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HomeMy WebLinkAboutApplication APPLICANT 1/11/2008 '..' Date Received: .- City of Springfield Development Services Department 225 Fifth Street . Springfield, OR 97477 Phone: (541) 726-3759 Fax: (541) 726-3689 SPRINGFIELD JAN t t 2008 ittal I<< DWP Overlay District Application, Type I Applicant Name. Address Property Owner Name Address Developer Name Address Property Address Assessor's Map No. Zoning of PropertY Size of Property Eric Hall Architects, Ine. Phone (541) 688-5594 . 116 H;Qhway 99N EUQene, OR 97402 ( .Jmpph R Hdwe, Phone (541) 335-9905 ' 2982 Crescent Ave. Eu.ene, OR 97408 Hawe; Investments, LLC Phone (541) 335-2205" 2982 Crescent Ave. EUQene, OR 97408 400 International Wav 17-03-15-40 C I (Camous Industrial) Tax Lot No, 500 Acres or Square Feet _ 266,192 Existing Use of Property Filbert Orchard Specific Description of ProposaL Corporate Headquarters and Administrative Offices: 81,420 d.'of .oHirpc: \/\lith .'I mj~tlJfP or 111;"',. inf'IIJrling c;.11rrnrt c:prvirpc: fnrpm~lnvPPC: .'Inrl....s.urrnllnrlin~npc:c:pc: Was this development propos the City through a Pre-application Report? Yes XI No_ in thJs application in corre~~ and accurate.. Applicant Signature ~ Date I )jl /Ofi}. . -=-- , I . ' If the applicant is other than the owner, the owner hereby grants permission for the applicant to act in his/her behalf Owner Signaturr~ '111}q-, '.. Date I } I I/o'? /1 / . For Office Use Only: Joum~l No. me '7 A\<7- ~ O&:iJ3> Received By -bYL. SOD Map No. \1-D;S-/5-4() Tax Lot No. Date Accepted as Complete ? ~J "2-IDb~ c;\:'::j)" \ / --- .' .. .-....-- .~ . 225 Fifth Street Springfield, Oregon 97477 541-726-3759Phone Job/Journal Number DRC2008-00003 DRC2008-00003 Payments: Type of Payment Check cReceintJ . RECEIPT #: Description CTY Drinking Water Protection + 5% TechnoJogyFee Paid By HA WES INVESTMENTS LLC I 3200800000000000031 Received By Ij Check Number Batch Number Page 1 of 1 Item Total: Authorization Number. , 10032 (i:i,ty of Springfield Official Receipt evelopment Services Department Public W'~rks'Depai'tment bate: 01/11/2008 3:04:28PM AmoLlnt Due 990.00 49.50 $1,039.50 How'Receive~L Amount Paid In Rerson .1' . Payment Total: $1,039.50 $1,039.50 Date Received: JAN t 1 2008 Original SUDmittal " -- -- ----- -- -::::-~ 1/1112008 .APPLlCATIOl\{ ....ACKET Date Received: ~ HAWES INVESTMENTS, LLC JAN t t 2008 Original SUbmittal_~ 555 International Way Springfield, Oregon DWP Overlay District Application DRC 2007 -00060 Index of Submittal Items: 1. Application Packet: Description of Submittal Items 2. Sports Way/I-S Well Protection Map 3. DWP Overlay District Application 4. Hazardous Material Management Plan 5. MSDS Sheets . 6. Generator/Fuel Containment Equipment Specifications ARCHITECTS Eric Hall Architects, Inc. 116 Hwy. 99 North Eugene, Oregon 97402 (541) 688-5594 ......./ :' ~ m.... I' f.\ ~~ .:..........; ~JG: 'I 1:..LI 'f L1l :z-"" Jo. u.'...Jo WAY/I-S 1 WELLHEAD PROTEcnON AREA L. Springfield, Or<gv. J '''''~.f: to.".....,,, ~ o ::I. (Q :r ... e. iii ~ ~ ill ~ ~ ~<D ~ - g ~ <: .~ ~ ~l""- rl~ It' r ~ . @@ .,.</ ~..y L. ~_1 ~~. r-/. 't~Q _OPTIlAVD. L.J I Y_ OSY... 10'1'.... aZOY" D"'''~ """"'" "-- - -..... -- COl'fTAMIlfAlCTsovaaI 6__ . .... o ..-........ .... 0..- :==:-0-,. ...~......... -.", .> . J ~:==.:.- I :UND~IIr- o - MAP 3 116 HWY ,99 N., Suite 100 E u ge I"le, ,0 R 97402 Ph 541.688.5594 F x 541.688.0530 v:;!'"!'",r~(; ~ acfC} e!=.-~s.c,?11!. H~'''ES INVESTMENTS, LLC -- DWP OVEk....,Y DISTRICT APPLICATION . d" Date Ke(,;<:>lve . Application Packet: Item 1. JAN 1 1 2008 The proposed development has been previously reviewed by the City ,qL~Ii\1ilf5ldbmittal. Development Services Department's Site Review process (DRC 2007 -btl&;O). The Site has been determined to lie within the 0-1 Time-Of-Travel Zone to the Sports Way Well. Referenced within this document is information requested in the "Response to Site Review", dated November 11, 2007, that affect General Construction, Operations and Storm Water. The requirements listed have subsequently included in the "Conditions of Approval" portion of the "Notice of Decision" and are addressed in the following submittal. Condition 29 requires a Drinking Water Protection Overlay District application for review by City of SpringHeld staff prior to the Final Site Plan approval. Subsequent "Conditions of Approval" will be addressed in the following DWP Overlay Application and referred to in the "Response to the Conditions" which will be submitted separately. A Hazardous Material Inventory Statement and a Material Safety Data Sheet for any or all materials will be entered in the Statement unless exempted under Section 3.3-230 of the SDC. 500 ga1l6ns/5000 pounds of hazardous materials is the limit in the 0-1 TOTZ. Within that inventory, no more than 1 SO gallons of hazardous materials that pose a risk to groundwater will be on the premises in opened containers for handling, treatment use production or dispensing on site. Maximum material size is 5-gallons, in original containers, unless approved by the City of Springfield. Application of fertilizers shall conform to the amounts recommended: maximum one half pound per 1,000 square feet of area; total yearly application of 5 pounds nitrogen fertilizer per 1,000 square feet. , The information that follows regarding policies, procedures, maintenance and supervision of the handling and disposal of hazardous materials shall be reviewed with the owner and contractor before development can commence. . DNAPL: The contractor and all sub-contractors are required to provide the Owner's representative with copies of MSDSs for all chemicals proposed for use on-site prior to use of delivery to the property. The Owner's representative will ask the SUB Water Quality Protection Coordinator, Amy Chinitz (744-3745) to review these submittals. A copy of the MSDS for all chemicals used on the project will remain on the job site as required by law. No products containing DNAPLs will be allowed on this project. As materials are deemed "hazardous", they will be added to the MSDS list in the Hazardous Material Inventory Statement (see attachment). . Chemical handling, storage and use: The contractor shall be responsible for the safe handling and storage of chemicals, petroleum products and fertilizers and the prevention of groundwater and storm water runoff contamination. Chemicals used during construction, including clean-up processes, shall not enter the soil or washed into the storm water system. All chemicals shall be stored in adequate secondary containment; 1 HAy., cS INVESTMENTS, LLC '" DWP OVERL.-d DISTRICT APPLICATION Refer to Containment Monitoring and Inspection Forms in the Application. The site development design planned for this facility involves elevating the building, including the emergency generator/fuel tank unit, above the ~f@!eR.~ived: Plain. . Equipment maintenance and Fueling: The contractor shall provide a dedicated area for fuelin~and mal'~l]Onc!'.llfl rI tna UDmlTIR equipment. This area shall be prepared and maintaine in~ way t at prevents spills or leaks from migrating to the soil or storm water drainage system. No fill materials containing hazardous materials will be used on this site. JAN t t 2008 . Operations: Dumpster areas will be covered and drained to catch basins designed to avoid wastes from leaking into the soil or storm water system, as per City of Spring~eld regulations. This includes paved vehicle parking areas. Refer to Condition 39 in the "Criteria of Approval responses". Policies and procedures de~ned in Section 3.3-200 are listed in the following sections of this DWP Application. Building tenants will be required to comply with all standards set forth in Section 3.3,200 of the Spring~eld Development Code. A sample of a lease agreement has been included in this Application. Tenants will be required to submit a hazardous materials inventory statement to the Spring~eld Utility Board Water Ouality Protection Coordinator to determine whether or not a DWP Application will be required. Rooftop mounted equipment, transformers and other fluid-containing equipment located outside the building shall be sealed and provided with secondary contoinment or a weather resistant enclosure. There will be no chemicals stored outdoors. o Storm Water: Storm water management is described in the Civil Site Plan. Refer to plans by Branch Engineering for Site Review. Wellhead protection signs will be placed as required by SUB. Requirements found in Uniform Fire Code Appendix II-E 3.2.6 for a monitoring program and in 8003.1.3.3 for monitoring methods to detect hazardous in the secondary containment system shall be met for all amounts of hazardous materials that pose a risk to groundwater unless exempted. Requirements found in UniForm Fire Code Appendix II-E Section 3.2.7 for inspection and record keeping procedures for monthly in-house inspection and maintenance of containment and emergency equipment for all amounts of hazardous materials that pose a risk to groundwater shall be met unless exempted. Refer to forms relating to these Code requirements in the following Application. 2 HAwtS INVESTMENTS, LLC c! DWP OVERL.r\)' DISTRICT APPLICATION Application Packet: Item 2. There are no known uses of hazardous materials that existed on the property that has been used as a ~Ibert orchard prior to May 15,2000. Date Received: Application Packet: Item 3. JAN t t 2008 (6) copies of the following infonmation are attached: Original Submittal a) A Hazardous Material Inventory Statement and Data Sheets for materials expected to be required are included. The Facility will ensure that the Hazardous Material Material Inventory Statement is kept current and updated as necessary. It is anticipated that the Facility will normally generate unregulated quantities of hazardous waste and will accumulate less than 2,200 pounds on-site and generate less than 220 pounds per month and be c1assi~ed as a "Conditionally Exempt Small Quantity Generator" (CESQG). Most of the products used in this facility will be related to the emergency generator, office supplies and cleaning agents. The use of "green" products is being encouraged; ( b) Ground water monitoring is not anticipated to be required. The use of hazardous materials that pose a risk to groundwater will be avoided; c) The use of a greater amount of hazardous materials to be used or stored on the site will not involve more than the allowable limits per the Overlay District Code. d) A description of containment devices is included in Section 3; Transformers to be supplied by S.U.B. The Generator/Fuel Tank is self- contained and not connected to sanitary or storm lines. e) The Hazardous Material Management Plan for the Facility addresses the following hazardous material management processes: o Hazardous materials to be stored, containment, spill and waste control and inspection reportsi o Waste management roles and responsibilitiesi o Record keeping and emergency training will be part of the Management Plan. Refer to Sections 5 & 6; g) Refer to 'Waste Determination Form": Waste products over the maximum allowable amounts of 500 gal. will not be used. . I 3 HA'vvIOS INVESTMENTS, LLC', DWP OVERl.r\Y DISTRICT APPLICATION Application Packet: Item 4. This DWP Application will be submitted with the supporting materials to the Director as speci~ed in SDC 5.1-125 for a Type I application. Application Packet: Item 5. A Site Plan Review has been completed (DRC 2007-00060). This DWP Application is submitted in response to Condition 29: "The applicant shall submit a complete Drinking Water Protection Overlay District application for review by staff prior to Final Site Plan approval." On January 7th, 2008, a meeting occurred at SUB with Amy Chinitz regarding this project. Application Packet: Item 6. Items required for support of this Application are enclosed. Additional forms or amended data will be submitted as allowed by the DWP Overlay District, Spring~eld Development Code and DEOprocesses. Application Packet: Item 7. Date Received: The Application fee: $1,039.50 JAN t t 2008 Application Packet: Item 8. Original Submittal A copy of the deed to show ownership is enclosed with the Application. 4 HAZARDOUS MATERIALS MANAGEM~T PLAN Section 1: Facility Description Part A n General Information Date Received: 1. Business Name: Hawes Investments, L.L.C. Address: 2892 Crescent Avenue Eugene, Oregon 97408 JAN t t 2008 Original submittpl 2. Responsible Company Representative: Name Joseph R. Hawes Title President Phone 541-335-2205 3. Emergency Contacts: Name Joseph R. Hawes Scott Penrod Title President Cheif Financial Omcer Home Phone 541-915-0006 541-915-0087 Work Phone 541-335.2205 541-335-2218 4. Person Responsible for the Application/Principal Contact: (HMMP) Kip Amend 5. Property Owner: Name Joseph R. Hawes Address 2892 Crescent Avenue Eugene, Oregon 997408 Phone (541) 335-2205 6. Principle Business Activity: ~nancial services 7. Number of Employees (maximum): 345 8. Number of Shihs: 1 9. Hours of Operation: Omces; 8am-5pm Supporting Businesses: 8am-5pm 10. Declaration: I certify that the inFormation above and on the Following parts is true and correct to the best of my knowledge. Signature: G?t '1--J-.---- I Name: (print). -::S-b~~1'l k. \Z., i. Date: !/1'lD"i3 /V\,,,, '^-"- y-r ~vJL-",> Title: Part B n General Facility Description/Site Plan Date Received: JAN t t 2008 Original Submittal . .IT=:'_.---------- I Date Received: II.....' ~.,.,..- ! --1 ! ------------~'=~=:~--=-~-:::.:.:~ I JAN 1 t 2008 """""\, '1 -'-~:;;;':::-~~'! .......T 0-" () ~"d~IB . (): ~ ENCLOSED TRASH I 1 AREA ( =t 'I , , , , , , , , , \\ \ , \ . , , . \ I \ \ I , \~. \ , ' ':_-~- --~ ~-) -r =\ _I -~ ,) EMERGENCV GENERATOR - WITH SELF.CONTAINED FUEL TANK - ..../ -...... i- . : _ 'Lr- , '1:0- I 1) ",- f) R~~OP . : I : () HVACUNITS : ~I 1 ~ ~" 'i--' 1-- ROOFTOP : if . " , HVACUNITS ,. ~ )1 LC=" :. I III :~ C\t1~;" : ~ 1 ~~""" rf' \ : {: .': gill II IIIIII1 9 =t;: :\ "I. ,~~-T I~\L, ~L_ III (~ : 1/ Iii \ \ @ 'V , , I I I I i r;:::~:d,:l '\?\ ---- _ 0 _~11111 ~II ,I ~~;;;r;:TY::-C'j=m~ y '=~ SITE PLAN J N. TER.N-A,TION.AL JlVA Y ..-J N.T.$. Part ( -- Facility Plan \IMer to IFe Section 2701.5.1) Date Received: JAN t 1 2008 Original Submittal '-=9/ l(l",Ol\\,=::_/i ('T-h""~ I' i' = 11 i I ~___J I I j "I "-, r'i i j-i-'[ ~ lW I, ,--kd.. i,l)' '=''''''-~~'~-~~- - IT':::'=' 'I"IH *1T1~ Tl;::~ .'11"1-'- : .. U ~ I ' 1, 1.-1 I I "-HF;' /41 ;:; n' '-] -II' [I.'.r- ~,' " "I.. L '- , I b_J~'~ t< '?1j~L ('Ld-l-<"vlr-Cj .:--'-.1. .Ir ""'1 I' j~= 1:1" ;Ii'."jl 71 ~..1~ idI. ~I' }-~)', ;'--fTl J;NITORI{ "t/l;1;>V~'j r ~ SUPPLIES ~. ':.------1 1.".1_ -----------I'.'..--j"i i · I i . (-,--1 ! \ r" , ~ ,,; 1- I' 'I ~_._~_! I[ [-,.--1 Date Received: JAN t t 2008 (.) 9 Original SubmittaJ (.) ? ~) .' " '~'!Jri = . . /,,:,,._~- :l.;>-- /f/ '" .1;/ ?" bf IX"~ .ti__IJ . \.~ (~~ k "',>---''''''----- . I ~ r~-' _-Jl,~~_____~ ,. t L. ~~ ~ <L. ~ '--'''''''-J~I-'- - ire- )J_~__,___ i!',:::~... ,~ JANITORIAL ,;:: SUPPLIES \1 t"- / (i~ \.... 