering. and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally. blistering. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction. or dermatitis. Repeated inhalation of'dust can produce varying degree of respiratory irritation or lung damage. D~to ... APR - 9 2010 p.1 Original Submittal . . Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention. . Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult. give oxygen. Get medical attention. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: May be combustible at high temperature. Auto.lgnition Temperature: >360'C (680'F) Flash Points: Not available. Flammable Limits: Not available. Products of Combustion: These products are carbon oxides (CO. C02). nitrogen oxides (NO. N02 ..). Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of heat, of combustible materials. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive in presence of shocks, of heat. Fire Fighting Media and Instructions: Oxidizing material. Do not use water jet. Use flooding quantities of water. Avoid contact with organic materials. Special Remarks on Fire Hazards: Contact with other material may cause fire. May ignite combustibles (wood, paper, clothing, oil. etc.) Special Remarks on Explosion Hazards: May react explosively with hydrocarbons (fuels) Section 6: Accidental Release Measures Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Large Spill: Oxidizing material. Corrosive solid. Stop leak if without risk. Do not get water inside container. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if n<l,e,iJeg. ElU;r1inate.all ignition.sources. Call for assistance on disposal. Uate Kecelved: APR -, 9 2010 p. 2 Original Submittal . . Section 7: Handling and Storage Precautions: Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials. metals, alkalis. Storage: Light Sensitive. Air Sensitive. Store in light-resistant container. Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Do not store above 240C (75.2"F). Preferably refrigerate. Section 8: Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available. Section 9: Physical and Chemical Properties Physical state and appearance: Solid. (Crystalline solid.) Odor: Not available. Taste: Not available. Molecular Weight: 94.07glmole Color: White. pH (1% soln/water): Not available. Boiling Point: Decomposition temperature: 600C (1400F) Melting Point: 800C (1760F) Critical Temperature: Not available. Specific Gravity: 1.4 (Water = 1) Vapor Pressure: Not applicable. Vapor Den'sity: Not available. Date Received: Volatility: Not available. Odor Threshold: Not available. APR -9 2010 Water/Oil Dist. Coeff.: Not available. Original Submittal lonicity (in Water): Notavailable. p.3 . . Dispersion Properties: See solubility in water. Solubility: Easily soluble in cold water. Section 10: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Excess heat, ignition sources. light. air. dust generation, incompatible materials Incompatibility with various substances: f3eactive with reducing agents, combustible materials, metals, alkalis. Corrosivity: Non-corrosive in presence of glass. Special Remarks on Reactivity: It is an oxidizer. Light Sensitive. Air Sensitive. Incompatible with heavy metals, alkalis, and combustible materials, reducing agents Special Remarks on Corrosivity: Not available. Polymerization: Will not occur. Section 11: Toxicological Information Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: Not available. Other Toxic Effects on Humans: Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Corrosive. Causes eye irritation and burns. Possible eye damage. Inhalation: Corrosive. May cause irritation and chemical burns of the respiratory tract (nose, throat) causing coughing and wheezing and possible inflammation, edema of the larynx and bronchi. chemical pneumonitis. and pulmonary edema. Ingestion: Corrosive. May be harmful if swallowed. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract irritation and burns.To the best of our knowledge, the toxicological properties of this substance have not been fully investigated. Section 12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The product itself and its products of degradation arE>ate>>Received: Special Remarks on the Products of Biodegradation: Not available. Original Submittal p. 21 . . Section 13: Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal. state and local environmental control regulations. Section 14: Transport Information DOT Classification: CLASS 5.1: Oxidizing material. Class 8: Corrosive material Identification: : Urea hydrogen peroxide UNNA: 1511 PG: III Special Provisions for Transport: Not available. Section 15: Other Regulatory Information Federal and State Regulations: Connecticut hazardous material survey.: Urea peroxide New Jersey: Urea peroxide TSCA 8(b) inventory: Urea peroxide Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. On the National Inventory Lists of China. Korea, and Philippines. Other Classifications: WHMIS (Canada): CLASS C: Oxidizing material. CLASS E: Corrosive solid. DSCL (EEC): R8- Contact with combustible material may cause fire. R34- Causes burns. 517- Keep away from combustible material. 525- Avoid contact with eyes. 536/37/39- Wear suitable protective clothing. gloves and eye/face protection. 545- in case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 1 Reactivity: 0 Personal Protection: j National Fire Protection Association (U.S.A.): Health: 3 Flammability: 1 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Spl~sh goggles. Section 16: Other Information References: Not available. Date Received: Other Special Considerations: Not available. APR - 9 2010 Created: 10/10/200512:13 AM unglnal SUbmittal p. 5 . . Last Updated: 11/06/200812:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suilability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of/he possibility of such damages. Date Received: APR - 9 2010 Original Submittal p. 6 . . MA TERIAL SAFETY DATA SHEET 1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product: Grafco@ AEROCELL Gencral Use: Cytoiogy Fixative Spray Gencric Namc: Aerosol Dispenser Chemical Name: Mixture Mannfacturcrs Name: GF Health Products, Inc. Emcrgency Telephone Numhcr: 800-347-5678 (Normal business hours) Addrcss: 2935 Northcast Parkway Atianta, GA 30360 Telephone Numher for Information: 800-347-5678 (Normal husincss hours) Datc Issued: 08/13103 Datc Revised: 08/13/03 CHEMTREC CHEMICAL TRANSPORTATION 24- HOUR EMERGENCY TELEPHONE DOMESTIC/NORTH AMERICA 800-424-9300 INTERNATIONAL 703-527-3887 (CALL COLLECT) 2.0 COMPOSITlON/INFORMATION ON INGREDIENTS OSHA Airborne Particulate ACGIH Airborne Permissible Exposure Limit Particulate Threshold Ingredient CAS (PEL, TWAI) Limit Value (TLV, TWAI) Propanc 74-98-6 Not Estahiished Not Established Isobutane 75-28-5 Not Established Not Established Benzyl Alcohol 100-51-6 Not Established Not Established Isopropyl Alcohol 67-63-0 Not Established Not Established PVP 9003-39-8 Not Established Not Estabhshed Date Received: APR - 9 2010 Grafco@AEROCELL Rev. A I'age I of 4 Original Submittal . . II 3.0 HEALTH HAZARDS IDENTIFICATlON II Eye Effects: Irritant Skin Effects: None Systemic Effects: None II 4.0 FIRST AID MEASURES ~ Icye Contact: Flush with water. If irritation persists, gel medical attention. Skin Contact: Wipc oll. Will not damage skin. Inhalation: Intentional misllse by deliberately concelltr~tillg and inhaling contents can be harmful or fatal. I f breathing is affected by vapor inhalation, remove patient to hesh air~ get emergency medical attention, administer al1ificial respiration andlor oxygen. II 5.0 FIRE FIGHTlNG MEASURES II Flammability Classitication: Flammable Aerosol Levell! Extinguishing Media: Water, C02. Dry chemical, Foam Unusual Fire and Explosion Hazards: Aerosol exposed to high temperatures will rupture, rocket and may cause secondary explosion. Fire Fighting Procedures: Copious amounts of water must be applied to reduce temperatures or any inventory not directly invoived in the fire. II 6.0 ACCIDENTAL RELEASE MEASURES 11 Steps to be Taken in Case Material is Released of Spilled: Large spiils or punctures should be well-ventilated. Air movement to dilute leaking gases is essential. Avoid ignition sources. Turn off electric power to area. Date Received: APR - 9 2010 Grafco@ AEROCELL Re\'. A Page 2 of 4 Original Submittal . . II 7.0 HANDLING AND STORAGE II Storage Temperature aud Pressure: Store in a cool, dry, wcll-ventiiated area. Store as a flammable aerosol Level 2 Other Precautions: Warehousing should be in comphanee with locaL state and federal codes. 8.0 EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Gloves: None. Eye Protcctiou: None. Other Protective Clothing or Equipment: None. II 9.0 PHYSICAL AND CHEMICAL PROPERTIES II Boiling Point: 170010 Vapor Pressure (mm Hg): @700F Vapor Deusity (AIR = I): 1.9188 Melting Point: N/ A Appearance and Odor: Clear Spray Freezing Point: N/A Specific Gravity (H20 = I): Product 0.797 Evaporation Rate: > I Solubility in water: Solubie II 10.0 STABILITY AND REACTIVITY II Stability: Stable Conditions to avoid: Applications to hot surt'lces. Storage above 120 F. Exposure to open flame. Hazardous Decomposition: Open flames can cause thermal degradation with the evolution of hydrogen chloride. Hazardous Polymerizatiou: Will Not Occur. II 11.0 TOXICOLOGICAL INFORMATION II No data was available. Date Received: Grafco@ AEROCELL Rev. A Page 3 of 4 APR - 9 2010 Original Submittal . . II I2.0 ECOLOGICAL INFORMATION II No data was availahle. II 13.0 DISPOSAL CONSIDERATIONS II Waste Disposal Method: Dispose of in accordance with applicabie federal, state, and iocal regulations. II 14.0 TRANSPORT INFORMATION II Consumer commodity. ORM-f) II 15.0 REGULATORY INFORMATION II NON-HAZARDOUS MATERIALS CONTAINED IN THIS PRODUCT II 16.0 OTHER INFORMATION II All information, recommendations, and suggestions appearing herein concerning the product are based upon data believed to be reliable. It is the user's responsibility to determine the safety, toxicity, and suitabiiity for their own use of the product described herein, and to compiy with ali applicable regulations. Since the actual use by others is beyond the MSDS devcioper's control, no guarantee, expressed or implied is made by GF Health Products, Inc. as to the effects of such use, the results to bc obtained or the safety and toxicity of the product nor does GF Health Products, Inc. assume any liability arising out of Lise by others of the product referred to herein. This MSDS is not intended as al license to operate under, or recommendation to infringe on, any patents. Appropriate warnings and safe handling procedures should be provided handlers and users. Note: CHEMTREC and NATIONAL RESPONSE CENTER emergency telephone numbers are to be used only in the event of CHEMICAL EMERGENCIES involving a spill, leak, tire, exposure, or accident involving chemicals. All non-emergency qucstions should be directed to GF Health Products, Inc. for assistance. PREPARED BY: CF Health Products, Inc. Rcvision No.: A Date: 08/13/03 SUPERSEDES MSDS DATED: N/A Date Received: Crafco@ AEROCELL Rev. A Page 4 of 4 APR - 9 2010 Original Submittal F01l11alin, 10% v/v Solution, Neutlecd . Page I of? .--.----.-.-,-,.- --^~~~~-,_._~,--_.. ._"----~~---....-_....~..^._..._---"~- MSDS Number: F5605 * * * * * E.t.Tcctive Dale: /1121/08 * * * * * Supercede.~'. 03/24/06 w."_,.'_"'~_"_""'. __ __~__."_.__. -----.----~-...__.-~--.--'~~- _._-,"_.._~----,.~,-,.__.._-----_..._._~,- ""_",,,*,~"',~,,,,,,,,,,~._.,..._.=___~_____~~'~_~=--_'_._"*"~_~"""'_'._'W",^,,_~__~"''' ?4"HQU( E")(lrff'l(l~Y felepho:1~~ 1lCS..ti!>!j.7;tl>1 CHt;'I.;1Af.C: !-MD-414-'UOO I MSDS I Material Safety Data Sheet / lit4$?, ,~ J.T.Baker ~ r;iI:ioo~1 ni!!I;:t1I:1~~ inCnltiidil C,ll,NUl~{:1 /;13.~";l$''''5G6 Qua,ide U,S. fmd CiH\>~dfl Cl'il'mlltc 703.527.J€Il1 .l='r<Jn1: Mnlllnc.:krodr Bllker, Inc, 222 Hod School Lonc Phillipsburg. NJ 08.SS5 IT l Mallinckrodr ~ J CHEMIC,\L<; . U01-tt f';HF.I.nf;::r::;, :~:"H!' fG ,),-,_j :-fn:i';"lp,~l FMpr.:rrA (:~:-t.-i'r <lm'~'1i12r..wmJmb"C f':; hi; ~~.~'~\,~,~Y}~~~~ ;:~~~'~'t~~~::;;~:;-:::,~'7,\'";~;~::~~,~' h.ctJi<.;ir,;; .~~~,;::,~j:; '\117;;jII'CF1('-;~;J.Hi,;;'/ -:;"..n::c;;lcr;", ~~)oi.lld be' ,j;IJ..,;;ttd 10 Cw:..1::mc! SP-Vi::2 F;;:..rJ0,.5~i2.2!}Jn :01 aSl;isi.tJl'i;0. .~_~_---,--__~___.-~____m___.~_~_____m~__~_m"__~-_~~__~"__-'~~__~_.~~~____~__m~_'-_'__'_~~~~_M__~ Formalin, 1 W1t1 v/v Solution, Neutralized 1. Product Identification S~'nonYl1ls: None CAS No., 50-00-0 i\'1olecular 'Veight: Not :ipplicable to mixtures. Chemical FormulJl: Not applic<lble to mixtures. Product Codes: J.T. B,ker: M518 Mallinckrodt: [058 w____~__~____ ."_...._~__.._._' m___~____.._..m__..__..__._..___.._..__~_.____._.._...._____..".... ,..____mmm___..~.._.........._m__m_'''''''___-~__~'__~__'___'~ 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ Formaldehyde Methyl Alcohol Water 50-00-0 67-56-1 7732-18-5 3 - 4% 1 - 1. 5% 94 - 96% Yes Yes No Date Received: _______.._.-______.._.,___.._._..._ _ __~~~_________.____..m_M_..... _..~~_____.__^..__ ----.--~~-.-..--.-.. ---------APR ;:;-91010 3. Hazards Identification Original Submittal Emergency Overview DANGER! MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CAUSES lRRITA TION TO SKIN, EYES AND RESPlRA TORY TRACT. STRONG SENSITIZER. MAY CAUSE BLINDNESS. COMBUSTIBLE LIQUID AND VAPOR. SUSPECT CANCER HAZARD. CONT AINS FORMALDEHYDE WHICH MAY CAUSE CANCER. Risk of cancer depends upon duration alld level of exposure. httn:/ /www.itbaker.com/msds/englishhtml/F5605.htm 4/8/2010 Formalin, 10% v/v SolutiOl.utralized . Page 2 of7 SAF-T-DAT A(tm) Ratings (Provided here for your convenience) ____________________~______________________________n____________n________________________________________ Health Rating: 3 - Severe (Cancer Causing) Flammability Rating: 2 - Moderate Reactivity Rating: 2 - Moderate Contact Rating: 3 - Severe (Life) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Cude: Blue (HC3lth) __________________________~__________n___________________u______ ---------------------------------------- Potcntiall-lcalth Effects The perception offofmaldchyde by odor and eye irritation becomes less sensitive with time as one adapts to fommldehydc. This can lead to overexposure if a worker is relying on formaldehyde's warning properties to alert him or her to the potenlial for exposure Inhalation: 1\1ay cause sore throat, coughing, and shortness of breath. Causes irrit<ltion and sensitization of the respiratory tract. Concentrations of 2S to 30 ppm cause severe respiratory tract injury leading to pulmonary edema and pneumonitis. May be fatal in high concentrations. Ingestion: Can cause severe abdominal pain, violent vomiting, headache, and diarrhea. Larger doses may produce decreased body temperature, pain in the digestive tract, shallow respiration, weak irregular pulse, unconsciousness and death. Methanol component affects the optic nerve and may cause blindness. Sldn Cont:lct: Toxic. May cause irritation to skin with redness, pain, and possibly burns. Skin absorption may OCCllr with symptoms paralleling those from ingestion. Formaldehyde is a severe skin irritant nnd sensitizer. Contact causes white discoloration, smarting, cracking unci scaling. Eye Contact: V;pors cause irritation to the eyes with redness. pain, and blurred vision. Higher concentrations or splashes may cause irreversible eye damage. Chronic Exposure: Frequent or prolonged exposure to formaldehyde may cause hypersensitivity lcarling to contact dermatitis. Repeated or prolonged skin contact with formaldehyde may cause an allergic reaction in some people. Vision impairment and enlargement of liver may occur from methanol component. Formaldehyde is a suspected carcinogen (positive animal inhalation studies). Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more sllsceptible to the effects of the substance. Previously exposed persons may have an nl1ergie reaction to future exposures. 4. First Aid Measures Inhalation: Remove to fi-csh air. lfnot breathing, give artificial respiration. If breathing is difficult. give oxygen. Get medical attention illlll1ediately. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth \0 3nunconscious person. Get medical attention immediately. Skin COllt~lCt: ]n case of contact, immediately flush skin with plenty of water for at least 15 minutes while removirig contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. D..ate.B.eceiv.ed~_ S. Fire Fighting Measures APR - 9 2010 Fire: Original Submittal httn' Ilwww.ithaker.com/msds/englishhtml/F5605.htm 4/8/2010 Fonnalin, 10% v/v Solution, NeUtI.,ed . Page 3 0[7 Fbsh point: 85C (185 F) CC Combustible liquid and vapor! Gas vaporizes Crom solution and is flammable in air. Explosion: Above the !lash point, explosive vapor-air mixtures may be formed. Containers may explode when involved in a fire. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event ofa fire, wc;]r full protective clothing and NJOSH-approvcd self-contained breathing apparatus with full faccpiccc operated in the pressure demand or other positive pressure Illode. Water spray may be used to keep fire exposed containers cool. Use watcr spray to blanket fire, cool fire exposed containers, and to flush non-ignited spills or vapors <lway from fire. 6. Accidental Release Measnres Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isol3te hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, caI1h), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable qll~mtitics. The toll free number for the US Coast Guard National Response Center is (800) 424- 8802. 7. Handling and Storage Store in (J tightly closed container. Protect against physical damage. Outside or detached storage is preferred. Inside stor<lgc should be in a standard flammable liquids storage room or cabinet. Separate from oxidizing materials. Storage and use areas should be No Smoking areas. Wear special protective cquipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Protect from freezing. Containers of this materia! may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Date Received: Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): APR .9 20 0.75 ppm (TWA), 2 ppm (STEL), 0.5 ppm (TWA) action level for forn13ldehyde _. 10 200 ppm (TW A) for methanol -ACGIH Threshold Limit Value (TLV): Original Submittal 0.3 pplll Ceiling formaldehyde, Sensitizer, A2 Suspected Human Carcinogen 200 ppm (TWA) 250 ppm (STEL) skin for methanol Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilalioll, A Manllal of Recommellded Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit _is exceeded and engineering controls are not feasible, a full facepiece respirator with a formaldehyde cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-facepiece positive~presslJre, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Irritation also provides warning. For Methanol: If the exposure limit is exceeded and engineering controls are not feasible, wear a supplied air, full-facepiece respirator, airlined hood, or ful1- facepieee self-contained breathing apparatus. Breathing air quality must meet the requirements of the OSHA respiratory protection standard (29CFR 191 0.134). Where respirators are required, you must have a written program covering the basic http://www.jtbaker.com/msds/englishhtmIlFS60S.htm 4/8/2010 FOllllalin, 100;;, V/v SolutiOl.Cutralized . Page 4 0[7 requirements in the OSHA rcspirutor stand;mL These include training. fit testing, medical approval, cleaning, maintenance. c:Jr1ridgc change schedules, clc. See 29CfR 19] 0.134 for details. Skin Protl~ctioll: Wear impervious protective clothing, including boots, gloves, lab coal, apron or coveralls, as appropriate, to prevent skin contact. Eve Protection: U;c chemical sufety goggles and/or J full face shield where splashing is pOSSible. Maintain eye wash fountain and quick- clrench facilities in work area. Other Control J\'leasurcs: See OSHA Standard for 1110re information on personal protective equipment, engineering and work practice controls. medical surveillance, record keeping, und reporting requiremcnts. (29 CFR 1910.1048) __...~__.._.._.^ ^ _..__.~__"M'_____"__-e"""'__~____'_ _--,.--^.___.__.-..,-,~..__.__.:___...,~-,---~.~.._____~___'_~ __~_'''''''''''O--''_''_'__'____.'_^~_ -- ._--~ 9. Physical and Chemical Properties Appeanlncc: Clear, colorless liquid. Odor: Pungent odor. Soluhility: Complete (100%) Specifit Gr:wity: 1.09 I'll: No information found. (~I Volatiles hy volume@ 21 C (701"): 100 Boiling Point: CD looe (ca. 2121') Melting Point: ca. oe (ca. 321') ""POI- Density (AiI=I): Essentially the samc llS water. Vapor Pressure (mm I-Ig): Essentially the same as water. E\'allOratioll Rate (BuAc=I): Essentially the same as water. 10, Stability and Reactivity Stahility: Stable under ordinary conditions of lIse and storage. Ilazanlotls Decomposition Products: May form carbon dioxide, carbon monoxide, and formaldehyde when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatihilities: Incompatible \",ilh oxidi:;.:ing agents and alkalis. Reacts eXplosively with nitrogen dioxide at ca. 180C (356F). Reacts violently with pcrchloric acid, perchloric acid-aniline mixtures, and nitromethane. Reaction with hydrochloric acid may form bis-chloromethyl.ether, an OSHA regulated carcinogen. Conditions to Avoid: HeDt. flames, ignition sources and incompatibles. Date Received: _._.-~--~._-~~_.~~--~."--~~-----~--_.,-,~~ ---APR-~9-2010 11. Toxicological Information Original Submittal Formaldehyde: Oral rat LDSO: 100 mg/kg; skin rabbit LDSO: 270 uLlkg, Irritation data: eye, rabbit, 7S0ug Severe; Inhalation rat LCSO: 203 rng/m3; investigated as a tumorigen, mutagen, reproductive effector; Cancer Status: an OSHA http://\vww.jtbaker.com/msds/cnglishhtm I/F 5605. htm 4/8/2010 Fomla1in, 10% v/v Solution, Neutl,ed . Page5ol"7 regulated carcinogen. Methanol: oral rat LD50: 5628 mg/kg; inhalation rnt LeSO: 64000 ppm/41-1; skin rabbit LD50: 15800 mg/kg; investigated as a tumorigen, mutagen, reproductive effector. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARe Category ------------------------------------ Formaldehyde (50-00-0) Metllyl Alcohol (67-56-1) Water (7732-J8-5) No Ho No Yes No No 2A None None 12. Ecological Information Environmental Fate: The following sti.ltcments refer to the environmental fate of formaldehyde. \Vhen released into the soil. this material is expected to leach into groundwater. When released into water, this material is expected to readily biodegrade. When released into water, this material is not expected to evaporate significantly. This material is not expected to significantly bioaccumulatc. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. \Vhen released into the air, this material is expected to be readily dcgraded by photolysis. Whcn released into the air, this material is expected to be readily removcd from the atmosphere by dry and wct depusition. When released into the air, this material is expected to have n half-life of less than I day_ The followmg statements refer to the environmental fate. of methanol. When released inio the soil, this material is expected to readily biodegrade. \Vhen released into the soli, this material is expected to leach into groundwater. \Vhcll released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to readily biodegrade. When released into the water, this material is expected to havc a half~life between] and 10 days. When released into the air, this material is expected to exist in the aerosol phase with a short h<:l1f-lik When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl wdicals. When released into the air, this material is expected 10 be readily removed from the atmosphere by wet deposition. \Vhen released into air, this material is expected to have a half-life between 10 and 30 days. Environmental Toxicity: The following toxicity information is for the formaldehyde portion. This material is expected to be slightly toxic to aquatic life. The LC50/96-hour values for fish are between 10 and 100 mg/1. The methanol portion is expected to be slightly toxic to aquatic life. The LC50/96-hour values for fish arc between 1 nand 100 mg/l. _ __.._~_~._,~,___~___~_._..._."__~..~._~___~.~.__ . ",,__,,___".'_'~'_ _WW"______~._.__ __~".._"_...___.~....__._~.____...w_..__~'~___...~ 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility Processing, llse or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Date Received: Not regulated. APR4-201O---- 15. Regulatory Information Original Submittal --------\Chelnical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- http://www.jtbaker.com/msds/englishhtml/F5605.htm 4/8/2010 F0n11alin, ] 0% v/v Sollltiw1\lelltralized . Page 6 01'7 Formaldehyde (50-00-0) Methyl Alcohol (67-5G-l) Water (7732-18-5) Yes Yes Yes Yes Yes Ye~:; Yes Y'2S Yes Yes Ye~ Yes --------\Chemical Inventory Status - Part 2\--------------------------------- --Canada-- Ingredient Korea DSL NDSL Phil. Formaldehyde (50-DO-D) Methyl Alcohol (67-56-1) Water (7732-18-5) Yes Yes Yes Yes Yes Yes No No No Yes Yes Yes --------\Federal, State & Internati.onal Regulations - -Sl\RA 302- RQ TPQ Part 1\---------------- ------SARA 313------ List Chemical Catg. Ingredient Formaldehyde (50-00-0) Methyl Alcohol (67-56-1) Water (7732-18-5) 100 No t'lo 500 No No Yes Yes No No No No --------\Federal, State & International Regulations - Ingredient CERCLA Part 2\---------------- -RCRA- -TSCA- 261.33 8(d) Formaldehyde (50-00-,-0) lvlethy.l AJcoho.l (67-56-.l) Water (7732-18-5) 100 5000 ~!o U122 015<1 No Ho No No Chemical I'Jeapons Convention: No TSCA 12 (b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No ReacLi vi ty: No ' (Mixture / Liquid) \\'ARNING: TillS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. AlIstrali~ln Ilazchcm Code: None allocated. Poison Schedule: None allocated. WII~IIS: This MSDS has bccn prepared according 10 the hazard criteria oCthe Controlled Products Regulations (CPR) and the ['vlSDS contains all orthe information required by lhc CPR. 16. Other Information NFPA Ratings: Health: 2 Flammability: 2 Reactivity: 0 LabellIazard \Varning: DANGERI MA Y BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CA USES I RRIT ATION TO SKIN, EYES AND RESPIRA TORY TRACT. STRONG SENSITIZER. MA Y CAUSE I3L1NDNESS. COMBUSTIBLE LIQUID AND VAPOR. SUSPECT CANCER HAZARD. CONTAINS FORMALDEHYDE WHICH MA Y CAUSE CANCER. Risk of cancer depends upon duration and level or exposure. Label Pn~calltions: Keep away from heat, sparks and flame. Do not breathe vapor. Keep container closed. Use only with adequate vcntilation. Wash thoroughly after handling. Do not gct in eyes, on skin, or on clothing. Physical and health hazard information is available frolll employer and from lll;]terial safety data sheets. Label FirstAid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by lllouth to an unconscious person. If inhaled, remove to fresh air. I r not breathing, give arti ficial rcspiration. If breathing is difficult, give oxygen. In case of contact, immediately nush eyes or skin with plenty of water for at least 15 minutes. In all cases get medical attention immediately. D te Received: Product Use: a Laboratory Reagent. Revision Information: No Changes. APR -; 9 2010 http://w\V\V.jtbaker.com/msds/englishhtml/F5605.htm Original Submittal 4/8/2010 Fomlalin, 10% v/v Soiution, Neut.ed . Page 70f7 Disclaimer: *.