'p ). ~ I' ,- L 'r- r i':-', ~~,~_J , , '-"T'---'r - - if-----~II '."H'_' . IT '. r 'r-. L' ]It:.... I 1 . ':1 . ~" , II I ;:!' ",. " ;,,_.- t ,- ,1:. Jl 'F"" "'l"'~"'" '-"':;~,"""',"""'-=~ii::.,~;~l""'""'='":::'~=-"i'=r-~ :,:.-:- , ''1! I'~ \ q :.\ T 'i' >'''-, I', I :"\ -:r- -----:1 '.i i -~tl' [I i ' i. a 11 _..",I . ;.! ~ FIRST FLOOR PLAN N.T.S.. Date Received: JAM t t 2008 "Original Su~ittal ",- , ]1 I' [' ~~-~.=rJ,:r'-..,[~~.~[~[~1[ ..T~,cl S ' ,- I ~ I 't ,-/, k~f~r,,!])"~ i- ---r' HL i ~l r" rr'J ;/ iW"i,m--ni iJAN$~~~,~i n '=),~l pitili1 ~J~ 'cf...T------i;''? "'- ..~............. ~ \'i) ,. rl I' I! , - -i'Ui II _' W~-j~ -, ! ~ I ~ . <,:)----.-. ~ - ;---. "r- (~ (j, ~--- Co " (!. JJ ___ J - '--- \ (~-;)",--,-"..."",,,.,.,,_. --I . I ,- 'I . ["', ~ -""" I' , I' 'I ' b-~I II I ' I~--!. f~'r ...1 'I ,~'- Ii j : '1clw'W, l I . LIt-,,-,--, , --- l;;;:i .=?-- '=- 2_ ~ ..F-- T'~ Iii 1'.1 Ii I , 1-T'" II,j~ ' = .-,LL~j €~~-'\" ~::: SECOND FLOOR PLAN. N.lS. (v " G "jJ~--- (0)"'''''''. C!:; ~:.~ 0':;-'" Date Received: JAN t 1 2008 (.\ c~ " r I , Original ~~,~mittal ~/" ! 1 ii 'r'==<]'=:r'"~""'" "-c~'-T..m~ "-~r<'~"-~["""--"-l I ' t.._. . j::,~j L-----, L.~: II \_~~ l~ r !I U~~ ~.=1) I 1 r I r II " Ii, /~'~r\ (1 r-'-<" ~ '",,! ! ,.' . --_.. JANITORIAL..... !I'" ') I I i 1 i SUPPLIES ___f. L11" t, i U "' q' -I , -,;j'I"' ----\ , . ,. Ic=~- I ' " II it , , , " V I I II -"l"'i~L-~ , I r~ " 'I ~ r','-~~ om;} " 'If ~-I 1 " \;LJ , r ~ I , ~' 1 I ,~I ~ '., " . . ~ 1 l. .,,,,' TC'~' "."-" f"1'- J...? I' I ,"'''''i'. . "I. ....,.I~ ,~"" , . I ._--"".,....\""" , _^==--_._~,~-"c,~~~--,'----ocJ~==~. @ THIRD FLOOR PLAN. N.T.S. Section 2: Hazardous Materials Inventory Statement The Following Products Are Stored On-Site Manufacturer's HaUlrdous HIIZllrdOUS Chemical M.~I)(imum Approx. Storage Stille of NFPA 704 . Lacellon of r Nllme Ingredients allssi~c"t,ion Abstrllct QUllntity Range of Conditions Materilll Ollssificlltion Chemiclll Codes Services No. Unit Nofed Container (SurveyTllble Stored (Survey Sizes IV&V) T.bl.VI) (1) (1) DieseJFuel Alkdnes,C14C16 OowlulfUl) Distillate Hyd,ol~dted 90622-46-1 Middle 64742-46-7 Distillate, A1ky1.h~1 64741.73.7 N.pthd,HedVY 64741.68-0 C.la/yt;cReformed Kerosine 4.5 8008-20-6 309ga!. Tank AI4 Liquid 1/2/0 (2) C9.C16Solvent 64742.94-5 (3) NdPlhd,Hed~ AromatieDi!li ales, Hydrolreatedlight 64742.47.8 Distillates 64742.55.8 Hyd,olredledLight Pa,affnic IMobil DelVdC MX IZincDjthiophosp~te 68649-42.] 1/2 gaL 1/2 gal. NI4 liquid 2/010 (4) 15W-40 ICoolant IEthyleneGfycol 107-21.1 1 gal. 1 gal. NI4 liquid" Diethylene Gfycol 4.5 111-46-6 2/1/0 (4) Coffee Stain Remover ISodiumMetabilulfate 6.2 7681;57-4 1/2 gal. 1.5# can KI4 Powder 1/0/1 (2) Comet ICakiumcarbonale- 13/7-65-3 1/29af. KI4 Powder Silka, quartz 6.2 14808.6Q..()7 1.5# can 1/0/0 (2) 'Sodium Hydroxide \310-73.2 Allrylpheno"Y. 26027.38-3 GP Forward Cleaner Poi}'etho"Yethanol 8 1344.09-8 49al. Igal. NI4 Liquid 3/010 Sodium silicate 1732.18.5 (2) Waler Silicon~ 63148-62-9 Butane 106-97.8 Isobutane 75.28-5 Pledge Propane 2.1 74.98-6 .25g.i!. .75# can F/l/4 Liquid 0/4/0 (2) IsopalilHinic 68920-06-9 Hydrocarbon 1732-18-5 Water Ammonium uu~th 67762_19-0 SoftCarePinkHdnd Sulfilte Soap Ammoniumuul)'1 6.2 68081-96-9 6 gal. 1 gal. NI4 liquid 1/0/0 (2) Sulfate 1732-18-5 Willer 'Petroleum Disb11ilte 64742-54.5 StainleslSteelCleaner Petroleum Distil!al<.: 6.2 8052-41-3 1/2 gilL .75# can KI4 Powder 2/2/0 I,obutane/Propane 75.28.5 (2) Blend 74.98-6 Str'd Ct N t IFI IAIcOhOll:lhO><Y!dle. 68439-46-3 ,e ,rus eura oor 6.2 4g.1. 1 gal. NI4 Liquid 1/0/0 (2) Cleaner Water 7732.18.5 (I.AlkyI Dimellr)! 8enC'{l 68424-85-1 Triad JI Germicidal Ammonuim Chloride Cleaner Di.N.Alkyl Dimelh0 49.1. lsal. N14 Liquid 31010 Ammonium Chloride 68424-95.3 (2) IGlance Glm Cleaner rOdiumUUrylSUlfilte I 151.21.3 Ammonium hydroxide 1336-21-6 3qt. lqt. N14 Liquid 3/3/0 (2) 2-butoxyethanol 111.76-2 /5,0,0", /AJIrrISUlfdteAnOiniC r 151.21.3 Surfactant 3.5 gal. 1 pint NI4 liquid \/010 (2) Acrr!aleCopolymer 25035-81.8 1 approx. 336.75 gal. stored on-site j Notes: Date Received: (1) See Attdched Tables (2) See Attdched Plans for Locations J!JI I 2008 (3) Double-Wall Steel Tank Enclosure Containment, Catch Basin, Cover During Refueling "'.., . 8uiXftltfej Hazardous Materials Inventory Statement Cont.Date Received: JAN t t 2008 Original Submittal The Following Products Are Stored OffMSite & Used During Quarterly Service Contrac~ Cleaning Mllnufllclurer's H.!!ZllrdOUS HlIUlrdOU5 Chemicl!ll Mllximum Approx. Slorllge Stllte ~f NFPA 704 . loclIlion of' Nllme lngr<<:lienh CllIssificllli Abstrllct QUlInlity Rllnge of Conditions Mllherilll CIIlSS!~clltion Chl!miclll On Codes Services No. Unit Container (Survey Table Stored (Survey Noted Sizes IV &V) TlIble VI) (1) (1) MonoethanolamTne 141-43.5 9'dvoHeavyDuty Sodium Hydroxide 8.0 1310.13.2 19.1. N/A N/A liquid (4) Stripper Sodium Silicate 1344-09.8 Water 7732.18.5 AkohoIEtllOxylate'S' 6843946-3 Sodium AI~ Aryl 58411-30-3 Sulfonate Deodorizer liquid.Fre~h Alkylo,,>,polyethylene- 68131-40-8 Is.1. N/A N/A liquid (4) o~lhanol Frasrilnce 7732.18-5 Wolter Alkyl Naphthalene Sodium Sulfonote Surfodont (NJTRS# ExlroctionRinse 489909.502O-P-PQ 1 sol. N/A N/A liquid (4) Sodium Xylene 1300.72.7 Sul(onote 79.14.1 Hydroxyocelicacid 7732-18-5 Woter EthylAJcohol 64.17-5 Diethylene Glycol 112-34-5 ButylElhe, 577-11-7 Heavy-Duty Pre-Spray DioctylSodium 68439-46.3 lsal. N/A N/A liquid (4) Sulf05uccindte 7732-18-5 AkoholEthoxyld~S Water IIOdiO'SP,"" I Sod',m Sol~" 7757.83.7 Sodium 8;sul~te 5.1 7631-90-5 Isdl. N/A N/A liquod (4) Waler 7732.18-5 Dipro~eneGlycol 34590-94-8 Methyl Ether T'ibutoryelhyl 78.Sl.3 O"er&Under Phosphdte 111-90-0 Igdl. N/A N/A Uquid DietheyleneGlycol (4) Ethyl Elher 7732-18-5 Acrylic Polymers Waler Tributo><yethyl 78-51-3 Phosphate 40861-29-8 ZiP'lC Ammonium 34590-94-8 Carbonate DipropyleneGlycol 111-90-0 PldzaPlus Methyl Ether 122.99-6 1 Sol. N/A N/A liquid Diethylene Glycol (4) Ethyl Ether 7732.18-5 EtheleneGlycol Phenyl Ether Acrylic Polymers Water Sodium Hydroxide 1310-73-2 Ethylene Glycol 122.99-6 Phenyl Elher 1300-72-7 Pro-Strip Sodium Xylene 141-43-5 19o1. N/A N/A liquid Sulfonate 8.0 111-76.2 (4) Monoethanolomine 7732-18.5 2.Buloxyetfrond Willer Manufacturer's Haurdous Haurdous Chemiclll Maximum Approx, Storage State of NFPA 704 location of Name Ingredients Classificati Abstract QUllntity Range of Conditions Material Classification Chemical on Codes Services No. Unit Container (Survey Table Stored (Survey Noted Sizes IV &V) r.bl,VI) (1) (1) I Shop Cledn I Sodium HydroKidl' 6,4 1310-76-2 2.Butoll)'elhanol 111-76-2 Igdl. N/A N/A liquid (.) Tributo"Yelhl 78.5\-3 Phosphdll' 111-90-0 Dielhyll'nl'G/ycol 34590-94.8 sndpbodUltraHish. ErhylElhl'r Spl'l'dRestorer Dipropyll'nl'GfycoJ 19d!. N/A N/A Liqui~ (4) MelhrlElher 7732-18-5 AcrylkPofymers Watl'r approx. 10 gal. are brought to site on scheduled maintenance (1)5.. A",chd r,bl.. (2)See AttdChed Pldns far Locdtians (3)Dauble-Wclll Steel Tdnk Enclosure Cantdinment, Cdtch Bdsin, Cover During Refueling (4)Product is Provided by Contracted Maintenance Date Received: JAN t 1 2008 Original supmittP1 Section 3: Separation, Containment and Monitoring Part A -- Above Ground Storage Areas Storage Area Identification (as shown on Site plan and Floor Plans): (1) Emergency Generator Enclosure - Fuel Tank (see Site Plans) (2) Custodial Room - Housekeeping Products (see Floor Plans) Date Received: JAN t 1 2008 Original Submittal 1. Storage Type: X Original Containers Inside Machinery 55-Gallon Drums Pressurized Vessel X Safety Cans Bulk Tank Outside Barrels Other: (309 Qal.).double-walled, fuel tank 2. Storage Location: X Inside Building (cleaning & janitorial) X Outside Building (fuel) Secured 3. Separation: X All Materials Compatible Separated by 20 feet One-Hour Separation Wall Approved Cabinets Other: 4. Secondary Containment: Approved Cabinet. Secondary Drums Tray Bermed, Coated Floor Vaulted Tank X Double-Wall Tank (Fuel) Other: 5-Gallon plastic bins to contain the volume of the material stored with-in bin 5. Monitoring: X Visual Oanitorial & cleaning) X Continuous Other: Fuel tank monitored electronically & per regular maintenance requirements 6. Monitoring Frequency: X Daily X Weekly (housekeeping materials) (fuel) X Other: Engine Coolant and Motor 01 (Custodial Room) Part B -- Undergrow.,d Storage. Areas N/A Date Received: Section 4: Waste Disposal JAN If 2008 Original Submittal N/ A Discharge to Sanitary /Sewer: Wastes: N/ A Pretreatment: Wastes: N/ A Licensed Waste Hauler: Wastes: N/ A Recycle: Wastes: N/ A Other: Describe Method: Wastes: X No Waste Section 5: Record Keeping Description of Our Inspection Program: Dailv use/inspection of c1eanin~ products and/or monthlv inspection bv contracted maintenance staff on products brou~ht into or stored within the buildin~. Weeklv inspection bv maintenance staff of the emerQenev ~enerator, enclosure and assemblv. (We will use the attached form in our inspection program.) EMERGENCY GENERATOR HAZARDOUS MATERIALS INSPECTION FORM INSTRUCTIONS 1. Use this form to inspect emergency generator enclosure, tank and oil and coolant materials within the facility. 2. Contractor will inspect the tank and enclosure weekly during construction, with Hawes Investments Building staff providing the weekly inspection aher construction. 3. 'Hawes Investments Building staff (or consigns) will inspect the Custodial Room and stored materials within the room monthly following construction, 4. Evaluate the condition of the tank, enclosure and Custodial Room! check for leaks, odors, ete. and for items listed below to ensure safe storage conditions. I MQNTH: I DATE: I Area is free from leaks/spills. I Ta nk/Enclosure I Custodial Room I Appropriate 'el11ergency. equipt (spil! kit) is in place. Tank/Enclosurel Custodial Room I All chemicals are segregated. T a nk/Enclosure I Custodial Room I All containers are prope~y labeled. I Tank/Enclosure I Custodial Room I All containers are closed & sealed. I Tank/Enclosurel Custodial Room I Secondary containers il1spech,d. I Tank/Enclosure I -I Custodial'Room I Notes: Probl~n1S Detected: Resoluti~n: 1 1 2 ' 3 I 5 617 I 8 9 110111 I I I 4 I I I , I I I I I IT 12113 14115 I I I 16117118119 I I I I I I 20 21 22 23 24 25 26127128129 I I I I 3' '1 ~ ~ l~: ~ i-}-- ~ I-I ~ I .!!. '" ~ Cl <' ~ <0 Co l I Section 6: Emergency Response Plan 1. In the event of an emergency, the following shall be notified: A. On-Site Responders: Name Title B. Method of Notification tci Responders: Automatic Alarm Manual Alarm Other; C. Agency: Fire Department; State Of~ce of Emergency: Services: Owner's contract service orovider: Other; dial 911 in the event of an emergencv or spill Phone Number: 911 2. Designated Local Emergency Medical Facility: Name: Address: 3. Mitigation Equipment: A. Monitoring Devices: Toxic or flammable gas detection X Fluid detection Other; X Telephone Verbal Date Received: JAN t t 2008 Original Submittal Phone Phone: (24-hours) B. Spill Conta" ,ment: X Absorbents (fuel tank) X Other: double-walled fuel tank and/or plastic bins for materials stored within buildin~ C. Spill Control and Treatment: Vapor Scrubber PumpsNacuums Neutralizer X X Mechanical Ventilation Secondary Containment Other: manufacturer-provided spill containment kit Date Received: 4. Evacuation: X X Immediate area evacuation routes posted Entire building evacuation procedures developed Assembly areas pre-planned Evacuation maps posted Other: JAN t t 2008 Original Submittal 5. Supplemental Hazardous Materials Emergency Response Plan On Site: Location: facility maintenance enQineer's omce Responsible Person: Phone: Section 7: Emergency Response Training Plan 1. Person Responsible for the Emergency-Response Training Plan: Name Title Phone (T. B. D ) Facility Maintenance Enqineer (T. B. D. ) 2. Training ReqUirements: A. All employees trained in the following as indicated: X Procedures. for internal alarm/notification X Procedures: For notification of external emergency-response organizations X Location and content of the emergency-response plan X Awareness'Df the facility's proximity to sensitive drinking water protection area X Drinking Water Protection Information Training/Presentation (contact SUB co-ordinator Amy Chinitz; 541-744-3745) B. Chemical handlers are trained in the folloWing as indicated: Safe methods for handling and storage of hazardous materials Proper use of personal protective equipment X Locations and proper use of Hre- and spill-control equipment SpeciHc hazards of each chemical to which they may be exposed C. Emergency,response team members are trained in the following: X Procedures for shutdown of operations Procedures for using, maintaining and replacing facility emergency and monitoring equipment 3. The Following Records are Maintained for All Employees: X Verification that training was completed by the employee Description of the type and amount of introductol}' and continuing training Documentation on and description of emergency-response drills conducted at the facility 4. A more comprehensive and detailed emergency-response training plan is maintained on site. Location: facility maintenance enQineer's office Responsible Person: Phone: (T. B. D. ) NOTE: A limited number of staff will. be involved with the storage, operation and maintenance of the emergency generator. These staff members are the only ones that will be trained in operating and inspecting the generator enclosure and equipment; they will be responsible for emergency response and weekly inspection of the generator as described in . .. this HMMP. The remainder of the staff and/or vendors associated with servicing the facility will be notified of the hazardous nature of the generator and its associated products and chemicals. Wellhead protection signs will be installed on-site as require to inform staff and visitors of the importance of reporting and cleaning up spills. Date Received: JAN t t 2008 Original Submittal t.:;1/V(f<:::VUt:l 11:'10:/ /"POX tJ41Dl:ll:l~::::14 THE JERRY BROWN COMPANY Ii!J002/021 MATERIAL SAFETY DA 1.. SHEET i MSDS No. APP(:341 DIESEL NO, 2 . Version: 7 . ('" Rev. Date OllOlf200Z IMPORTANT: Read !his MSDS before handting and disposing of this product and pass this information on to employees, I," . customers, and users of this product. 