**.__.._***......*.*_*.***.*__.*.**.*.....**.***......e*...e.*****_*...*__**....*..*._*...**** Mallinckrodt Bllkcr, Inc. provides the information contained herein in good faith but makes 110 representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the apl}ropriatc l)rCcautionary handling of the material by a properly tnlincd person using this l)rodllet. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLlNCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY. FITNESS FOR A PARTICULAR PURPOSE WITlI RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WIIICII TIlE INFORMATION REFERS. ACCORDINGLY, MALLlNCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESIJLTlNG FROM USE OF OR RELIANCE UPON TillS INFORMATION. *.****......*-****-***.*....*--_..*.**.**...*.*.*.*.*.*.*..***.._.........*.*..*.*...***.***..*. Prepared by: Rnvironmcntall:lcahh & Safety Phone Number (314) 654-1600 (USA.) Date Received: APR - 9 2010 Original Submittal 1...++......"",,,,,,' ;th"\.r",,,- rvn"""/l"nC'~C'/pnO"l;C'"hhhnl/p"hn" "htn, Ll/R/?n10 . Material Safety Data Sheet Science Stuff, Inc. 1104 Newport Ave Austin, TX 78753 ISection 1 Identification Product IC2360 Number: , I Health: Flammabilit Reactivit Hazard Rating: I Least Slight Moderate High Extreme o 1 2 3 4 I NA ~ Not Applicable NE ~ Not I Established , Product Name: Potassium Hydroxide 10 % wjv Trade/Chemical I Synonyms , IFormula: IIN/A IRTEC5: IINONE ICA.s Ilsee Below ISection 2 Component Mixture rs;;;:;;]1 II IDD Exposure ~ Component CAS Number % ~ Limits: [] ff~~"n'[~ed ASTM CA5# 7732-18S/Balance Ilv/v I ~~t~~IiShed If=l Potassium [CASh 1310-58-31~lw/v I OSHA PEL 2 UHYdroxlde. .~ mg/mf ]Section 3 Hazard Identification (Also see section 11) Causes severe irritation and burns. May Be harmful if swallowed. Avoid breathing vapor or dust. Use with adequate ventilation. Avoid contact with eyes, skin, and clothes. Wash thoroughly after handling. Keep container closed. ISection 4 First Aid Measures Causes severe irritation and burns. May Be harmful if swallowed. Avoid breathing vapor or dust. Use with adequate ventilation. Avoid contact with eyes, skin, and clothes. Wash thoroughly after handling. Keep container closed. FIRST AID: CALL A PHYSICIAN. SKIN: In case of contact, immediately flush skin with water for at least 15 minutes while removing contaminated clothing and shoes. Thoroughly clean clothing and shoes before reuse. EYES: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen INGESTION: Give several glasses of milk or water. Vomiting may occur spontaneously, but DO NOT INDUCE! Never give anything by mouth to an unconscious person. ISectionS Fire Fighting Measures Fire Extinguisher Type: Fire/Explosion Hazards: Any means suitable for extinguishing surrounding fire. Negligible fire hazard when exposed to heat or flame. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin Fire Fighting Procedure: h up:li www.sciencestuff.com/msds/C2360.htm I . u-s.... .- '-',.:... . 3 o o Phone (512) 837-6020 Chemtrec 800-424-9300 24 Hour Emergency Assistance ISection 6 Accidental Release Measures Take up with sand or other inert material and in conatier for later disposal. Neutralize with \ acid. !Section 7 Handling and Storage Store in a cool dry place. Do not get in eyes, skin, on clothing. \:Vash thoroughly after hand Keep containers tightly closed. Section 8 Ex osure Controls & Personal Prote< Respiratory Protection: None required Mechanical: Hand NIOSf I I' Protection: Appro' Ventilation: Glove, Local Eye Splasl Exhaust:!7 Protection: Goggl, Other Protective Equipment: Wear appropriat( c10thin to revent skin ex osure Section 9 Physical and Chemical Properties Inforr not availa Information 5 'f' t pecl IC no G' '1 bl ravlty aval a e Information Percent not Volatile by available Volume: Information E r not vapora Ion available Rate: Information E . not vaporatlon '1 bl Standard: aval a e Solubility in Soluble Water: Colorless Appearance d I ' o or ess and Odor: I' 'd IqUI Inforr not availa Melting Point: Boiling Point: >90 Vapor Pressure: Vapor Density: Auto ignition Not Temperature: applic Lower Flamm. in Air: Limit Not applic Upper Flamm. in Air: Flash Point: Not flammable Limit Not applic [Section 10 Stability and Reactivity Informatio Stabilit : Stable Cond!tio.ns to Avoid:. Moistur y may IgnIte combustibles. Materials to Avoid: Acids, Acrolein, alcohols, aluminum, Chlorine Halogenates Hazardous Decomposition Products: None known Hazardous Polymerization: Not reported to oc under normal conditions Condition to Av 'ved: ISection 11 Additional Information I APR - ~ 201U Original Submittal 4/8/20 I 0 MSDS :: Potassium Hydroxide lOew/v . Page 2 of2 II and clothing. II DANGER! CORROSIVE! Reacts with water to generate heat. (orosive by skin contact, eye contact, inhalation, and ingestion. Target arg; No data available. Toxic by ingestion. At incrE risk from exposure are persons with preexisti skin and eye conditions. DOT Classification: Potassium Hydroxide Solu 8, UN1814, PG II DOT regulations may change from time to tilT Please consult the most recent version of the relevant regulations. Revision Date Entered: No:O.l 9/1/2006 Approved WPF The information contained herein is believed to be accurale and is offered in good failh fOf the user's consider<Jlion and investigation. No warranty is expressed or implied regarding (he completeness or accur;;JCY 01 (his information, whether originating from Science Stufr, Inc. or from an alternate source. Users of this material should satisly themselves by independent invesligation of currenl scientific and medical information lhat !Ills malerial may be safely handled. Date Received: APR - 9 2010 original submittal nffn.//w\V\:J,J ~r.ip;nr,P:.~hlff ('.()I11/m~ds./C).l(}()_html 4IRn.n]n Liquid Nitrogen Material ety Data Sheet (MSDS) . Page 1 of6 Liquid Nitrogen MATERIAL SAFETY DATA SHEET SECTIQr,u .J'ROD_U_CTJDe:i'lI!FIC.o.IIQN PRODUCT NAME: Nitrogen, refrigerated liquid CHEMICAL NAME: Nitrogen FORMULA: N, SYNONYMS: Liquid Nitrogen, UN, Cryogenic Liquid Nitrogen, Nitrogen MAN UF ACTU RER: ft.. irJ:rodl.Lc..ts,_and_CJJJnn.icals,Jnc. 7201 Hamilton Boulevard Allentown, PA 18195-1501 PRODUCT INFORMATION: 1-800-752-1597 MSDS NUMBER: 1041 REVISION: 5 REVISION DATE: July 1995" SE{:I!O_i'l_2._C9Mf'.QSIIIOi'lfINI'9RM.o.ILQIILPl'UNGRe:QlEi'lIS Nitrogen is sold as pure product> 99%. CAS NUMBER: 7727-37-9 EXPOSURE LIMITS:. OSHA: Not established ACGIH: Simple asphyxiant SEC]"JO_i'l_3.W~Z.o.RD_I[)Ei'lIII'IC.o.TIOi'l EMERGENCY OVERVIEW Liquid nitrogen is a colorless, odorless. extremely cold liquid and gas under pressure. 1t can cause rapid suffocation when concentrations are sufficient to reduce oxygen levels below 19.5%. Self Contained Breathing Apparatus (SCBA) may be required. Contact with liquid or cold vapors can cause severe frostbite. Cold vapors in the air will appear as a white fog due to condensation of moisture. While this may indicate the presence of the gas it should not be used to determine its concentration in the atmosphere. Oxygen concentrations must be monitored in the release area. All cryogenic liquids produce large volumes of gas when they vaporize. One volume of liquid nitrogen will expand to produce 696.5 equivalent volumes of gas. \ EMERGENCY TELEPHONE NUMBERS: 800-523-9374 Continental U.S., Canada and Puerto Rico 610-481-7711 other locations POTENTIAL HEALTH EFFECTS INFORMATION: Date Received: INHALATION: Simple asphyxiant. APR - 9 2010 EYE CONTACT; Tissue freezing and severe cryogenic burns if contacted into eyes. Original Submittal SKIN CONTACT: Tissue freezing and severe cryogenic burn of skin. http://stores.biochem.uiowa.edu/Pages/ln2msds.htm 4/8/2010 Liquid Nitrogen Material Safety. Sheet (MSDS) . Page 2 of6 CHRONIC EFFECTS: None established. EXPOSURE INFORMATION: ROUTE OF ENTRY: Inhalation TARGET ORGANS: None EFFECT: Asphyxiation (suffocation) SYMPTOMS: Exposure to an oxygen deficient atmosphere (<19.5%) may cause dizziness, drowsiness, nausea, vomiting, excess salivation, diminished mental alertness, Joss of consciousness and death. Exposure to atmospheres containing 8-10% or less oxygen will quickly bring about unconsciousness without warning, leaving individuals unable to help or protect themselves. Lack of sufficient oxygen can cause serious injury or death. Skin contact with liquid nitrogen can cause tissue freezing, resulting in Severe burns. The burns are caused by th~ extremely low temperature of the cryogenic liquid and not the result of chemical action. Skin may appear red with the formation of blisters. In cases that involve prolonged or severe exposure, tissue may freeze and have a waxy or yellow appearance. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None CARCINOGENIC POTENTIAL: Nitrogen is not listed by NTP, OSHA or IARC as a carcinogen or suspected carcinogen. SECTION 4.J'IRST.<IIQ INHALATION: Persons suffering from lack of oxygen should be moved to fresh air. If victim is not breathing, administer artificial respiration. If breathing is difficult, administer oxygen. Obtain prompt medical attention. SKIN CONTACT: Remove any clothing that may restrict circulation to frozen area. Do not rub frozen parts as tissue damage may result. As soon as practical place the affected area in a warm water bath which has a temperature not to exceed 1050F (40oC). Never use dry heat. Call a physician as soon as possible. Frozen tissue is painless and appears waxy with a possible yellow color. It will become swollen, painful, and prone to infection when thawed. If the frozen part of the body has been thawed, cover the area with dry sterile dressing with a large bulky protective covering, pending medical care. In case of massive exposure, remove clothing while showering with warm water. Call a physician. EYE CONTACT: For exposure to liquid, immediately warm frostbite area with warm water (not to exceed 1050F). SEC11Qt>t5._EIRE.<INILE;)(~LO_SION FLASH POINT: AUTO IGNITION: FLAMMABLE LIMIT: Not Applicable Nonflammable Nonflammable EXTINGUISHING MEDIA: Nitrogen is nonflammable and does not support combustion. Use extinguishing media appropriate for the surrounding fire. HAZARDOUS COMBUSTION PRODUCTS: None SPECIAL FIRE FIGHTING INSTRUCTIONS: Nitrogen is a simple asphyxiant. If possible, remove nitrogen containers from fire area or cool with water. Do not direct water spray at the container vent. Self contained breathing apparatus may be required for rescue workers. Evacuate the area. UNUSUAL FIRE AND EXPLOSION HAZARDS: Liquid nitrogen when spilled will vaporize rapidly forming an oxygen deficient vapor cloud. Evacuate this area. Pressure in a container can build up due to heat and it may rupture if pressure relief devices should fail to function. Contact with cold liquid or gaseous oxygen may cause frostbite. Visibility may be obscured in its vapor cloud. ~E_CJIOJ'L6cACJ;IDENT AL_RELEA&E_MElISURES Date Received: Evacuate aU personnel .from affected area. In~re~se ventilation to release area and monitor oxygen level. Us~ appro~~iatAPJt~t9 20tO equipment (SCBA). To Increase rate of vaponzatlon spray large amounts of water on to the spill from an upWind pOSition. If leak IS from container or it's valve, call the Alr Products emergency telephone number. Do fjQI spray water directly at leak. If leak is in user's system close Original Submittal http://stores.biochem.uiowa.edu/Pages/ln2msds . h tm 4/R/2010 Liquid Nitrogen Material ety Data Sheet (MSDS) . Page3of6 cylinder valve and vent pressure before attempting repairs. l>E_GJIOJ'LZ._H,<\t'lPJ,ING AND_S.J.P.RAGE STORAGE: Store and use with adequate ventilation. Do not store in a confined space. Cryogenic containers are-equipped with pressure relief devices to control internal pressure. Under normal conditions these containers will periodically vent product. Do not plug, remove, or tamper with pressure relief device. HANDLING: Never allow any unprotected part of the body to touch uninsulated pipes or vessels which contain cryogenic fluids. The extremely cold metal will cause the flesh to stick fast and tear when one attempts to withdraw from it. Use a suitable hand truck for container movement. Containers shall be handled and stored in an upright position. Do not drop, tip, or roll containers on their sides. Do not remove or interchange connections. If user experiences any difficulty operating container valve or with container connections discontinue use and contact supplier. Use the proper connection. !LO NOT U_S.E ADAPTERS. Use piping and equipment adequately designed to withstand pressures to be encountered. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. To prevent cryogenic liquids or cold gas from being trapped in piping between valves the piping shall be equipped with pressure relief devices. Only transfer lines designed for cryogenic liquids shall be used. Some metals such as carbon steel may become brittle at low temperatures, will easily fracture and should not be used with cryogenic liquids. It is recommended that all vents be piped to the exterior of the building. SPECIAL PRECAUTIONS: Some metals, such as carbon steel, may become brittle and fracture at low temperatures. For additional information concerning storage and handling refer to Compressed Gas Association pamphlet p~ 12 Safe Handling of Cryogenic Liquids available from the Compressed Gas t\ssociation, Inc., 1725 Jefferson Davis Highway, Arlington, VA 22202-4102 Telephone (703) 412- 0900. SE_G.Ilor,U.J~E~S.QN,!l.L.e~PJECTION f EXPOS_UBE~G.QN:rRQL ENGINEERING CONTROLS: Natural or mechanical ventilation to prevent oxygen deficient atmospheres under 19.5'% oxygen. RESPIRATORY PROTECTION: General Use: None required. Emergency Use: Self contained breathing apparatus (SCBA) or positive pressure airline with mask and escape pack are to be used in oxygen deficient atmosphere. Respirators will not function. PROTECTIVE GLOVES: Loose fitting thermal insulated or leather gloves. EYE PROTECTION: Full face shield and safety glasses are recommended. OTHER PROTECTIVE EQUIPMENT: Safety shoes when handling containers. Long sleeve shirts and trousers without cuffs. SECIIOt,t9._eI:lY_SIGAL 8ND_CI:lEMIG,!l.LeBOf'E~IIES APPEARANCE: Colorless, cryogenic liquid ODOR: Odorless MOLECULAR WEIGHT: 28.01 BOILING POINT 11 "ml: -320.4' F (-195.8 0 C) Date Received: SPECIFIC GRAVITY (Air = 1): 0.967 APR - 9 2010 FREEZING POINT/MELTING POINT: _345.80 F (-209.9 0 C) VAPOR PRESSURE (AT 20 0 C): Not applicable Original Submittal http://stores.biochem.uiowa.edu/Pages/ln2msds.htm 4/8/2010 Liquid Nitrogen Material SafetY.1 Sheet (MSDS) . Page 4 of 6 GAS DENSITY {At 70 " F (21.1 0 C) and 1 AIm}: 0.072 Ib/ft3 (1.153 kg/m3) SOLUBILITY IN WATER (VoINol at 32 0 F /0 0 C)): 0.023 EXPANSION RATIO: (For liquid to gas) at 70 0 F (21.1 0 C): 1 to 696.5 SECTIOtUO._BEACJ]),fIH_'-SIABILln: CHEMICAL STABILITY: Stable CONDtTIONS TO AVOID: None INCOMPATIBILITY: None HAZARDOUS DECOMPOSITION PRODUCTS: None HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11. TO)(IC_QLO~JCAL1NFORMA]"IOJ~ Nitrogen is a simple asphyxiant. SECTIONJ~EC_O_L_O_GLCALIN(ORMA riOI'! The atmosphere contains approximately 78% nitrogen. No adverse ecological effects are expected. Nitrogen does not contaIn any Class lor Class II ozone depleting chemicals. Nitrogen is not listed as a marine pollutant by DOT 49 CFR SE~TION_13.J:!Ls~QSAL UNUSED PRODUCTfEMPTY CONTAINER: Return container and unused product to supplier. Do not attempt to dispose of unused product. DISPOSAL: For emergency disposal, discharge slowly to the atmosphere in a well ventilated area or outdoors. S.EC.ILOl'!iLTRANSPORIAILON DOT HAZARD CLASS: 2.2 DOT SHIPPING lABEl: Nonflammable Gas DOT SHIPPING NAME: Nitrogen, Refrigerated Liquid IDENTIFICATION NUMBER: UN1977 REPORTABLE QUANTITY (RQ): None SPECIAL SHIPPING INFORMATION: Containers should be transported in a secure upright position in a well ventilated truck. Never transport in passenger compartment of a vehicle. SEC.IION 15. REG_UJ..iI.IORY INFQRMATlON U.S. FEDERAL REGULATIONS: CERClA: Comprehensive Environmental Response, Compensation, and Liability Act of 1980 requires notification to the National Response Center of a release of quantities of hazardous substances equal to or greater than the reportable quantities (RQ) in 40 CFR 302.4. CERCLA REPORTABLE QUANTITY: None Date Received: SARA TITLE III: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 APR - 9 2010 Original Submittal http://stores.biochem.uiowa.edu/Pages/ln2msds.htm 4/Rl7n 1 n Liquid Nitrogen Material.ty Data Sheet (MSDS) . Page 5 of6 SECTION 302: Requires emergency planning based on threshold planning quantities (TPQ) and release reporting based on reportable quantities (RQ) of EPA's extremely hazardous substances (40 CFR 355). Nitrogen is not listed as an Extremely Hazardous Substance. SECTIONS 311/312: Require submission of material safety data sheets (MSDSs) and chemical inventory reporting with identification of EPA defined hazard classes. The hazard classes fOf this product are: IMMEDIATE HEALTH: Yes PRESSURE: Yes DELAYED HEALTH: No REACTIVITY: No FIRE: No SECTION 313: Requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372. This information should be included in all MSDSs that are copied and distributed for this material. Nitrogen is not listed as a toxic chemical. TOXIC SUBSTANCE CONTROL ACT (TSCA): Nitrogen is listed on the TSCA inventory. Environmental Protection Agency (EPA) . 40 CFR Part 68: Risk Management for Chemical Accident Release Prevention. Nitrogen is not listed as a regulated substance. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) 29 CFR 1910.119: Process Safety Management of Highly Hazardous Chemicals. Requires facilities to develop a process safety management program based on Threshold Quantities (TQ) of tlighly hazardous chemicals. Nitrogen is not listed as a Highly Hazardous Chemical. STATE REGULATIONS: CALIFORNIA: . Proposition 65:This product does NOT contain any listed substances which the State of California requires warning under this statute. SCAQMD Rule: VQC = Not applicable SECT1oNJ6.JillPPLEMENJ:""l.,lIIlJ:oBM""TIQII! NFPA RATINGS: HMIS RATINGS: HEALTH: 3 HEALTH: 3 FLAMMABILITY: 0 FLAMMABILITY: 0 REACTIVITY: 0 REACTIVITY: 0 Date Received: SPECIAL: SA' 'Compressed Gas AssoCiation recommendation 10 designate simple asphyxiant. APR - 9 2010 u OriginaLSubmiJtal http://stores.biochem.lIiowa.cdll/Pages/ln2msds.htm 4/R/7()] () Liquid Nitrogen Material Safety Data Sheet (MSDS) . . ** Documents with effective dates of July 1995 arid July 1998 are identical in content and either may be used. http://stores. biochel11.uiowa. edu/Pages/]n2l11sds.htl11 Page G of G Date Received: APR ..: 9 2010 Original Submittal 4/8/20] 0 ISOPROPYL RUBB!NG~OHOL 70% MSDS . Page 1 of6 <,...#....~~ .......... MSDS MATERIAL SAFETY DATA SHEET ISOPROPYL RUBBING ALCOHOL 70% I. === Produd Id(~ntification =---= Synonyms: Isopropyl alcohol; see-propyl alcohol; isopropanol: see-propanol: dimethyl carbinol CAS No.: 67-63-0 Molecular '''eight: GO.! 0 Chemical Formula: (CH3)2 CHOH _'___._'_~**'.~~~~_~~_"'~__'*~~__"_'_'U"_'_"" "_"_'""_~'_'___*__"_~_."_"'_'_'_"".m"__",,__,*,___.....~_..u____ 2. ==:::= COll1pusiiiollllnforlllution on Ingrl'diC'llts ==:= I Ingredient II CAS No II Percent II H~IZardolls Ilsopropyl Alcohol 1167630 1170% IIYes IWatcr 117732-18-5 1130% IINo ....__.__._.___________._,.__..M__" __,__",_,_,__*_,_"_,,,*_,~_,,___,_,,_________ ""_"*~__'*'__" M _.~__,__,.__._ J. == naz:lnls hh'lllitic..ltion = Emergency Overview WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALE(). CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. MAYBE HARMFUL IF ABSORBED THROUGH SKIN. MA Y CAUSE IRRITATION TO SKIN. Health Ratmg: 2 - Moderate Flnmmability Rating: 3 - Severe (Flammable)' Reactivity Rating: 2 - Moderate Contact Rating: J - Severe Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Code: Red (flammable) Potentiall-lcalth Effects Inhalation: Inhalation of vapors irritates the respiratory tract. Exposure to high concentrations has a narcotic effect, producing symptoms of dizziness, drowsiness, headache, staggering, unconsciousness and possibly death. Ingestion: Can cause drowsiness, ullconsciollsncss, and death. Gastrointestinal pain, cramps, nausea, vomiting, and djarrhc::J may also result. The sin?lc lethal dose for a human adult = about 250 mls (8 ounces). Date Received: Skm Contact: May calise irri.tatioll with redness and pain_ J'v1ay be nhsorbcd through the skin with possible systemic effects. Eye Contact: APR 9 2010 Vapors cause eye irritation. Splashes cause severe irritation, possible'corneal burns and eye damage. - Chronic Exposure: Original Submittal http://www.hvcl1emical.com/msds/isal-70.l1lm 4/8/20 I 0 ISOPROPYL RUBBING ALCOW 70"/" MSDS . Page 2 of6 Chronic exposure may cause skin effects. Agg,-anltion of Pre-existing Conditions: Pc'rsons with pre-existing skin disorders or impaired liver, kidney, or pulmonary function may be more susceptible to the effects of this agent. .'~_'~_'._~~~"_^'__M_~_'_~_~~_."'______'____,___~_~"~___'~_____~~_ 4. ==First i\id I\'h'<l!'urcs === Inh~llatioll: Remove to fi'csh air Ifnot breathing, give urtificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Give large amounts of water to drink. Never give anything by mouth to all unconscious person. Get medical attention. Skin COllt~lct: Immediately flush skin with plenty of water for at least ]5 minutes. Call a physician if irritation develops. Eve Contact: lI~mediately flush cyes with plenty of\V~ller for ai least 15 minutes, lifting lower and upper eyelids occasionally Get mcdical attention immediately. '~~~'-"~"~~-~-~-'~-'~~'_""~M_~_'~~~~_ 5. = Fire Fighting i\'ll':l~U"C~ === Fire: flash point: 12C (54f) CC Autoignition temperature: 399C (7S0F) Flnl11lllablc limits in air (Yo by volullle: lei: 2.0; uel: 12.7 Listed fire data is for Pure Isopropyl AlcohoL Explosion: Above flash point, vapor-air mix!Urcs arc explosive within flammable ]il11its noted above. Contact with strong oxidizers may causc fire or explosion. Vapors can flow along surfaces to distanl ignition source and flash back. Sensitive to static discharge. Fire Extinguishing J\lcdia; \Vatcr spray, dry chemicuL alcohol loam, or carbon dioxide. Water spray may be used to keep fire exposed containers cool, dilute spills to nonflammablc mixtures, protect personllel attempting to stop leak and disperse vapors. Spcciallnfonnation: In the cvent ofa fire, wear full protective clothing ancl NIOSH-approved self-contained breathing apparatus with full facc:piece operated in the pressure demand or other positive pressure mode. .'-~~._.~_..._.~-,_._'.-._..~_._-._----_ ____.,w__.~__~_______ G. === A,ddl'ntal Rl'Ieasc \lcasurcs === Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section S. Isolate hazard <lrea. Keep unnecessary and unprotec!cd personnel from entering. Contain and recover liquid when possible. Use non- spnrking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and pbcc in a chemicul waste container. Do not LIse combustible materials, sLlch as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disrerse the vapors, to rrotect personnel attempting to stop leak, and to flush spills away from exposures. 7. == Handling and Storage === Protect against physical damage. Store in a coo], dry well-ventilated location, away from any area where the fire haz:lrd may be acute. OLllside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage 31ld use areas should be No Smoking areas. Use non-sparking Iype tools and equipment, including explosion proof ventilation. Containers of this m3terialmay be hazardous when empty since they retain product rcsidues (vapors, ]iquid)~ observe all warnings and precautions listed for the product. Small quantities of peroxides can form on prolonged storage. Exposure to light and/or air significantly incrcases the rate of peroxide formation. If evaporated to a rcsidue, the mixture of peroxides and isopropanol may explode when exposed to heat or shock. Date-Reeeived;-...-- 8. === Exposure Controls /Pcrsonal Protedion == . APR - 9 2010 Airborne Exposure Limits: Original Submittal http://www.hvchemicaI.com/msds/isaI-70.htm 4/R/?0l 0 ISOPROPYL RUBBING .OHOL 70% MSDS . Page 3 of6 For Isopropyl Alcohol (2-Propanol): -OSHA Permissible Exposure Limit (PEL): 4110 ppm (TW A) -ACGIH Threshold Limit Value (TLV): 200 pplll (TWA), 400 ppm (STEL), A4 - not classifiable as a human carcinogen Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can conlrollhe emissions of the conlaminant at its source, preventing dispersion of it into the genera! work area. Please refer to the ACGIH document. Indus/ria! Vell/i/alioll, A fiJ(/lIual (~r Recol/1!/1ended Practices, Illost recent edition, for details. Personal Respirators (NIOSII Approved): If the exposure limit is exceeded, U full f3ccpiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximulll use concentration specified by the appropriate regulatory agency or respirator supplier. whichever is lowest. For emergencit:'s or instances where the exposure levels arc not known, use a full-faeepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Weal: imperviolls protective clothing, including boots, gloves. Jab coal, apron or coveralls. as appropriate, to prevent skin contact. Neoprene and nitrile rubber are recommended materials. Eyc Protection: Use chemical safety goggles and/or a full face shield when' splashing is possible. l'vlaintain eye wash fountain and quick-drench facilities in work area. 9. "'.oc,,=-= PhysicJtl/Chcllli{~al Propertic~ = Appt'ar:lncc: Clear, colorless liquid. Odor: Rubbing alcohoL Solubility: Miscible in water. Spccific GraYity: 1J.79 @ 2IJCl4C pll: No lnform3tioll found i}';f Vohltilcs by \'olume@21C(70F): 100 Boiling Point: 82C (180F) Mt'-lting Point: -89C (-128F) Vapor Density (Air=I): 2.1 Vapor Pressure (rnm Hg): 44 @ 25C (77F) Eyaporation Rate (BIIAc=l): 2.83 10. === Stability and Reactiyity Data === Date Received: Stability: APR Stable under ordinary conditions of use and storage. Heat and sunlight can contribute to instability. - 9 2010 Ilazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerizatiou: . Original Submittal \Vill not OCCLlr. Incompatihilities: Heat, flame, strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, hydrogen-palladium combination, hydrogen peroxicle.sulfuric acid combination, potassium tet1:butoxide, hypochlorous acid, isocyanates, nitrofonll, phosgene, aluminum, oleum and pcrchlorie acid. Conditions to Ayoid: Heat, flames, ignition sources ;:md incompatibles. 1.,...,..,..//",,,,,,,1...,,,...1.,0.....,;.....,,1 .....^....'/m"rl,.,/;,.,,,! i()l.,t...,... A 10/'11\1 1\ ISOPROPYL RUBBING ALCOl. 70% MSDS . Page 4 of6 II. === To_\:icologj(';tllnformation === Oru] fat LD50: 5045 mg/kg; skin rabbit LDSO: 12.8 gm/kg; inhalation fat LCSO: 16,000 ppm/S-hollr; investigated as a tUlTIorigcn, Illutagen, reproductive effector. --------\Cancer Lists\----------------------------------____________________ ---NTP Carcinogen--- Ingredient Known Anticipated rARe Category Isopropyl Alcohol (67-63-0) Water (7732-18-5) No No No No 3 None .----"._~..~_..~----_._._.--'-..---_..~ . ._--_....__.~.~_._.._--,-,- - '-'--'-'--'-"- 12. = Ecologit.'allnformation === Environment::.1 Fate: When released into the soil, this material is expected to quickly cvaporntc. When released into the soil, this material 11l3y leach into groundwater. When released into the soil, this material may biodcgrade to a moderate c:\tenl. When released to water, this material is expected to quickly evapof;lte. When releuscd into the water, this mnterial is expected to have a half-life between I and 10 days. \Vhen released into water, this mafcrialmuy biodegrade to a moderate extent. This material is not expected to significantly bioacculllulate. When rele;lscd into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. \Vhen released into the air, this material is expected to have <l h;llf-life between I and I 0 days. Whcn released into the air, Ihis materiallllay be removed from the atmosphere to a moderate extent by wet deposition. Environmental Toxicity: The LCSO/96-hollr v;llues for fish ;lre over 100 mg/1. This m:.Jteri;l1 is no! expectcd to bc toxic to aquatic life. 13. === DispoS;:11 Considerations === Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA appl'Ovcd incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state cllldlocal requirements. ^~_._._."___m.__.~,~^_~_,_,.__,_~____.._.._'^"...__.__...~~__.__m_,.~__~.___,___ l..t. === MSDS TranspOI"t Information = Domestic (Land, D.O.T.) Proper Shipping Name: rSOPROPANOL Hazard Class: 3 UNINA: UNI219 Packing Group: II Information I-eported for product/size: J55U3 Intemational (Water, I.M.O.) Proper Shipping Name: ISOPROPANOL I-Iazard Class: 3 UN/NA: UNI219 Packing Group: II Information reported for product/size: 355LB Date Received: APR - 9 2010 Original Submittal 15. == Regulator)' fnfonnation === --------\Chemical Inventory Status - Part 1\----------~------------~--------- Ingredient TSCA EC Japan Australia Isopropyl Alcohol (67-63-0) Yes Yes Yes Yes J...f--f-_.lln~~~.. 1_.._L.___;__1 _____I____.J_I:__l '""1" L.. ISOPROPYL RUBBTNG.COJ-JOL 70% MSDS . Page 50[6 Wate~ (7732-18-5) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\------------------------------___ --Canada-- Ingredient Korea DSL NDSL Phil. 1 sopropyl Alcohol (67 - 63-0) Water (7732-18-5) Yes Yes Yes Yes No No Yes Yes --------\E'ederal, Slate & International Regulations - -SARA 302- RQ TPQ Part 1\---------------- ------SARA 313------ List Chemical Catg. Ingredient Isopropyl .Zl..lcohol (67-6]-0) \-Jater (7732-18-~,) No No No No Yes No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA-, -TSCA- Ingredien~ CERCLA 261.33 B(d) Isopropyl .l,U,cohol (67-63-0) Water (7732-18-5) No No No No No No Chemical \'Ieapons Convention: No TSC!1 12 (b): SARA 311/312: Acute: Yes Chronic: Yes Fire: Reactivity: No (Mi;.:ture / Liquid) No CDTA: Yes Pressure: NO No Austr:i1i:lll lIazchem Coue: 2[S12 Poison Schedule: None allocated. WIIMIS: This MSDS has been prepared according 10 the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. --~~_.~.~-~..__.~-~ 16. === Other Information == NF'PA Ratings; Health: 1 Flammability: 3 Reactivity: 0 Label Hazard \\'anling: WARNING' FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO EYES AND RESPIRATORY TRACT AFFECTS CENTRAL NERVOUS SYSTEM. MA Y BE HARMFUL IF ABSORBED THROUGH SKIN. MA Y CAUSE IRRITATION TO SKIN. Label Precautions: Keep away fwm heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handlmg. A voiel breathing V3por or mist A void contact with eyes, skin anel clothing. Label First Aid: If sW<.lllowed, give large amounts of w::l!er to drink. Never give anything by mouth to an unconscious persall. If inhaled, remove to fresh <lir. Ifnot breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing ancl shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent. Date Received: ----~---~--APR~-10ro___-- fji;.;h Val/f)}' .P/"odllct,y, Inc. provide.~..the informat.io~1 contained herein in Foodfaith hut ma~es 110 rep/~f(Mf\~' ~~ab,,"i tal _ , comprehensrveness or accuracy. TillS documellt IS IlItended only as a gUIde to tlte appropriate precaultOlI'r'?,'y IUlIl7f!lIIgojt!te '1mI,"" I'" 0) " properly trained perso/l using this product. Individuals receiving tlte if/jorlllation must exercise Iheir indepelldentjudgmem ill determining its appropriateness/or a particular purpose. hth,.!!",!",,,,, hu....hpIYlT("''l1 ("'n.......I...""A"/;,,,,1 '71l1~4__ ISOPROPYL RUBBING ALCor., 70% MSDS . Page 6 of6 HIGH V ALLEY PRODUCTS, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, fNCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDlNGL Y, HIGH VALLEY PRODUCTS, INC WILL NOT 1310 RESPONS1l3LE FOR DAMAGES RloSULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. Revision Dale 3/20 I () Date Received: APR - 9 2010 Original Submittal htt"",'//nT11J"'H \-,...,r-h""",;,....ql r>"'........./n.......;J"/~<'...,l '7() 1...+...."" ,t In '''''''' ^ . . Material Safety Data Sheet May be used to comply with OSHA's Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific requirements U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMS No. 1218-0072 Identity (As used on label and list) BIOLOGICAL ODOR ELIMINATOR Manufacturers Name Chester Labs, Inc. Address 1900 Section Rd., Suite A City, State. Zip Code Cincinnati, OH 45237 Note: Blank spaces are not permitted. If any item is not applicable. or no information Is avai/abfe, the space must marked to indicate . that. . 'SECTION.!..'.:";",' ...,.--- Emergency Telephone Number 1-800-354-9709 Telephone Number for Information 1-800-354-9709 Date prepared 12/2007 ,. "'<::i~:) '." ...... ': ; ::.-.' =a._ . _ _. ", "_ j '~~E.-9_tlo.~_~~f~H~~~i(to_u~s}~gr~~.i.e_n~~!!~~_nJi.iY.J_t:lfofijla.f(Q~':' ',n Hazardous Components (Specific Chemical Identity: Common Name(s)) OSHA PEL %(Oplional) Elhanol SDA 40B 190 1000 ppm , .. .,., .. .... OTHER LiMITS ACGIH TL V RECOMMENDED Polysorbale 20 NA Fabric Refresher Concentrate N.A. 1000 ppm NA N.A. N.A. N.A. N.A. N.A. N.A. Fragrance N.A. .SECTION.III c. Phs ic'aI/Cfle.midil. CfiaradeiisUcs:':>' '. .'..C'" ...._,.,. X.. '..' .,",....~,., .,.."". "'.,,' , ...."--.... ,.<on- - ........ ;;, .-' "-;"..". . ...~. " .. "'0 - ..-. .. .-"-- .~'. .". ---. ... Boiling Point >212F,> IOOC Specific Gravity (H20::; 1) 1 Vapor Pressure (mm Hg.) <18 Melting Point NA Vapor Density (AIR 1) <1 . ~~~~,7ration Ral~) <I Bu 1 Acetate - 1 Solubility In Water Appreciable Appearance and Odor UghUy scented solution 1;~ECTIONi~C Fire'a~~Haza~d~~t~ :.' Flash Point (Melhod Use) None Extinguishing Media: NA - ---...',..,.,....'.. , .... ......" ,.,-~.,.,'-.,.,., .."..- ,.'-"", '--",'" --'--..--- . - --... ~ - - , . . .... , ,.;'O..e Flammable limits NA Spedal Fire Figtlting Procedures; None Unusual Fire and Explosion Hazards: None ,...!)E,<::);I()foI....y:..~eaf!i)'.ity.[)a.t~ .. ,. "'" ,,". .....,:..,.,...' -..' """';:.'-'" . ,'--...'. ..,..'.--,..... .. ...... -- --... ".. ,...,.... ...". '-"..... Slability Unstable Stable X Conditions to Avoid None Incompatibility (Materials to Avoid) Oxidizers Hazardous Decomposition or Byproducts None known Hazardous Polymerization May Occur X Date Received: Will Not Occur Conditlons to Avoid None Pa901 Original Submittal . . 'SEC'f!()NVi ;HeallhH,azardData .,' .. -- ,- - . Route(s) of Entry: Inhalation? No Skin? Yes Ingestion? Yes Health Hazards (Acute and Chronic) EYE CONTACT MAY CAUSE TEMPORARY MODERATE IRRITATION, EXCESSIVE SKIN CONTACT WITHOUT RINSING THOROUGHLY MAY CAUSE TEMPORARY DRYNESS AND IRRITATION, INGESTION MAY RESULT IN GASTRIC DISTURBANCES, SKIN: AVOID EXCESSIVE EXPOSURE, MAY CAUSE DRYNESS, Carcinogenicity: NTP? No No Signs and Symptoms of Exposure See Health Hazards Medical Conditions Generally Aggravated by Exposure: None Emergency and First Aid Procedures SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. EYES:AVOID RUBBING EYES, IMMEDIATELY FLUSH WITH CLEAN WATER WHILE HOLOING EYELIDS APART, CONTINUE FLUSHING FOR AT LEAST FIFTEEN (15) MINUTES OR UNTIL IRRITATION SUBSIDES, CONTACT PHYSICIAN AS SOON AS POSSIBLE, INGESTION:CONT ACT A PHYSICIAN IMMEDIATELY, ',l;g;cS;pq~'"yi:rr~~~ul~~?Sif~r~rf,~~o~,n~li~gan"?:us~ ',"" ',','" Sleps 10 be Taken in Case Material is Released or Spilled Wipe Up. Waste Disposal Melllod Dispose of bv normal means Precaullons to be Taken in Handling and Storing None Other Precaulions: NOTE: UNDER NORMAL CONDITIONS OF USE, THIS PRODUCT IS NOT A HAZARDOUS MATERIAL AS DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD, :~~S!19~;~~~'sohtiotMea~ure~:: ,,':' ", " IARC Monograplls? No OSHA Regulated? .. ,) Respiratory Prolection (Specific Type): None required Ventilation Local Exhaust Norma! room ventilation NA Protective Gloves: Wear gloves Special Other Other Protective Clothing or Equipment: None Work/Hygienic Practices: Normal Page 2 Date Received: APR - 9 2010 Originsi Subm,ttal JohnsonDiversey (,-::2" t;; :i.IS't ~"': t: ::7'TtH HMIS Health Fire Hazard Reactivit Version Number: . . MATERIAL SAFETY DATA SHEET VIREX II 256 3 1 o NFPA 3 1 o Preparation date: 2008-06-18 ui ment @ .:r:..... 7'~ '<(2;./,.y L:;;_i-;:r-~4~o/f-, .t + <:L~)>::' ?~ ;x;,,',.;;~ ,'<<"';"',." .,'r. Product name: MSDS #: Product Code: Recommended use: Manufacturer, importer, supplier; US Headquarters JohnsonDiversey, Inc. 8310 16th 51. Sturtevant, Wisconsin 53177-1964 Phone: 1-888-352-2249 MSDS Internet Address: www.johnsondiversey.com Emergency telephone number: _, ,1. -'PRODUCT AND COMI?ANY IDENTIFICATION: .:v.': 1 VIREX II 256 114331002 03781.04329.04331,04332,04333.04337.03916, 3062637, 3062768, 3364740, 5019317 Disinfectant. This product is intended to be diluted prior to use. 1-800-851-7145 (Prosar); 1-651-917-6133 (Inl'l Prosar): 01-800-710-3400 (Mexico) I" ~. t.<" " 'l.~w*,"",/, 'b.,.M~ 'I "".."~t _~;;;; 'e;i.';. 1"2:'HAZARDS IDENTIFICATION' ,A"';" ":",'7", EMERGENCY OVERVIEW DANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS. HARMFUL OR FATAL IF SWALLOWED. COMBUSTIBLE L10UID AND VAPOR. Principle routes of exposure: Eye contact: Skin contact: Inhalation: Ingestion: Eye contact. Skin contact. Inhalation. Corrosive. Causes permanent eye damage, including blindness. Corrosive. Causes permanent damage. May Cause irritation and corrosive effects to nose, throat and respiratory tract. Corrosive. Causes burns to mouth, throat and stomach. H d' ",,1\>' ./ii_ "( ,,", '-~,rl~~C.~ ":'3. COMP.OSFrlONIINFORMA TION:ONINGREDIENTS2" :.'=:''':'', azar ous mare len 5 tngredient(s) CAS # Weight % LDSO Oral. Rat LD50 Dermal. LC50 Inhalation - Rat Imolkoi Rabbit N-alkyl Dimethyl Benzyl Ammonium 68424-85-1 5 -10% 426 Not available Not available Chloride Didecvl dimethyl ammonium chloride 7173-51-5 5-10% 84 Not available Not available Ethyl alcohol 64-17 5 1-5% 7060 Not available Not available Laurv! dimethvl amine oxide . 1643-20-5 1 5% 2700 Not available Not available 1 "'~,. _ ,,::~",'='h;';" ih~, d Eye contact: Skin contact: Inhalation: Ingestion: Aggravated Medical Conditions: Suitable extinguishing media: Specific hazards: VIREX 11.256 u~;~~ ~ -I .~ ,.;.4;_FIRS'EAID MEASURES" " Immediately flush eyes with running ,water for 15-20 minutes, keeping eyelids open. Get medical attention immediately. Immediately flush with plenty of water for 15-20 minutes. Get medical attention immediately. If breathing is affected, remove to fresh air. Get medica) attention immediately. If swallowed. rinse mouth. Give a cupful of water or milk. THEN IMMEDIATELY CONTACT A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Individuals with chronic respiratory disorders such as asthma. chronic bronchitis. emphysema, etc., may be more susceptible to irritating effects. Use dry chemical, C02, water spray or "alcohol" foam. Although this product has a flash point below 200 Deg. and does not sustain combustion. F, it is an aqueous solution containing an alcohol APR - 9 2010 1 of 3 Original Submittal 1__TI/:"7.! "'7' TI' Unusual hazards: Specific methods: . . ';:" ".;;;';'j, "~,":., 1 '; 1i:;\;~:~'";i ~0 ,;~;..5;',F;1 RE4flGHTI NG~IVIEASU RESj2'"Jl<;;Jilw~Tfif:~ ':it;.,',;;,HC <1>,::;1f ;;i:.:,~~tj~;~0:(>j:" Corrosive material (See sections 8 and 1 0). No special methods required Special protective equipment for firefighters: As in any fire. wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available I "';TI' r ': ' .;.;li;"Y0oS:",>' Personal precautions: Environmental precautions and clean-up methods: I' '~'. ~CM' "<"':':.. ,K ACCI[)ENTALREBEASE'MEASLJRES, '" " 'H;I ,,:;.... Use personal protective equipment Clean-up methods - large spillage. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use a water rinse for final clean-up. ">:':;'*-, >; -\ '\ .J' ,(.j:t~~'g::;i'J~1ti::~;;'~'~F' . .~~, """"' " n,,: ~., 7,\HANDBING AND,STORAGE,' \1 , ',^\",'" ,,~ Handling: Avoid contact with skin, eyes and clothing_ Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain onlin empty containers. All precautions for handling the product must be used In handling lhe empty container and residue. COMBUSTIBLE LIQUiD AND VAPOR, Keep away from open flames, hot surfaces and sources of ignition. Use only in well-ventilated areas. FOR COMMERCIAL AND INDUSTR!Al USE ONLY. Storage: Protect from freezing. Store in a cool, dry. well ventilated area away from heat or open flame. KEEP OUT OF REACH OF CHilDREN. I ~':;,::t;}"dt": "ift" 'I ;1\ . :, ;ti;S: EXPOSURECONTROLS:J-PERSONAB:F?ROT:ECTION; , Engineering measures to reduce exposure: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures: 1,,,:-:. _e'f" Physical State: pH: Appearance: Color: Odor: Specific gravity: Density: VoC: Flash point: Solubility: Viscosity: In redient s Ethyl alcohol Chemical-splash goggles. Chemical-resistant gloves Protective footwear. If major exposure is possible, wear suitable protective clothing and footwear. In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Handle in accordance with good industrial hygiene and safety practice OSHA 1900 mgfm3 (TWA) 1000 m TWA ACGIH 1000 ppm (TWA) ,. ">";';(:;C~ ::;" .,-':9,'P,HYSICAB1'AND:CHEMICA",'P,ROPERTIES';P\c:; ":.; ''; '-';:, ;;f,<~::;;r:;.::r;:rJ :::::.:.;,/': 1 :,~;.:;~;~; ^ l' ^ 'i<~.J't,<uJi!f;' Liquid 10,2 Liquid Clear Blue Minty 1.0 8.32 lbs/gal 3.10/0 . 187"F 860C completely soluble No information available Stability: Polymerization: Hazardous decomposition products: Materials to avoid: Conditions to avoid: Bulk density: No information available Dilution pH: 8.8 (1 :256) Vapor density: No information available Evaporation Rate No information available Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Partition coefficient (n~octanol{water): No information available Solubility in other solvents: No Information available Elemental Phosphorus: 0 %P I""" , ",'..,,:.:~( ;-; . - Title 17, California Code of Regulations. Division 3, Chapter 1, Subch.apter 8.5, Article 2. Consumer Products. Sections 94508 ,""'''~i+..,"", ;c';_' ,",c,._ A 10::;SJABILlT,v,AND'REACTIVIT.'t':i: :: >"':;"'."1 ",,~+,,""'%;""~ ^,'-='->-,oA.:!,f,'"S' ;J:.:~'f~~4:;bi:,;~:;- ,';;~>*r;f~{1l; The product is stable. Hazardous polymerization does not occur None reasonably foreseeable. Oxidising agents. Keep away from heat. Keep away from open flames, hot surfaces and sources of ignition. Oral lD50 estimated to be between 1000 - 2000 mg/kg Acute toxicity: VIREX II 256 '1",,,, :::11::;J0XICO[OGICALINf'ORMATI0N7!" '::!L,bi':':. APR - 9 2010 2 of 3 Original Submittal . . 'TOXICOLOGICA[~IN~ORMA TION 'iSh CC,<:C:" :"t"-< See Section 3 Chronic toxicity: Specific effects Carcinogenic effects: Mutagenic effects: Reproductive toxicity: Target organ effects; None known None known None known None known None known Hazardous in redients In redient s Elh I alcohol CAS # 64 1?5 NTP X IARC OSHA X :::,,~:' 12,:ECQLOGICAL:lNEORMAJION Environmental Information: No data available ',~13.:'DISf'OSAL CONSIDERATIONS~'" !l!;:, '-~, , ~", 00 no! contaminate water. food, or feed by storage or disposal Waste from residues I unused products: Handle as a Pesticide waste Do not bury, Do not dispose of with Commercial or Household waste. PESTICIDAL WASTE _ Observe all applicable Federal/Provincial/Slate regulations and Local/Municipal ordinances regarding disposal of pesticide wastes. Pesticide wastes are acutely hazardous Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact YOllr State Pesticide or Environmental Control Agency, or the Hazardous Waste reporesentative at the nearest EPA Regional Office for guidance. Pesticide Storage: Store in original container in areas inaccessible to children. Open dumping is prohibited. Do not reuse empty container Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate, or, if allowed by State and local authorities burn. Jf burned. stay out of smoke ~":14:'TRANSf'ORT,INEORMATION DOTfTDG: Please refer to the Bill of Ladinglreceiving documents for up to dale shipping information ",-1S:,REGUI2ATORY:INEORMATION ,:v,z!"":'!' :,H,;d:',~: ," International Inventories All components of this product are listed on the following inventories: U.S,A. (TSCA), Canada (DSlINDSL), Europe (EINECS/ELlNCS/NLP). Australia (AICS), New Zealand (NZloC), China (IECSC). U.S. Regulations EPA Reg. No. : 70627-24 California Proposition 65: This prOduct is not subject to the reporting requirements under California's Proposition 65 CERCLA/ SARA SARA 311/312 Hazard Categories Immediate: Delayed: Fire: Reactivity: Sudden Release of Pressure: X X Reason for revision: Prepared by: Additional advice: Not applicable NAPRAC None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or Implied, as to the accuracy of the information contained within. Actual conddions of use aod handling are beyond seller's con/rol. User is responsible to evaluate all avaifable information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and cegulations. Date Received: VIREX II 256 APR ,,;'9 2010 3 of 3 Original Submittal . . ALLEGIANCE ENZV -CLEAN DUAL ENZVMA TIC PRE-SOAK AND DETERGENT 25132 BURNISHINE PRODUCTS Revised: 11/12/1999 Internal 10" N/A Primary CAS: N/A Filename- 012685 This product is also known as NfA other Information Cardinal Catalog 25132 NQ.: V9 Date Received: APR - 9 2010 Original Submittal BID Material Safety Data Sheet . . MJ'TERIAL SAFETY DATA SHEET COMPLY WITH OSHA'S HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. PRODUCT CODE, V9, UPDATED, NOVEMBER 12, 1999 PRINTED, NOVEMBER 12, 1999 HMIS RATING, HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 PROTECTION B NFPA RATING, HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 IDENTITY - AS USED ON LABEL AND LIST, ALLEGIANCE ENZY-CLEAN DUAL ENZYMATIC PRE-SOAK AND DETERGENT, #25132 SECTION I - CONTACT INFORMATION MANUFACTURER'S NAME & ADDRESS, BURNISHINE PRODUCTS 1100 LAKESIDE DRIVE GURNEE, IL 60031 EMERGENCY TELEPHONE NUMBERS, CONTACT YOUR REGIONAL POISON CONTROL CENTER OR 1-800-535-5053 (24 HOURS) FOR INFORMATION CALL 1-847-263-3500 DISTRIBUTED BY, ALLEGIANCE HEALTH CARE 1430 WAUKEGAN ROAD MCGAW PARK, IL 60015 FOR INFORMATION CALL 1-800-323-9088 SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS SPECIFIC CHEMICAL IDENTITY; CAS NUMBER OSHA PEL .oTHER LIMITS ACGIH TLV RECOMMENDED % (OPTIONAL) NONIONIC SURFACTANT, # 9016-45-9 N/D N/D N/D BACTERIAL PROTEASE, # 9014-01-1 0.06 N/D (MICROIG/M3 BACTERIAL AMYLASE, # 9000-85-5 N/D N/D N/D N/D VOC, N/D Date Received: APR - 9 2010 DOT, NON-HAZARDOUS Original .submittal . . ALL INGREDIENTS IN THIS PRODUCT ARE ON THE TSCA LIST. THIS PRODUCT DOES NOT CONTAIN ANY AMOUNT OF ANY CHEMICAL REQUIRED TO BE REPORTED UNDER SARA 313. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: 212 - 220 DEG. F SPECIFIC GRAVITY (H20 = II : 1. 018-1. 024 VAPOR PRESSURE (MM HG.I: EVAPORATION RATE (BUTYL ACETATE N/D N/A N/D 1): N/D MELTING POINT: VAPOR DENSITY (AIR = 1): SOLUBILITY IN WATER: COMPLETE PH: 8.25-8.75 APPEARANCE AND ODOR: BLUISH-GREEN LIQUID WITH SPEARMINT ODOR. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): OVER 200 DEG. F FLAMMABLE LIMITS: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, AND WATER FOG. SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE SECTION V - REACTIVITY DATA STABILITY: STABLE INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: OXIDES OF CARBON, NITROUS OXIDES, AND AMMONIACAL VAPORS. HAZARDOUS POLYMERIZATION: lULL NOT OCCUR. CONDITIONS TO AVOID: NONE Date Received: SECTION VI - HEALTH HAZARD DATA ROUTE(S) OF ENTRY: APR -' 9 2010 INHALATION: YES SKIN: YES INGESTION: YES Original Submittal . . HEALTH HAZARDS (ACUTE AND CHRONIC) , INHALATION, NONE EXPECTED UNDER NORMAL USE CONDITIONS. EYES, CAN CAUSE IRRITATION. SKIN, PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION. INGESTION, CAN CAUSE IRRITATION TO MOUTH, THROAT AND GASTROINTESTINAL SYSTEM. CARCINOGENICITY, NTP, N/A IARC MONOGRAPHS, N/A OSHA REGULATED, N/A SIGNS AND SYMPTOMS OF EXPOSURE, INHALATION, NONE EXPECTED UNDER NORMAL USE CONDITIONS. DRIED ENZYMES OR IMPROPER USE RESULTING IN CREATION OF MIST MAY RESULT IN HAY FEVER TYPE SYMPTOMS. EYES, IRRITATION, REDNESS, AND/OR TEARING. SKIN, IRRITATION AND/OR REDNESS. INGESTION, NAUSEA, DIARRHEA. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE, DERMATITIS AND OTHER PREEXISTING SKIN CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. EMERGENCY AND FIRST AID PROCEDURES, INHALATION, REMOVE TO FRESH AIR. IF PERSON IS HAVING DIFFICULTY BREATHING, GIVE OXYGEN AND CALL A PHYSICIAN IMMEDIATELY. EYES, RINSE WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, SEEK MEDICl"L ATTENTION IMMEDIATELY. SKIN, WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. INGESTION, RINSE MOUTH AND THROAT WIT~ WATER. DRINK A QUART OF WATER. IMMEDIATELY. NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. CONSULT A PHYSICIAN SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Date Received: STEPS TO, BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED, ABSORB SPILL WITH DRY ABSORBENT WASH DOWN WITH SOAP AND WATER. APR ..:: 9 2010 Original Submittal . . WASTE DISPOSAL METHOD, DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. PRODUCT IS BIODEGRADABLE. PRECAUTIONS TO BE TAKEN IN fffiNDLING AND STORING, KEEP IN COOL PLACE. KEEP OUT OF REACH OF CHILDREN. OTHER PRECAUTIONS, AVOID LONG EXPOSURE TO HEAT. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION (SPECIFIC TYPE), NONE VENTILATION, LOCAL EXHAUST, MECHANICAL (GENERAL), SPECIAL, OTHER, NONE NONE NONE NONE PROTECTIVE GLOVES, RUBBER/POLYETHYLENE EYE PROTECTION, SAFETY GLASSES OTHER PROTECTIVE CLOTHING OR EQUIPMENT, NONE WORK/HYGIENIC PRACTICES, AVOID SPLASHING AND/OR CREATION OF MIST. NOTE, N/A OR N/D AS AN INFORMATION ENTRY MEANS THE DATA IS NOT APPLICABLE OR DETERMINED, RESPECTIVELY. Date Received: APR ..; 9 2010 Original Submittal . . Page 1 of 5 Material Safety Data Sheet Sodium Hypochlorite Solution, 4-6% ACC# 40179 Section 1 - Chemical Product and Company Identification MSDS Name: Sodium Hypochlorite Solution, 4-6% Catalog Numbers: 580183, 5801831, CRN552904, NC9828282, 55290 1, 552904,552901,552904 Synonyms: None Company Identification: Fisher Scientific 1 Reagent L~ne Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECSjElINCS 7681-52-9 Sodium hypochlorite 4-6.0 231-668-3 7732-18-5 Water 94.21 231-791-2 Hazard Symbols: C Risk Phrases: 31 34 II Section 3 - Hazards Identification II EMERGENCY OVERVIEW Appearance: clear light yellow green. Corrosive. Danger! Causes eye and skin burns. Causes digestive and respira~ory tract burns. May cause methemoglobinemia. Target Organs: Blood. Potential Health Effects Eye: May cause irreversible eye injury. Contact with liquid is corrosive to the eyes and causes severe burns. Skin: Causes skin burns. Ingestion: May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Inhalation: Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause pulmonary edema and severe respiratory disturbances. . Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingesOate Received: II Section 4 - First Aid Measures API< - 9 2~~O Original Submittal Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Skin: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT http://avogadro.chcm.iastate.edu/MSDS/NaOCI-6pct.htm 4/R/20 10 Pagc2of5 . . use mouth-ta-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively. II Section 5 - Fire Fighting Measures II General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHAjNIOSH (approved or equivalent), and full protective gear. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Extinguishing Media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as i[ldicated in Section 8. Spills/leaks: Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as saw dust. Provide ventilation. II Section 7 - Handling and Storage II Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Discard contaminated shoes. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. EXDosure limIts Chemical Name ACGIH NIOSH OSHA - Final PELs Sodium hypochlorite none listed none listed none listed Water none listed none listed none listed OSHA Vacated PEls: Sodium hypochlorite: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical. p'ersonal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 91910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: clear light yellow green Odor: chlorine-like pH: Not available. Vap?r Pressure: 14 mm Hg Date Received: APR ..i 9 2010 http://avogadro.chem.iastatc.cdu/MSDS/N aOCl-6pct.htm Original submittal 4/8/2010 . . Page 3 of5 Vapor Density: 2.60 Evaporation Rate: > 1 (ether= 1) Viscosity: Not available. Boiling Point: Decomposes. Freezing/Melting Point:32 deg F Autoignition Temperature: Not applicable. Flash Point: Not applicable. Decomposition Temperature:Not available. NFPA Rating: (estimated) Health:'2; Flammability: 0; Reactivity: 0 Explosion limits, Lower:Not available. Upper: Not available. SOlubility: Soluble in water. Specific Gravity/Density: 1.1 Molecular Formula:NaOHCI Molecular Weight:75.4492 II Section 10 - Stability and Reactivity II Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, combustible materials. Incompatibilities with. Other Materials: Sodium hypochlorite is incompatible with amines, ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, ammonium ptlOsphate, cellulose, and ethyleneimine, strong acids, reducing agents, amines, and ammonia salts. Hazardous Decomposition Products: Chlorine, sodium.oxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 7681-52-9: NH3486300 CAS# 7732-18-5: 2C0110000 LDSOjLCSO: CAS# 7681-52-9: Draize test, rabbit, eye: 10 mg Moderate; Oral, mouse: LD50 = 5800 m9/k9: CAS# 7732-18-5: Oral, rat: LDSO = >90 mL/kg; Carcinogenicity: CA5# 7681-52-9: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732 18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: No data available. Teratogenicity: No data available. Reproductive Effects: No data available. Neurotoxicity: No data available. Mutagenicity: No data available. Other Studies: No data available. II Section 12 - Ecological Information II No information available. II Section 13 - Disposal Considerations II Odlt:: kecelved: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determi~ation are listed in 40 CFR Parts 261.3. Additionally, was~e generatorSA,fDIljit cORsult state and local hazardous waste regulations to ensure complete and accurate classification. I'\rn -:1 2010 RCRA P-Series: None listed. RCRA U-Series: None listed. Original Submittal 1~ LL.~ . 1/ __. _ _ _ .1 __ . . Page 4 of 5 II Section 14 - Transport Information II US DOT lATA I RID/ADR I IMO Canada TOG HYPOCHLORITE HYPOCHLORITE Shipping Name: SOLUTION SOLUTION 4- 60/0 Hazard Class: 8 8(9.2) UN Number: UN1791 UN 1791 Packing Group: III III II Section 15 - Regulatory Information II US FEDERAL TSCA CAS# 7681-52-9 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting list None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ) CAS# 7681-52-9: final RQ = 100 pounds (45.4 kg) Section 302 (TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS # 7681-52-9: acute, flammable. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone dep\etors. Clean Water Act: CAS# 7681-52-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7681-52-9 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level; None of the chemicals in this product are listed. European/International Regulations European labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 31 Contact with acids liberates toxic gas. Date Received: R 34 Causes burns. Safety Phrases: S 28 After contact with skin, wash immediately with.. S 45 In case of accident or if you feel unwel" seek medical advice immediately (show the label'where possible). . APR ~. 9 2010 Original Submittal http:// a yogadro .chelll. i astate.erlll/MSnS/1\f ,,()I'Lhnrt ht~ . . Page 5 of5 5 50 Do not mix with manufacturer). (to be specified by the WGK (Water Danger/Protection) CAS# 7681-52-9; 2 CAS# 7732-18-5: No information available. Canada CAS# 7681-52-9 is listed on Canada's DSL list. CAS# 7681-52-9 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-'18-5 is listed on Canada's DSL List. This product has a WHMIS classification of E. CAS# 7681-52-9 is listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 IS not listed on Canada's Ingredient Disclosure List. Exposure Limits II Section 16 - Additional Information II MSDS Creation Date: 9/28/1998 Revision #2 Date: 4/10/2001 Tlnl information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merc/lantabifity or any other warranty, express or implied, with respect to SUcll informatIon, and we assume no liability resulting from its use. Users should make their olvn investigations to determine the suitability of tile information for theIr partIcular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any t/lird party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised 01 the possibility of SUcll damages. Date Received: APR .. 9 2010 Original Submittal htt......//'''r.....~T,..,A.." ",I..".~~ ~~~,j-~".~ _...L.Ill. KC'.r'\C'!1..T_f"'\r'll , COASTWIDE LABORATORIES Formerly Paulsen & Roles Laboratories 10000 SW Commerce Circle Wilsonville, OR 97070 Office PHONE: 503-416-5300 or FAX 503-416-5301 24-HR EMERGENCIES: MEDICAL 800-808-4691 Hazard RatinQ Health Flammability Reactivity Special DOT CHEMTREC: HMIS 1 1 o None NFPA 1 1 o None 800-424-9300 MATERIAL SAFETY DATA SHEET Complies with ANSI Z400. 1 Format I Product: SECTION 1: PRODUCT IDENTIFICATION Orange Oil Polish rM ~ MSDS CODE: Cl3440.0306 GENERIC DESCRIPTION Multi-Surface Furniture and Fixture Polish DATE ISSUED 3-1-06 SUPERSEDES PREPARED BY 6-1-02 Regulatory Compliance Dept. SECTION 2; COMPOSITION AND INFORMATION ON INGREDIENTS Components' % bv Wt. CAS # Exposure Limit Orange Oil 5-15 Mixture None Mixed Salls of Fatly Acid 10-15 ND None Balance is water and similar non-hazardous ingredients. . There are no components in Ihis product that are currenUy reportable in eilher SARA Title III: Section 313, 40 CFR part 372 or the California Proposition 65 requirements. NA = Not applicable NSR == No Special Requirements NO == Not Determined PEL = OSHA TLV-TWA == ACGIH SECTION 3: HAZARD IDENTIFICATION Primary Entry Routes; Skin and eyes. Signs & Symptoms of Exposure: INHALATION: None known EYE CONTACT: Liquid and mist may irritate the eyes. SKIN CONTACT: May dry out the skin. Prolonged contact may irritate the skin. INGESTION: None known Effects of Overexposure: None known. I SECTION 4: FIRST AID MEASURES r Emergency First Aid Procedures: INHALATION: Remove to fresh air. EYE CONTACT: Immediately fiush eyes with water for 15 minutes, lifting eyelids occasionally. If irritation persisls get medical atlention. SKIN CONTACT: Immediately wash skin with soap and water. INGESTION: Drink plenty of water. Get medical atlention. 24-HRMEDICAL EMERGENCY PHONE; 800-808-4691 " SECTION 5; FIRE FIGHTING MEASURES Flash Point: 145F Flammable Limits: NO Extinguishing Media: NA Special Fire Fighting Procedures: No special procedures required. Unusual Fire and Explosion Hazards: None known. SECTION 6; ACCIDENTAL RELEASE MEASURES Release or Spill: Absorb with diatomaceous earth or similar inert material. Sweep or scrape up and conlainerize Rinse affected area Ihoroughly with water. Wear or use appropriate protective equipment All Federal, Slate and Local regulations should be carefully followed. J SECTION 7: HANDLING AND STORAGE I Keep out of reach of children. Store in a cool, dry place with adequate ventilation. Keep from freezing. Wash Ihoroughly after handling. Emply container may contain small amounts of undiluted product. Be certain to dispose of according to all regulalions. Date Received: APR - 9 2010 Original Submittal . . COASTWIDE Laboratories Material Safety Dala Sheet Page 2 - Orange Oil Polish ™ CL3440.0306 SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Respiratory Protection: No special requirements under normal use conditions. Protective Gloves: No special requirements for normal use conditions. Eye Protection: No special requirements for normal use conditions. However, it is a good safe practice to wear eye protection when using any chemical product. Other Protective Measures: Use good personal hygiene practices. Launder contaminated clolhing/equipment before reuse. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance/Odor: Clear, Orange Color and Odor Boiling Point: 335F Evap. Rate: NA Vapor Density: NO Vapor Pressure: NA Specific Gravity: 0.93 Solubility in Water: >50% pH: NA %VoJatile: NA l SECTION 10: STABILITY AND REACTIVITY I Stability: Stable Conditions to Avoid: None known to COASTWIDE Incompatibility: None known to COASTWIDE Hazardous Decomposition Products: None known to COASTWI DE. Hazardous Polymerization: Will not occur. Conditions to Avoid: None known to COASTWIDE. SECTION 11: TOXICOLOGICAL INFORMATION Oral Toxicity: Non-toxic based upon current informalion available 10 COASTWIDE. I SECTION 12: ECOLOGICAL INFORMATION Contains no phosphates, heavy metals or toxins. r ~ SECTION 13: DISPOSAL CONSIDERATIONS r Waste Disposal Information: No special method. Observe all applicable Federal, State and Local regulations, rules and/or ordinances regarding disposal of non-hazardous malerials. ~ SECTION 14: TRANSPORT INFORMATION DOT EMERGENCY 24-HR: (800) 424-9300 DOT Class: Not Regulated t SECTION 15: REGULATORY INFORMATION SARA Title III Section 313 and 40 CFR Part 372 Notification: See Section 2. No ingredients in Ihis product are currently listed as carcinogens by NTP, IARC or OSHA All components of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. I f ~ SECTION 16: OTHER INFORMATION I Always follow label directions carefully when using this or any other chemical produc!. If Information about this producl is required, please contact COASTWIDE Laboratories al 503-218-4900. Keep MSDSs filed and organized in an area accessible to workers according 10 the Hazard Communication Standards. A/I information appearing herein is given in good faith. No warranty is made, expressed or implied including merchantability or fifness for a panicular purpose. A/I conditions of use are beyond the control of COASTWIOE Laboratories. Therefore, users are responsible for verifying the data under their own operating conditions to determine whether fhe product is suitable for their panicu/ar purposes. The data contained . herein is confidential and intended solely for the user's internal use. Date Received: APR -' 9 2010 Original Submittal . CLQRQX CO . -- CLORQX BLEACH - FOR INSTITUTIONAL USE ------------------------------------------------------- ----.-- -- ------------------ -------------- --- ------------ MSDS Safety Information ------------------------------------------------------- ------------------------------------------------------- FSC: 6810 NIIN: 01-~57-0255 MSDS Date: 11/01/1992 MSDS Nurn: CJQNN Product 10: CLOROX BLEACH - FOR INSTITUTIONAL USE t1FN: 01 Responsible Party Cage: 93098 Name: CLOROX CO Address: 1221 BROADWAY Box: 24305 City: OAKLAND CA 9'612 Info Phone Number: 510-271-'7000 Emergency P]lone Number: 800-446-1.0J4; 800-424-9300 Cherntrec INO/Pllone: .(800)424-9300 Revieh' Ind: Y Published: Y ------------------------------------------~------------ ------------------------------------------------------- Contractor Summary ------------------------------------------------------- ------------------------------------------------------- Cage: 93098 Name; CLOROX CO THE HE.l\DQUARTERS Address; 1221 BROADWAY Box: 24305 City: OAKLAND CA 94612-1305 Phone: 510-271-7000 ------------------------------------------------------- ------------------------------------------------------- Item Description Information ------------------------------------------------------- ------------------------------------------------------- Item Name: SODIUM HYPOCHLORITE SOLUTION ------------------------------------------------------- ------------------------------------------------------- Ingredients ------------------------------------------------------- ------------------------------------------------------- Cas: 7681-52-9 RTECS #: NH3486300 Name: SODIUM HYPOCHLORITE Percent by Wt: 5.25 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------------------------------- ------------------------------------------------------- Health Hazards Data ------------------------------------------------------- ------------------------------------------------------- Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO -lARC: NO OSHA: NO Date Received: APR - 9 2010 Original Submittal . . Effects of Exposure: Cl\USES SUBSTANTIAL BUT TEMPORARY EYE INJURY. MAY IRRITATE SKIN. MAY CAUSE NAUSEA AND VOMITING IF INGESTED. EXPOSURE TO VAPOR OR MIST MAY IRRITATE NOSE, THROAT AND LUNGS. UNDER NORMAL CONSUMER USE COND ITIONS THE LIKELIHOOD OF ANY ADVERSE HEALTH EFFECTS ARE LOvl. NONE OF THE INGREDIENTS IN THIS PRODUCT .~RE ON THE IARe, NTP OR OSHA CARCINOGEN LIST. OCCASIONAL CLINICAL REPORTS SUGGEST A LOW POTENTIAL F OR SENSITIZATION UPON EXAGGERATED EXPOSURE TO SODIUM HYPOCHLORITE no SKIN DAMAGE lEG IRRITATION) OCCURS DURING EXPOSURE. ROUTINE CLINICAL TESTS CONDOCTED ON INTACT SKIN WITH CHLOROX LIQUID BLEACH FOUND NO SENSITIZATION IN THE TEST SOBJFCTS. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cand Aggravated By Exposure: FOLLOWING MED CNDTNS MAY BE AGGRAVATED BY EXPOS TO HIGH CONeS OF VAPOR OR MIST: HE.~RT CNDTNS OR CHRONIC RESP PROBS SUCH AS ASTHMA, CHRONIC BRONCHITIS OR OBSTRUCTIVE LUNG DISEASE. First Aid: EYE CONTACT: Il1MEDIATELY FLUSH EYES WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEE A DOCTOR. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASIl AREA WITH WATER. INGESTION: DRINK A GLASSFUL OF .mTER A NO CALL A PHYSICIAN. INHALATION: IF BREATHING PROBLEHS DEVELOP REHOVE TO FRESH AIR. ------------------------------------------------------- -------------------------------------------------- Handling and Disposal -----================================================== Spill Release Procedures: SMALL SPILLS (<5 GALLONS); l)ABSORB, CONTAINERIZE, AND LANDFILL 1/ A/FI LOCAL REGULl\TIONS. 2) vJl\SH OOlr.JN RESIDUAL TO SANITARY SE\'ifER. L.~RGE SPILLS 1>5 GF.LLONS), I,) ABSORB, CONTAINERIZE AND LANDFILL I/A/W LO CAL REGULATIONS; WASH DOWN RESIDUAL TO SANITARY SEWER - OR (2) PUMP MATERIAL TO WASTE DRUM IS) AND DISPOSE OF I/A/W LOCAL REGULATIONS; WASH DOWN RESIDUAL TO SANITARY SEWER. Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCP.L REGULATIONS I FP N). Jiandling And Stoiage Precautions: KEEP OOT OF THE REACH OF CHILDREN. ------------------------------------------------------- ------------------------------------------------------- Fire and Explosion Hazard Information ------------------------------------------------------- ------------------------------------------------------- Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT IFP N). IN .~ FIRE, COOL CONTAINERS TO PREVENT RUPTURE AND RELEASE OF SODIUM CHLORATE. Unusual Fire/Explosion Hazard: NOT FLAMMABTJE OR EXPLOSIVE. ======================================================= Control Measures ------------------------~------------------------~----- --------------------------~---------------------------- Respiratory Protection: USE NIaSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN IFP NI . Ventilation: USE GENERAL VENTILATION TO MINIMIZE EXPOSURE TO VAPOR OR MIST. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N). Work Hygienic Practices: AVOID EYE AND SKIN CONTACT AND INHALATION OF VAPOR OR tHST. Supplemental Safety and Health: MATLS TO AVOID: WITH METAL MAY CAUSE PITTING OR DISCOLORATION. ======================================================~ Date Received: Physical/Chemical Properties APR ..;.9 2010 Original Submittal . . ------------------------------------------------------- - ------ -- ---- ---------- ---------._- ------- -- ------ ------ Boiling Point: =100.C, 212.F B.P. Text, DECOMPOSES Decamp Temp: =100.C, 212.F Spec Gravity: 1.085 (HJ.20=1) PH, 11.4 Solubility j,n Water: COMPLETE Appearance and Odor: CLEAR, LIGHT YELLO\tJ LIQUID \'lITH CHLORINE ODOR. ------------------------------------------------------- ------------------------------------------------------- Reactivity Data ------------------------------------------------------- ------------------------------------------------------- Stabili t Y Indicator: YES PROLONGED CONTACT (SUPDAT) Stability Condition To Avoid: STABLE UNDER NORMAL USE AND STORAGE CONDITIONS. Materials To Avoid: STRONG OXIDIZING AGENT. REACTS W/OTHER HOUSEHOLD CHEMICALS SUCH !-l.S TOILET BOvn CLEANERS, RIJST REHOVERS, VINEGAR, l\CIDS OR .n.MMONIA CONT.~INH]G PRODUCS TO PRODUCE HAZARDOUS GASES SUCH AS CHLORINE AND OTHER CHLORINATED SPECIES. Hazardous Pol~nerizacion Indicator: NO ======================================================= MSDS Transport Information =============================~========================= Transpol~t Information: US DOT HAZ.n.RD CLASS: NOT RESTRICTED. US DOT PROPER SHIPPING NANE, HYPOCHLORITE SOLUTION (HTH NOT MORE THAN 7% AVAILABLE CHLORINE. NOT RESTRICTED PER 49 CFR I72.101IC) (12) (IV) ------------------------------------------------------ =------------------------------------------------------ Regulatory Information ======================================================= Sara Title III Information: EPA CERCLA/SARA TITLE III SUPERFUND AIvlENDMENT AND REAOTHORIZATION ACT, CERCLA/304 - SODIUM HYPOCHLORITE RQ, 100 LBS. SODIUIM HYDROXIDE, RQ 1000 LBS, 3111312, YES. ======================================================= Other Information ======================================================= Other Information:: HEALTH J" FLAMMABILITY 0, REACTIVITY O. OTHER DESIGNATIONS: EPA REG NO 5813-1, SODIUM HYPOCHLORITE SOLUTION, LIQUID CHLORINE BLE.~CH, CLOROX LIQUID BLEACH, CLOROX GERMICIDAL BLEP.CH. ======================================================= Transportation Information ======================================================= Responsible Party Cage: 93098 Trans TO NO: 150538 Product 10, CLOROX BLEACH - FOR INSTITUTIONAL USE MSDS Prepared Date, 11/01/1992 Review Date: 12/06/1999 !"IFN: 1 !"Iul tiple KIT Number: 0 Date Received: APR - 9 2010 Original Submittal ======================================================= Detail DOT Information ==-==================================================== DOT PSN Code, ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION . . ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IHO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTI.l.TION ======================================================= Detail lATA Information ======================================================= lATA PSN Code: ZZZ lATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code, ZZZ AFT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ------------------------------------------------------- ------------------------------------------------------- HAZCOM Label ------------------------------------------------------- ------------------------------------------------------- Product 10: CLOROX BLEACH - FOR INSTITUTIONAL USE Cage' 93098 Company Name: CLOROX CO THE HEADQUARTERS Street.: 1221 BROADh1.In PO Box, 24305 City, OAKLAND CA Zipcode, 946]2-1305 Health Emergency Phone: 800-446-1014; 800-424-9300 Label Required IND: Y Date Of Label Review: 09/07/1999 Status Code: A Origination Code: F Eye Protection INO: YES Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Sligllt Fire Hazard: NOlle Reactivity Hazard: None Hazard And Precautions: ACUTE: CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY. MAY IRRIT SKIN. MAY CAUSE NAUS AND VOMIT IF INGESTED. EXPOSURE TO VAPOR OR MIST MAY IRRITATE NOSE, THROAT AND LUNGS. UNDER NORMAL CONSUMER USE CONDI TIONS THE LIKELIHOOD OF ANY ADVERSE HEALTH EFFECTS ARE LOW. CHRONIC, NONE OF THE INGREDIENTS IN THIS PRODUCT ARE ON THE IARC, NTP OR OSHA CARCINOGEN LIST. OCCASIONAL CLINICAL REPORTS SUGGEST A LOW POT ENTIAL FOR SENSITIZATION UPON EXAGGERATED EXPOSURE TO SODIUM HYPOCHLORITE IF SKIN DAMAGE(EG IRRITATION) OCCORS DURING EXPOSURE. ROUTINE CLINICAL TESTS CONDUCTED ON INTACT SKIN WITH CIILOROX LIQUID BLEA CH FOUND NO SENSITIZATION IN THE TEST SUBJECTS. ------------------------------------------------------- -~----------------------------------------------------- Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of _~erica in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims, all liability for such use. AnYOat~Received: utllizing this instruction who lS not a military or civilian employee of the APR .:: 9 2010 Original Submittal . . United States of America should seek competent professional advice to verify and assume responsibility for the suitabil.ity of this information to their particular siCllation regacdless of similarity to a corresponding Department of Defense or other government situation. Date Received: APR ~ 9 2010 Original Submittal . . J~~~"N:lJlllgiM Material Safety Data Sheet J-SPRA Y GLANCE GLASS CLEANER - USE SOLUTION National Fire Protection Association (NFPA) Fin' Hazard lleallh ~j Reactivity Specific HazanJ Hazardous Material InfOl"matioll System (111\1[8) o o o Protecliw None required. Clothing Emergency Clear Blue. Liquid. See Section 9. Ovmiew CAUTION: COMBUSTIBLE. c. Se-ction 1. Clien1ical Producfaild c;o[TIp,!nyjdentifir;ation':" I'e .~ ;. --" - ... ... '-_ Coo'"~ .i"C"'=J,"~.:;;;:":; :'k..."., 'C':''''':,,,,,,,'_',"'':;':',,,,. :'-:..:.L. ..:...__ .__ i"O-.-;;"j,;," P,"oduct Name J-SPRAY GLANCE GLASS CLEANER _ USE Code SOLUTION 1140010 Prod lIet (he Industrial/Institutional: Cleaning product. P!\'IS# 114001/1-DIL Validation Date U.S. Hl'ad1luartl'l's Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com C:ln:-I(lian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Print Oat(. Supersedes In Case of Emcn:!enc\' Not available. 1211712002 12/1712002 MSfJS# No PreviOlls Validatioll. (800) 851-7145 Section 2. Composition and Information on Ingredients Ingn>dicut.'i CAS # 'x, by Weight Exposurc_ Limits LC50lLfJSO Ethoxylated Alcohol 61827-42-7 <1 Not available. Not available. Water 7732-18-5 60-100 Not available. Not available. Secffon3.Hazardsldenffficaffon Routes of Entry Inhalation. Skin contact. Eye contact. . POlential Acute Health Effecls t.)'t'S None known. Skin None known. lulU/haion None known. /llgesrioll None known. Medical Conditions None known. Aggravated by OverexfloslI,.e: See Toxicological Information (section]l) Section 4. First Aid Measures Eye Contael Rinse with plenty of running water. Skin Contact Rinse with plenty of running water. Inhalation No specific first aid measures are required. Ingestion No specific first aid measures are required. Date Received: APR - 9 2010 Continued on Next Page Orininal Submittal Page: 11T }~IJJlJf/!!Il!!~ . U".Jl~ f.___.",~"'~..__, W" d., . . J-SPRAY GLANCE GLASS CLEANER - USE SOLUTION Material Safety Data Sheet Section 5. Fire Fighting Measures Flammability of the Pmduct None known. Flash Points CLOSED CUP: >93"C (199.4"F). ProdtH:ts of Comhm;lion None known. Fire Fighting i\'kdia Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Norma! fire and Instructions fighting procedure may be used. Prot{'ctin' Clothing (Fire) Put on appropriate personal protective equipment (see Section 8). Spl'dal Remarks on Fire and None known. EX[llosion Hazards Personal Pn'cautions Section 6. Accidental Release Measures Environmental PI-ecautions and Cll'an-lIp J\lethods Put on appropriate personal protective equipment (see Section 8). In the event of major spillage: 'Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean~up. Section 7. Handling and Storage Handling Use appropriate hygiene measures when handling product. FOR INDUSTRIAL USE ONLY Storage Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHilDREN. Section 8. Exposure Controls/Personal Protection Engineering Controls No special ventilation requirements. General room ventilation is adequate. P('rsonall'rott.t"tion l:.)es No special protective clothing is required. H{f"ds No special protective clothing is required. Re.\pimt01J' No special protective clothing is required, Feet No special protective clothing is required. Body No special protective clothing is required. Section 9. Physical and Chemical Properties Physical State :1II<! Appearance Otlor Culm' pH Sredlie Gravity Boiling/Condensation Poinl Melting/Freezing Point Viscosity Soluhility in water Liquid. Characteristic. Clear Blue. 10 [Basic.] 1 >93"C (199.4"F) OOC (32"F) <50 cP (Dynamic). Complete, Section 10. Stabifity and Reactivity n...+o '"" ,d: St:lhility and R(':lctivity The product is stable. Conditions of Instability None known. ADD n .",,, Incompatibility with Various None known. ~... 