1. Material Identity Trade Name(s) Other Name(e) Manufacturer's Address PRODUCT and COMPANY IDENTIFICATION Diesel No.2 Diesel No.2, Off-Road Diesel #2. Export Diesel #2 Off-Road Diesel, Export Diesel No.2. Diesel.. Fuel Oi/-lll.lhi ijl,d\l6~1~1 Oil (Medium), ASTM NO. 2-0 Grade Diesel,'iFuel Oillql$75T This material is an organic petroleum liquid_ ' This is a Cl;)mplex (C9 TO C20) hydrocarbon mixture which contains less than .5 WT% 'sulfur. BP West CoastProducls LLC SF'. We$1 Coast Producl$ LLC Carson Business Unit Cherry Point Business Un~ 1801 E. Sepulveda Boulevard 4519 Grandview Road Carson, California 90749-6210 Blaine, WaShIngton 98230 uate Kec~IVt:u. JAN t t 2008 Chemical Description Telephone Numbers Emergency Health Infonnation: Emergency Spilllnforma~on: Other Product Information: 1 (800) 447-8735 1 (800) 424.9300 CHEMTREC (USA) 1 (866) 48P-MSOS (aOO-427-6737 Tall Free - North America) el1]llil: bpca.es@bp.com 1 (800) 322-2726 INFO Cl1stomer Service: 2. COMPONENTS and EXPOSURE LIMITS Coml2O,...nt1 ,CUNo_ 11% C:ftrnnft~ttlftn Rv Volum,.2 Exposure L;mi1S ACGIH OSHA ILl! PEL'.!!!!!!!; !m!. HYDROCARBONS WI BOILING PT RANGE 32SoF TO 69BoF 68476-34'6 EQ 100 NfAP Other applicable exposure guidelines; STODDARD SOLVENT 8052-41-3 100 N/AP 100" ppm TWA lCllllUlOOfll'di!JlI6ye:lstW.... .", . NanJ. L..mIbyft)NTP.f2)IARC,f3)OSHA,~)QhOr : ~Ab!ll'~lion:l;bIII IHI pa~ " T.... OSHA ~ure ItrnIl5 were ct\anged In 1993 dlle lDaf!KJeml caurt I'\IIln; ARCO ~ eMsen 1CI1lSl!toe ,e8S OSH^ elpoflUfe IImW. In lIIiS docull'lt1'11 1M lI\ey are genaaDy Mort' s.ni"nglllnl ~ t,..... more))l'(ltldVe \I\Iln (he N1Tenf 8XIIOOUre Dmlt&. ~If ttlN a=R 101O.100D). 3. HAZARD IDENTIFICATION IMMEDIATE HAZARDS COMBUSTIBLEI OSHAlNFPA Class II or Class iliA combustible liquid. Keep away from heat. sparks, and open flame. Avoid tile .switch loading" hazard (See Section 7), .. . ASPIRATION HAZARD! If swallowed, do not induce vom~ing since aspiration into the lungs may cause chemical pneumonia. Obtain prompt medical attention. . May cause irritation or more serious skin disordets! May be harmful if inhaled! Avoid prOlonged or repeated liquid, mist, and vapor contact with eyes, skin, and respiratory tract , May cause irritation of the nose, throat, and Il1ngs, headache, diZZiness, drowsiness, confusion, loss of COordination, fatigue, nausea and labored breathing, May lead to unconsciousness. convulsions. and possibly death. Wash hands thoroughly after handling, Print Dale: 01/0112002 -'FOR "DISCtAIMEROF L1AElIUTV', SEE THE STATEMENT' ON LAST PAGE'" Page 1 0/6 I ACUTE HEALTH HAZARDS . I Routes of EXDosure Inhalation (Primary) IJ I (IJ j I LVVlj I I : q~ DIESEL NO.2 Eye Conta,:t ,. . Skin Contact Ingestion Summary of Chronic Hazards and Special Health Effects 4, Inhalation Eye Contact Skin Contact Ingestion Emergency Medi....1 Treatment Procedures 5. , i , ^' o~ 1 DD~~L 14 THE JERRY BRUWN COMPANY Ii!J003/0;'1 MSDS NO. APPC341 Ver. 7 n~t~ Received: .Sions and SymDtoms JAN t t 2008 E;:xposures llt airborne concentrations well above the recommended El~lI\'!!llliSl1f1il\ittal Section 2 may cause irritation of the nose. throat. and lungs, headachlt."Sl~lIfess, - ..drowsiness, confusion, loss of coordinllUon. fatigue, nausea, labored brealhing aod irregular heartbeats. May lead to unconsciousness, convulsions. and possibly dellth. Airborne concentrations above the recommended exposure ijmits are not anticipated during normal .'; workplace or refueling activities due to Ihe slOW evaporation of this mllterial at ambient lemPeratures. Not.expected 10 ....use prolonged or significant eye irritation. MOderate skin irritation may occur upon short-term exposure. Exposure 10 sunlight may increase the degree of skin irrltation_ ASPIRATION HAZARD! This material can enter thelun!js during swaliowingorvomiting and may cause acute lung inflammation 'and damage which in severe CllSes may be fatal. May cause irritation of the mouth, throat, and sastrointestinal lract leading to nausea, vomiting, diarrhea, and restlessnesS. May Clluse headache, di:zziness, drowsiness, confusion, loss of coordination, fatigue, nausea and labored breathing. May lead to unconsciousness, convulsions, and possibly death. - Exposures at airborne concentrations well above the recommended exposure limits in Section 2 may aggravate medical condilions such as skin disorders or chronic respiratory diseases. Prolonsed/repeated skin expOSure, inhalation or ingestion of this material above the recommended'l.imits may result in adverse dermal or systemic effects. Avoid prolonged or repeated overexposure. See Section 11 for edditionaltoxicology information, EMERGENCY and FIRST AID Immediately mOVe personnel to area of fresh air. For respiratory distress. give oxygen, . rescue breathing, or admintster CPR (C<lrdiopulmonary resuscitation), if necessary. Obtain prompt medical attention, if braathing difficulty continues. Flush wilh clean low-pressure water for at least 15 minutes. If pain or irritation persists after flushing, obtain medical atlention. Promptly remove contaminated clothing, Thoroughly wash affected skin with soap aM water. If there are signs or symptoms of irritation, obtain mediCal attention. Do not induce vomiting since aspiration into the IUllgs may cause chemical pneumonia. if aspiration occurs, promptly obtain mediCal attention, See above procedures, FIRE and EXPLOSION i Flash Point (Method) sOe"FI",.n.ExoloSonHaz><< AP 1250lQ 1500F (0-93) NFPAHazard Rating: Autoignition Temperatilre (Method) AP 4940F . Health: 0 = Insignificant Flammable umits (% Vol. In Air) Lower AP 0.7 : Fire: 2 = Moderate . AI Nonn" Almo<ph"'C TomperaOnean<! ......,ure UJwer AP 5.0 Reactlvlty: 0 = Insigntficant ;;: a::FPA 'Pi 0' No. ~OMBUSTIBLE! When8~::;::::1 :~~~h point. this 5;::::1 ~II rele:se flammable Ellplosion I vapors which, if exposed to an ignition source. can burn in the open or be explosive in Hazards I confined spaces. Mists or sprays may be flammable at temperatures below the normal flash point I Print Date: 0110112002 Page 2 016 ! DIESEL NO.2 01/07/2008 11:45 FAX 5418888214 ~ 004/021 Extinguishing Media , Special Firefighting Procedures 6. Precautions if Material is Spilled Or Released 7. Handling, Storage and Decontamination Procedures 8. Engineering Controls Respiratory Eyes Skin Print Dale: 01111112002 . 'J ," THE JERRY BROWN COMPANY Dab eceived: MSDS fIIO. APPC341 Ver. 7 . JAN t 1 2008 FOr "switch loading" prOcedures (filling ccintainer which previously contained flammable material, such as gasoline), see S~Tnal Submittal Foam. Dry chemical, Carbon dioxide, Water ~pray or Fog \Nater clOd water fog may be used to coollhe fire bUI may nOI extinguish the fire. For fires Involving this material, do nol enter any enclosed or confined fire space without proper protective equipment This may include se~-co1l!ained breathing apparatus to protect against the hazardous effects 01 combustion producls and oxygen deficiencies. COOl tanks and containers exposed 10 fire with water. ACCIDENTAL RELEASE MEASURES Contain spill, evacuate non-essential personnel, and safely stop flOW. On hard surfaces. spilled material may creale a slipping hazard_ Equip cleanup crews with proper protective eqUipment (as specified in Section 8) and advise of haiards. Cle9n up by recovering as much spilled or contaminaled materials as possible and placing into dOSed containers. Consult with an environmental professional for the federal, state and local cleanup and 'reporting requirements for spills and releases, ' HANOLING and STORAGE Special SlOW load procedures for "switch loading" rnust be followed to avoid the static ignition hazard that can exist when this material is loaded into tanks previously containing gaSOline or other low flash point products (see API Publication 2003), Avoid exposure to liqUid and gas vapors. Odor is not a reliable warning 01 overexposure. Use only wilh adequate ventilation~ ' Electrical equipment shOUld comply with National EleCtripal Code (NEe) standards. Keep away from SOurces of heal flames, sparl<s or other ignition sources. Storage and use areas should be "No Smoking" areas_ ; Empty containers may retain some liquid and vapor reSidues and, if exposed to an ignition source. may explode. " OUl$ide or detached storage is preferred. Inside storage should IlE! in a standard combustible liquids storage Warehouse, TOOrn or cab,net. Separate from oxidizing materials, EXPOSURE CONTROLSfPERSONAL PRO II:... liON Where possible, use adequate ventilation to keep vapor and mist concentrations of this material below the occupational exposure limits shown in Section 2, A NIOSH/MSHA-approved air-purifying respirator with an organic vapor cartridge may be permissible under cenain circumstances where airborne cOncentnations may exceed the exposure limitS in Section 2. Consult with a /leanh and safely professional for guidance in respirator selection. Respirator use should follow OSHA 29 CFR 1~10_134, CAUTION: The protection provided by air"purifylng resp~ators is limiled. Use a positive pressure air-supplied reSpirator if there is any potential for an uncontrolled release, if eXpOsure levels are not known, or if concentrations eKceed the protection limits of the air- purifying respirator_ Eye protection should be worn. If there is a potential for splaShing or spraying, chemical- type goggles and, if appropriate, a face shield should be Wom. If contact lenses are wom, conlaot an eye specia6st or a safely professional for additional precautions. Suitable eye wash should be available in case of eye contact with tI1is,material. ' Avoid skin contact with this material. If conditions or frequency of use make skin conlact likely, clean impervious Clothing such as gloves, apron. boots and facial protection should be worn. Nitrile, neOprene. or Vilon protec:tive clothing material is recommended. . , . Non~lmpervious clothing which becomes contaminated with this material should be removed Promptly and not rewom until the material is effectively removed from the clothing, Page3o/6 I Boiling Point: I I Viscosity Units; Temp, (Method): Ory Point. ~ - I Freezing point:1 Vapor Pressure, Temp. (Method): I Volatile Chal'llcteristics: SpBcifiCGravi~ (H20" 1 @ 39.2'F): , Vapor Sp. Gr. (Air" 1.0 @ 60'F .90"F): Solubility In W~ter: PH: I Appearance and OClor: I Other PhySiealllnd Chemical Properties: I I I Stability I Hazardcus Po..111Iow.l-.1Uon other Chemici>1 Reactivity I Conditions to! "'void Materials to AvoId HazardOUS Qrl Decomposition Products I I 01/01/2008 ":48 I I I F'AX , DIESEL NO.2 Other Hygi'enic and Work Practices 9. 10. 11. I Toxicological Information I , , Inhalation Eye Contact P<in\ Oat.: 01/0112(102 I I 5418888214 THE JERRY BROWN COMPANY ~005/021 '. MSDS NO. APpeJ41 Ver. 7 " When working around equipment or processes which may creale the potential for significant skin contact. fuU body coverage:should consist of impervious boots and oil-resiStant coated Tyvek suit or other imperviouS jackeland pants, Use good personal hygiene practices- InCase of skin contact, wash with mild soap and water or a waterless hand cleaner, Wash hands and other exposed areas thoroughly before eaUng. drinking. smoking, or using toilet faCilities. PHYSICAl and CHEMICAL PROPERTIES AP 325<F to 69BoF AP 3 ~ 3.5 al1000F (0-445) UK AP 0' to 24'F AP 0,04 at 100'F (REID.PSIA) Slight AP 0.B5 to 0.B7 AP6 Negligible N/AP Light yellow to amber ~;~. ~J liquid; kerosene odor. When sold for off-road vehicle use In the United States, this material will be dyed red. Sulfur Contei'll" L T 0:5 wt% Cetane # ,,40 to 57 Date Received: JAN \ t 2008 Original submittal_- . STABILITY and REACTIVITY Stable Not expected to occur N/AP Heat and Ignition sources, Strong aCids, alkalis, and oxidizers such as liquid chlorine and oxygen, Burning or excessive heating may produce carbon monoxide and other harmful gases or vapors inclUcling oxides of sulfur and nitrogen. . TOXICOLOGICAL INFORMATION The Information found in this section is written for medical, toxicology, occupational heallh and safety professionals, This section provides technical information on the toxicity testing of this or similar materialS or its components. If clarificatiol1 of the technical content is . needed, consult II profeSSional in the areas of expertise listed ..boYe. Toxicity studies on a similar material resulted in LeSO values greater than 5 rngll indicating II lOW potency, However, cluring exposure Ihe material caused labored bre<lthing, reduced activity and nasal discharge. Animal studies have been performed on a similar malerial with minimal to no irritation beir-.g reported. T en.mlnute el<pOsures to diesel oil aerosols (166 ppm) have been reported lO,bl! ;non-irritating in humans. Page 4 c.! & 61/07/2008.11:46 FAX 5418888214 DIESEL NO.2 Skin Contact Ingestion Prolongedl Repeated Exposures Additional Information on Diesel Exhaust Toxicity 12. 13. Waste Disposal Methods 14. THE JERRY 6ROWN COMPANY Date r ;eived; Ii!I 006/021 MSDS NO. APPC341 Ver. 7 JAN t t 2008 Animal studies with a similar ma~ihl!ltlSlilWJtllti41lTlOderate'skin irritation following short-term exposure or prolongedf.';...~~;~J expOsure. Tn,s material appears to be non- sensitiZing. Exposure to sunlight may increase skin irr~ation_ The aCLlle dermal toxicity tests indicate L050 values greater tnan 2.0 g/kg indicating a low potency_ The acute oral toxicity tests on a similar material indicate L050 values greater than 5.0 g/kg indicating a low potency, In young children. ingested diesel fuel ~roduced symptoms of cough, dyspnea (labored breathing), pneumonia, tachycardia (rapid heartbeat), somnolence (drowsiness), cardiac dilation, vomiting, fever and breath and vorilib.Js of a characteristic odor. Aspiration can result in a fatal chemical pneumonia., Twenty-eight day and ninety-day dermal toXiCity studies w~h material resulted in skin irritation and no systemiC toxicity. . This product contains petroleum distillates similar to those shown to produce skin tumors and kidney damage in laboratory animals. EKposure to diesel exhaust may resufi in reversible symptoms, such as respiratory tract irrilalJon (WIleezing, chest Ug"'tness), mucous membrane irritation, central nervous system effects (headache and Iighthaadedness). nausea, vomiting and heartburn. Lifetime exposure to whole diesel exhaust has been shown to prO,duce lung tumors in laboratory animals. The exact relalionsl1ip between lhese findings and possible human effects is nolknown. " ECOLOGICAL INFORMATION Not. AVOlilable DISPOSAL CONSIDERATIONS Consult with an environmental professional to detenmine if state or federal regulations would classify spilled or contaminated materials' as a hazardous waste, Use only approved transporters. recyclers, treatment, storage or disposal facilities_ Comply with all federal. stale and local laws pertaining to waste management. ' TRANSPORT INFORMATION UN Proper Shipping Name UN HaZard Class UN Number UN PaCking Group 15. Diesel fuel 3 NA1993 PGIII REGULATORY INFORMATION SUPERFUND AMeNDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), TITLE JII Section 3111312 Hazard Categories: Immediate (acute) health hazard Delayed (Chronic) health hazard Fire hazard SECTION 313; No chemicals in this Product exceed the threshold reporting level established by SARA litie III, Section 313 and 40 CFR 372. , TOXIC SUBSTANCES CONTROL ACT (TSCA) All Components of this prOduct are listed on the TSCA Inventory. COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA) This material is COvered by CERCI.A's PETROLEUM EXEMPTION, (Refer 10 40 CFR 307,14) Print Dale: 01/01/2002 Page 5 of6 I 1 IJI/Vl/l:lJlJtl .11:q.1j t"I\X :)qH:itHH1~H I I I ] I CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 . PROPOSITION 65 I " '. .- Based on information currently available, this product is not known to contain "ny chemicals currently listed as carcinogens or reproductive toxins unoer California Proposition 65 at levels which would be subjecl to the Proposition. I Prop 65 chemicals will resu~ under certain conditions from the use of this material. For example, burning fuels produces combustion products including diesel exhaust, a Prop 65 carcinogen, and carbon monoxide. a Prop 65 reproouctive toxin. . I THE JERRY BROWN COMPANY ~ 007/02'1 DIESEL NO.2 MSDS NO. APPC341 Ver_ 7 ;. , 16. Ol'HER INFORMATION General Comments Some of the information presented and conclusions drawn herein lIre from sources other than 'oirec\ test data on the mixture. itself. 1 EO. EQUSI Ll = 1.9$5 TF'IMI GT t. Gfell\8l TtJOIn I . I ' Prepared by: Product Stewardship I I Disclaimer 01 UDbnltr I The InformatiOf'lln thlli. MSOS was obLained frOm SOura3B whicn wt' believe are reliaDle. HOWEVER" 1HE: INFDRMAltON IS PROVIDED wlTltOUT ANY wARRANTY. EXPRESS OR !UPUEI>, REGARD"C IlS CORRECTNE88- ~ condllicns Or'meJls D1 handlif'19. ilOrage. use &nCI dlsposal or ttle product art! beyOftO our control ar'Id mey be bs)O"ldI our knowledgB. FOR nus AND OTHER REASONS. we DO NOT ASSUME RJ!SPONSIBIUTY AND EXPRESSLY DISCLAIM UASn,.lTV FOR LOSS DAMAGE OR E)(FJENSE ARlSINC OUT DF OR IN ANY WAY CONNEciD_ mE HANDUIIG, STORAGE. use OR DISPOSAL OF THE PRODUCT. This; MSOS1AItIS PJ1!PSld and is lObe U!ied 0tlI)'1crlhls product. II1hO prooUlftilu&eC'!JB~" t' "r ,." BnothBr~, this MSDS itIformalaon mayl'tOtce oppllcable. I A~evl8en8: AP ~ AP~lm;I1Cly Uj(=V'*nOWll TR"Tr~ NIP . r..o A~~ InlonnetlQf\ Found HlAP=~~llaIbl8 ttlDA._NOONAvail.ab1e Date Received: JAN t t 2008 Original Submittal P~nt Dato: 01/01i2002 I Page 6 016 ~ 01/07/2008 11 :46 FAX 5416888214 THE JERRV BROWN COMPANY Ii!I008/021 Product Name: MOBIL DELVAC MX 15W-40 Revi;ion Date: 29Aug2006 Pag.1of8 EJf(onMobil MATERIAL SAFETY DATA SHEET I SECTION 1 PRODUCT AND COMPANY IDENTIFICATION! PRODUCT Product Naml!!: MOBIL DELVAC MX 15W-40 Product Description: Base Oil and Additives Product Code: 201520402010, 441048-00. 97E501 Intended Un: . Date Received: COMPANY IDENTIFICATION ,Supplier. JAN t t 2008 EXXON MOBIL CORPORATION 3225 GALLOWS RO. FAIRFAX. VA. 22037 24 Hour Health Emergency Transportation Emergency Phone ExxonMobil Traneportation No, . MSDS Requests , Product TechnicallnfOrn,alion II/J$DS Internet AddreSs USA 609-737-4411 800--424-9300 281-834-3296 . 713-513-3661 800-662-4525.800-947-9147 hltp:JIwww.exxon.com.http://www.mcbil.com Original submittal I SECTION 2 COMPosmON 1 INFORMATION ON INGREDIENTS j RepOrtable Hazardous Substance/el or Comolex Substance(sl I Name I CAS# , I Concentration" I ~ ZINC CffillOPHOSPHATE 6864ll-<12-3 < 2.5% . All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume, I SECTION 3 HAZARDS IDENTIFICATION lllis material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). POTENTIAL HEALTH EFFECTS Low order of toxicily. Excessive exposure mey result in eye. skin. or respiratory irritation. High-pressure injection under skin may cause serious damilge_ NFPA Hazard tD: HMIS Huard 10: Health: 0 Health: 0 Flammability: 1 Flammability: 1 Reactivity: 0 Reactivity: 0 NOTE: This material should not be used for any other purpose Ihanthe intended use in SeCtion 1 without expert advice. Heal1h studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. I SECTION 4 FIR.ST AID MEASURES i , 01/07/2008 1146 FlAX 5416888214 THE JERRV BROWN COMPANY IiiI008/021 EJf<.onMobil Product Name; MOBIL DELVAC MX 15W40 Revision Date: 2SAuQ2006 Pag.2of8 I INHAL.ATION I . . Remove fr~ further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea. or unconsciousness occurs. seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mbuth resuscitation. SKIN CONTACT I Wash contact areas with soap and water. If product is injected into or under the skin; Or into any part of the body,regard!ess of ltie' appearance of the wound or its siZe. the individual should be evaluated immediately bV a Physician[as a surgical emergency. Even though initial symptoms from high preSSure injection may be minimal or absent, early surgical treatment within the first few hours may Significantly reduce the ultimate extent of injury. . EYE CONTACT , ';.' . : .}, Flush thoroughly with waler. If irritation occurs, get medical. assistance. INGESTION I . First aid is normally not required. Seek medical attention if discomfort occurs. Date Received: JAN , t 2008 Original submittal - I SECTION 5 FIRE FIGHTING MEASURES I EXTINGUISHING MEDIA App(l~priaie Extingui$hing Media: Use water fog, foam, dry chemical or carbon dioxide (C02) to extinguish flames. i Inappl'Opristll Extinguishing Media: Straight Streams of Water I FIRE FIGHTING : Fire Fighting Instructions; Evacuate area_ Prevent runoff from fire control or dilution from entering streams, sewers. or :diinking water supply, Firefighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire '"^I"'..d:l surfaces and to protect perSonnel. , I Hazardous Combustion Ptoducls: Smoke, Fume, Aldehydes, Sulfur oxides, OXides of carbon, Incomplete . , combustion products I FLAMMABILITY PROPERTIES Fla-sh Point [Method): 216C (419F) [ASTM 0-92) Flammable LimilS (APIl...:' .,...:. volume % In air): LEL: 0.9 UEL: 7.0 Autoignition Temperature; NID \ I SECTION 6 I ACCIDENTAL RELEASE MEASURES I NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance w~h all applicable regulations. U.S. regulations require reporting releases of this material' to the environment which ellceed the reportable!a.uantity or oil spillS which could reach any waterway including intermittent dry creeks, The Nation,!1 I , I 01/07/2008 11:48 FAX 5418888214 THE JERRV 8ROWN COMPANY ~010/021 Product Name: MOBIL DElVAC MX 15W--40 Revision Date: 29AlJg2Q06 Page 3018 Date Recei"edEJf(~nMobil JAN 1 I 2008 Original Submittal. Response Center can be reached at (800)424-8802. SPILL MANAGEMENT Land Sp/l/: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent. , , Water SpHl: stop leak if you can do it without risk, Confine the spill immediately wi\t1 booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. W<Jter spin and land spar recommendations are based on the most 6kely spill scenan" for this material; however, geographic conditions, Wind, temperatura, (and in the case of a \'later spill).,wave and current direction and speed lTlay greatly Influence the appropriate action to be taken, For this reason,; local eXperts should be consulted. . Note: Local regulations may prescribe or limit action to be taken. . ENVIRONMENTAL PRECAUTIONS large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas, I SECTION 1 HANDUNG AND STORAGE HANDLING Avoid contact with used produel Prevent small spills and leakage to avoid1slip hazard. Static Accumulator: This material is a static accumulator. STORAGE Do not store in open or unlebelled containers. I SECTION B EXPOSURE CONTROLS' PERSONAL PROTECTION EXPOSURE LIMIT VALUES Exposure limits/standards for materials' that can be fonned when handling this product: When mists I aerosols can occur, the following are recommended: !)mg/m' - ACGIH TLV, 10 mglm' - ACGIH STEL, !) mg/m' _ OSHA PEL. NOTE: Limits!standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS The level of protection and types of controls necessary will vary depending upon potential exposure conditions, Control measures to consider: No special requirements under ordinary conditions of use and with adequate ventila~on, PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such a~ applications, handling practices, concentration and ventilation. In:~. ,,~~Iln on the selection of protective equipment for use VI/VI/lVVi:l IL'H t-....;c. ::J41ol::ll::ll::lz14 THE JERRY, BROWN COMPANY @011/021 .;~".t, bL.Yc..oL.. T- ((,oo......N, ') '.' Product Name: MOBIL DELVAC MX 15W-40' Revision Date: 29Aug2006 Page 4 018 ....' ~ ,.; ..' EJf(onMobil Date Received: JAN t t 2008 with this material, as provided below, Is based upon intended, normal usage. . , .. Original Submitt"'l Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection. use, and maintenancemusl be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: . No special requirements under ordinary conditions of use and with ~dequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode, Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exCeeded., '. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Work conditions can greatly effect glove durability; inspect and replace wo~ or damaged gloves. The types of gloves to be considered for this material include: No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely. safety glasses' WITh side shields are recommended., Skin and Body Protection: Any speCific dothing information provided is based on pUblished'literature or manufacturer data. The types of clothing to be considered for this material include: . No skin protection is ordinarily required under normal conditions of use. In acCOrdance with good industrial hygiene practices, precautions should be taken to avoid skin contact. . Specific Hygiene Measures: Always observe good personal hygiene meaSures, such as waslhing after handling themateriOl' and before eating, drinking, and/or smoking. Routinely wash work clothing OInd protective equipment to remove contaminants. Discard contaminated clothing and footwear that Cannot be cleaned. Pr;;u;;tice good housekeeping. . .. ENVIRONMENTAL CONTROLS See Seclions 6, 7, 12, 13. I SECTION 9 PHYSICAL AND CHEMiCAL PROPeRTIES Typical physical and chemical propertlesiare given below. GENERAL INFORMATION Physical State: Liquid Color: Brown ~_._____Odor:___Characteristic Odor Threshold: NJD IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 C): 0.879- Flash Point [Method]: 215C (419F) [ASTM 0-92] Flammable limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignltlon Temperature: N/D Boiling PointfRange: ,. 316C (600F) Vapor Density (Air = 1): N/D Vapor Pressure: <.0-013 kPa (0.1mm Hg) at 20 C Evaporation Rate (n-butyl acetate = 1): NJD vl/vr/LVU~ I I:qr ~^X 341otl~~Z14 IHo JoHHY ~HUWN ~UMPANY 1aI012/021 ~:.;ft:: E~l\n 1I1obil "'~te ~ecelved: Product Name: MOBIL DELVAC MX 151N-40 ..:. Revision Date: 29Aug2006 Page 5 018 JAN t t 2008 pH: N/A Original Submittal Log Pow (n-OctanollWater Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 123 cSt (123 mm2/sec) al40 C I 15.6 cSI (15.6 mm21sec) at 100e Oxidizing Propertlss: See Sections 3, 15. 16, OTHER INFORMATION Freezing Point: N1D Melting Point: N/A Pour Point: -27'C (-17'F) DMSO Extract (mineral oU only). IP-346: < 3 %wt I SeCTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under nomal conditions. CONDITIONS TO AVOID: Excessive heat High energy sources of ignition_ MATERIALS TO AVOID: Strong oxidizers , HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. 'I I SECTION 11 HAZARDOUS POLYMERIZATION: Will not occur, TOXICOLOGICAL INFORMATION ACUTE TOXICITY h Route of E~nn5ure Inhalation I TOJdcity (Aat): LC50 > 5000 mglm3' I Irritation: No eno point dala. I InA_ Toxicity (Rat): LD50 > 2000 rnglkg - I Skin I Toxicity (Rabbit): L050 > 2000 mglkg I<<Ration (Rabbit): D~laa\lailable. Eve Irritation (Rabbit): Data available. ConcIUlllon_L8Ji!roarks Minimally Toldc. Based on test oate for stnJCJUral1y simillll' mat..ria/s. " Negligible hazard ~t ambient/nonnel handling temper.rturea. Based on assessment of ttle comllOl'lenl9. Minimally Toxic. Based on teat data for SltuCIurally similar . materials, I "Minimally Toxic. Based on test oala for s~urally simaar materials. . Negligible .irritation to skin at ambient temperalu...... Based on test dala for structurall-, sim~ar materials. May cause mild, short-Ias!itlg discomfort 10 eyes. Based on lest data fot structurallv similar materials. ' CHRONIC/OTHER EFFECTS For the product Itself: Diesel engine oils: Not carcinogenic in animals tests. Use\! and unused diesel engine oils did not produce any carcinogenic effects in chroniC mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properti",,: Ol!O(/~OO~ 11:47 FAX 5416888214 THE JERRY.BROWN COMPANY \tj013/021 l:~!,:~.. E~~~1!2~~I: Product Name: MOBIL DELVAC MX ~ 5W-40 Revision Date: 29Aug2006 Page 6 of8 JAN 1 I 2008 CarcinogeniC in animal tests- Caused mutations in vitro. Possible allergen and photQilllml1e~l]. &,ql!!ain;;_1 pOlycyclic aromatic compounds (P.A,Cl from combustion products of gasolin~ andlor'tR~Ii'ct~g\'!l'cUIIICt, products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes I P-346, Modified Ames test, and/or other screening tests. Dermal arid inhalation studies showed minimal effects; lung non- specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals. Additional information is available by request. The following ingredients are eited on 'the liSts below: None. 1 ~ NTP CARC 2 ~ NTP SUS -REGULATORY USTS SEARCHED- 3 = IARC 1 5 = IARC 2B 4 = IARC 2A 6 = OSHA CARe I SECTION 12 eCOLOGICAL INFORMATION I ' The information givel\ is based Qfl data available for the material, the components o,f the material, and similar materials. ECOTOXlCITY Material - Not expected to be harmful to aquatic organisms_ M061LITY . Base oil component ~ low solubility and floats and is expected to migrate from water to the land. Expected.to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABllfTY Biodegradation: Base oil component - Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component - Has the potential to bioaccumulate, llowever metabolism or physical properties may' reduce the bioconcentralion or limit bioavailability. ': I SECTION 13 DISPOSAL CONSIDERATIONS' Disposal recommendations based on material as supplied, Disposal must be in ac~rdance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed conltolled bumer for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable ~mbustion products. 01/07/2008 1147 FAX 5416888214 THE JERRV 8ROWN COMPANY IiIJ 014/021 .:~~6. Product Name: MOBIL DELVAC MX 15W.40 Revision Date: 29Aug2006 Page 7 ofa t\< . EJf(tmtMQlilUl; JAN t t 2008 REGULATORY DISPOSAL INFORMATION ungm8' OUIJIIIIl"" RCRA Information: The unused product in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 2610), nor is it fonnulated to contain materials whiGh ~re listed as hazardous wastes_ It does not exhibilthe hazardous Gharacteristics of ignitability. corrositivity or reactivity alld is not fonnulated with contaminants as detennined by the Toxicity Characteristic Leaching Proce<jure (TCLP)- However, used product m;;ly be regulated. Empty Container Warning PRECAUTIONARY LABEL TEXT: Empty containers may retain residue and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRill, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FL4.ME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUS'E INJURY OR DEATH. Do not attempt to refill or clean container since residue is difficult to remove. Empty drums should be completelY drained, properly bunged and promptlY returned to a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. I SECTION 14 TRANSPORT INFORMATION LAND (DOT): Not Regulated for Land Transport LAND (TDG): Not Regulated for Land Tr,msport SEA IIMDO): Not Regulated for Sea Transport according to IMDG-Code AIR llAT A): Not Regulated for Air Transport I SECTION 15 REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is.oot classified as hazardous in accordance with OSHA 29 CFR 1910.1200, " NATIONAL CHEMICAL INVENTORY LISTING: AICS, IECSC. DSL, EINECS, ENCS, KECI. PICCS, TSCA EPCRA: This material contains no eJ<tremely hazardous substances. SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. SARA (3131 TOXIC RELEASE INVENTORY; I Chemical Name I CAS Number , ZINC DITHIOPHOSPHATE 68649-42-3 I Typical Value <2.5% .. The FOllowing In!lredlents are Cited on the Lists Below:. I Chemical Name I CAS Number ZINC OITHIOPHOSPHATE 68649-42-3 I List Citations. 