'y ~''''f Substances Hazanlolls Decomposition When exposed to fire: Produces normal products of combustion. Original Submittal Products Hazardous Polymerization Will not occur. Continued on Next Page Page: 2/3 . . john5on wax P'RaJJ:'W:5<vOlY/f\I, J-SPRA Y GLANCE GLASS CLEANER - USE SOLUTION Material Safety Data Sheet Section 11. Toxicological Information Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). DERMAL (LD50) Estimated to be oreater than 2000 maiko irat). Effects of Chronic Expo.'iure None known. Other Toxic Em'cts Not available. Section 12. Ecological Information I\'ot'l\':lilahle. Section 13. Disposal Considerations \Vasft'lnformation No special precautions. Dispose of according to all federal, state and local regulations. Section 14. Transport Information DOT C1assilicrltioll Nul regulated TOG Classilication Nol reg:ulaled Section 15. Regulatory Information Reporting in this section is based on ingredients disclosed in Section 2 US Reg:uJalions Rl'f~jstrred Product Not applicable. Information C:lI1adian Regulations WIIMIS ClassilicMioll Not controlled under WHMIS (Canada), WIIMISlcon @ H.l'gislered Product Not applicable. Information Chemical Inventory StatuS' All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Section 16. Other Information Otht"o Special Not available. Considerations Vt'rsiOIl 1 Nnlice to Reader T"i~' documeJlt has heelt prepared u~illg data from sources cOllsidl'red techllict1lly rl'liable. It doe~' /lot ('OIlstitl/te a warraltQ', express or implied, as to tlte accuracy of the i"formatioflcolltaifled withilt. Actllal cOllditioll,'i ofl/sealld hal/dlillg are beyond seller's cOlltrol. User is re!opoJlsible to ellaluatl' all ami/able illformation wheu llsing product for ally pOlticular use amI to COIllp(" with all Federal, State, Provillcial ali(I Locallaws aud regulationso Date Received: APR "' 9 2010 Original Submittal ~ Georgia.pacific . . MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product list Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free Material name Product use Manufacturer information 2. Hazards Identification Emergency overview Target organs Potential health effects Eyes Skin Inhalation Ingestion Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free Hand Sanitizer 1000 mL SKU - 43331 45 mL SKU.48003 Manufactured for: Georgia-Pacific Consumer Products LP 133 Peachtree Street, NE Atlanta, GA 30303 MSDS Request: 404.652.5119 Technical Information: 866.435.5647 Chemtrec - Emergency: 800.424.9300 Contact with product may cause irritation to eyes and skin. Eyes May cause eye irritation. Symptoms may include discomfort or pain, excess btinking and tear production. Prolonged and/or repeated skin contact with this product may cause irritation. Not applicable under normal conditions of use. Not applicable under normal conditions of use. May cause gastrointestinal irritation if ingested. Components 3. Composition tlnformation on Ingredients ETHYL ALCOHOL WATER Composition comments 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion 5. Fire Fighting Measures Extinguishing media Suitable extinguishing media CAS # PercentIWt PercentIVol 64-17-5 62 70 7732-18-5 36 This product is considered not hazardous under 29 CFR 1910.1200 (Hazard Communication Standard). Meets Alcohol Requirements stated in FDA Tentative Final Monograph for aTe Healthcare Anliseptic Drug Products - 21 CFR Part 333.410 (a). In case of eye contact flush eyes with plenty of water. Seek medical attention if irritation persists. If irritation occurs, flush skin with plenty of water. Seek medical attention if irritation persists. Not a normal route of exposure. If symptoms develop, remove to fresh air. Get medical attention if irritation persists. If ingested seek medical attention or call a poison control center. Date Received: Powder, water spray, foam, carbon dioxide. APR ... 9 2010 OriQinal Submittal ~---------- Material name: Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free 10: 61768 Effective date: 09-11-2009 \1SDS COSMETICS DRUG 1/4 Protection of firefighters Protective equipment and precautions for firefighters Explosion data Sensitivity to static discharge Sensitivity to mechanical impact Hazardous combustion products . I . I Firefighters should wear full protective clothing ihcluding self contained breathing apparatus. I . Not applicable. Not applicable! Small amounts of nitrogen oxides. carbon monoxide, carbon dioxide, and hydrocarbons may be released. Personal precautions 6. Accidental Release Measures Environmental precautions Methods for containment Methods for cleaning up 7. Handling and Storage Handling Storage Use personal protection recommended in Section 8. Isolate area. Keep unnecessary personnel away from the release. Remove all solurces of ignition. If large quantities enter a waterway, advise locallauthorities. I Contain and/or absorb spill, then place in a suitable container. Soak into absorbent material. Spills of this mate~rial may become a slipping hazard. Thoroughly wash the area with water after a spill or leak. I . .. I Keep away from heat and sources of Ignition. For external use only. Keep out of the reach of children. Avoid contact with the eyes. Wear gloves and safety glasses or goggles if handling large quantities. I Keep away from children. Keep container tightly closed. Keep at temperatures below 49 o~. 8. Exposure Controls I Personal Protection ETHYL ALCOHOL (CAS # 64-17-5) TWA ACGIH OSHA Personal protective equipment Eye I face protection Skin protection Respiratory protection Not established 1000 ppm TWA; 1900 mg/m3 TWA STEL 1000 ppm Not established Ceiling Not' established Not established. None necessary under normal conditions of use. large quantities. None necessary under normal conditions of use. Not normally needed. ;Wear safety glasses or goggles if handling I I ":Near gloves if handling large quantities. 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state pH Melting point Freezing point Boiling point Flash point Evaporation rate Flammability Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Clear transparent liquid Colorless Alcohol Not available Liquid. 6-8 Not available Not available Not available 62.6 'F (17 'C) Not applicable Flammable 18 Not available Date Received: APR .. 9 2010 Not available )ngin:~: $ulJrnittal Not available Material name: Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free ro: 61768 Effective date: 09-11-2009 v1S0S COSMETICS DRUG 2/4 Vapor density Specific gravity Relative density Solubility (water) Partition coefficient (n-octanollwater) Auto~ignition temperature Decomposition temperature . . Not available 0.897 Not available Complete Not available Not available Not available 10. Chemical Stability & Reactivity Information Chemical stability Conditions of Reactivity Incompatible materials Hazardous decomposition products 11. Toxicological Information Stable at normal conditions Heat. Incompatible materials. Oxidizers. Acids. Chlorine. Metals Small amounts of nitrogen oxides, carbon monoxide, carbon dioxide and hydrocarbons may be released. No toxicological data available for this product. Toxicological information for components of this product is listed below. Toxicological information (Ingredients) ETHYL ALCOHOL (CAS # 64-17-5) Toxicology Dala - Selected L050s and LC50s Oral L050 Rat: 7060 mg/kg Irritancy Product may cause eye and skin irritation. Chronic effects Chronic toxic effects are unlikely under normal conditions of use. Carcinogenicity Not hazardous under normal conditions of use. ETHYL ALCOHOL (CAS # 64-17-5) IARC - Group 1 (Carcinogenic to Humans) Monograph 96 [2007] (in alcoholic beverages) U.S. - OSHA - Hazard Communication Carcinogens Present Mutagenicity Not hazardous under normal conditions of use. ReprOductive effects Not hazardous under normal conditions of use. Chronic ingestion of ethanol can cause reproductive/developmental and central nervous system effects, and liver disorders. Not available Not available Toxicological information Teratogenicity Synergistic materials 12. Ecological Information No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic systems and treatment plants is not considered environmentally harmful. ETHYL ALCOHOL (CAS # 64-17-5) Ecotoxicity - Freshwater Fish Species Data Ecotoxicity 13. Disposal Considerations Disposal instructions 14. Transport Information General 15. Regulatory Information US federal regulations 96 Hr LC50 Oncorhynchus mykiss: 12.0~ 16.0 milL [static]; 96 Hr LC50 Pimephales promelas:>100 mg/L [stalic]; 96 Hr Le50 Pimephales promelas:13400-151 00 mg/L [flow-through} This product, if discarded as supplied, is considered a hazardous waste under RCRA, 0001. DOT CLASSIFICATION ORM-O (Ground/Rail Transport) Flammable liquids no.s (Contains ethyl alcohol) Class 3; UN1993; PG II (Air Transport) TOG CLASSIFICATION Limited Quantity (Ground/Rail Transport) Flammable liquids n.o.s (Contains ethyl alcohol) Class 3; UN1993; PG II (f)"amsR~ceived: This product is regulated under the US Federal Food, Orug"and Cosmetic Ac~PR ...' 9 2010 Material name: Pacific Garden@ Foam Hand Sanitizer, Dye Free, Fragrance Free 10: 61768 Effective date: 09-11-2009 Original'SUlffltlU13! DRUG 3/4 . . Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. This product is regulated under Canada's Food & Drug Act. ETHYL ALCOHOL (CAS # 64-17-5) Canada - WHMIS - Ingredient Discfosure List 0.1 % 16. Other Information HMIS@ ratings Health: 1 Flammabilily: 3 Physical hazard 0 Health: 1 Flammabilily: 3 Instability: 0 IMPORTANT: The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification. Buyer assumes all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. Georgia Pacific and its subsidiaries make no warranty of any kind, expressed or implied, conceming the accuracy or completeness of the information and data herein. The implied warranties of merchantability and fitness for a particular purpose are specifically excluded. Georgia Pacific and its subsidiaries will not be liable for claims relating to any party's use of or reliance on information and data contained herein regardless of whether it is claimed that the information and data are inaccurate, incomplete or otherwise misleading. 11-Sep-2009 Georgia-Pacific LLC 404.652.5119 NFPA ratings Disclaimer Effective Date Prepared by Date Received: APR ~. 9 2010 Original Submittal Material name: Pacific Garden@Foam Hand Sanitizer, Dye Free, Fragrance Free 10: 61768 Effective. date: 09-11-2009 lASDS COSMETICS DRUG 4/4 . . tljc:a Healthcare KenDAll MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 1. PRODUCT AND COMPANY IDENTIFICATION Product Name UsetSize Product Numbers Man ufactu rerlS u pplier Address WEBCOLlCURITY Alcohol Prep Pads Wound Cleaner 5033, 5110, 515~ 575~6818 Tyco Healthcarel Kendall 15 Hampshire Street Mansfield, MA 02048 Phone Number (508) 261-8000 (Monday - Friday 8:00 am to 5:00 pm) Chemtrec Number (800) 424-9300 Revision Date: January 30, 2004 MSDS Date: September 14,1999 This MSOS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.120.0.) 2. COMPOSITION/INFORMATION ON THE COMPONENTS Component Name Isopropyl alcohol CAS#/Codes 67-63-0 200-746-9 Concentration R Phrases Classification >60% Rll, R36, R67 F, Xi 3. HAZARD IDENTIFICATION EU Main Hazards Highly flammable. Irritating to eyes. Vapors may cause drowsiness and dizziness Routes of Entry - Absorption - Eye contact - Ingestion - Inhalation - Skin contact Carcinogenic Status Not considered carcinogenic by NTP, IARC, and OSHA. Target Organs - Central Nervous System - Skin - Eye - Liver - Respiratory System Health Effects - Eyes Liquid, mist or vapor will cause conjunctival irritation and possibly corneal damage. Health Effects - Skin Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. Liquid may be absorbed through the skin but not in toxicologically significant amounts, unless the area of contact is large and exposure prolonged. Health Effects - Ingestion Swallowing may have the following effects: ; irritation of mouth, throat and digestive tract - central nervous system depression A large dose may have the following effects: - dizziness - drowsiness - headache - mental confusion - nerve damage leading to numbness and muscle weakness - fall of blood pressure - liver damage - lung damage Date Received: Health Effects - Inhalation Exposure to vapor may have the following effects: API? - 9 2911l Page 1 of7 Original Submittal Revision Date: January 30. 2004' . . 1:QCD ffea/thcare KEnDAll MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 3. HAZARD IDENTIFICATION - irritation of nose, throat and respiratory tract - central nervous system depression Exposure to vapor at high concentrations may have the following effects: - dizziness - drowsiness - headache - mental confusion - lung damage - fall of blood pressure liver damage - nerve damage leading to numbness and muscle weakness 4. FIRST AID MEASURES Eyes: Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention if soreness or redness persists Skin Immediately flood the skin with large quantities of water, preferably under a shower. Remove contaminated clothing and continue washing Contaminated clothing should be washed or dry- cleaned before re-use. Obtain medical attention if blistering occurs or redness persists. Ingestion Do not induce vomiting. Have victim drink 1-3 glasses of water to dilute stomach contents. If there is difficulty in brealhing, give oxygen. Obtain medical attention immediately. Inhalation Remove from exposure. If there is difficulty in breathing, give oxygen. Obtain medical attention immediately. Advice to Physicians Monitor for systemic secondary effects on liver and kidney; support and treat. 5. FIRE FIGHTING MEASURES Extinguishing Media Use foam, dry chemical or carbon dioxide. Be aware of the possibility of re-ignition. Keep containers and surroundings cool with water spray. Unusual Fire and Explosion Hazards Vapors can travel a considerable distance to a source of ignition and flashback. Flashback can occur if air temperature exceeds flash point. Be aware of possibility of re-ignition. Protective Equipment for Fire-Fighting Wear full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Wear appropriate protective clothing. Eliminate all sources of ignition. Vapors can accumulate in low areas. Consider need for evacuation. Prevent the matElr~.lr'l!l1&l'<l!li'O~d' drains or water courses. Notify authorities if spill has entered water cours~lii'l'S"ew~~'i:(I"'~as . contaminated sailor vegetation . APR - 9 2010 7. HANDLING AND STORAGE Use in well ventilated area. Use local exhaust ventilation. Ori~iRal ~blbwitt,,1 Avoid inhaling vapor. Avoid contact with Revision Date: January 30, 2004 Page 2 of? "tqeD . . Hea/thcare KEnDALL MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 7. HANDLING AND STORAGE eyes, skin and clothing. Keep container tightly closed when not in use. Store away from sources of heat or ignition. Storage area should be - cool - dry - well ventilated - away from incompatible materials 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards Exposure Limits are listed below, if they exist. Isopropyl alcohol UK EH40 OES 400ppm (980mg/m3) 8h TWA. UK EH40 OES 500ppm (1225mg/m3) 15min TWA. ACGIH TLV 200ppm (980mg/m3) 8h TWA. ACGIH STEL 400ppm (1225mg/m3) 15min TWA OSHA PEL 400ppm (980mg/m3) 8h TWA Can be absorbed through skin. Engineering Control Measures Good general room ventilation is expected to be adequate to control airborne levels. Respiratory Protection Respiratory protection if there is a risk of exposure to high vapor concentrations. The specific respirator selected must be based on the airborne concentration found in the workplace and must not exceed the working limits of the respirator. Hand Protection Chemical resistant gloves For isopropyl alcohol, gloves made of polyvinyl alcohol do not provide adequate protection. Eye Protection Chemical goggles or safety glasses with side shields Body Protection If there is danger of splashing, wear: - overall or apron 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Color Odor pH Specific Gravity Boiling Range/Point rC/F) Melting Point (OC/F) Flash Point (PMCC) (OC/F) Vapor Pressure Density Solubility in Water Vapor Density (Air = 1) Viscosity (cSt) Non-woven cloth saturated with liquid Clear Alcoholic No data. 0.8405 80/176 No data. 20/68 No data. No data. Miscible 2.1 2.9 cps at <@2> oC Date Received: APR ., 9 2010 Original SubmittaL Revision Date: Ja~uary 30, 2004 Page 3 of 7 . . tqc:o Healthcare KEnDAll MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to Avoid - Heat - High temperatures - Static discharge - Exposure t6 direct sunlight - Mechanical shock Materials to Avoid - Strong oxidizing agents - Acids - Halogens - Aluminum - Acid anhydrides - Isopropyl alcohol may attack some forms of plastic, rubber and coatings Hazardous Polymerization Will not occur. Hazardous Decomposition Products - oxides of carbon 11. TOXICOLOGICAL INFORMATION Acute Toxicity Low order of acute toxicity predicted. Material may be harmful by skin absorption Isopropyl Alcohol: Oral LD50 (rat) 5045 mg/kg. Dermal LD50 (rabbit) 12800mg/kg. Inhalation LCLO (rat) 1600ppm 4h Chronic Toxicity/Carcinogenicity This product is not expected to cause long term adverse health effects. (Isopropyl Alcohol) IARC assessment: this product is nol classifiable as to its carcinogenicity to humans (Group 3). Chronic/Subchronic studies resulted in adverse effects to: - liver - spleen _ biochemical effects - brain tissue degeneration - changes in reflex behavior - sensory nerve damage Genotoxicity This product is not expected to cause any mutagenic effects. Reproductive/Developmental Toxicity This product is not expected to cause reproductive or developmental health effects. (Isopropyl Alcohol) Experimental studies in animals have provided some evidence of embryo/fetoxicity and birth defects only at doses prod~cing marked maternal toxicily. 12. ECOLOGICAL INFORMATION Mobility (Isopropyl Alcohol) If released to soil, isopropyl alcohol is expected to have very high mobility. PersistencelDeg radabi I ity (Isopropyl Alcohol) Isopropyl alcohol is readily degraded in aerobic aqueous systems. Bio-accumulation (Isopropyl Alcohol) An estimated BCF of 3 suggests the potential for bioconcentralion in aquatic organisms is low. Ecotoxicity (Isopropyl Alcohol) Date Received: Tests on the following species gave a 96h LC50 of 1150mgllitre: - brown shrimp Tests on the following species gave a 96h LC50 of6.12-9.64mg/litre: - fathead minnows APR - 9 2010 Revision Date: January 30,' 2004 origi~~~'StBfJittal . . tileD Hea/rhcare KEnDAll MA TERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 13. DISPOSAL Dispose of in accordance with all applicable local and national regulations. Labels should not be removed from containers until they have been cleaned. Do not cut, puncture or weld on or near to the container. Do not incinerate closed containers. Empty containers may contain hazardous residues. Dispose of containers with care. 14. TRANSPORT INFORMATION DOT CFR 172.101 Data Proper Shipping Name Class UN Number Packing Group Classification for AIR Transport(IATA): Not Regulated per 49 CFR 173.4 Small Quantity Exemption None None None None Consult current lATA Regulations prior to shipping by air. 15. REGULATORy'INFORMATION lEU label Information I Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC including amendments. EU Hazard Symbol and Indication of Danger F - Highly flammable Xi -Irritant R phrases R11 - Highly flammable. R36 - Irritating to eyes. R67 - Vapours may cause drowsiness and dizziness. S phrases S2 - Keep out of reach of children. S7 - Keep container tightly closed. S16 - Keep away from sources of ignition - No smoking. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US REGULATIONS Federal, State and INTERNATIONAL CHEMICAL REGISTRATION lAWS TSCA Listing This producf contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance Control Act Chemical Inventory. EINECS Listing All ingredients in this product are listed on the European Inventory of Existing Commercial Chemical Substances (EINECS) or are exempt from listing. DSl (Canadian) Listing Date Received: All ingredients in this product are listed on the Domestic Substance List (DSL). MA Right To Know law ADD"; 9 2010 All components have been checked for inclusion on the Massachusetts Substance List (MSL). "Th&e Revision Date: January 30. 2004 ciriglMI ~JbmittaL . . 1:qCD Hea/thcare KEnDAll MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 15. REGULATORY INFORMATION components present at or above the de minim us concentration include: - Isopropyl Alcohol PA Right To Know Law This product contains the following chemicals found on the Pennsylvania Hazardous Substance List: - Isopropyl Alcohol NJ Right To Know Law This product contains Ihe fOllowing chemicals found on the NJ Right To Know Hazardous Substance List: - Isopropyl Alcohol California Proposition 65 This product does not contain materials which the Stale of California has found to cause cancer. birth defects or other reproductive harm. SARA Title III Sect. 302 (EHS) This product does not contain any chemicals subject to SARA Title III Section 302. SARA Title III Sect. 304 This product does not contain any chemicals subject to SARA Title III Section 304. SARA Title III Sect. 311/312 Categorization Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard Flammable SARA Title III Sect. 313 This product does not contain a chemical which is listed in Section 313 al or above de minimis concentrations. 16. OTHER INFORMATION NFPA Ratings NFPA Code for Flammability - 3 NFPA Code for Health - 1 NFPA Code for Reactivity - 0 NFPA Code for Special Hazards - None HMIS Ratings HMIS Code for Flammability - 3 HMIS Code for Heallh - 1 HMIS Code for Reactivity - 0 HMIS Code for Personal Protection - See Section 8 Abbreviations N/A: Denotes no applicable information found or available CAS#: Chemical Abstracts Service Number ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration TL V: Threshold Limit Value PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit NTP: National Toxicology Program IARC: International Agency for Research on Cancer EU: European Union R: Risk S: Safety Prepared By: EnviroNet LLC. Date Received: APR .. 9 2010 Original Submittal '. Revision Dale: January 30. 2004 Page 6 of 7 . . tqCD flea/thcare KEnDAll MATERIAL SAFETY DATA SHEET WEBCOLlCURITY Alcohol Prep Pads 15. REGULATORY INFORMATION The information and recommendations presented in this MSDS are based on sources believed to be accurate; therefore, The Kendall Company assumes no liability for the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of the information for their particular purposes. Date Received: APR - 9 2010 Original Submittal Revision Date: January 30, 2004 Page 7 of7 . . MATERIAL SAFETY DATA SIIEET FOR EZK ANTISEPTIC TOWELETTE POI - PROFESSIONAL DISPOSABLES INTERNATIONAL THE ilEAL THCARE DIVISION OF NICE-PAK PRODUCTS, INC TWO NICE-PAK PARK ORANGEBURG NY 10962-1376 845-3(,5-1700 REVISION DATE: 7/00 I-PRODUCT IDENTlFICA TlON PRODUCT/TRADE NAME: BZK ANTISEPTIC TOWELETTE D35 [00, D35185, D35187, K45881 HAZARD RATING (NFPA) HEALTH: () FLAMMABILITY: () REACTIVITY: () SPECIFIC: NONE EMERGENCY OR INFORMATION TELEPHONE NO: 845-365-17IJO (M-F DA YTIME) AT OTHER T[MES, CONTACT THE LOCAL POISON CONTROL CENTER CHEMICAL NAME: MIXTURE II-IIAZARDOUS INGREDIENTS PER2YCFR IYIO.1200 Hazardous Ingredients % ACGIH TLV CAS NUMBER NONE. NO COMPONENTS OVER 1% OF FORMULATION HI-PII\'SICA LlCII EM ICAL CIlARACTERISTlCS COLOR/ODOR/APPEARANCE: TOWELETTE SATURA TED WITH CLEAR COLORLESS LIQUID. BO[LlNG POINT: N/A FLAS[I POINT: NOT APPLICABLE VAPOR DENSITY: N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: COMPLETE SPECIFIC GRA VITY (H2O ~ I): 1.0 /V-FIRE & EXPLOSION HAZARD DATA FLASIl POINT(Method Used): NOT APPLICABLE: LEL:N/A UEL:N/A EXTINGUISHING MEDIA: ANY SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE V-REACTIVITY DATA STABILITY: STABLE CONDITIONS TO A VOID: N/A INCOMPA TIBILlTY: ANIONIC SURFACTANTSISOAPS HAZARDOUS DECOMPOSITION OR BYPRODUCTS: NONE POLYMERIZA TION: WILL NOT OCCUR CONDITIONS TO A VOID: NONE Date Received: APR '" 9 2010 Original Submittal . . VI-I/EALTI/ HAZARD DATA EFFECTS OF OVER EXPOSURE: SKIN: NONE EYES: MA Y CAUSE DISCOMFORT INI.IALATION NONE INGESTION NONE EMERGENCY AND FIRST AID PROCEDURES: SKIN CONTACT: DISCONTINUE USE IF RASH OR IRRITATION OCCURS EYE CONTACT: FLUSH WITH COLD WATER IF SPLASHED IN EYES INHALATION: NONE INGESTION NONE TARGET ORGANS: NONE VI/-SPILL AND DISPOSAL PROCEDURE SPILL CONTROL RINSE INTO SEWER SYSTEM WASTE DISPOSAL METHOD: FOLLOW LOCAL STATE AND FEDERAL REGULATIONS HANDLING AND STORAGE NONE VII/-CONTROL MEASURES/PROTECTION RESPIRATION: NONE. VENTILATION: NONE. PROTECTIVE GLOVES: NONE EYE PROTECTION: IF SPLASH POTENTIAL EXISTS HYGIENIC PRACTICES: GOOD HOUSEKEEPING PRACTICES SHOULD BE FOLLOWED. OTHER: NONE IX- TRANSPORT/SH IPPING DOT SHIPPING NAME: TECHNICAL SHIPPING NAME: DOT SHIPPING CLASSIFICATION: DOT Not Rcgulalcd DOT ID NO.: DOT; LABEL; REQUIREMENTS: UN/NA NUMBER REGULATIONS: REPORTABLE QUANTITY X-DISCLAIMER THE INFORMATION FURNISHED HEREIN IS BELIEVED TO 13E ACCURATE AND REPRESENTS THE BEST DA TA CURRENTLY A VAILA13LE TO US. NO WARRANTY. EXPRESSED OR IMPLIED IS MADE AND NICE-PAK PRODUCTS, INC ASSUMES NO LEGAL RESPONSll3ILlTY OR LIABILITY RESULTING FROM ITS USE Date Received: APR -' 9 2010 Original Submittal ~,,~ BD Material Safety ~ Data Sheet Becton Dickinson and Company SECTION 1 - IDENTITY NAME ADDRESS Becton Dickinson Consumer Hcalthcare One Becton Drive, Franklin Lakes, NJ 07417-J 883 TELEPHONE NUMBER FOR ADDITIONAL INFORMATION CONTACT: DATE PREPARED (201) 847-4288 Hitcsh Patel March 22, 200] COMMON NAME (USED ON LABEL) CHEMICAL FAMILY 70% Isonrol)v] Alcohol Preps Alcohol CHEMICAL NAME FORMULA Isopropyl Alcohol (CH,hClIOH TRADE NAME & SYNONYMS 80 Alcohol Swabs SECTION 2 - HAZARDOUS INGREDIENTS HAZARDOUS COMPONENT CAS # %(WT) fLV PEL IsoproryJ Alcol1ol 67-63-0 70 no !'