13, 15, 17 -REGULATORY LISTS SEARCHED- 01/0712008 11 :47 FAX 5418888214 THE JERRY 8ROWN COMPANY ~015!021 '~.i Product Name: MOBIL DELVAC MX 15W-40 Revision Date: 29Aug2006 page e ole '. E'f{o~M9c.tljJd: JAN t t 2008 1 = ACGIH ALL 2 ~ ACGIH Al 3 = ACGIH A2 4 = OSHA Z 5 = TSCA4 6 = TSCA 5a2 7 = TSCA Se 8=TSCA6 9 = TSCA 12b '0 = CA P65 CARC 11 = CA P65 REPRO 12=CARTK 13 = IL RTK 14 = LA RTK 15 = MI 293 16 = MN<<anTBmal ::;UOffilnal 17=NJRTK 18=PARTK 19=RIRTK Code key: CARC=Carcinogen; REPRO=Reproductive . EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currenUy appearon a TSCA 4 or TSCA 12b list. I SECTION 16 OTHER INfORMATION N/D = Not determined, N/A = Nol applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 09: PhyslChem Properties Note was modified. Section 09: Flash Point C(F) was modified. Section 15: List Citations Table was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Section 16: MSN, MAT 10 was modified_ Section 08: Exposure Limit Values.- Header was added. The information and recommendations GOntaine<! herein are, to the best of ExxonMbbil's knoWlec:lge aM belief, accurate and reliable as of the date issue<!. You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil. The information and recommendations are offered for the use(s consideration and examination. It is the lIse(s responsibility to satisfy itself that the product is suitable for the intended uSe. If buyer repackages this product, il is the use(s responsibility to inSllre proper health, safety and other necessary infonnation is inclllded with andlor on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and usel'S. Alteration of this document is strictly prohibited. Except to theeKtent required by law, re- publication or retransmission of this document, in whole or in part. is not permitted. . The term, ftExxonMobilft is used for convenience, and may include anyone or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly 0/' indirectly hold any inmrest Internal Use Only MHC: 0, O. 0, O. 0, 0 DGN: 2003490XUS (1012126) PPEC: A Copyright 2002 Exxon Mobil Corporation. All rights reserved 01/07/2008 11:47 FAX 5418888214 THE JERRV BROWN COMPANY Ii!)018/021 :~'f.:~i.~ fJJ Material Safety Data Sheet . . <I> WHMIS (CwsirlClllion) Class D.2A: "'lo"" e.....ng """'r lexle _ (VERY TOXIC). Personal ProUCtlve Equipment WHMIS (Pielograms) ~*'- J Section 1. Product and COmpany Identification Producl ' Name I Global Extended Lifo Rad SO/50 Premix Trade name Synonym Coolonl and antilteeu. I..;: ,;.-.......... Associated P,odu<I'.llem 86-1140EM II Code , lcAS # Mixture. j V slidation Date Juna 12 20081:1 Chemical Vamily Glycol. Chemical V.nnula Not appllc:at>le. Prinl Date , J,:"", 12 2006 II - Manufacturer Rec:ochem Ine.. 850 Montee de Uesse Montreal, Quebec 51+341-J~O Industrial applications: CooIari: an.d antifreeze formula1lans. (11 CUi' IIf Reeod'lMn Ine.. E~n" Cammunlci1Illons and Regulatory Affairs Oepanmenl (905) 791-1788 ~ M.terial U... Section 2. Hazardous Ingredients Name CAS # . % by I E~POSllre LimitS Wei'3bt Canadian Values (ACGIH) 4S - 55 ACGIH (Canada, zOP'~ CSt: 100 rngIrn' E1hyIene glycol 107-21-1 U.S. Values (OSHA) E"'_ ACGIH (C....da, 2UU'~ - CEIL: 100 mgtm' J Section 3. Hazard Identification I - Emergency Overview . WARNING. POlential Acute Health Elfeor. HARMFUl. OR FATAL IF SWAllOWED_ F'ouIble damage to liver and Iddneys. H!IIated material tan eause thl!lrrnal bumti. MIS! or vapour trnrn no_ mal!~a1. may cauSo..,.. sldn and rosplratory lrTIlallon. _ 6ec1lon .11: '"ToxIcolog....ln~.forfUrtIler homan heallll ..- Toxic by ingestion. May cause abdQmD1al discomfort or pain, nausea, vomitit'9', di.zzi1'1ess, centra, nervous system ~ IiIfIQ gJrrRl. Cardiae falu-e, pulmonwy edemu and severe kidney damage m~ deveIQ", Moy ciuoe thild eye ""tali"". May C3lJt;t! mild slcin irritatiOn. UnDkety to be m.aled because of physical chanc:terlstla. howe.vef. heated ma~rial may produce vapcurs, whidl may cause.lrriration to lungs if inhaled excesslwly. InhalatJem. particularly of mist. may cause irritation of the nose ~nd throat with headache. High vapour c... ,.,..:......,.Jons may )Ioduce nausea, vomiting, headache, diZZiness ~(J irtegular eye movemenl. Contl/Illed on Next Page J Date Receivea: JM~ 1 1 zeos Cr:oiral Subrnihsi 01/07/2008 11:48 FAX 5418888214 THE JERRV BROWN COMPAHV Ii!J017/021 ~1:,~;;\';( tiJI- .'Page; 1/6 VaUdate<! on June 12 :a Global &tended Life Rad 50150 Premix Note to Physician n Tne :r;lgns and symplDms in ethylene glycol poisoning a"'etho$~ nfmMabol!,c addosls, centra.l nervous system depression and kidney injury. C6nical cl1emistry m")' reveill.anlon-gap rnltabollcltcldosls and urerTia. TRfatmen1 with efhand to intibil the metiJboflsm of glycol tD oxalate. Early admfnl:!:itratlcn of ~.anol may counter the toxic effects of ethylene glycol (eardioputmonBry effet:ls ettribut.ed to metabolic acldolils and ranal damage). Hemodialysis or peri10neel dia~:s have been of benefit- P..,..,.;sting skin. <fie. ond IeSpir1llOry disorders may Ile aggtav..od by e""""uni'lo Ihis produot. Treot symplomaticslly ond Soppof\l\l\!ly. Section 4. First Aid Measures Eye Contact IMMEOIA TEL Y flush eyes with running Wilterfor ~ Ie. 21;1 minutes, kl!ll!lplng eyelids open. If initation peBist5, seek medical attention.' ,- Gently and thoroughly waa.h the contaminated skill with nan~ing water il'ld non..abrasjye soap. If irritation pe~$b, seek medical attention. WEh eontarninaled c1crlt1il1g before telJ$ing. Allow me Vlc.1lm to rest In a,;well-ventilated area. ttiJTitBtion peruiiti:, seek 1I'\8d.1C<!1 attention. If breathing is diffiwll adrnlnlsmr oxygen. If victim is not breathing have qualified perGOnnea administer artlfldal resplraUon. 00 NOT indUce, \IDmIlIng unless directed to do so by medicsl pelSO'Inel.SEEK I~MEDIATE MEDICAL ATTENTION. If ~dlcal al1vlcels delayed; and a moderate volume has been swallowed, havl!llndlvldual consumB three 10 four ounce, of hard liquor, SU~ as whiskey (antidote is inhibition gf alCOhol dahydragen3s1!1 to Jlre'll8nt kidney damage). Skin Contact Inhalation Inge.tion Section 5. Fire Fighting Measures 1'roduds or Combustion Thes. products are csrIlon oxides (CO. Co,). Fl.... 'Fi&hting Medi. anlllPstruetions SMALl FI~E: U:!i~ DRY diemicals. COl. watef .spray or foam. l..AttGE FIRe: Use water spray, fog or foam. DO NOT use w$tetJel Cool ~talnlng ~sels wth water jet in order to pwent presGl.B"e bUlIcklf), aut~gnlllon or explosion. . lM\an htiated to decomposilion, il emits acrid.smOke dr'Id initallng fumes. May};l,e combustible at high lempetatute. Not a product. presenting risks of explosion. Fire Hazards ExplosioD Hazanl! Section 6. Accidental Release Measures Ln.-g. Spill and Leak Dilute with water and mop up, or absorb vvith al1 inert DRY material ~d pla'ce'in an appropriate Waste disg05F;l1 conta.iner. stop leak IfwitholJl: risk. PreWJIt entry into sewer'$. b4\$l!lmenlS Of confined &reas; dike U~~ed, Abt.0l"b wlth In inert material illld puttl1e splled rnale~alln an aPll~a'" waste disposal, Dispose Of In aCGOl'dance w11h rEglon.1 regutafims. 'I SmaU Spin and Leak Section 7. Handling and Storage Handling 00 NOT PIWBIIDw.Avold contact with I!lyet;. Avoid breathing vaPOUB or SpI'il)' ~istEl. Wear auftab1e prorec:tive dorhing. U'ee in CI_well Ventilate.d area. Avoid contamination Ylrith reactive subetal1~i Aftar hanlJtlng. atways wash hands thoroughly with soap and Water. I' See S.CIInn 1110 lor applicable Inc:omplltlllle malllrlala. K8ep container dlY- Kee~ conlainer tightty closed. Keep in a <:001, wel&-ven,~lared place. Store in an apprvptie.le container. If the fluid is exposed to excessiyely high lem~ra'LJres. rherm~l degradation can oceur, ~VQit;l high mmperatures or sources at heat IjlJrin:/ ~ended storage periods. ~ : Stora2' I continued on Next Page j Date Received: JAN 1 1 2008 Original Submitt,,1 Ul(UlnOU~ 11 :48 FAX 5416888214 THE JERRV BROWN COMPANY Validated on June 1211 .f~(":":'# En,;neering Controls Section 8. Exposure COntrols, Personal Protection GlobEII &tended Life Rad 56150 PremiX . ',:', . -... -. .,-" Personal Protection D fi1i @018/021 Page; .116 I I Eya SpIollh goggl... Fa... shield ......n "ondflf1g "evale<l., ,.".~;we met,,"a!. Bo~ We", ,"~ahI. proll!C\ive dotl1ing Vlhen handling elevated t.mpel1llure "'atelIaJ, Respiratory Wear *"oprlate respirator when \IeI'ItIlalim is insdequate. Ra~da Gloves OmpelVious). NltriJe glove.. Neopren. glove.. Provide extlaust \lentllatlon or other engineering controls to keep the airbome con~nlrations of vapors below their n!;spectlve tnreshQld lImit value. En&Uttt that eyewasl1 ,tatlons iU1d safety snOW8l"s are proxilYlal to the work-station tcca~on. Section 9. Physical and ChemiclIl Properties Physical State and Appearance Mol..ular Weiehl .n" - Boiling/Condenaation Polnl Melting/Fnezillg Poilll Specific Gravity : Vapour Pressure Vapour D....;'" _ VOC COlltont The Product i.: . Auto-lpitiOll TeOlpenllure Flash Point Flammabl. Umits Clear visroU5 Iiql,li(l. Odour Nor..,.,,.,l."'O.....w. Taste Colour Odowtess. $W!l.l L\,IIl'lir'Jescent yellQW. O%(w~^ lilac 112fOlm. 0.01 comp~ IO"BU\yI .ee10Ie. NOI ovaiIaIlle. NoIavelal>le. Soluble in waler . ~eth~nol, diethyl fitheJ'~_ Not lMlillll>le. Fir. Ha~ards in Presen.. May be co_ble In sitUa60ns where enough water h... evopauraled 011. o( Van.US Substances 7.B to B.5 [B_.) 120'C (2114.2'F) ..,~._........_- hac 1'- lDlII .37'C (-3U'F) Evapo..non .Rate Odour Thre..bold ViScosity SOlubilitv Other Properties 1_0710 1,06 (WOtor-l) 0.06 mm of Hg (@ 20'C) 2.1 (A1r-1) Nol avallahll!. May be comllUOdble at tligh iemporalUMl. NDne. None. AQUeOU& solutions are nCf't'"ftamrnabIe. NoIopplical>lo. I Continued on Next Page Date Received: JAN t t 2008 Original Submittal 01/07/2008 11:48 FAX 5416888214 THE JERRV.B'ROWN COMPANY 1i!J019/021 . ~;S~?'~. /JJI Page: 416 Va6dated on June 12 :t1 Global Eldel/ded Life Rad 50/50 Pl8I1Iix . ~ ,., '" '... g' Section 10. Stability and Reactivity Stability The ptO<luel is a18ll1e. Conditions ofTn,tabiUty No .ddl~on.'_""'- Incompatibility witb R.~. IMIh Ol/idlzlog "9"nI$. ''''ds. a1kslia. Various Substances Section 11. Toxico'ogica"nlormation J Roules of Entry Toxicity to ADim~1I1ii Absorbed through skin. EYIl contact. InhalatIon. h1gestIQn. AOlJle 0tllI \OI(iClly (LD5O): 5000 mgikg [R.n AouI8 dermal ''''''city (L050): 9500 mg/Iql [RaIlblt]. Acute Effects on Humans EyeS May C8Uie mild eye irritation. Skin May cause mild skin irril8tiOfl. Heated material may also cause skin bum3. wiU1 dired CtIn~ct. '"kolall." U<Ilikely to be inhalellbec8"". of phyoical cI1.rac\eliS~"', howevEr, h.."'. ...Wi", tnSy pnxluCl>"'POU"'. ""'... may cause ;rr;tatioo 10 lIJ"9a w itIIlaIed "",,",",.eIy., Innala~on. particoAsrIY of miSl. mav.ca.ee i I... " 200{g' nose ano th J....11 2""i1""'O. H;g~ vapout coocenll'aPons may ptO(luce no....ea. '001"'119. headache. 012>10." am Irregular f!fYO mo..,mem. IrtLalCltlon 01 mIst or vapour from heated m~ertal may cal.$8 IWirdra10ry Irritation. Ingestion TOlde by ingestiOn. HARMFUL OR FATAL IF SWALLOWED. EUlyIene glycol is! mare aculely toxic lo 111.1T1smJ thlln to animals. The lelI'lal dose in I'IumanG is esam~ to f)@ 100ml (3 .......~ May cause abdOminal di$:c:omt'ort or pain, n'-:Usea. vOmiting. dimneSS, central nervous syslem effects and coma. Cardiac fallure. Pulmonary edema and severe kidney damage may develop. ; SmaB ~mounts swallowed incidenlalm normal handing. cperaooris are not likely to cau.se injury; hOwe\lel' GWalI~ amounlS larger ,than that may cause serious injury, ~n death. CARCINOGENIC EFFECTS: M (Not classifiable for human... animal.) by ACGIH. Ethylene glycol did notoilu.e o,,,_i" long """' anw""hludiea. ' MUTAGENIC El"FEC'TS: In vitro aPd in Vivo rnutagOnicilystuli.. W01e ~\IB. TERATOGENIC EFFECTS: Tet=ogenlc In mice 0\ 10\lOI$1)01"", ma1IIlmal tmdcily. DEVELOPN","AL TO~ FelolOlcie In mice $lle\lels bolow m.lemal toxIclly, Exee&$1IIe _aure may....... centralneMllJS sys1llm (CNS) depreaslon. kidneyfeilule and pOMibly Mr ellecl3. Repeated or j:lrolongl!ld 8}(pDSUN!lla the substance c:anproducetargel mganl damage. ' F ,'" >." anclrep.atod contad. wIIh ,kin eon coUs. drylng 01 \he skin resUling '., ilTitation and d""".Iiti.. R.ap8aled 8:q:lOSure rD' a hlghly lOXIc mKlerlal may produce gerierat deterioration 'of health by II" a<<:a.llJ1Jlatiun in one or many human organs. . l~paired rep,ooudive, liver. kidney and central nervoFJ's system functions from pre-exlsdng disorders maybe aggravated by exposure tQi this product. Pfe.existing eYe. skin and I'(!$piratory dlSiorders may be ...."..!II..:., ......J by 8XP9SUTe to ffiPfodu~ I Olronic Effects on HumallS Section 12. Ec%edes"nformation Ecotoxicity For occldanlllll dlscha.gas Into onvlronmllflt, see 5ecIIon #6: . Aocidenti'" Ral_. _ures- iar suggostod lnatrucllona. Ec;:otoxit;ityin~ter: '100 mgll peso. A1g.'_I. 1 hO<U($) [Algae]. >100 mgil [LC50. "',"",1. 24.00<U(S} (FISI\I. "00 O1gil (EC50. Dapbnla.14 hourIs) [Dap~nla]. Prac1loally nnrHoxlcto ,quaUe oryanism..Biodegradabl.. SigdegTUdption "'I'lder aerobic $tath~ laboratOry QQndJtlQnlS 1$ high. " Tnit prod\lCl is not gp!IcMd to bloac:cumufate It1rougi'l food mains in !he emiironment. ~0'5B&'a &igni1icanl riSk of Dxygen depll!ltlon in aquatkl syttems.' J ~ Continued on Nut P"ge j Date Received: JAN t t 2008 Original Submittal THE JERRY 8ROWN COMPAMY Ii!J 020/021 01/07/2008 11 :48 FAX 5416888214 Valid.aiM on June 12 U ~;#.(~> fJJ1 Page; SIt; I I Global Extended Life Rad SO/SO premix IIlI ",.",' . SecUon13.D~posa'Conside~Uons Wtlste InfoMnation vw.ste m.uat be.dlsposed of in acccmlance \MIt'I'l fedl!ral,.s.tI1e of provinCial and l~ l;1Invlmnmental conb'1;J1 fli:!iJulatJQns. J .' I Section 14. Transporllnfom1ation Canada TrUSDortalloll ofUangerouR Gooda rrnGl!l\fo~atio.. Primary Oa.. ,.01. TOG ecntrolled material. Subsidiary Class (it npplicablel Proper .hipping name Hazard Identification Number Packing Group Speda) Provisions ..----- No' applicable. No! applicable. lIIa.applleoble. NOloppllcable. _I~l!ruational Maritime Dan~erou. Goods IIMDm Transoortation InfonnatioD Primary 0... No' """trolled under IMDG. Subsidiary Cia.. (if Not applicable. applicable) 'Proper shipping n.me Ha""rd Idenllflcation Number Packing Group Marine PoDUl:mt Special Pro~.ion. JUIf! 12 200f1 ~1mC 12. l.tJNCI Nat ......t';~_.