\'lg/M3 no !'vlg/M3 PEL: Pellllissible Exposure Limit established by the Occupational Safely and Health Administration (OSHA). TLV: Threshold Lilllit Value established by the Amelican Confcrci1ce ofGovemmcnt.allnduslriaJ Hygienists, llJ8(i-] 987. SECTION 3 - PHYSICAL DATA BOILING POINT I SPECIFIC GRAVITY (H,O-I I VAPOR PRESSURE (mm Hg) 82.4 degrees C .869 - .879 at 25 degree; C 33mm al 20 degrees C PERCENT VOlATILE BY VOlUME (%) I VAPOR DENSITY (AIR-I) I EV APORA TIOt, RA TE (Bulyl Acetate -I) lVO'% 2.07 2.88 SOLUBILITY IN WATER REACTIVITY IN WATER I Soluble Docs IlOl anuly APPEARANCE AND ODOR Water white with an alcohol odor. SECTION 4 - FIRE AND EXPLOSION DATA fLASH POINT FLAMMABLE LIMITS IN AIR (% by Volume) 12 dCi!rccs C LOWER: 2.0% UPPER: 12.7% EXTINGUISHING MEDIA AUTO IGNITION TEMPERATURE Carbon Dioxidc, alcohol foam or dry chemical 399 dC"l'ces C UNUSUAL FIRE AND EXPLOSION HAZARDS None SPECIAL FIRE FIGHTING PROCEDURES Date Received: None SECTION 5 - HEALTH INFORMATION ~..; Q ?nm PRIMARY ROUTES Of EXPOSURE Skin, Eye, Inhalation or Ingestion Original Submittal . . . . SIGNS AND SYMPTOMS OF EXPOSURE Direct contact with eyes may result in irritation Target Organs: Eyes, skin and respiratory (I) ACUTE OVEREXPOSURE tract . (2) CHRONIC OVEREXPOSURE- Prolonged contact with skin may result in drying or irritation. Prolonged inhalation of va pOT;; may callse slight headaches or dizziness. Prolong_cd exposure to vapOrs may result ill eye irritatioll. MEDICAL CONDITIONS GENERALL Y AGGRA V A TED BY EXPOSURE Isopropyl :llcohol is not a known liver or kidney toxin: persons with impaired I iver or renal function should limit expOSllre. CHEMICAL/COMPONENT LISTED A5 CARCINOGEN OR POTENTIAL CARCINOGEN NTP I.ARC OSHA None 0 Yes @ 0 Yes o No DYes IE] No No OTHER EXPOSURE LIMITS None detennined. EMERGENCY & FIRST AID PROCEDURES: EYE CONTACT: Flush with waler lor]5 minutes, seek medical attention SKIN CONTACT: Flush with watcr for 15 minutes II,GESTlON: NOlllkcly: if ingestion OCCUl'3, do not induce vomiting, seek medical ultenlioll. SECTION 6 - REACTIVITY DATA STABILITY 1 CONDITIONS TO A VOID Ullslable 0 Slable IE] NOllc Detcrmincd. INCOMPATIBILITY (MATERIALS TO AVOIDI Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS Not determined HAZARDOUS POL YMERIZA TlON I CONDITIONS TO A VOID May Occur 0 Will not Occur IE] NOllC SECTION 7 - SPILL OR LEAK PROCEDURES 8 STEPS TO BE TAKEN IN CASE MATERIAL IS LEAKED OR SPILLED Not like]y Lo spill or leak. WASTE DISPOSAL METHOD Dispose orin accordance \\tlh applicable loca], state and fedcrJllaws. SECTION 8 - PERSONAL PROTECTION INFORMATION RESPIRATORY PROTECTION Respinl\ory protection is not required under nonnal use. VENTlLA TlON For nOlmal use - use in a well ventilated arca. PROTECTIVE GLOVES I EYE PROTECTION Not required under non11a] use. Not required undernonnaluse. OTHER PROTECTIVE CLOTHING OR EQUIPMENT Date Received: Not required undernonnal use. APR .. 9 2010 SECTION 9 - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING & STORING urlgmal Store away tram heat and ignition sources. . . OTHER PRECAUTIONS No! determined. TIfE INI:ORMATION CONTAINED WfTlIIN WAS ()BTAJNl~D FROM A UT/IORITA'f'/JlE SOURCES AND IS BEL/EYED 'jO BE ACCURATE FOR THE MANNER IN WfffCf! TIfE PRODUCT IS' il'lTENDED TO BE U.VED. OTiltR U.)'ES COULD RESIJ/J IN CONSEQUENCES WHICH ANE NOT CONSIIJERED W1TJJJN TI-flS DOCUMENT Date Received: APR .;; 9 2010 Original Submittal . . MA TERlAL SAFETY DA T ^ SHEET 3l\ffM Cavilon™ No Sting Barrier Film with Foam Applicator (10) 3343, 3344. 3345, 3343E, 3344E, 3345E, 3343P, and 3345P 11/16/09 Material Safety Data Sheet Copyright, 2009, 3M Compnrty. All rights reserved. Copying ancl/or downloading ot'this infonnation lor the purpose of properly utilizing 3M products is allowed provided thaI: (I) the infol1nation is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed \'-/ith (he intention of etnling a profit thereon. SECTION 1: PR0DUCT AND COMPANY IDENTIFICATION. I PRODUCT NAME: 3MTM Cavilon™ No Sting Barrier Film with Foam Applicator (10) 3343, 3344, 3345, 3343E. 3344E, 3345E, 3343P, and 3345P 3M Skin & \Vound Care Division MANUFACTURER: DIVISION: ADDRESS: 3M Center Sl. Paul, MN 55144-10011 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-65111 (24 hours) Issue Date: Superccdcs Date: 11/16109 11/16/119 Document Group: 20-0585-8 Product Use: Intended Use: Skin protcctal1l barrier Jl]1ll. SECTI@N2:INGREPIENTS I Im!:redient Foam applicator Hcxamethyldisiloxane booctanc Acrylate Terpolymer PolyphenylmcLhylsiloxane Copolymer C.A.S. No. Unknown I 07.46-0 540-84-1 Trade Secret 73559-47.4 lYo bv \Vt 92. 96 2 - 8 0.1 . 3 0.] . I <O,S Liquid is saturated onto foam applicator. There is no frcc-Oowing liquid. I SEC1;IbN 3: HAZARDS IDENTII<;ICATION I Date Received: 3.1 EMERGENCY OVERVIEW Spedtk Physical Form: fluid on foam apphcator or wipe. Odor, Color, Grade: Foam applicator or wipe with clear, odorless liquid. General Physical Form: Solid Immediate health, physical, and environmental hazards: Flammable solid. APR ~ 9 2010 Original Submittal Page 1 of 7 . . MATERIAL SAFETY DATA SHEET 3j\rr~1 Cavilon™ No Sting Barl'icr Film with Foam Applicator (IO) 3343, .1344; 3345. 3343E, 3344[,33451':, 3343P, mid 3345P 11/l(i/U9 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms Illay include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Cout<lct: No health effecls arc expectl:d. Inhalation: No health clTcC1S are expected. Ingestion: No health ctT~C(S arc expected I SECTION 4: FtRSTAlD MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations arc based on an asslImption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, gel medical attention. Skin Cuntact: No need for first aid is anticipated. Inhalation: No nccd for first aid is anticipated. If Swallowed: No need for first aid is anticipated. I SECTION 5: FIRE-cFIGHTING MEASURES.c . 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL 665 "1' 14 'T [Teot Method. Closed Cup] 0.8 % 14.1 % Date Received: 5.2 EXTINGUISHING MEDIA Use {ire extinguisl!ers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). APR .,. 9 2010 5.3 PROTECTION OF FIRE FIGHTERS Original Submittal Page 2 of 7 . . iVlA TERJAL SAFETY DATA SHEET ]l\f1~1 Cavilon'nl No Sting Barrier Film with F03111 Applicator (10) 3343, 3344, 3345. 3343E, 3344E. 3345E,.H43P, and 3345P 11/16/119 Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatLls (SeBA). Unusual Fire and Explosion Hazards: FI<1lTllllablc solid. The liquid absorbed onto the l'oam applicator has a flash point 01'30 degrees F. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous eomhustion and thermal decomposition inf'ormation. SECTION 6: ACCIDENTAL RE.LEASE MEASURES Accidental Release tvlcasurcs: Place in a mc(,d container approved Cor tr<lIlsportalion by appropriate authorities. Refer to other sections oCthis MSDS lor infollllation regarding physical and health hazards, respiratory protection, ventilation, and personal protectivc equipment. Call 3M-HELPS line (I -800-364-3577) for more information on handling and managing \he spill. Collect ,IS Illuch of the spilled material as possible llsing non-sparking tools. Clean up rcsidue. In the cvcnt of a release ofthis materi:.tll the user should determine ifthe release (IUalifies as report~lble according to loe:11, state, and federal reoulat'ions. SECTION 7: HANDLING A~D;S:rQRAGE 7.1 HANDLING Contellts may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. No smoking whik handling this material. Kecp out of the rC<lch of childrcn. ^ void contact' with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heal. Store out of direct sunlight. Keep container in well-ventilated area. Store away from oxidizing agents. I SECTION 8: EXPOSlJR~,~0NTRQLs/PERSONA:L PROTECTION 8,1 ENGINEERING CONTROLS Not applicable. 8.2 . PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection A void eye contact. Date Received: S.2.2 Skill Protection Not applicable. APR ... 9 2010 Original Submittal 8.2.3 Respiratory Protcc.tion Page 3 of 7 . . MATERIAL SAFETY DAT;\ SHEET 3MTM Cavilon1M No Sting Barrier Film with Foam Applicator (10) 3343, 33-14, 3345, 3343E, 3344E, 3345E, 33431'. <llld 33451' 11/16109 Under Ilormalusc conditions, airbomc exposures arc not expected to be significant enough to require respiratory prott'ctioll. N.lA Prevention of Swalluwing Do 1101 ingest. 8.3 (eXPOSURE GUIDELINES III!!rcdil'nt Isooclan~ ISlJodanc Authorit\' ACGIH ACGIH T"pe T\VA STEL Limit 300 ppm 375 ppm Additionallnfarmation SOURCE OF EXPOSURE LIMIT DATA: ACGII-1: American Conference of GOvcrJlIllcnlal Industrial Hygienists CjvlRC,: Chemical I'vlanufacturcr Recolllmended Guideline OSHA: Occupational Safety and Health ^dministratioll 1\11-11\: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SE:CTION 9: PHYSICAL AND CHE:MICAL PROPE:RTIES Spccilic Physical Form: Odor, Color, Grade: General Physical Form: :\utoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - VEL Boiling point Fluid all foam applicator or wipe. Foam applicator or wipe with clear, odorless liquid. Solid 665 "F 14 "F [Tesl MelhoJ Closed Cup] O.R %1 14.1 % 212 "I' [Tesl Melhod: ASTM METHOD] [Details. (For liquid p0l1ion)] 0.78 g/ml [Details: (For liquid portion)] Not Applicable Ilensity Vapor Density Vapor Pressure <= 41mml-lg S()ecific Gravity flll Melting point Solubility In \Vater 0.78 [Test Melhod: ASTM METHODlrR~fStd. W^TER=I] Approximately 7 [Details: (For liquid porlion)] No Data Available <=.1 % [Test Method: ASTM METHOD] E\'~lporation rate Volatile Organic Compounds Kow - Oct/\Vatcr partition cocf Percent volatile voe Less 1-120 & Exempt Solvents Viscusity <""I [Test Methad: ^STM METHOD] [RefS/(I: ETHER~I] 720 g/l [Delails: (For liquid portioo)] No! Applicable 88 - 94 % No Dara Available 5 ceulipoise [Tesl Method: ASTM METHOD] [Details: (For liquid portion)] SECTION 10: STABILITY AND RE:ACTIVITY Date Received: Stability: Stable. Original Submittal Page 4 of 7 . . l\lATERIAL SAFETY DATA SHEET 3i\pM Ca\'ilonH1 Nu Sting Barrier Film with Foam AppliC:ltor (10) 3343, 3344, 3345, 3343E, 3344E. 3345E. 3343P. and 3345P 11116/09 i\'lnfcrials and Conditions tu A void: 10.1 Conditions to :t\'uid Heat, Sparks and/or flames 10.2 Materials tu avoid Strong oxidizing agents I--I<lz.udous Polymerization: Hazardous polymerization will nol occur. Hazardous Decomposition or By-Products SuhshlllCC Carbon monoxide Carbon dioxide Condition During Combustion During Combustion SECTION II: TOXICOLOGICAL INFORMATION Please cOlltaclthc address listed on the lirst page of the MSDS for Toxicologicallnlomlalion on this material and/or ils COlll Janents. I SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. I SECTION 13: DISPOSA'L CONSIDERATIONS \Vastc Ilisposal i\lcthod: Incinerate in a pennitted hazardous \\'aste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EI'A Hazardous Waste Number (RCRA): DOOI (Ignitable) Date Received: licahlc rc ulatiolls ur authorities before dis osal. SECTI0N 14:TRANSPORT INFORMATION R..;9,nm ID Numbcr(s): 44-0042-8868-2,70-2007-4653-8, 70-2007-4654-6, 70-2007-4655-3, 70-2007-4656-1, 70-2007-4657-9, 70-2007-4658-7, 70-2007- 4659-5,70-2007-4660-3,70-2007-4673-6 Original Submittal Page 5 of 7 . . I\'IA TERIAL SAFETY DATA SHEET 3!\FJII CuvilonHI No Sting B;uricr Film with Foam Applicator (10) 3343, 3344, 3345. 3343E. 3344[,3345[, 3343P, and 3345P II/Hi/ll9 Please contact the emergency numbers listed Oil the first page of the I\1SDS for Transportation Infonnatioll fur- this lII:lterial. SECTION 15 :REGULNf:QRY'llNF<?RM.:\'tI0N US FEDERAL REGULATIONS Contact 3M for morc infonnation, J J 1/3 I 2 Uazar"d Categories: Fire: Hazard - y~s Pressure Hazard - No Reactivity Hazard - No Immediate J-/<lzard - Yes Delayed Hazard _ No STATE REGULATIONS ConIne! 3M for more jnfo)lJJation. CHEMICAL INVENTORIES This material contains one or more substances lIollisted on the TSCA Inventory. COl1llllcrcialusc of this material is regulated by the FDA. Contact 3M for more infonnalion. INTERNATIONAL REGULATIONS Contact 3M for more infonnatioIl. This MSDS has been rc ared tu meet the U.S. OSHA Hazard Cummunication Standard, 29 CFR 1910.1200. SECTION 16:0fFIlifRI'NFORl\1A;rJIQN Date Received: API< . 9 2010 NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Spcciall-lazards: Nonc Original Submittal National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel 10 address the haf.arcls that are presented by shoft-term, acute exposure to a materia! under conditions of/ire, spill, or similar emergencies. Hazard ratings are primarily based all the Page 6 of 7 . . MATERIAL SAFETY Hi\. T A SHEET 3MTM C:n'ilon™ No Sting- Barrier Film with Foam Applicator (10) 3343. 3344, 3345, 334JE, 3344[,3345[, 3343P, and 33451' 11/1(ifll9 inherent physical anu toxic properties oflhe material but also incluck: th~ toxic properties ol'combustioll or Jccomposition products that are known to be generated in significant quantities. Revision Changes: Section 9: Properly description for optional properties was modified. Section 9: Density infomlation was modified. Section 9: Vapor pressure valuc was modified. Section 9: Boiling point infol1llation was modified. Section 5: Autoignition temperature infonmllioll was modified. Section 5: Flash poillt information was modified. Section 9: Specific gravity information was moJiried. Section 9: Flash point inCormation \\'as moJdi\'d. Section 9: Autoignition temperature infonllation was modified. DISCLAIMER: The information in this Material Salety Data Sheet (MSDS) is believed to be correct as of the date issued. 31'\'1 MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, IJUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3rvl product is !it for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can aflCct the use and application of a 3M product. some of which are uniquely within the user's knowledge and control, it is esscIHial that the llser evaluate the 3M product 10 determine whether it is fil for a particubr purpose and suitable for user's method of use or application. 3M provides information in electronic foml as a service to its cllstomers. Due to the remote possibility that electronic transfer may have resulted in errors, omissiolls or alteratiolls in this information, 3M makes no reprcsentalions as to its completeness or accuracy. In addition, infonnallon obtained from a database may not be as current as the information in the I'vtSDS available directly from 3M. 3M MSDSs are available at w\\'w.3M.com Date Received: APR - 9 2010 Original Submittal Page 7 of 7 . . MATERIAL SAFETY DATA SHEET Revised/ Reviewed: October 11, 2007 SURGICAL INSTRUMENT CLEANER AND LUBRICANT Cata10guc Number 3-710 Section 1" Product andCollJpany Information Manufactured for: Miltex, Inc.; 589 Davies Drive, York, FA 17402 Information: 717-840-9335, 717-840-9347 (fax) Chemical Name & Synonyms: n Chemical Descri]Jtion: Concentrated solution with surlnctanls, lubricants, and corrosion inhibitors. Section 2~ Composition/ Information onlngr.edients No hazardous components as defined by OSHA Hazard Communicalion Standard 29CFR 1910.1200. Section 3 -Health Identification Potential Health Effects: May cause buming if contact with eyes occurs. Degree of bum depends upon duration of contact. May iITitate and bum the skin. Severily orirritalion depends upon duration of contact. Rinsing contact area immediately with water will dramatically recluce irritation. Halllllltl if swallowed; may cause buming. If inhaled, may cause headache, nausea, irritalion or the nose, throal, and lungs. Primary Route!s) of Entry: Ingestion, Eyes, and Skin Conlact Carcinogen: No infol111ation. Medical Conditions Aggravated by Exposure: No information HMIS Ratings: Health ~ I; Fire = 0, Rcactivity = I Section :4 - FirstAid ;Measures Eyes: Following eye contact, flush eyes immediately with plcnty of water for 15 minutes. Assure adequate flushing of the eyes by separating the eyelids withfingcrs. Get medical attention ifilTitation OCCllrs. Skin: Following skin contact, wash area at once with plenty of water for 15 minutes. Rinsing promptly with water will reduce irritation considerably. Ingestion: If swallowed, wash mouth out immediately with water provided person is conscious. Giye person a glass of water. Never give anything by mouth to an unconscious person. DO NOT INDUCE VOMITING. Get medical attention immediately. Inhalation: Moye person to fresh air if irritation occurs. Get medical attention. Date Received: APR ..; 9 2010 Original Submittal Page ] of 3, Cleaner and Lubricant MSDS . . Section 5 - Fire Fighting Measures Flash Point crest Method): Non-flammable Auto Ignition Tcmperature: Non-tlammable Flammable Limits- Not applicable Extinguishing Media: Use water spray, carbon dioxide, dry chemical powder or appropriate foam. Special fire fighting Procedures: Wear MSI-IA/NIOSH approved selt~contained breathing apparatus and appropriate protective clothing. Unusual Fire and Explosion Hazards: Could release hydrogen gas, carbon monoxide and carbon dioxide. Physical State: Liquid. Appearance and Odor: A clear, green-colored liquid with a slight soap-type scent. Boiling Point (oC): No inti:nmation Spccitic Gravity (H20~]): 1.00 Vapor Density (Air=]): No infol111alion Evaporation Rate (butyl acctate=]): No information Section 6 - Physical and Chemical Properties Vapor Pressure (mm Hg): No inJol111ation Solubility in Water: Soluble Jili: 7.5-8.6 Stability: Stable. Conditions to Ayoid: No intormation. Incompatibility/ Materials to A void: Do not mix with strong acids such as HydrochlOlic acid or Sulfuric acid (heat can develop). Hazardous Polymerization: Will not occur. Hazardous Decomposition Producls: Could release hydrogen gas, carbon monoxide, and carbon dioxide. Section 7 - Stability and,Reactivity Section 8~ ActideotaLRelease, Disposal; and;EcoI6gical'Jriformation Spill Response: For small spills, add inert absorbent, sweep up, and place the material in plastic drums for disposal. For larger spills, dike to con lain and pump into drums approved for disposal. Wastc Disposal Mcthod: Dispose in accordance with all applicable federal, state, and local regulations. Ecological. General: No information Section 9 - Exposure Controls! Personal Protection Eye and Face Protection: In cases where there is the likelihood of eye contact, wear chemical goggles. Respiratory Protection: None normally reqnired. Ventilation Recommendations: General local exhaust Skin Protection: Wear imperyious gloves as standard handling practice. Other: Protect from clothing by wearing coyeralls. Date Received: APR ... 9 2010 Original Submittal Page 2 of3, Cleaner and Lubricant MSDS . . Section 10 - Storage and,Handling Slora~e: Keep eonlainer tightly closed when not in use and during transport Store at room temperature. Handling: Empty containers should be rinsed and discarded in a waste conlainer or ot1ered for recycling ifpossible, Do not use empty containers lor other purposes, Handle wilh Care and ayoid unnecessary personal contact ^ void contact with eyes and prolonged or repeated skin contact Wash thoroughly arter handling, Section 11- Miscellaneous Toxicological Inlol111ation: No infoI1llation, Transportation Information: Nol a DOT hazardous material, Liability Disclaimer: MSDS infonnatioll is provided based on OSHA'5 Hazardous COllllllunication Regulatioll <Iml for use of the persons rCqllired to receive this information under this regulation. The information is neither-designed nor recommended for any other lIse Or for Ilse by any olhcrpersoT1. including compliance with other laws. Mille;.,: Incorporated [Millex] does not warralll the suitability for llse of this tvtSDS for allY other lIlaterial or product not specifically identified herein. Miltex does not \V<lrrant the accuracy or authenticity of this rvlSDS unless it has been obtained directly from Millex, or pas/cd or vicwed on a Mil/ex wcbsitc. This MSDS is based on information that is believcd to he reliable, but may be subject to change as new information becomes available. l3ecause it is not possible to anticipate all conditions of use, additional safety precautions may be required. Since the use of this material is not undt:r Miltex's control. each llser is responsible for making their OWn determination as to the safe and proper handling of this matelial in thcir own particular use of this matclial. Miltex makes 110 representation or warranty, either express or implied. including as to merchantability or fitness for a particular purpose. Date Received: Page 3 of 3, Cleaner and Lubricant MSDS APR .. 9 2010 Original Submittal . . Nycomed US Inc. MA TERIAL SAFETY DA TA SHEET Prepared to u.s. OSHA, CMA ANSI, and Canadian WHM/S PART I I Wllat is tile material and wllat do I need to know in an emergency? 1. PRODUCT /DENT/FICA T/ON TRADE NAME/MA TERIAL NAME: Double Antibiotic Ointment DESCRIPTION: NDC#: CHEMICAL NAME (for active ingredient): CHEMICAL FAMIL Y (for active ingredient): HOW SUPPLIED: FORMULA (for active ingredient): PRODUCT USE: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: Bacitracin Zinc and Polymyxin B Sulfate Ointment 0168-0021-09; 0168-0021-31; 0168-0021-35 Bacitracin Zinc and Polymyxin B Sulfate Peptide Antibiotics Ointment C"H 'o3N 17016SiC"HB2N'60,,'H,O,S Pharmaceutical for Human Use NYCOMED US INC. 60 Baylis Road Melville, NY 11747 1-631-454-7677 1-800-424-9300 (24-hrs) + 1-631-454-7677 BUSINESS PHONE/GENERAL MSDS INFORMATION: EMERGENCY PHONE (U.S./Canada/Puerto Rico): EMERGENCY PHONE (OUTSIDE U.S.): NOTE: ALL United States Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. Stale equivalent Standards. and Canadian WHMIS [Controlled Products Regulations] required information is included in appropriate sections based on the U.S. ANSI Z400.1-2004 format This product has been classified in accordance with the hazard criteria of the countries listed above. 2. HAZARD /DENT/FICA T/ON EMERGENCY OVERVIEW: Product Description: This product is a pale yellow ointment with a petroleum jelly odor. Health Hazards: The chief health hazard associated with exposure during normal use and handlin9 is the potential for irritation of contaminated skin. Individuals who have had allergic reactions to products containing the active ingredients, Bacitracin Zinc, Polymyxin B Sulfate, or any other components of this product may experience allergic reactions to this product. Allergic reactions may be severe and can be life-threatening in certain individuals. Flammability Hazards: This product is combustible. When involved in a fire, this material may decompose and produce irritating vapors and toxic compounds (including carbon oxides, nitrogen oxides, and sulfur oxides). Reactivity Hazards: This product is not reactive. Environmental Hazards: This product has not been tested for environmental effects. Emergency Considerations: Emergency responders should wear appropriate protection for situation to which they respond. 3. COMPOSITION and INFORMA T/ON ON INGREDIENTS , CHEMICAL NAME CAS# %w/w Bacitracin Zinc 1405-874 500 Units Polymyxin B Sulfate 1405-20-5 10,000 Unils White Petrolatum 8009-038 Propne\ary PART II What sllould I do if a hazardous situation occurs? I 4 FIRST-AID MEASURES Persons developing hypersensitivity reactions should receive medical attention. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Take a copy of label and MSDS to physician or health professional with the contaminated individual. SKIN EXPOSURE: If adverse skin effects occur, discontinue use. Seek medical attention. EYE EXPOSURE: If this product contaminates the eyes, rinse eyes under gently running water. Use sufficient force to open eyelids and then "roll" eyes while fiushing. Minimum flushing is for 15 minutes. The contaminated individual must seek medical attention if any adverse effect continues after rinsing. INHALATION: If vapors of this product are inhaled, causing irritation, remove victim to fresh a;nata.eR~ill,lI,'H~d' artificial respiration to support vital functions. Seek medical attention if adverse effect continues alfer rl!"moiMi'f<5"~\!~ . air. PAGE10F9 APR .. 9 2010 EF'15f;HYrfcR-tJa6Mff(af' 2009 DOUBLE ANTIBIOTIC OINTMENT MSDS . . Nycomed US Inc. I 4 FIRST-AID MEASURES (Continued) INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, havinq convulsions or unable to swallow, If victim is convulsing, maintain an open airway and obtain immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin conditions may be aggravated by repeated overexposures to this product RECOMMENDA TlONS TO PHYSICIANS: This product should only be given to patients by persons experienced in management of patients receiving the type of therapy intended for this product Treat symptoms and eliminate exposure. 5, FIRE-FIGHTING MEASURES FLASH POINT (closed cup): 199'C (390'F) AUTOIGNfTION TEMPERATURE: Not established. FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. Upper IUELI: Not applicable. FIRE EXTINGUISHING MA TERIALS: Use extinguishing media appropriate for surrounding fire. Water Spray: OK Carbon Dioxide: OK Foam: OK Dry Chemicai: OK Halon: OK Olher: Any "ABC" Class FIRE EXTINGUISHING MA TERIALS NOT TO BE USED: None known. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is combustible. When involved in a fire, this material may decompose and produce irritating vapors and toxic compounds (including carbon oxides, nitrogen oxides, and sulfur oxides). Explosion Sensitivity to Mechanical Impact: Not sensitive, Explosion Sensitivity to Stalic Discharqe: Not sensitive. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus (SCBA) and full protective equipment If protective equipment is contaminated by this product, it should be thoroughly washed with running water prior to removal of SCBA respiratory protection. Firefighters whose protective equipment becomes contaminated should thoroughly shower with warm, soapy water and should receive medical evaluation if they experience any adverse effects, I 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Proper protective equipment should be used. In the event of a spill, clear the area and protect people, The atmosphere must have levels of components lower than those listed in Section 8, (Exposure Conlrols and Personal Protective Equipment) if applicable, and have at least 19.5 percent oxygen before personnel can be allowed into the area without Self-Contained Breathing Apparatus (SCBA), Small Soifls: Wear goggles and 910;e5 while wiping up small spills of this product with polypad or sponge. Laroe Soilfs: Trained personnel following pre-planned procedures should han'dle non-incidental releases. Access to the spill areas should be restricted. Protective apparel should be used with a respirator when there is any danger of mists or sprays being generated, Minimum Persona! Protective Equipment should be rubber gloves, rubber boots, face shield, and Tyvek suit. The dispersal of mists or sprays into surrounding air and the possibility of inhalation is a serious matter and should be treated as such. Minimum level of personal protective equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and Self~Contained Breathing Apparatus. Absorb spilled liquid using polypads or other suitable absorbent material. Prevent material from entering sewer or confined spaces, waterways, soil or public waters. Monitor area and confirm levels are bellow exposure limits given in Section 8 (Exposure Controls-Personal Protection), if applicable, before non-response personnel are allowed into the spill area. Decontaminate the area of the spill thoroughly using detergent and water, Place all spill residue in an appropriate container and seal. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). Date Received: NFPA RATING HEIt.TI-l INSTABIUTY 0,"'" Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe APR - 9 2010 PAGE 2 OF9 Oriainal Submittal EFFECTIVE DA TE: MA Y 07, 2009 DOUBLE ANTIBIOTIC OINTMENT MSDS . . Nycomed US Inc. PART III I How can I prevent hazardous situations from occurring? 7. HANDLING and USE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Do not eat, drink, smoke, or apply cosmetics while handling this product. Wash hands thoroughly after handling this product or equipment and containers that contain this product. Follow SPECIFIC USE INSTRUCTIONS supplied with this product. Particular care in working with this product must be practiced in pharmacies and other preparation areas, during manufacture of this product, and during patient administration. STORAGE AND HANDLING PRACTICES: Employees must be trained to properly use this product. Use of this product should be performed in a designated area for working with drugs. Ensure product is properly labeled. Store this product away from incompatible materials. Store this product in original container. PRODUCT PREPARATION INSTRUCTIONS FOR MEDICAL PERSONNEL: Handle this material following standard medical practices and following the recommendations presented on the Package Insert. SPECIFIC USErS): This product is a human pharmaceutical. Follow all industry standards for use of this product. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: When cleaning non- disposable equipment, wear latex or butyl rubber (double gloving is recommended), goggles, and lab coat. Wash equipment with soap and water. Wipe equipment down with damp sponge or polypad. Collect all rinsates and dispose of according to applicable U.S. Federal, State, and local hazardous waste disposal regulations or waste disposal regulations of Canada. All disposable items contaminated with this product should be disposed of properly. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Follow standard medical product handling procedures. During decontamination of work surfaces, workers should wear the same equipment recommended in Section 6 (Accidental Release Measures) of this MSDS. EXPOSURE LIMITS/GUIDELINES: CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR ACGIH-TLVs OSHA PELs NIQSH-RELs NIOSH OTHER 1WA STEL 1WA STEL 1WA STEL IOLH maim" maim] mq/mJ mn/mJ mn/m" maim] mq!mJ maim:! Bacitracin Zinc 1405-874 NE NE NE NE NE NE NE NE POlymyxin B Sulfate 1405-20-5 NE NE NE NE NE NE NE NE While Petrolatum 8009-03-8 NE NE NE NE NE NE NE NE NE = Not Established See Section 16 for Definitions of Terms Used The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standards of Canada (including CSA Standard Z94.4- 02 and CSA Standard Z94.3-07). Please reference applicable regulations and standards for relevant details. RESPIRA TORY PROTECTION: A respirator is not required for routine conditions of use of this product. If respiratory protection is needed, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, or Canadian CSA Standard Z94.4-02. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910 134-1998) . EYE PROTECTION: Not normally needed during normal use. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or Canadian CSA Standard 294.3-07. HAND PROTECTION: For situations in which prolonged skin contact is anticipated, double glove, using latex, nitrile, or rubber gloves. Check gloves for leaks. Wash hands before putting on gloves and after removing gloves. Gloves should cover the gown cuff. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate'standards of Canada. BODY PROTECTION: During patient administration, use of lightweight cotton gown or other medical attire is recommended. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the teet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136 and the Canadian CSA Standard 2195-02, Protective Footwear. 9, PHYSICAL and CHEMICAL PROPERTIES BOILING POINT: > 2500C (4820F) FREEZING/MEL TlNG POINT: 550C (131 OF) EVAPORA TlON RA TE (nBuAc = 1): 0 SOLUBILITY IN WA TER: Insoluble. Date Received: VAPOR PRESSURE (air = 1): Not established. SPECIFIC GRAVITY (water = 1): < 1 ODOR THRESHOLD: Not established. pH: Not established. APR _ 9 2010 COEFFICIENT WA TER/OIL DISTRIBUTION: Not established. DOUBLE ANTIBIOTIC OINTMENT MSDS PAGE 3 OF9 EFFEcn.vE10ill:1i!: ~Jt'lroltl2d09 . . Nycomed US Inc. I 9. PHYSICAL and CHEMICAL PROPERTIES (Continued) APPEARANCE, ODOR AND COLOR: This product is a pale yellow ointment with a petroleum jelly odor. HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product can be a distinguishing characteristic to identify it in event of accidental release. 10. STABILITY and REACTIVITY STABILITY: This product is stable. DECOMPOSITION PRODUCTS: If exposed to extremely high temperatures, thermal decomposition may generate irritating fumes and toxic gases (e.g., carbon oxides, nitrogen oxides, and sulfur oxides). MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is generally compatible with other common materials in a medical facility. Acids, caustics, and other chemicals that could affect its performance should be avoided. HAZARDOUS POL YMERlZA TlON: Will not occur. CONDITIONS TO A VOID: Avoid heat, light, and contact with incompatible chemicals. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The health hazard informalion provided below is pertinent to medical employees handling this product in an occupational setting. This product is designed for application on the skin. The following paragraphs describe the symptoms of exposure by route of exposure. INHALA TlON: Although unlikely due to form of product, inhalation of vapors may slightly irritate the nose, throat, and lungs. Symptoms are generally alleviated upon breathing fresh air. CONTACT WITH SKIN or EYES: Skin contact may cause burning sensation, stinging, prickling, itching, and tingling. Bacitracin Zinc has a low order of toxicity when applied topically; however, rashes and allergic anaphylactoid reactions have occurred in some patients. Anaphylactoid reactions have ranged from generalized itching, swelling of the lips and face, sweating, and tightness of the chest, to hypotension, unconsciousness, apnea, and cardiac arrest. Reaction may be life-threatening in certain individuals. Eye contact can cause temporary blurred vision. SKIN ABSORPTION: The components of this product are not known to be absorbed through the skin. INGESTION: Ingestion is not a significant route of occupational overexposure. Acute ingestion of large quantities of this product or chronic ingestion caused by poor hygiene practices may cause nausea, vomiting, and diarrhea. INJECTION: Though not anticipated to be a significant route of exposure for this product, injection (via punctures or lacerations by contaminated objects) may cause redness at the site of injection. Symptoms of intramuscular injection of Bacitracin Zinc may include loss of appetite, nausea, vomiting, diarrhea, rectal itching and burning, skin rashes, pain, hives, fever, bone marrow toxicities, blood dyscrasias, eosinophilia: kidney damage, and anaphylactoid reactions. Reaction may be life- threatening in certain individuals. GENERAL TOXICITY INFORMA TlON: Individuals who have had allergic reactions to products containing the Bacitracin Zinc component of this product or any other components of this product may experience allerDateJ::~C"el~d: product. Symptoms descnbed In patients given therapeutic doses of thiS substance Include the following. For Males and Females: Persons using the product in therapeutic doses may experience temporary, lI.lurred vision, itching. swelling, and redness. AI'R - 9 2010 IRRITANCY OF PRODUCT: This product may mildly to moderately irritate contaminated tissue. SENSITlZA TION OF PRODUCT: Bacitracin Zinc has a low order of toxicity when applied tw.i0.'!Y' hA~~:~::( rfishes and allergiC anaphylactoid reactions have occurred In some patients. Anaphylactoid reac[;!lHS'~kiilPHlI1~t!illfeffi generalized itching, swelling of the lips and face, sweating, and tightness of the chest, to hypotension, unconsciousness, aRnea, and cardiac arrest. Reaction may be life-threatening in certain individuals. HAZARDClJS MAlER IAL IDENTFICATICN SYSTEM I HEJt..1li HAZARD (BLUE) rJ I FlAMMABI UTY HAZARD (RED) [J A-fYSICAL. HAZARD (YELL~ I PROlEC1NE ECUI AVlENT I I "''' I ffiSRRATORY I HANDS I 800Y 1 I 1 I r.::\ I t ! ','7 cr;E$.CTICN8 "'E"'CTlO''' j Fa- Rruire trdLElrial Usemd rmdirg fl..ppicalion; Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe . = Chronic hazard DOUBLE ANTIBIOTIC OINTMENT MSDS PAGE40F9 EFFECTIVE DA TE: MA Y 07, 2009 . . Nycomed US Inc. I 11. TOXICOLOGICALlNFORMATlON (Continued) HEAL TH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Overexposure to this product may cause the following health effects: Acute: The primary health effects that may be experienced by medical personnel exposed to this product is mild irritation of contaminated skin. Accidenlal ingestion may cause nausea, vomiting, and diarrhea. Eye contact will cause temporary blurred vision. Chronic: Bacitracin Zinc has a low order of toxicity when applied topically; however, rashes and allergic anaphylactoid reactions have occurred in some patients. Anaphylactoid reactions can be life-threatening. TARGET ORGANS: Acute: Occupational Exposure: Skin, eyes. Therapeutic Doses: Gastrointestinal system, kidneys, bone marrow. Chronic: Occupational Exposure: Skin. Therapeutic Doses: Skin. TOXICITY DA T A: The toxicity data available for the active components of this product, Bacitracin Zinc and Polymyxin B Sulfate, are presented in this MSDS. Additional data are available for the excipient components of this product, but are not presented in this MSDS; Contact Nycomed US, Inc. for more information. BACITRACIN ZINC~ BACITRACIN ZINC (continued): LDso (Oral-Mouse) > 3750 mgfkg TeLa (Skin-Human) 20 pphf48 hours-continuous: LD~ (Oral-Guinea Pig) 2 gmlkg Skin and Appendages: dermatitis. allergic (after lD~o (Oral-Quail) > 316 mglkg topical exposure) LOS(! (Intraperitoneal-Rat) 190 mg/kg: Lungs. DNA Adduct (Bacteria-Eschericllia coli) 50 fJmol/L Thorax, or Respiration: other changes POL YMIXIN B SULFATE: LD~o (Intraperitoneal-Mouse) 300 mg/kg LDso (Oral-Mouse) 790 mg/kg LD50 (Subcutaneous-Mouse) 1300 mg/kg: lDso (Intraperitoneal-Mouse) 20,500 IJglkg Behavioral: somnolence (general depressed l050 (Subculaneous-Mouse) 59,500 1J9/kg activity) LD50 (Subcutaneous-Guinea Pig) 58 mg/kg LD50 (Intravenous-Mouse) 360 mglkg: Behavioral: LD50 (Intravenous-Mouse) 5400 IJgfkg somnolence (general depressed activity), LOLo (Intravenous-Dog) 8 mglkg convulsions or effect on seizure threshold; Lungs, Thorax, or Respiration: other changes CARCINOGENIC INFORMATION: The components of this product are not found on the following lists: U.S. EPA, U.S. NTP, U.S. OSHA, U.S. NIOSH, GERMAN MAK, IARC, or ACGIH and therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies REPRODUCTIVE TOXICITY INFORMA TlON: Listed below is information concerning the effects of Bacitracin Zinc and Polymyxin B Sulfate on animal or human reproductive systems. Mutaaenicitv: The components of this product are not reported to cause mutagenic effects in humans, Embrvotoxicitv: Studies have not been performed to evaluate the embryotoxic effects of this product. Teratoaenicitv: Studies have not been performed to evaluate the teratogenic effects of this product. ReDroductive Toxicitv: Polymyxin B has been reported to impair the motility of equine sperm, but it's effects on male or female fertility are unknown No adverse effects on male or female fertility, litter size, or survival were observed in rabbits given Bacitracin Zinc 100 g/ton of diet. A mutaaen is a chemical that causes permanent changes to genetic material (DNA) such that the changes wi{{ propagate through generation lines. An embryo toxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does flat propagate across generationa! lines. A teratoaen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reDroductive toxin is any substance that interferes in any way with the reproductive process. ACGIH BIOLOGICAL EXPOSURE INDICES (BEls): Currently, there are no ACGIH Biological Exposure Indices (BEls) determined for components of this product. I 12. ECOLOGICAL INFORMA TlON ALL WORK PRACTICES MUST BE AIMED A T ELlMINA TlNG ENVIRONMENTAL CONTAMINA TlON ENVIRONMENTAL STABILITY: This product has not been tested for persistence, biodegradability, bioconcentration, soil absorption or mobility. EFFECT OF MA TERIAL ON PLANTS or ANIMALS: No specific information is currently available on the effect of this product on plants or animals in the environment. This product may be harmful to contaminated plant and animal life, especially in large quantities. EFFECT OF CHEMICAL ON AQUATIC LIFE: Release of this product to an aquatic environment may be harmful to aquatic plant and animal life in contaminated bodies of water, especially in large quantities. ENVIRONMENTAL EXPOSURE CONTROLS: Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. OTHER ADVERSE EFFECTS: No component of this product is known to have ozone depletion pote'Mte Received: POL YMIXIN B SULFATE (continued): LOLo (Intracerebral-Dog) 320 J.l9Ikg: Behavioral- coma TOLo (Subcutaneous-Mouse) 284 mg/kg/9 days- intermittent Behavioral: muscle weakness Skin and Appendages: dermatitis. other (after systemic exposure); Skin and Appendages: hair DNA Adduct (Bacteria-Escherichia coli) 50 mg/L Mutation Test Systems-Not Otherwise Specified (Microorganism-Not Otherwise Specified) 25 mg/L Mutation Test Systems.Not Otherwise Specified (Yeast-Saccharomyces cerevisiae) 5 mg/L APR ~ 9 2010 Original Submittal PAGES OF9 EFFECTIVE DA TE: MAY 07, 2009 DOUBLE ANTIBIOTIC OINTMENT MSDS . . Nycomed US Inc. I 13. DISPOSAL CONSIDERATIONS DISPOSAL METHODS: It is the responsibility of the generalor to determine at the time of disposal whether the product meets the criteria of a hazardous waste per regulations of the area in which the waste is generated andlor disposed of. Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. Shipment of wastes must be done wilh appropriately permitted and registered transporters. DISPOSAL CONTAINERS: Wasle materials must be placed in and shipped in appropriate 5-gallon or 55-gallon poly or metal waste pails or drums. Permeable cardboard containers are not appropriate and should not be used. Ensure that any required marking or labeling of the containers be done 10 all applicable regulations PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING: Wear proper protective equipment when handling waste materials. PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance wilh appropriate U.S. Federal, State, and local regulations or with regulations of Canada. This producl, if unaltered by handling, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. All gowns, gloves, and disposable materials used in the preparation or handling of this drug should be disposed of in accordance with established hazardous waste disposal procedures. Handle as if capable of transmitting infectious agents. Incineration is recommended. Reusable equipment should be cleaned with soap and water. U.S. EPA WASTE NUMBER: Not applicable 10 wastes consisting only of this product. I 14. TRA NSPOR TA TlON INFORMA TlON U.S. DEPARTMENT OF TRANSPORTA TlON SHIPPING REGULA TlONS: This product is not classified as hazardous under regulations of U.S. DOT 49 CFR 172.101. . TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not classified as Dangerous Goods, per regulations of Transport Canada. I 15. REGULA TORY INFORMA TlON UNITED STATES REGULA TlONS: U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 Ib (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITIES (RQ): Not applicable U.S. TSCA INVENTORY STATUS: This product is regulated by the Food and Drug Administration; it is not subject to requirements under TSCA. ' CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The components of this product are not on the California Proposition 65 lists. OTHER U.S. FEDERAL REGULATIONS: Not applicable. ANSI LABELING (Based on 129.1, Provided to Summarize Occupational Exposure Hazards): CAUTION! MAY CAUSE ALLERGIC REACTION. MAY CAUSE SKIN AND EYE IRRITATION. Avoid contact with skin, eyes. and clothing. Wash thoroughly after handling. Wear gloves, goggles, and appropriate body protection during handling or administration. FIRST-AID: In case of contact, flush skin or eyes with plenty of water. If adverse respiratory reaction occurs from allergic reaction, give oxygen and seek immediate medical attention. If ingested, DO NOT induce vomiting- seek immediate medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO" or "alcohol" foam. IN CASE OF SPILL: Wipe up spilled product. Place residual in appropriate container and seal. Dispose of according to applicable regulations. Consult Material Safety Data Sheet for additional information. CANADIAN REGULA TlONS: CANADIAN DSUNDSL INVENTORY STATUS: This product regulated by the Therapeutic Products Programme (TPP) of Health Canada and so it is exempt from requirements of the DSLINDSL Invenlory. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this product are not on the CEPA Priorities Substances Lists. OTHER CANADIAN REGULA TlONS: Not applicable. CANADIAN WHMIS'CLASSIFICATlON AND SYMBOLS: This product would be classified as a Controlled Product, Hazard Class D2B,as per the Controlled Product Regulations. Date Received: (f) APR "' 9 2010 PAGE 6 OF9 Original Submittal EFFECTIVE DA TE: MA Y 07, 2009 DOUBLE ANTIBIOTIC OINTMENT MSDS . . Nycomed US Inc. I 16. OTHER INFORMATION This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR, 1910.1200. Other government regulations must be reviewed for applicability to this product. To the best of Altana, Inc.'s knowledge. the information contained herein is reliable and accurate as of Ihis dale; however, accuracy. suitability or completeness are not guaranteed and no warranties of any type, either express or implied, are provided. The information contained herein relates only to this specific product. if this product IS combined 'Nlih other materials, all component properties must be conSidered Data may be changed from lime to time. Be sure to consul, the latest edition PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc, PO Box 3519, La Mesa, CA 91944-3519 800/441-3365 . 619/670-0609 May 14, 2009 DEFINITION OF TERMS DATE OF PRINTING: A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each constituent EXPOSURE LIMITS IN AIR: CEILING LEVEL: The concentration that shall not be exceeded during any part of the working exposure. DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens that have been shown to increase the mutanl frequency in the progeny of exposed humans 2: Germ cell mutagens that have been shown to increase the mutant frequency in the progeny of exposed mammals. 3A: Substances that have been shown 10 induce genetic damage in germ cells of human of animals. or which produce mutagenic effects in somatic cells of mammals in vivo and have been shown to reach the germ cells in an active form. 38: Substances that are suspected of being germ cell mutagens because of their genotoxic effects in mammalian somatic cell ill vivo; in exceptional cases, substances for, which there are no in vivo data, but that are clearly mutagenic in vitro and structurally related to known in vivo mutagens. 4: Not applicable (Category <:I carcinogenic substances are those with non-genotoxic mechanisms of action. By definition, germ cell mutagens are genotoxic. Therefore, a Category <:I for germ cell mutagens cannot apply. At some time in the future, it is conceivable that a Category <:I could be established for genotoxic substances with primary targets other than DNA [e.g. purely aneugenic substances) if research results make this seem sensible.) 5: Germ cell mutagens, the potency of which is considered to be so low that, provided the MAK value is observed, their contribution to genetic risk for humans is expected not 10 be significant OFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can lead to damage of the developing organism, 8\1en when MAK and BAT (Biological Tolerance Value for Working Materials) values are observed. Group B: Currently available information indicates a risk of damage to the developing embryo or fetus musl be considered to be probable. Damage to the developing organism cannot be excluded when pregnant women are exposed, even when MAK and BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing embryo or fetus when MAK and BAT values are observed. Group 0: Classification in one of the groups A~C is not yet possible because, although the data available may indicate a trend, they are not sufficient for final evaluation IOlH: Immediately Dangerous to Life and Health. This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury lOQ: Limit of Quantitation MAK: Federal Republic of Germany Maximum Concentration Values in the workplace. NE: Not Established. When no exposure guidelines are established, an entry of NE is made for reference . NIC: Notice of Intended Change. NIQSH CEILING: The exposure that shall not be exceeded during any part of the workday. If instantaneous monitoring is not feasible, the Ceiling shall be assumed as a 15-minute TWA exposure (unless otherwise speCified) that shall not be exceeded at any time during a workday. NIOSH RELs: NIOSH's Recommended Exposure Limits PEL: OSHA's Permissible Exposure Limits. This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL" is placed next to the PEL that was vacated by Court Order. SKIN: Used when a there is a danger of cutaneous absorption. STEL: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that should not be exceeded at any time during a workday, even if the 8-hrTWA is within the TLV-TWA, PEL-TWA or REL-TWA. TlV: Threshold Limit Value. An airborne concentration of a substance that represents conditions under which it is generally believed that neariy all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour TWA: Time Weighted Average exposure concentration for a conventional 8-hr (TL V, PEL) or up to a 10-hr (REL} workday and a <:IO-hr workweek. WEEl: Workplace Environmental Exposure Limits from the AIHA. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS: This rating system was developed by the National Paint and Coating Association and has been adopted by industry to identify the degree of chemical hazards. HEALTH HAZARD: 0 Minimal Hazard: No significant health risk, irritation of skin or eyes not anticipated. Skin Irritation: Essentially non-irritating. Mechanical irritation may occur. PII or Draize " O. Eye Irritation: Essentially non-irritating, minimal effects dearing in < 24 hours. Mechanical irritation may occur. Draize = O. Oral Toxicity LDso Rat: > 5000 mg/kg. Dem/al Toxicity L050 Rat or Rabbit: > 2000 mg/kg. Inhalation Toxicity 4-hrs LCsa Rat: > 20 mg/L. 1 Shoht Hazard: Minor reversible injury may occur; may irritate the stomach if swallowed; may defat the skin and exacerbate existing dermatitis. Skin Irritation: Slightly or mildly irritating PII or Draize > 0 < 5. Eye Irrifation: Slightly to mildly irritating, but reversible within 7 days. Draize > 0 ::; 25. Oral Toxicity L050 Rat: > 500-5000 mg/kg. Dermal Toxicity LO:;a Ral or Rabbil: > 1000~2000 mg/kg. Inhalation Toxicity LCsa 4-hrs Rat: > 2~20 mg/L. 2 Moderate Hazard: Temporary or transitory injury may occur: prolonged exposure may affect the CNS Skin Irri/aUon: Moderately irritating; primary irritant; sensitizer. PII or Draize ?: 5, with 110 destruction of dermal tissue Eye Irritation: Moderately to severely irritating: reversible corneal opacity; corneal involvement or irritation clearing in 8--21 days. Draize " 26~100, with reversible effects. Oral Toxicity LD;,c Ral: > SO~500 mg/kg. Dermal Toxicity LO;,c Rat or Rabbit: > 200-1000 mgfkg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L. 3 Serious Hazard: Major injury likely unless prompt action is taken and medical treatment is given; high level of tOXicity: corrosive. Skin Irritation: Severely irritating and/or corrosive; may cause destruction of dermallissue, sk\1'I burns, and dermal necrosis. Pll or Draize :> 5-8, with destruction of tissue. Eye Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation persisting for more than 21 days Draize > 80 with effects irreversible in 21 days. Oral Toxicity LOsa Rat: > 1-50 mg/kg. Dermal Toxicity LOw Rat or Rabbit: > 20~200 mglkg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L 4 Severe Hazard: Life- threatening; major or permanent damage may result from single or repeated exposures: extremely toxic; irreversible injury may result from brief contact. Skin Irritation: Not appropriate. Do not rate as a 4, based on skin irritation alone. Eye Irritation: Not appropriate. Do not rate as a 4, based on eye irritation alone. Oral Toxicity LD~ Rat: ::; 1 mg/kg. Dermal ToxiCity LD50 Ral or Rabbit: ::; 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: ::; 0.05 mglL FLAMMABILITY HAZARD: 0 Minimal Hazard: Materials that 'Nill not burn in air when exposure to a temperature of 815.5"C (1500"F) for a period of 5 minutes 1 Sliqht Hazard: Materials that must be pre-heated before ignition can occur. Material requires considerable pre-heating. under all ambient temperature conditions before ignition and combustion can occur. This usually indudes the following: Materials that will burn in air when exposed to a temperature of 815.S'C (1500'F) for a period of 5 minutes or less; Liquids, solids and semisolids having a flash point at or above 93.30C (200"F) (ie. OSHA Class lI1B); and Most ordinary combustible materials (e.g. wood, paper, etc.). 