~. Not appliCable. ......;,,_.._-- Not applicable. Not pollu!ant Not app6cable. Uftited Slates D_nartmont of Trmsoorllllion roo" Information Primary Clas. Subsidiary d... (if applieable) I'roper ,hipping name Hazard Identification Number ra.king Group ;;;; Special Provbioll5 Class 9: Miscellaneous halardous lRIIerial. ~ Environmentally hazardOUS substance. liquid. n.o.s. (EthY1l!lne gJycal) UN 3()82 In In Qontainets of 5000 Ibs captlr;ity or less this ptoduct Is exempt ft'om DOT regulatiorni (non ,.gld_). Regulote<l Quanllly (RO)- 5000 lb. (226e kg) (0. eth"""'. glyco~ ~(lIr bulk shipments e!qu$l to of gl'eater than Regulated Quar'luty (RO), ple~6e Bdl'll!lre to classification :n Qutlint:lo In DOT CIlitssiliadiQn sedJon. For air shipment classifICation and associated regulations. please refer to the latest ediuon of lATA Dangerous Goods RegUlations. Int_malional All' Transport Association (lATA) Co/ltlnfled on Next Page I Date Received: JAN 1 1 2008 J Original Submittal 01/07/2008 11 :48 FAX 5418BBB214 THE JERRV BROWN COMPANY \11021/021 (~:<,.:'... i1J1 Page: 615 Validated 011 June 12:n Global Extended Ufe Rad 5015!J Prymix Section 15. Other Regulatory Information and Pictoglillfl$ a WHMIS Classification (Caoada 1 Canada l,)omestic Substances List (DSL) Status HCS Classifi<ation Class: Target organ effects. (U.s.A.) CI... D-2A; Malen.1 causing ._ toxio effeots (VERY TOXIC). (f) This product andJ Ot all of Its components are: on the DSL . U,S.A. Regulatory Lists This product andl or ill or ils COfJIIJonenlo are on !he TSCA Inventory lisl Hl\Z3rd..,us Material Information System (U.S.A.) ~",.w2'1 i.I'i".,,;;;.!'~.i":il.";ffi ..d'.'~;.".li",_' 1.'7<.:'11' It".tlJ., , ~o- R9cllvlly :0: I Permn.1 Pratacllon : ~ : National Fire Protection Association (U.S.A.) H<tllb . Section 16. Other Information V"lidQccd .nd vcrl"ed by C0U1p1h'nc:e aad Teebnlul iilrl;lnntiOll M:analJlfr aD Ju~ 11100f1 .IPriukd.' JIIDC' 12: 1'*i1 N~tite to Regder _ " " To rite 11m of (JUT ~MINI'lJIIllII8lnJlmnnlon mAtaInBcl' henJIn Is ~ Uowvww; 1laMwrJ..:rbowI r--' su(JpiiItI'lI<< lilY "'''IfIINIf/,."...asUlDM my ".blllfywhafSalnlWlbr - r11I1ICCUlllCYDl'.. ,..' '" ,,0''''', '. .. COIIUUJNb8nJID. RtNII CfltonrJf'nd.\U't ar 511""'01 In, 1ItG'hI""'''''''' "OICI ,.s." '. .,." '. DIM UUIT. AD /rWIId.I/C ~ ptU..-lIId:MlIM rtu'" MfI.1Ioufd _01_ "itt! ~ AIII'mutIh '*-III = IYnn'I mcfN~If"U1Mrt111. n~JUWInWI "..,,,,-,.. m.an'Y~ rf'lalem.r. MSDS are available at www.recochem.com , , I ; Date Received: JAN 1 t 2008 Original Submitt~1 l1.'\LAHuH.-'\ilrU "EXTRElE )=-HIGf 2=t.t:JOERATE '''SlIGI-fT OrIN9fGNIFICANT FIIl~O . - I i REACTMTY HEAl TIf 0 8F'ECw. MATERIAlS-"5Bi:Y~~LET ~fJT Z 4-J . '~;. :::.'., , COFFEE STAIN REMOVER ACGIH TLV 5 mgiM' 5 mgiM' ISECTlON 2 - PHYSICAL I CHEMICAL CHARACTERISTICS BOILING POINT: None VAPOR PRESSURE (mmHG): N/A pH (1% SOL): 5.0 SPECIFIC GRAVITY (H,O=1): 1.48@25C APPEARANCE AND ODOR: White Powder, Slljlhl Sulfur Dioxide Odor ISECTION 3 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: None METHOD USED: TCC EXTINGUISHING MEDIA Water spray, Carbon Dioxide. Foam. or Dry Chemical SPECIAL FIRE FIGHTING PROCEEDURES: Wear self-contained positive-pressure breathing apparatus and protective clothing. , . UNUSUAL FIRE AND EXPLOSION HAZARDS: Sulfur Dioxide gas evolved at a rate which increases with the temperature. ISECTION 4 - REACTIVITY HAZARD DATA STABILITY: Stable POL YMERIZA liON: Will not occur INCOMPATIBILITY: MOisture, Acids. Oxidizing Agents. Reducing Agents. and Strong Alkali HAZARDOUS DECOMPOSmON: Sulfur Dioxide . . CONDmONS TO AVOID: He!!!, ~en flames. and prolonged storage at elevated temperatures. .ISECTION 5 - HEALTH HAZARD DATA ) PRIMARY ROUTES OF EXPOSURE: EYE INGESTION INHALATION SKIN CARCINOGEN: No ' - - - ; 1-, ~" ACUTE HEALTH HAZARDS: Irritating to eyes. skin, nose. throat, respiratory system, and stomach. Harmful if swallowed, Sulfite-sensitive individuals and persons iluffering from asthma or other respiratory problems may experience an allergic reaction characterized by nausea. diarrhea, itching. swelling, hives, acute asthma attack, loss of consciousness, or anaphylactic shock. CHRONIC HEALTH HAzARDS: None EMERGENCY FIRST AlO PROCEDURES EYE CONTACT: 1n-medla1ely flush with large amounts of water for at leasi 15 minutes. Seek me,dical attention. INGESTION: Give 1-2 g1aSMiI of tnllk or water to victim If conscious and alert, then induce vomiting. Seek medical attention. INHALATION: Remove to hsh afr, give artificial respiration If not breathing. Seek ..ro~;"oi attention. SKIN r.ONTACT: Remove corlfamjnated clothing and launder. Wash with water. If irritation persists. seek medical attention. ISECTION 6 - CONTROL AND PROTECTIVE MEASURES VENTILATION: Local Exhaust _ RESPIRATORY PROTECTION: Dust Mask I NIOSH-Approved respirator with an acid gas co, ~ ;~"C and dust filter. EYE PROTECTION: Chemlcal Safety goggles PROTECTIVE GLOVES: Rubber gloves HYGENIC WORK PRACTICES: Wash hands thoroughly after handling and before eatinQ. drinkinQ, or smokinQ.__ ISECTlON 7 - PRECAUTIONS FOR SAFE HANDLING AND USE I LEAK PROCEDURES HANDLING SPILLS OR LEAKS: Ordinary housekeeping is adequate. WASTE DISPOSAL METHODS: According to federal, state. and local regulations HANDLING AND STORAGE PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN. Store in a dry area irway wom acids and oxidizinQ aQents. ISECTION 8 - TRANSPORTATION DATA DOT SHIPPING NAME: Not Regulated % VOLATILE ORGANIC COMPOUNDS: N/A.. . SOLUBILITY IN WATER (% BY WT.): 40 % AUTO IGNITION: N/A 1 Arhe statements. lechnicallnformalion and recommendationscoritained herein ar~ believed to be reliable and accurate; however. they are provide~ without warranty or guaranlBe of any kind. express' or Implied. as 10 their accuracy or completeness. As the condlHons or methods of use are beyond our control. the manufacturer and seller do not assume any responsibility;and expressly disclaim any liability for use of this product This Information Is offered for your Infonnation. consideration, and Investigation. You should satisfy yourself that you have all current data relevant to your particular use. MaslerBlend, 100: assumes no responsib~ity for any loss. damage, or expense, direct or consequential, arising.out of their use. . 5- ",,,...~\,.... .. ,~ ) JAN t t 2008 MA TERIAL SAFETY DATA SHEiEllUbmittal Page 1 of5 Procter'& Gamble Fabric and Home Care Division Sharon Woods Technical Center 11530 Reed Hartman Highway Cincinnati,OH 45241-2422 Date Received: MSDS #: H94000M Supersedes: NI A Issue Date: 11/1199 Last Issue Date: NI A 4~EXTREME 3~HIGH 2~ MODERATE I=SLlGHT Emergency Telephone Number: 24hr P&q Operator - 1-800-926-94410r "all Local Poison Control Center Identity: Disinfectant Pnwder Cleanser Use: Powdered All-Purpose Cleanser Brands: COMET (Regular and Lemon Fresh fragrances) Hazard Rating: I Health: I Flammability: 0 Reactivity: 0 ) Ingredients/Chemical Name: Bleach; cleaning agents (calcium carbonate, sodium carbonate, anionic sur~actants), quality control agents, perfume, color. Comet Cleanser contains no phosphorus. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. I" Chemical I Common CAS No. Recommended Limits Name Name Calcium Limestone carbonate 1317-65-3 ACGlHcTWA: 1Omglm' (total dust) 1 5 mglm3 (respirable dust) OSHA PEL:..li..mjl/m3 . Comoosition ' l,D50/LC50 Range 60-100% NAlNA Silica, quartz Quartz (naturally occuring component of limestone) 14808-60-7 ACGlH TWA: O.lmg/m' (respirable dust) OSHA TWA: 0.1 mg/m' 0.1-1% 9 glkgiNA ) . ,..-. 5-2 '. . ","'I~', ) COMET DISINFECTANT POWDER CLEANSER MSDS (Continued) , ". . '''.. '" ~" Page 2 of5 Health Hazards (Acute aud Chronic): Ingestion: Mild mucous membrane irritant. Date Received: Eye Contact: Mild eye irritant. Inhalation: Mild respiratory irritant. JAN 1 t 2008 Skin: Mild skin irritant Signs and Symptoms of Exposure: Original Submittal Ingestion: Oral ingestion may result in gastrointestinal irritation with:nausea, vomiting and diarrhea, Eye Contact: Prolonged skin contact or direct contact with eye may result in superficial, temporary irritation similar to those produced by other household detergents. Skin: Prolonged skin contact or direct contact with eye may result in superficial, temporary irritation similar to those produced by other household detergents. Inhalation: No hazards under nonnal conditions. of product use or within the occupational exposure guidelines. Unusually high exposures may cause coughing or irritation of nose and throat. " ) Emergency and First Aid Procedures: Ingestion: Dilute with fluids and treat symptomatica,!IY. . Eye Contact: For accidental eye'contact, flush thorougllIy with water for 15 minutes. Skin: Wash with soap and water and discontinJe use. Inhalation: For accidental. high level inhalation, remove to fresh air. Get medical attention if coughing persists"'" Other: Consumer product package has a caution statement: CAUTION: KEEP OUT OF REACH OF CHILDREN. May cause eye irritation. In case of eye contact, flush thoroughly with water. Ifirritation persists. see a physician. If swallowed, drink a glass of water to dilute. Do not mix with other products especially toilet bowl cleansers and products that contain ammonia. Flash Point (Method.Used): N/A Extinguishing Media: Use CO2, water, or dry chemical. Special Fire Fighting Procedures: None required. Unusual Fire Hazards: None known. Explosive Limits: LEL: N/A UEL: N/A Stability Unstable: Conditions to Avoid: None known Stable: X Incompatibility (Materials to Avoid): Ammonia and acids. Hazardous Decomposition/By Products: Chlorine gas. Hazardous Polymerization: May Occur: Conditions to Avoid: None known Will Not Occur: X ) '1 I , 2 .. . Date Received: 5-: ~'I"".; ~, COMET DISINFECTANT POWDER CLEANSER MSDS (Continued) .. ." JANplg1m ) : :,'<.'.: '.i,f:i~Dillm!{\'1t'Jll~mF~~JlflmDit~j1'JI_lj~j~a._Jii~; Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN CoMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULA nONS. Product contains biodegradable surfactant If pennitted, flush small quantities down sewer drain with large excess of water or dispose of at landfill~1 Steps To Be Taken in Case Material is Released or Spilled: Vacuum to remove spill. and place in trash container for disposal or flush with water. Do not dry sweep. ' Precautions To Be Taken in Handling and Storing: A void moisture when storing to prevent Joss of bJeaohing action and to prevent caking. Other Precautions: None required. Respiratory Protection (Specify Type): None required wiih nonnal use. For bulk handling or other dusty conditions, use respiratory protection approved by NIOSH for dust. Veritilation Local Exhaust: None required with normal consumer use. Special: None ) Mechanical (General): Acceptable. Eye Protection: None required with normal consumer use. Industrial Setting: For splash proteotion,.use chemical goggles. Protective Gloves: None required with normaJuse. , Other Protective Equipment: None required with nonnal use. . Other: None Boiling Point OF: N/ A Vapor Pressure (mm Hg): N/A Vapor Density (Air=l): N/A Odor Threshold: N/ A ~Wd~ *mmma:m:ijiDm~qwf~p~imf'~., - Specific Gravity (H:10=1): ca. I Percent Volatile by Volume (%): ca. I Evaporation Rate (nBuOAc=l): N/A Freezing Point: N/ A pH (1% solution): N/A Solubility in Water: Moderately Reserve Atkalinity: 1>1/ A Coeflicient of Water/Oil Distribntion: N/A Scooped Density: N/ A Appearance and Odor: Green powder, cedar pine or lemon -scent. ) 3 5-4 ) ) . ' ,~" ) COMET DISINFECTANT POWDER CLEAN~ER MSDS (Continued) Page 4 of5 Possjble Hazardous Reactions/Conditions: None known Date Received: Explosion Data - Sensitivity to Mechanical Impact: None Explosion Data - Sensitivity to Static Discharge: None JAN t t 2008 Conditions to A void: None Original Submittal Materials to Avoid: None Hazardous Decomposition Products: None known Other Recommendations: None - Calcium carbonate, an ingredient of this product, c.ontains small amounts of crystalline silica (quartz) as a naturally occurring impurity. Prolonged, excessively high expos~res to respirablc'crystalline silica may result in reduced lung function in some iridividuals. IARC has found sufficient evidence to c1as'sify crystalline silica as a carcinogen in animals, but there is limited evidence in humans. LDSO (rats oral): 9 g/kg ED50: 0.23 g/kg .) PRODUCT as a whole: CARCINOGENICITY: None Known I .' . SENSITIZATION EFFECTS: None Known REPRODUCTIVE EFFECTS: None Known SYNERGISTIC EFFECTS: None Known I ~o concerns at relevant environmental concentrations. 111' Waste Disposal Method: Product contains biodegradable surfactant. If permitted, flush small quantities down sewer drain with large excess of water or dispose of at landfill. DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. DOT Classification: Comet cleanser is not DOT hazardous, and is not regulated under the DOT Hazardous Material Regulations (49 CFR, parts 171-180) which govern the sale and transport 6fhazardous materials. I 4 ') ) ~ 5-~ " COMET DISINFECTANT POWDER CLE4-NSER MSD~.rContinued) Page 5 of5 All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA !i5. ! No components of Comet are subject to California Proposition 65. All ingredients are CEP A approved for import to Canada by Procter & Gamble'. This product has been ciassified with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required by the Canadian Products Regulation. . *N! A. - Not Applicable *N!K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained' herein has been compiled from sources consid~red by Procter & Gamble to be dependable and is accurate to the best of the Company's knowledge. The information relates to the specific material designated herein, and does' not relate, to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipie~t or third persons, for any damage to anypropeTty resulting from ~isuse of the controlled product. . ."':'" Date Received: JAN 1 1 2008 i ~, , Original Submittal 1 i 5 i. . Date Received: 12 john5on wax PROFESSIONAL JAN t t 2008 ) . ~mM ~lWit\l!lta SIJeet GP FORWARD GENERAL PURPOSE CLEANER Ii , . ,., '.'; ,- Health Reactivity Hazardous Material Information System (HMIS) National Fire Protection Association (NFP A) Fire Hazard Specific Hazard Protective Clothing ~~ ~~ Emergency Overview Clear Green. Liquid. See Section 9. DANGER. CORROSIVE. CAUSES EYE AND SKIN BURNS. HARMFUL OR FATAl.IF SVY~LlOWED. Product Name GP FORWARD GENERAL PURPOSE CLEANER Industrial/Institutional: Cleaning product. 114520008 'Code Product Use MSDS# PMS# 4518 432232 04/1912000 04/1912000 04112/2000. (800) 851-7145 - U.S. Headquarters Johnson Wax Professional 8310 16th Street. Sturtevant. Wisconsin 53177-0902 Phone: (888) 352-2249 MSOS Internet Address: ~.jwp.com Canadian Headquarters Johnson Wax Professional' 100 Matheson Blvd. East;Suite 203 Mississa'uga, Ontario L4Z2G7 Phone: (905) 755-0913 or (888) 746-5971 Validation Date Print Date Supersed'es 'n('ase of Emerp"enev , ~ ., _. ff~~Ifi1J~Ii!Stl!lJ!u,fJrtJ!!!Liflmil1liiffJJ.I'.j~'~I.'J.