2 Moderate Hazard: Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not, under normal conditions, form hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release vapor in sufficient quantities to produce hazardous atmospheres with air, This usually indudes the following: Liquids having a flash-point at or above 37.8'C (100"F); Solid materials in the form of course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid materials in a fibrous Of shredded form that may burn rapidly and create flash fire hazards (e.g. cotton, sisal, hemp); and Solids and semisolids (e.g. viscous and slow flowing as asphalt) that readily give off flammable vapors. 3 Serious Hazard: Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or,' unaffected by ambient temperature, are readily ignited under almost all conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited under almost all conditions. Date Received: APR '-, 9 2010 DOUBLE ANTIBIOTIC OINTMENT MSDS EFFECTIVE DA TE: MA Y 07, 2009 Original Submittal PAGE70F9 . ~ Nycomed US Inc. . HAZARDOUS MATERIALS RATINGS (continued): FLAMMABILITY HAZARD: J (continued) This usually includes the following" liquids having a flash point below 22.8"C (730F) and having a boiling point at or above 38"C (100'F) and those liquids having a flash point at or above 22.8"C (73QF) and below 37.8"C (10QoF) (i,e. OSHA Class 18 and Ie); Materials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air (e.9., dusts of combustible solids, mists or droplets of flammable liquids): and Materials thai burn extremely rapidly, usually by reason of self-contained oxygen (e.g, dry nitrocellulose and many organic peroxides). 4 Severe Hazard: Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air, and that will burn readily. This usually includes the foHowing: Flammable gases; Flammable cryogenic materials: Any liquid or gaseous material thaI is liquid while under pressure and has a flash point below 22.8"C (73"F) and a boiling point below 37.8"C (100"F) (i.e. OSHA Class IA); and Materials that ignite spontaneously when exposed to air at a temperature of 54.40C (130"F) or below (pyrophoric) PHYSICAL HAZARD: 0 Water Reactivity: Materials that do not react with waler Organic Peroxides: Materials that are normally stable, even under tire conditions and will nol react with water. Explosives: Substances that are Non-Explosive. Compressed GClses: No RClting. Pyrophorics: No Rating. Oxidizers: No 0 rating. Unstable Reactives: Substances that will not polymerize, decompose, condense, or self-react.). 1 Water Reac(ivity: Materials that change or decompose upon exposure to moisture. Organic Peroxides: Materials that are normally stable, but can become unstable at high temperatures and pressures. These materials may react with water, but will not release energy violently. Explosives: Division 1,5 & 1,6 explosives. Substances that are very insensitive explosives or that do not have a mass explosion hazard, Compressed Gases: Pressure below OSHA definition. PyropllOrics: No Rating. Oxidizers: Packaging Group III oxidizers; Solids: any material that in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. liquidS: any materiallhat exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid {65%)/cellulose mixture and the criteria for Packing Group I and II are not met. Unstable Reactivos: Substances that may decompose condense, or se!l-react, but only under conditions of high temperature and/or pressure and have little or no potential to cause significant heat generation or explosion hazard. Substances that readily undergo hazardous pOlymerization in tile absence of inhibitors. Substances that readily undergo hazardous polymerization in the absence of inhibitors. 2 Waler Reaclivity: Materials that may react violently with water, Organic Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent chemical change, but will not detonate. These materials may also react violently with water. Explosives: Division 1.4 explosives, Explosive substances where ll1e explosive effects are largely confined to lhe package and no projection of fragments of appreciable size or range are expected, An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package. Compressed Gases: Pressurized and meet OSHA definition but <: 514.7 psi absolute at 211"C (70"F) [500 psig] Pyrophorics: No Rating, Oxidizers: Packing Group II oxidizers. Solids: any material that either in concentration tested, exhibits a mean burning time of less than or equ;1 to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for Packing Group I are not met. Reac/ives: Substances Ihat may polymerize, decompose, condense, or self-react at ambient temperature andfor pressure, but have a low potential (or low risk) for significant heat generation or explosion Substances that readily form peroxides upon exposure to air or oxygen at room temperature. 3 Wafer Reac/ivity- Materials that may form explosive reactions wilh water. Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong initiating sourCe or must be heated under confinement before initiation; or materials that react explosively with water. Explosives: Division 1.3 explosives. Explosive substances that have a fire hazard and either a minor blasl hazard or a minor projection hazard or both, but do not have a mass explosion hazard. Compressed Gases: Pressure 2: 514.7 psi absolute at 21.1"C (70"F) [500 psig]. Pyrophorics: No Rating, Oxidizers: Packing Group I oJ(idjzers. SoUds: any material that, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3:2 potassium bromate/cellulose mixture. Liquids: any material that spontaneously ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure and have a moderate potential (or moderate riSk) to cause significant heat generation or explosion. 4 Water Reactivity Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: Materials that are readily capable of detonation or explosive decomposition at normal temperature and pressures, Explosives Division 1.1 & 1.2 explosives. Explosive substances that,have amass explosion hazard or have a projection hazard. A mass explosion is one thai affects almost the entire load instantaneously DEFINITION OF TERMS (Continued) IDENTIFICATION SYSTEM HAZARD HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD RATINGS (continued): PHYSICAL HAZARD (continued) 4 (continued) Compressed Gases: No Rating Pyrophorics: Add to the definition of Flammability 4. Oxidizers: No 4 rating Unstable Reactives: Substances that may polymerize, decompose, condense, or self-react at ambient temperature and/or pressure and have a high potential (or high n"sk) to cause significanl heal generation or explosion. NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS: HEALTH HAZARD: 0 Materials that. under emergency conditions, would offer no haz.ard beyond that of ordinary combustible materials Gases and vapors with an LCso for acute inhalatiOn toxicity greater than 10,000 ppm. Dusts and mists with an LC~ for acute inhalation toxicity greater than 200 mg/L. Materials with an LDS{! for acute dermal toxicity greater than 2000 mg/kg. Materials with an LDso for acute oral toxicity greater than 2000 mg/kg. Materials essentially non-irritating to the respiratory tract, eyes, and skin. 1 Materials that, under emergency conditions, can cause significant irritation. Gases and vapors with an LCso for acute inhalation toxicity greater than 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists with an LC50 for acule inhalation toxicity greater than 10 mg/L but less than or equal to 200 mg/L Materials with an LDSo for acute dermal toxicity greater than 1000 mg/kg but less than or equal to 2000 mg/kg. Materials that slightly to moderately irritate the respiratory tract, eyes and skin. Materials with an LDso for acule oral loxicity grealer than soa mg/kg bul less than or equal to 2000 mglkg. 2 Materials that, under emergency conditions, can cause temporary incapacitation or residual injury, Gases with an LCso for acute inhalation toxicity greater than 3,000 ppm but less than or equal to 5,000 ppm, Any liquid whose saturated vapor concentration at 20"C (68"F) is equal to or greater than one-fifth its Leso for acule inhalation toxicity, if its LC50 is less than or equal to 5000 ppm and that does not meet the criteria for either degree of hazard 3 or degree of hazard 4. Dusts and mists with an LCso for acute inhalation toxicity greater than 2 mg/L but less than or equal to 10 mg/L. Materials with an LD"o for acute dermal toxicity greater than 200 mg/kg but less than or equal to 1000 mglkg. Compressed liquefied gases with boiling points between -30'C (-22"F) and -55"C (_66.50F) that cause severe tissue damage, depending on duration of expOsure. Materials that are respiratory irritants. Materials that cause severe, but reversible irritation to the eyes or are lachrymators. Materials that are primary skin irritants or sensitizers. Materials whose LDso for acute oral toxicity is greater than 50 mg/kg but less than or equal to SOD mg!kg. 3 Materials that, under emergency conditions, can cause serious or permanent injury. Gases with an LCso for acute inhalation toxicity greater than 1,000 ppm but less than or equal to 3,000 ppm, Any liquid whose saturated vapor concentration at 20"C (68"F) is equal to Or greater its LCoo for acute inhalation toxicity, if its LCso is less than or equal to 3000 ppm and that does not meet the criteria for degree of hazard 4. Dusts and mists with an LCso for acute inhalation toxicity greater than 0.5 mg/L but less Ulan or equal to 2 mg/L. Materials with an LDso for acute dermal toxicity greater than 40 mg/kg but less than or equal to 200 mglkg. Materia(s lhal are corrosive 10 lhe respiratory lraet, Maten"afs thai are corrosive 10 Ihe eyes or cause irreversible corneal opacity, Materials corrosive to the skin. Cryogenic gases that cause frostbite and irreversible tissue damage. Compressed liquefied gases with boiling points below -55"C (-66SF) that cause frostbite and irreversible tissue damage. Materials with an LOso for acute oral toxicity greater than 5 mg/kg but less than or equal to 50 mg/kg. 4 Materials that, under emergency conditions, can be lethal. Gases with an LCso for acute inhalation toxicity less than or equal to 1,000 ppm. Any liquid whose saturated vapor concentration at 20"C(68"F) is equal to or greater than ten times its LCso for acute inhalation toxicity, if its LCso is less than or equal 10 1000 ppm, Dusls and mists whose LCso for acute inhalation toxicity'is less than or equal to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or equal to 40 mglkg Materials whose LDsD for acute oral toxicity is less than or equal to 5 mglkg. FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, induding intrinsically noncombustible materials such as concrete, stone, and sand. Materials that wi!! not bum in air when exposed to a temperature of 816"C (1500"F) for a period of 5 minutes in according with Annex D of NFPA 704. 1 Materials that must.be preheated before ignition can occur. Materials in this degree require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur: Materials that will burn in air when exposed to a temperature of 8160C (1500"F) for a period of 5 minutes in according with Annex 0 of NFPA 704. Liquids, solids, and semisolids having a flash point al or above 93.4"C (2000F) (i.e, Class IIIB liquids). Liquids with a flash point greater than 35"C (95"F) that do not sustain combustion when lesled using the Me/hod of Testing (or Sustained Combustibility, per 49 CFR 173, Appendix H or the UN Recommendations on the Transport of Dangerous Goods, Model Regulations (current edition) and the related Manual of Tests and Criteria (current edition), Liquids with a flash point greater than 35"C (95"F) in a water-miscible solution or dispersion with a water non-combustible liquid/solid content of more than 85% by weight. Liquids that have no fire point when tested by ASTM D 92, Standard Test Me/hod for Flash and Fire Points by Cleveland Open Cup, up to the boiling point of the liquid Of up to a temperature at which the sample being tested shows an obvious physical change, Combustible pellets with aAPresentative diameter of great~r. than 2 mm (10 mesh). ~ost ordinal)' cOr&atfQ.rrI8il&~t;Sr'ij9~d' contammg greater than 0.5% by weight of a flammable or combuslib)Rart~ Nr~ . rated by the dosed cup flash point of the solvent APR ~'9 2010 DOUBLE ANTIBIOTIC OINTMENT MSDS EFFBfir,;iJmi~iuA*tit! 2egg PAGE 8 OF9 . Nycomed US Inc. . . DEFINITION OF TERMS (Continued) NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS (continued): FLAMMABILITY HAZARD: 2 Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials in this degree would not under normal conditions form hazardous atmospheres with air. but under high ambient lemperai.ures or under moderate healing could release vapor in sufficient quantities to produce hazardous atmospheres with air. Liquids having a flash point at or above 37.8.C (10QoF) and below 93.4"C (20Q"F) (i.e. Class II and Class IliA liquids.) Solid materials in the form of powders or coarse dusts of representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but that generally do not form explosive mixtures with air. Solid materials in fibrous or shredded form that burn rapidly and create flash fire hazards, such as collon, sisal, and hemp. Solids and semisolids that readily give off flammable vapors. Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash point of the solvent. 3 Liquids and solids that can be ignited under almost all ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all conditions. liquids having a flash point below 22.8T (73"F) and having a boiling point at or above 37.8.C (100"F) and those liquids having a flash point at or above 22.8T {n.F) and below 37.80C (100.F) (i.e. Class 18 and IC liquids). Malerials that on account of their physical form or environmental conditions can form explosive mixtures with air and are readily dispersed in air. Flammable or combustible dusts with representative diameter less than 420 microns (40 mesh). Materials that burn with extreme rapidily, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed cup flash poif1l of the solvent 4 Materials that will rapidlY or completely vaporize at atmospheric pressure and Ilormal ambient temperature or that are readily dispersed in air and will burn readily. Flammable gases. Flammable cryogenic materials. Any liquid or gaseous materials that is liquid while under pressure and has a flash point below 22.80C (73"F) and a bailing point below 37,8"C (100.F) (ie. Class IA liquids). Materials that ignite when exposed to air, Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the dosed cup flash point of the solvent. INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire conditions Materials that have an instantaneous power density (prOduct of heat of reaction and reaclion rate) at 250"C (482"F) below 0.01 WlmL Materials th@t do not exhibit an exotherm at temperatures less than or equal to 500"C (932"F) when tested by differential scanning calorimetry, 1 Materials that in themselves are normally stabl~, but that can become unstable at elevated' temperatures and pressures. Materials that have an instantaneous power density (product of heat of reaction and reaction rate) at 250.C (48TF} a\ Of aoove 0,01 W/mL and below 10 W/mL. 2 Materials that readily undergo violent chemical change at elevated temperatures and pressures. Materials that have an instantaneous power density (product of heat of reaction and reaction rate) at 2S0.C (482"F) at or above 10 W/mL and below 100WfmL. 3 Materials that in themselves are capable of detonation or explosive decomposition or explosive reaction, but that require a strong initiating source or that must be heated under confinement before initiation. Materials that have an estimated instantaneous power densi\y {product of heat 01 reac1ion and reacflon rate) at 2500C (482"F) at or above 100 W/mL and below 1000 W/mL. Materials that are sensitive to thermal or mechanical shock al elevated temperatures and pressures. 4 Materials that in themselves are readily capable of detonation or explosive decomposition or explosive reaction at normal temperatures and pressures, Materials that are sensitive to localized thermal or mechanical shock at normal temperatures and pressures. Materials that have an estimated instantaneous power density (product of heat of reaction and reaction rate) at 250.C (482"F) of 1000 W/mL or greater. FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point: Minimum temperature at which a liquid gives off sufficient vapor to form an ignitable mixture with air near the surface of the liquid or within the lest vessel used. Autoionition Temoerature: Minimum temperature 01 a solid. liquid. or gas required to initiate or cause self- sustained combustion in air with no other source of ignition, LEL: Lowest concentration of a flammable vapor or gas/air mixture that will ignite and burn with a flame. UEL: Highest concentration of a flammable vapor or gas/air mixture that will ignite and bum with a flame TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data. animal studies, or from the results of studies will', similar compounds are presented. ~: Lethal Dose (solids & liquids) that kills 50% of the exposed animals, LC5o: lethal Concentration (gases) that kills 50% of the exposed animals Q2!TI: Concentration expressed in parts of material per million parts of air or water. mq/rrf-: Concentration expressed in weight of substance per volume of air. !!:!.9L!ill: Ouantity of material, by weight, administered to a test subject. based on their body weight in kg. TDLo: lowest dose to cause a symptom, TClo: Lowest concentration to cause a symptom. TOo, LDLo. and lDo, or rc, Teo, LCLo, and lCo', lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: IARC: International Agency for Research on Cancer. NTP: National Toxicology Program. RTECS: Registry of Toxic Effects of Chemical Substances. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A. 2B, etc.) are also used. Other Information: BEl: ACGIH Biological Exposure Indices, represent the levels of determinants which are most Ii~.ely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. ECOLOGICAL INFORMATION, EC: Effect concentration in water. BCF: Bioconcentration Factor, which is used to determine if a substance will concentrate in life forms that consume contaminated plant or animal matter. TLm: Median threshold limit. 10Q Kow or~: Coefficient of OilIWater Distribution is used to assess a substance's behavior in the environment. REGULATORY INFORMATION, u.s.: EPA: U.S. Environmental Protection Agency. ACGIH: American Conference of Governmental Industrial Hygienists, a professional association that establishes exposure limits. OSHA: U.S. Occupational Safety and Health Administration. NIOSH: National Institute of Occupational Safety and Health, which is the research arm of OSHA. DOT: U.S. Department of Transportation. Te: Transport Canada. SARA: Superiund Amendments and Reauthoriz.ation Ad.. TSCA: U,S. Toxic Substance Control Act. CERCLA' Comprehensive Environmental Response, Compensation, and Liability Act. Marine Pollutant status according to the DOT: CERCLA or Superfund; and various state regulations. This section also includes information on the precautionary warnings that appear on the material's package label. CANADA: WHMIS: Canadian Workplace Hazardous Materials Information System. TC' Transport Canada. DSUNDSL: Canadian Oomes\iclNon-Domes1ic Subslances List. Date Received: APR ~. 9 2010 Original Submittal PAGE 9 OF9 EFFECTIVE DA TE: MA Y 07, 2009 DOUBLE ANTIBIOTIC OINTMENT MSDS MSDS: POVIDONE-fO. SOLUTION 10% . Page I of 4 Rcltu:I].Jo.-!)ISDSJ,lst , r.r_e~jo.usj~.:ISl!S, ~t.'xL.!~ls.ns MATERIAL SAFETY DATA SHEET SECTION I. Product and Company Identification POVIDONE-IODINE SOLUTION 10'1.. Product Code: F-POVID-IODINE Product Name: POVIDONE-IODINE SOLUTION ]0% Chemical Family: Compound M:HlUf..cturer Name and Address: Distributed by: Farnam Companies, Inc. 30] West Osborn Road Phoenix, AZ. Addilionalldcntity Inform:.tioll 1(,(101 32-oz CHEMTREC District or Columbia Farnam Companies, III Telephone Numbers: (800)424-9300 (202)483-0414 (800)234-22(,9 Dates: Date Created: 03/11/1992 Revision: 07/23/2007 Printed: 07/26/2007 SECTION 2. Composition/Information on Ingredients POVIDONE-IODINE SOLUTION 10% Ilazardolls Components (Chemical N:llne) I. POVIDONE-IODINE CAS# NA Concentration 10.0% I. OSHA PEL No data. ACGIH TLI' No data. SECTION 3. Hazards Identiticatioll POVIDONE-IOmNE SOLUTION 10% Emergency Overview No data available. ROlltC(S) of Entry: Inhalation? Yes, Skin? Yes, Eyes? Yes, Ingestion? Yes Potclllial Health Effects (Acute and Chronic) NE Carcinogenicity: NTP? N.A. , rARC Monographs? N.A. , OSHA Regulated? N.A- Carcinogenicity/Other Infonmltion No data available. Recommended Exposure Limits NE Signs <Iud Symptoms Of Exposure NE i\o1cdical Conditions Generally r\ggravatcd By Exposure Sensitivity to Iodine Date Received: SECTION 4. First Aid Measures POVIDONE-IOmNE SOLUTION 10% APR ..: 9 2010 Original Submittal Emergency and First Aid Procedures EYES: Flush with l:1rge volumes of water. Call physician if irritation persists. INGESTION: Do NOT induce vomiting. Drink two glasses orwatcr und contact physician or Poison Control Center. Do not give anything httn.II......."r1" r.....n....'Y> ,-,.,-,.""..I.......nnn'Jt:.() l...~ MSDS: POVIDONE-IODINE SceT!ON 10% . Page 2 of4 by mouth to an unconscious person. IF INHALED: Remove patient to I"resh air. IF ON SKIN: Wash with soap and water. Consult physician if irritation persists. Note ((J Physici<HI No datu available. S~:CTION 5. Fire Fighting Me:l'lIres POVIDONE-IODINE SOLUTION 10':;', FI::1SI1 PI: N.A. Method Used: No data. EXllIosive Limits: LEL: NE UEL: NE Extinguishing Media Aqueous solution: may lIse dry chemical or waleI' spray/fog Fire Fighting Instructions Firefighters should be equipped with SC8A and protective clothing when fighting all fires involving chemicals. FhlOHmlble Properfjrs and Ilazards Nonc Known Haz4Irdolls Combustion Products No data available. SECTION 6. Accidental Release Me.tsurcs POVIDONE-IODINE SOLUTION 10% Steps To Be Tal{cn In C.Ise Material Is Released Or Spilled SOJk up spills with inert absorbellt; shovel into waste containers. SECTION 7. I"'ndling :lnd Stor:lge POVIDONE-IOmNE SOLUTION 10% Hazard Labellnfonn:ltion: Where splashing is possible, full che Precautions To Be 'Liken in Handling Store in cool. well ventilated area. Avoid freezing. Precautions To Be T:lken in Storing No data available. Other Precautions KEEP OUT OF REACH OF CHILDREN. SECTION 8. Exposure Controls/Personal Protection POVIDONE-IODINE SOLUTION 100;', Respiratory Equipment (Specify Type) SCBA, for fire fighting Date Received: Eve Protection s;fety glasses APR - 9 20\0 Protective Gloves rubber Original submittal Other Protective Clothing sufficient to protect fmm splashes if exposure likely I...f-f-_.//......"A~ c"_,,....~ "".__I__IlIlI"\'"l~'" 1_....__ MSDS: POVIDONE-rOD. SOLUTION 10% . Page 3 of4 Engineering Controls (Ventilation etc.) Local Exhaust: use adequate ventilation Special: Mec/wnical (Gen): Other: Wor"k/llygicllic/l\'l:lintenancc Practices Wash hands before eating, smoking, or using restroom, SECTION 9. Physical alld ChcmicalProperties POVIDONE-IODINE SOLUTION 10% Solubility Notes soluble Physic:ll States: Boiling Point: Melling Point: Specific Gnlvity (\V:lter = I): Density: Vapor Pressure (\'S. Air or IUIII IIg): VaIHU' Density (\'s. Air = I): Evaporation Rail' (\'S Rutyl Acctatc=l): Soluhility in \\'ater: Pcn.'l'nt VOI:ltilc: Salur:ltcd Vapor Concentration: Viscosity: pll: ApPc:lnlllce ,lIId Odor C!e:lr, dark brown liquid; slighl halogen odor [J Oas , [ X ] Liquid, [] Solid 202.00 F N.A. 1.10 Nu data. N.1\. >1 <I 100% N.A. No data. No data. NE SECTION 10. Stahility alld Reactivity POVIDONE-IODINE SOLUTION 10% Stability: Unstable I J Stable r X 1 Conditions To Avoid -Instability high hen I Incompatibility - Materials To Avoid Strong oxidizing or reducing agents Haz:lrdous Decomposition Or Byproducts In fire: alllmonic:.lI vapors, iodine compounds HaZ:lrdous Polymerization: Will OCCllr r J Will not occur [X] Conditions To Avoid - Hazardolls Polymerization will no! occur SECTION II. Toxicologicallllformatioll POVIDONE-IODINE SOLUTION 10% Date Received: No data available. APR .:. 9 2010 Original Suomiffiil SECTION 12. Ecologicallllformatinll POVIDONE-IODINE SOLUTION 10% h1tn.//rno:::t1o.::. f~l'n~l1Yl rnnl/nlnnn1..c:;Q hi,,1 MSDS: POVIDONE-IODINE SeJTION 10% . Page 4 of 4 No darn available. SECTION 13. Disposal Considerations POVIDONE-IODINE SOLUTION 10% 'V~lstc nispos~t1 jH(~thod Dispose of In accordance with Federal. State and local regulations. SECTION 14. Transport Infonn:!!ion POVIDON~:-IODlNE SOLUTION 10% DOT Proper Shipping Name No data available. DOT 1I:1zard L:lhcl: None UN/NA !\'umhl'r: No dat Additional Transport Informatioll No data aVJibblc. --_.~----------_._._--~------- S~:C'fION 15. Regul:!tor)" Infonnal;on POVIDONE-IODINE SOLUTION 10';\, No data available. SECTION 16. Other Information POVIDONE-IODINE SOLUTION 10% Supcrccdes Re\'ision 03/05/2004 IIMIS Ihzanl R.ltings: 11('all'll: =[!] IT] IT] C Minimal: () Slight: fvlodcfJIC: 2 Serious: 3 Extreme: 4 Flammability: Physicll Hazard: Protection: The mformatlon and data herem arc believed to be accurate and have been compiled from sources believed to be reliable It is offered for your considcration, invcstigation and verific3tioll. ._--~---_..~-----_.~--"--~._---_._- ',""--"_."-~---"."~',---,-"_._--~-~._--"--,---..--,--,-----"---_._-"-~"~...~-~_.-----.- "- Date Received: APR ;; 9 2010 Original Submittal httn'//n-1C'..1C' t'"....."......... '"',............/......nnn"1:::n 1_..~_