-IIlP~I. . Ingredients, CAS # I % by Weight . Exposure Limits. LC50ILD50 ~ Sodium Hydroxide 1310-n-2 1-5 CEil: 2 (mg/m') from OSHA Not available. (PEL) [United Statesl STEl: 2 (mg/m') from ACGIH (Tl it) [United States] Not available. Not available. Not available. Aikylphenoxy Polyethoxyethanol Sodium silicate Water 26027-38-3 1344-09-8 ,7732-18-5 1-5 1-5 .60-100 Not available. Not 8\iailable. Not applicable. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes .Corrosive..May cause permanent damage including blindness. Skin Corrosive. May cause permanent damage. Inhalation .May cause irritation and corrosive effects to nose, throat andT~s~iratory tract. Ingestion Corrosive. May cause bums to mouth, throat, and stomach. Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis. emphysema, etc., may - Aggravated by Overexposure: be more susceptible to irritating effects. See Toxicological Information (section 11) Eye Contact Immediately'f1ush eyes with running water for at least 15 minutes, ~eeping eyelids open. ,Get medical attention immediately. . Flu_shimmediately with plenty of wateE}or at !eas~ ~~~in~e.s.. ~:t~edi~~~ttention immediately. If breathing is difficult: Remove to fresh air. Get medical attention imme'diately. Do not induce vomiting! Immediately drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. II Skin Contact ~. Inhalation ,'lngeS'ion Cantinuedon Next Page II Page: 1/4 12-2 juh1l5unwax PROFESSIONAL GP FORWARD GENERAL PURPOSE CLEANER Material Safety Data Sheet Flammability of the Product Flash Points Products of Combustion _ Fire Fighting Media and'lnstructions Protective Clothing (Fire) Special Remarks on Fire and Explosion Hazards None known. Not available. ~one kpown. Extinguish 'with water spray or carbon djoxi~e, dry chemical. powder or appropriate foam. Normal fire fighting procedure may be used. Put on appropriate personal protective equjpm~nt (see Section 8). Corrosive material (See sections 8 and 10). Environmental Precautions and Clean~up Methods Put on appropriate personal'protective Section 8). In the event of major spillage: Use appropriate co~tainment to ,avoid environmental cOntamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by'-approved'methods. Use a water rinse for final clean-up. ' Handling Storage Avoid'contaCt with eyes, skin,; and clothing~.Do not taste or swallow. Avoid breathing vapors or spray . mists. Wash thoroughly, after handling. 'Remove and wash contaminated clothing and footwear before re-use. Product residue"may remain on/in empty containers.,AJI precautions for handling the product must. be used in handlinq the empty container and residue::FOR INDUSTRIAL USE ONLY. Store in a dry, cool and well-ventilated area. Protect from f~eezing. Ke~p container tightly closed. KEEP OUT OF REACH OF CHilDREN. -. Personal Protection Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not reQuired if !load ventilation is maintained. I ) j Eyes Chemical splash goggles. l!ands Chemical resistant gloves. Includes: Neoprene gloves. Respiratory If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over expos,:,re. A respiratory protection program that meets OSHA's 29 CFR 1910; 134 and ANSI Z88.2 requirements must be followed whenever workplace, conditions warrant'aTespirator'suse. Feet Protective footwear. Body If major exp'osure is P?ssible, wear suitable protective clothing an~ footwear. Physical State and Appearance Odor Color pH Specific Gr~vity Boiling/Condensation Point Melting/Freezing Point Solubility in water ) ConUnuedon Next Page liqUid. Mild. Citrus. Clear Green. 12.5 [Basic.] 1 lODoC (2120F) DOC (320F) Complete. Date Received: JAN t 1 2008 Original Submittal J- Page: 2/4 john5on wax . PROFESS/ONAL ') .."~4"\, . :I';:'~'t, '''':' , 12- GP FORWARD GENERAL PURPOSE CLEANER Material Safety Data'Sheet ,.,'. Stability and Reactivity Conditions,of Instabilitv Incompatibility with Various Substances Hazardous Decomposition Products _ Hazardous Polymerization The product is stable. None known. Reactive with oXidizing agents, acids. When exposed to fire: Produces normal products of combustion. Will not occur. Acute to%icity ORAL (LD50) . Estimated to be greater than 5000 mg/kg (rat), Effects of Chronic Exposure None known. Other Toxic Effects Not available. Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Disposr~ of accordinftto all federal, 'state ahd local regulations. ./ DOT Classification DOT Proper. Shipping Name DOT Class UNINA Packing Group TOG ' Classification TDG Proper Shipping Name TDG elas.!! PININIP Packing Group Corrosive liquid, basic, inorganic, n.o.s. Sodium hydroxide . Sodium silicate ) Class 8: Corrosive material j UN3266 J II Corrosive liquid, basic, inorganic, n.o.s. ( Sodium hydroxide ,Sodium silicate Class 8: Corrosive material UN3266 II Reporting in this section is based on, ingredients disClosed in Sectlon 2 us Regulations Date Received: Federal Clean Water Act (CWA) 311: Sodium Hydroxide CERCLA: Hazardous substances.: Sodium Hydroxide State New Jersey spill list: Sodium Hydroxide New Jersey: Sodium Hydroxide Massachusetts spill list: Sodium Hydroxide Massachusetts RTK: Sodium Hydroxide Pennsylvania RTK: Sodium Hydroxide This product is not subject to the reporting requirements under California's Proposition 65. JAN 1 t 2008 Original submittal Register~d Product Not applicable. Information , j Canadian Regulations Canadian"NPRI Canadian NPRI: Alkylphenoxy Polyethoxyethanol. Continued on Next Page . Page: 3/4 12-4' }ohn50n WiJX . PROFESSIONAL ': ',~' GP FORWARD GENERAL PURPOSE CLEANER Material Safety Data Sheet .~~ WHMJS Classification CLASS 0-28: Material causin'g other toxic effects (TOXjC). ,1 CLASS E: Corrosive liquid. WHMIS Icon (I)@ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the u.s. l'oxic Substances 'Control Act (TSCA) the-mical Substance Inventory. ., Version Nntil'P to Rp9dpr This document has been prepared using data from s~urces considered tech~;cal/Y reliable. it 'do'~s not constitute a warranty, express or implied, as to the accuracy of/he i,iforma/fon coh,ained within. Actual conditions of use and handling are beyond seller'sco",,/;o{ User is responsible to evaluate all available'information when using productfor any particular use and to comply with all Federal, State, P;o~incial and Loca/laws and regulations.. .. Date Received: . ) JAN , , 2008 original submittal ) ,., 16-: .m6lii.:":-". MATERI:t.L SAFETY DATA SHEET Page 10f4 ) PLEDGE AEROSOL. LEMON ''I' ; .:; ~._' MSDS # 110338037 Date Issued:OSFeb2002 Supersedes:03Febl999 US MANUFACTURER: S.C. Johnson & Son, Inc. Phone: (BOO) 725-6737 Racine, Wisconsin 53403-2236 Emergency Phone: (888) 779~7920 International Emergency Phone: (262) 886-1480 4-Very High 3-High 2-Moderate l-S1 ight a-Insignificant o Health 4 Flammabi 1 ity o Reactivity Special o 4 o CANADIAN MANUFACTURER: S.C. Johnson and Son, Limited Phone: ' (800) 725-6737 1 Webster Street 8rantford, Ontario N3T 5Rl Transportation Emergency: CANUTEC (collect) (613) 996-6666 Poison Control: (888) 779-7920 DISTRI8UTED IN CANADA BY: S.C, Johnson and Son, Limite>L . Phone: (800) 725-6737 uate Received: 1 Webster Street. 8rantford, Ontario N3T 5Rl HAZARD RATING HMIS HAZARD NFPA JAN t t 2008 -----.-..-----. SECTION 1- PRODUCT IDEl'innCATION -----------------.------Origiriiiisuomiftiir------------------ PRODUCT NAME..,.. _ . . . , , REASON FOR CHANGE...... PRODUCT USE, _ _ _ . . . . . . . _ PLEDGE@ AEROSOL - LEMON No significant changes. Furniture care UPC SCJ CODE QUA NT ITY ---------------------------- -------- 62300 00332 21009 12 ) 62300 00334 21010 12 62300 00329 329 12 19800 08399 329 12 46500 00338 329 12 US SIZE CANADIAN SIZE 200 GM 350'GM 500 GM 20 OZ 12.5oz ------------- SECTION 2 . INGREDIENT INFORMATION .----------._-.--------------.._____________~__________ INGREDIENT WEIGHT% EXPOSURE LIMIT/TOXICITY ------------------------------------ Sl1icones (CAS# 63148-62-9)...",......._,..". 3-7 Butane (CASH 106-97-8),............... _'. _.... 1-5 I sobut ane (CAS# 75-28-5).. _ _ _ . . . , " . . _ , . , , . . . . 1-5 Propane (CAS# 74-98-6)..".".".............. 1-5 NOT ESTABLISHED 800 ppm ACGIH/OSHA TWA NOT EST ABLI SHED 1000 ppm OSHA PEL , 2500 ppm ACGIH TWA NOT ESTABLISHED NOT EST ABLI SHED Isoparaffinic Hydrocarbon Solvent......~...... 5-10 (CASH 68920-06-9) Water (CASH 7732-18-5),.........."" _"""" 65-80 ---------.---.- SECTION 3 - HEALTH HAZARDS IDEl'i HJ'.lCATIO~ (Also See Section 11) . ROUTE(S) OF ENTRy...... Skin contact. Ingestion. EFFECTS OF ACUTE EXPOSURE: EyE....,....... _...., May cause: Sensation of irritation. SKIN..".........".. None known. INHALATION.,_......_. None known. INGESTION_.._........ Aspiration into the lungs may cause severe health effects. MEDICAL CONDITIONS_..., None known. GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE )-------------.- SECTION 4 - FIRST AID MEA' SURES -------.----------------....--------------.___._____ ' '-----------.--------- EYE CONTACT.........." Rinse with plenty of water. Page 20f4 ,PLEDGE AEROSOL. LEMON ) Date Issued:08Feb2002 '16-2 . MATER! .,~; ~AFETY DATA ~.Illi.ln 'Yk~:~: MSDS # 110338037 ',,", Date Received: Supersedes:03Feb1999 JAN t t 2008 ......-.......- SECTION 4. FIRST AID lWEASURES (continued) ............................................._............. . Original Submittal .sKIN CONTACT.... '_" ... INHALATION_,.. _........ INGESTION.. _. _...... _.. Wash contaminated area with water and soap:. Remove to fresh air, Immediately drink 1-2 glasses of water or milk_ Seek immedi.ate medical attention. SECTION 5.....Ilili AND .....ArLOSION INFORMATION .FLASH POINT............ FLAMMABLE LIMITS. ...,., AUTOIGNITION...... _ _... TEMPERATURE EXTINGUISHING MEDIA. .__ SPECIALFIREFIGHTING.. . PROCEDURES UNUSUAL FIRE AND....... EXPLOSIDN HAZARDS < 20M' (< -7^C) (TCC) (propel 1 ant) Not available. Not appl icable_ foam. C02. Dry chemical. Water fog, Fight fire from maximum distance or protected area. 'Cool and use caution when approaching or handling fire-exposed containers. Fire fighters should wear selfCcontained breathing apparatus and protective'clothing. . Aerosol product - Containers may rocket Or explode in heat of fire. ._-.. SECTION 6 . PREVENTIVE RELEASE lWEASURES .._...._.............................. STEPS TO BE TAKEN IN... Eliminate all ignition sources. Absorb with o11-dri or similar CASE MATERIAL IS inert material. Sweep or scrape up and containerize. Rinse ) RELEASED OR SPILLED affected area thoroughl y with water.. . . . . ,............-.... SECTION 7 . HANDLING AND STORAGE .-......_..._..........._....._......._.._._._._..._ ) PRECAUTIONARY.,._...... CAUTION: fLAMMABLE:, Contains: petroleum distillate. CONTENTS INfORMATION UNDER PRESSURE_ Do not use near open fire, 'flames or heat. Do not puncture or incinerate. Do not store at temperatures above 120 ^F (50 ^C): 00 not spray Or use on floors. Keep out of reach of ch11dren_ OTHER HANDLING AND..... Store in a COOl,' dry place with adequate ventilation. Keep from STORAGE CONDITIONS freezing. ...-...-..... SECTION 8. SPECIAL PROTECTION INFORMATION ......._................_........_....__._.._ RESPIRATORY PROTECTION. VENTILATION.. _,.. _.. _.. PROTECTIVE GLOVES...... EYE PROTECTION.,__..__. OTHER PROTECTIVE.. ..... MEASURES No speCial requirements under normal use conditions. No speCial requirements. No special requirements under normal' use conditions. No special requirements under normal use CO~d1t1ons. No special requirements. ............... SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES ..._.................................._........_ COLOR,...... _., _....... PRODUCT STATE.......... ODOR.....:............ . pH........... _..."..... ODOR THRESHOLD......... SOLUBILITY IN WATER.,.. SPECIFIC GRAVITy....... (H20=1) VAPOR DENSITY (AIR=1).. eVAPORATION RATE (BUTYL ) ACETATE=l) Opaque Dispensed as a spray mist. Lemon Not appl icable. Not ava 11 abl e. Oisperslble 0.B28 Not ava 11 abl e. Not ava11able. .. ) MATER, SAFEIT DATA SHEET .i,~~)lf; Page 3 of 4 MSDS # 110338037 16- ) PLEDGE AEROSOL-LEMON Date Issued:08Feb2002 ,', ,." Supersedes:03Febl999 --------------- SECTION 9 - PHYSICAL AND L.lllilvlICAL PROPERTIES (continued) _______________.__._. VAPOR PRESSURE (mm HG). Not available. Date Received: BOILING POINT.......... Not applicable. FREEZING POINT.......,. Not applicable. COEFFICIENT OF......... Not available. WA TER/OI L PERCENT VOLATILE By".. Not available. VOLUME (%) . VOLATILE ORGANIC....... COMPOUND (VOC) THEORETICAL VOC......... 1.44-1.46 lb/gal (LB/GAL) --------------- SEClION 10 - STABILITY AND REACTIVITY ---..--------______________"___________________.____..___. JAN t f 2008 Original Submitt"'l Hydrocarbon propellant Isoparaffinic Hydrocarbon, STABILITV...., ,.... ..,.. Stable STABILITY - CONDITIONS. Not applicable. TO AVOID INCOMPATIBILITy.... ,... No special requirements. HAZARDOUS DECOMPOSITION No special requirements. PRODUCTS HAZARDOUS...,...., ..... Will not occur, POLYMERIZATION HAZARDOUS.. . . . . . .. . .. .. Not app 1i cab Ie. POLYMERIZATION - . ) CONDITIONS TO AVOID . . . ' , ------------ SEClION 11. TOXICOLOGY INFORMATION (Also See Section 3) -._.___________.._____________ LD50 (ACUTE ORAL TOX),. LD50 (ACUTE DERMAL TOX) LC50 (ACUTE INHALATION, TOX) EFFECTS OF CHRONIC..... EXPOSURE SENSITIZATION.. ........ CARCINOGENICITy,...... . REPRODUCTIVE TOXICITY" TERATOGENICITy..... .... MUTAGENICITY..... ... ... Greater than 5000 mg/kg (rats) Not applicable. Not applicable. None known. None known. None known. None known. None known. None known. --------------- SEClION 12 . ECOLOGICAL INFORMATION --..------__________________._..__________ ENVIRONMENTAL DATA,. ... Not available, --------------- SECTION 13 - DISPOSAL CONSIDERATIONS -------.--._________._________________.______.______________.__ WASTE DISPOSAL.,. ..,... If possible. recycle empty aerosol can to nearest steel INFORMATION recycling center. Use up package or give to someone who can. -----.--------- SECTION 14 - TRANSPORTATION INFORMATION --._.__.___....____._._________________ US DOT INFORMATION..... BUffin~ or polishing compounds, N,O.I. Consumer commOdity. ORM-D CANADIAN SHIPPING NAME. PLEDGE AEROSOL - LEMON . ) '16~4' MATERII ,)AFETYDATA S.tlJ:UH' ,"""'.. ~" li,;,~.\Sj Page 4 of 4 fLEDGE AEROSOL. LEMON Date Issued:08Feb2002 MSDS # 110338037 ."' .~. ." Supersedes:03Febl999 I ....-..----.. SECI'ION 14. TRANSPORTATION INFORMATION (continued) ..gete-ReGe~\'eG;..... TDG CLASSIfICATION.".. Not applicable, PIN/NIP................. Not applicable. PACKING GROUP.......... Not appl icable. EXEMPTION NAME......... Consumer commodi ty 0" IS b 'tt I . nglna u ml a ......-....... SECI'ION 15 . REGULATORY INFORMATION ....-.............".............._............................ JAN I I 2008 WHMIS CLASSIfICATION... Non-regulated. All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. . All ingredients in this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). This product is not subject to the reporting requirements under California's Proposition 65. ............... SECI'ION 16. OTHER INFORMATION .-..........._....._...~......._..._."............_.... ADDITIONAL INfORMATION. NfPA 30B Levell Aerosol. EPA REGISTRATION #,..,. Not applicable. ..........-... PREPARATION INFORMATION ..-....-........ ------------------------------------- " )PREPARED BV.........,.. j Manufacturer's Technical Support Department. Refer to page 1 (ManUfacturer) for.contact information. . . 1 . ------------------------------~-------T---------------------------------- This document has been prepared using data from sources considered technlca.lly reI iable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual 'conditions of use and handling are beyond seller's control.. User is responsible to evaluate all available information when uSing:'produc:t for any particular use and to comply with all federal, State, Provincial and Local laws and regulations, " PRINT DATE: l1Sep2002 i ,I , 21-1 ,~.Yt":\ " ?'l~ johruion WilX PROFESSIONAL ) ,-.;",.':"'.. Material Safety Data Sheet SOFT CARE PINK HAND SOAP Fire Hazard Health ~ Reactivity Specific Hazard Protective None required. Emergency Pink. Liquid. See Se~ion 9. Clothing Overview CAUTION: May be mild.1y irrit~ting}o eyes. iIl~i;Tlbm~rGRWl!!1fii~'21!IIiftt!alfPl~'afjj~h~lriflfJfiil~!itf,3n.~'fJI!1~~"li~'~"'!i!'fIiif_.I!/;t!1j,!&7!j' ~~%il~Im1~~{(l,~lli~1ffil#!tli~ttt2~&~j;~~i%ji!1tai~.~I'~sJ.ftl~tIj\111\5di:lr;~~~#~)]&~%,.~ Produ~t Name SOFT CARE PINK HAND SOAP j'code 5639 Product Use Industrialllnstitutional: Personal care product. PMS# 443798 MSDS# 115640002 IValidatio~-Date . 2/2112001 National Fire Protection Association (NFP A) Haz'ardous Material Iufo'rmation System (HMIS) U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com. Calladi,an- Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746.5971 Print Date Supersedes 2121/2001 2/6/2001. (BUD) B51-/145 InC'an.of Fmerfi-encv Ingredients. CAS#' I % by Weight Exposure Limits LC50ILD50 ~\Ammonium Laureth Sulfate 67762-19-0 -1Il'Ammonium Laury! Sulfate 68081-96-9 I Water ' 7732-18-5 -'t!lfJs~tlr,'flf!i'~-'f{8tfnTJ[~. ~0,~!fut~!~'r:W'!L~~;itt10i6IW'FMii:dili ~ Routes of Entry Eye contact. Skin contact 1-5 1-5 60-100 Not available. Not available. Not available. Not available. Not available. Not Applicable. Potential Acute Health Effetts Eyes May be mildly irritating to eyes. -Skin ~rolonged or repeated contact may dry skin and calise irritatio~ _ Inhalation None known. Ingestion May cause abdominal discomfort, nausea,. vomiting and diarrhea. Medical Conditions Persons with pre-existing skin disorders may be more susceptable to irritating effeCts. Aggravated by Overexposure: J See Toxicological Information (section ll) lnhalation Flush"immediately with plenty of water. Get medical att~tion jf ir~tati(:m occurs. Rinse with plenty of running water. No specific first aid measures are required. Immediately drink plenty of water. If discomfort persists, get medical attention. Eye Contact Skin Contact , Ingestion Date Received: ) , r JAN t t 2008 j Original Submittal I Continued on Next Page' Page: 1/3 21-2 t.~{rt::.<' Material Safety Data Sheet john5on wax PROFESSIONAl. SOFT CARE PINK HAND SOAP ...t. : Flammability of the Product ~ Flash Points Products of Combustion . _ Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. None. None known. Extinguish with water spray or carbon dioxide. dry chemical powder or appropriate foam, Normal fire fighting procedure may be used. None known. Personal Precautions Environmental Precautions and Clean-up Methods Put on appropriate personal profective equipment (see Section 8). In the event of major spillage: Useappropriat~ containment to avoid environmental oontamina'tion. Sweep or scrape up material. Place in suitable clean. dry containers for disposal by approved methods. Use a water rinse for final clean-up. ----~.. Handling Storage Avoid contact with eyes. Use appropriate hygiene ,measures ~hen handling product FOR INDUSTRIAL' USE ONLY. Store in a dry. cool and well-ventilated area. Protect'trom freezing. KEEP OUT OF REACH OF CHILDREN. Engineering Controls Personal Protection No specii:1I ventilation requirements. General room ventilation is adequate. Eyes No special requirements under normal use conditions. Hands No special requirements under nonnal use conditions. Respiratory No special requirements, under normal use conditions. Feel No special r;quirementsuri'i:ter normal use conditions. Body No special p~otective clothing is required. " \ I " Physical State and Appearance Odor Color pH Specific Gravity Boiling/Condensation'Point MeltinglFreezing Point Viscosity Solubility in water Liquid. Mild. Pink. 6.8 to R95 [Neutral.] 1.0 >93'C (199.4'F) <O'C (3Z'F) Z000-4000 cps Complete. Date Received: JAN t I. 2008 Original SiJbmillai Stability and Reactivity The product is stable. Conditions of Instability None known. Incompatibility with Various None known. Substances Hazardous Decomposition When exposed to fire: Produces normal products of combustion. _Products :fazardous Polymerization Will not occur. Continued on. Next Page Page; 213 , rt~.\~~ 21-3 johll!ion WilX PROFESS/ONAL SOFTCARE PINK HAND SOAP Material Safety D~ta Sheet Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). DERMAL (LD50) Estimated to be greater than 2000 mg/kg (rabbit). None known. None known. Effects of Chronic Exposure Other Toxic Effects Waste Information No special precautions. Dispose of according to all federal, state and local regulations. DOT Classification Not regulated TDG Classification Not regulated Reporting in this section is based on ingredients disclosed in Section 2 us Regulations -\ ) This product is 'not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Oassification Not applicable. WHMIS Icon Registered Product Not applicable. Information Chemical Inventory Status All Ingredients of this product are listed or are excluded from listing on the u.s. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. . Other Special Considerations Not available. Version 1.02 Nntil'P tn Rplllk,r This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.' Date Received: , ) JAN t ,1 2008 Original,SUbmiital " 'L~:... ~\""No~~ S~e.L C~~ 22-1 ') MATERIAL SAFETY DATA SHEET This MSDS cOmplies with OSHA'S Hazard Comr1]~~icalion_~ta~c!a!!l,~9" CER 1910.1200 a_n.~QSHA Form ',174 . . IDENTITY AND DI:> I RIBU:I,l!~:>.INrURMA:I'IO_N . __ _ _ Flammabilitt~2; ReadlVlty-O; ~pec'al.() e-!".!!~ ~all",a.: _ '"!.~altn-~;, HammaOI~tt-~; Reactivity-O: Personal Protection-B UNI.SOURCE WORLDWIDE, INc.;. fUU I Hazard (;Iassltication: UK,M-D 6600 Governors Lake Pkwy. Identity (trade name as used on label): . Norcross. GA 30071 ___ _ __ ' ALLSTAR SATIN lU175301 IPhone: BOO-UNISOURCE J~'!U~ Numb~r:._p'QO~~l Revision-13 I IEMERGENCY RESPONSE N.UMBER: 1-888-660-6737 ale r-reparea. Ubl'IL/UJ Prepared By: LFIIB I !NOTICE: JUDGMENT BASED ON INDIRECT TEST DATA ,nlormationCalls: m0)422-2071 " I ' _, SECTI9N 1 -1!I~TERIALluj;NTlFICATION ANu iNj:'UKM!'T!ON _ . " I ICOMPONENTS:-CHEMICAl NAME:> ANU COMMUN riAMt:S CAS Nurn~~" '::iAKA' USHA PE:L A{,;GIH I Carcinogen I kt'azardous Com~onents 1% or Qrea!er. Carcinogens 0.1% or greater) III LIST {ppml TlV (ppm) Ref. Source ,U I PETROLEUM DISTILLATE ~J.'!.:i-_04~5 I Yes /5m9\M3 1 5m9\M3 d I PETROLEUM PISTILLATE O~~L5'=j I No I 100 100 I d I rSOBUTANE I PROPANE BLEND !.a-~!,-~ ' J N.<> J 800 "I 800 I d I I4-Htl-O I No I 1000 "I 1000 I d I I I, L " I I SECTION 2 - PHYSICAUCHEMI0AL CHARACTERISTICS /Bolllnq Point: N/A r;.eeclfic Gravity jH20=1): Concentrate Only = .856 !Vapor Pressure: PSIG (ii) 70GF (Aerosols): Max:60 l!apot_Pressure {Non-Aerosols)(mm Hg and Temperature): N/A rVaporDensi!y (Air = 1): NlE E~apor.atlon.Rate ! = 1l: NlE I ~olubllltv In Water: Insoluble -. ,Waler Keacbve: No ~DDearance and Odor. Clear liQuid. lemon fraQrance. i SECTION 3. FIRE AND EXPL<jSIO!l HALkRD DATA ~LAMMABILlTY as per USA FLAME PROJECTION TEST I Auto 'gMlon lemperalure flammability Limi~. inAJr by % in Volume: aerosols) FLAMMABLE >lBlnches 'NIE tYo LEL: NIE % UEL: N/E .' LASH POINT AND METHOD USED (non-aerosols): N/A IEXTINGui:;H~. H -M~.:IIA: ~oam. dry chemical, carbon dioxIde. PECIAL fiRE FIGHTING PROCEDURES: Self-contained breathing apparalus. I _. . _ _ _ lUnusual Fire & Explosion Hazards: Do not expose aerosols to lemp~ratures above 1:30'"1"' _O!,,~ contamer may rupture. I 'SECTION 4 . REACTIVITY HJl.;ARD DATA rTABILITY [X J STABLE [ ] UNSTABLE jHAZAADOUS POLYMERIZATION [ ] WILL [X] WILL NOT ., ' . !OCCUR ,ncom[>3tibilitv (Mat. to avoid): Slrong oxidizers. ,conditions to Avoid: Open flame. welding arcs. heat. sparks. lHazardous.Decompositlon Products: CO. C02. . I SECTION 5. HEALTH HAZkRD DATA I PRIMARY ROUTES OF ENTRY: ! X] INHALATION, I IINGESTIUN r,( i i;K'N Asi;oRPTION !ACUTE EFFECTS ' nnhalatl?n: E){~ssive inhalation of vapors can be harmful and may cause headache, dizzinf3ss, asphyxia, anesthetl~ effects and possible UnconsCIousness. ~ve Contact: Mild irritation.. . . /Skin Contact: Mild Irritation due to defatiing of the skin. b-ngestlon:-. Possible chemical pneumonitis if aspirated into lungs. Nausea. , )CHRONIC EFFECTS: (Effects due to excessive exposure to the raw. materials of this mixture) May cause cardiac abnormality, liver ~bnormallties. luno and kidney damaoe. ' , lMedical Conditions Generallv AgQravated bv Exposure: May aggravate existing eye. skin. or upper respiratory conditions. ( , . EMERGENCY FIRST AID PROCEDURES , lEye Contact: Flush with water for 15 minutes. If Irritated. seek meaical attention. !skin Contact: Wash with soaD and water. If Irritated. seek medical attention. IInhalation: Remove to fresh air. Resuscitate if necessalV. Get medical attention. !Ingestion: DO NOT INDUCE VOMITING. Drink two larae plasses afwater. Get immediate medical attention. , SECTION 6 - CONTROL AND PROTECTIVE MEASURES I[tespiratory Protection (specify typel: If vapor concentration exceeds TLV. use respirator approved by NIOSH for or}lanic vapor. IPr~ective~loves: Pol'{ethv]ene !Iloves . IEye Protection: Safety olasses recommended. (ventilation Reauirements: Adeauate ventilation to keep vapor concentration below TLV. . IOther Protective ClothinQ & EQuipment: Eyewash station if desired. . . lH~ienic Work Practices: Wash with soa.2. and water before handli".9. t~~. !'lem~~~_contamlnated clothino. I SECTION 7 -PRECAUTIONS FOF< SAFE HANULlNG AND USE /Steps To Be Taken If Material Is Spilled Or Released: Absorb with suitable mec.;'um. Incinerate or landfill according to local, state or IFederal requlations. DO NOT FLUSH TO SEWER. ' lWaste Dlsposai Methods: Aerosol cans when vented to atmosoheric pressure throuQh normal u~~. pose no disposal hazard. . /Pre&Jutions To Bp: T~~en In Handling & S~,?r,~,8~: ':?r: not puncture or incinerate containers. Do not store'at temperatures above 130oF. /Other Precauti~ns. &lor Special Hazards: KEEP OUT OF REACH OF CHILDREN. Avoid food contamination. Avoid breathing ~apors.Remove IQmbon sources. . . '.. We believe the statemen.ts, technica' information and recommendations contained he.rein are reliable. but they are given without warranty o~tee of a'll{ Ipnd. .. Chemical listed as Carcinogen or potential Carcinogen. [aJ NTP (b) IARC Monograph [c] OSHA [d] Nol U~t~te-II elveU. I INFPA RatinCl: Health-2: l~al1ufactured For: rddress: ) ! ] EYE! J NOT HAZARDOUS j I J j j J ) / JAN 1 1 2008 Original Submittal " .;~~' 23-1 johll!ion wax ') PROFESSIONAL Material Safety Data Sheet STRIDE CITRUS National Fire Protection Association (NFP A) Fire Haiard ~ Health ~ Reaetivity Hazardons Material Information System (HMIS) Specific Hazard Protective None required. Clothing Emergency Overview Orange. ,liquid. See Section 9. CAUTION: May be mildly irritating'.to eyes.. May be mildly irritating to skin. Product Use STRIDE CITRUS Code _Industrial/Institutional: Cleaning product. This product is intended PMS# to be diluted prior to:use. 113905004 Validation Date 3904 445761 Product Name U.s. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant. Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: WNW.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East. Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888)746-5971' Print Date. I Supersedes hi Case of 'Rmerpencv 4/12/2001 4/1212001 4/1212001. " MSDS# (euo) e51-f145 ''',. J Ingredients % by Weight Exposure Limits LCSO/LDSO ORAL (LD50): Acute: 1378 mglkg [Rat). DERMAL (LD50): Acute:. >2000 mg/kg [Rabbit]. Not applicable. -7 Alcohoi Ethoxylates 68439-46-3 1-5 Not available. Water 7732-18-5 60-100 Not available. Routes of Entry Eye contact. Skin contact Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly irritating to skin. Inhalation None.known. Ingestion None known. Medical Conditions None known. Aggravated'by Overexposure: See Toxicological Information (section 11) Ingestion Flush immediately with plenty of water. Get medictll a!te~!ion !f irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. No specifiC first aid measures are required. Date Received: Eye Contact Skin Contact - Inhalation ) JAN t t 2008 Original Submittal Continued on Next Page Page: 113 23-2. '~,~\~~. Material Safety Oa~a Sheet Johnson wax PROFESSIONAL STRIDE CITRUS . .. , "" ~ Flammability or the Product ~ Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None:'known. None~ Non~-known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam'; Normal fire fighting procedure may be used. None;known. _, S"''',""L''-6''!''''''''''''~_''-''ir.R'-if'''-:1!i''--~'''.'_''''''~''-IIiIIIi!P'PBll1' '..'!.'''_'''''''Y''''~_'~' '1{J;l!l!II' '!~_?iI!'-.' "''''''Iii, -Il\t;q;;~: eCu01J2 iii'ktC(Uue,al;ied3ase"lIIIeaSllr~~~''f1'" -'.,. ,- 'i',' 0',;': :Jr'B-"'" ";'?iI!*'+,i",j., ,.",,<~%m-"', "l~: r '0;'~Y 0,&'" Ill: ,f: tl'V::JcZ.l.,""-"'4l,"1=t'i4d""";,.cw"..= . ."",,,",,,,~'f_"'ii'k~~",,,",,~!0"''''''='~';:rs:' .C''" ",' ".c;" " ",~. ' ,j)ffi .m" ,- .'-""~ ',' Wi .,^..-' , ;, j' ." ." j', i""'*#7;Jl",__.~,.._~~_~w . '" =",=,,,,_,,,,,,,,,,,,,,,,~-=;t#_=,~ ,..,,,,,. ,. m ' '",^-". , '_"m ' . '~"'_ -~....., Yif/;, .~,_ ."',~, ,~... .... . . ~,i . . Putan appropriate personal protective equipment'{see Section B.).. ' hi theeyent of major spillage: Use appropriate COfl~ainme~t to avoid environmental cont.amin~tion. Sweep or scrape up material. Place in suitable dean, dry containers for disposal by approved met~ods. Use a water rinse for final clean-up. ' Personal Precautions Environmental Precautions ~ and Clean-up Methods i Handling Storage Avoid contact with skin,md eyes. FOR INDUSTRIAL USE ONLY. Store in a dry, cool and well-ventilated, area. Protect from freezing. KEEP OUT OF R-EACH OF CHILDREN. . Eyes.!'JO special requirements under no,:"al use conditions. Hands No special requirements under normal use conditions. Respiratory No special requirements under normal use conditions. Feet No ;special requirements under normal use conditions. Body No special protective clothing is required. I Engineering Controls Personal Protection ) No special ventilation requirements. General room ventilation is__~dequate. '- -~(~'t:Il11i?b~Cil~~~l6h~~'S71Rrq~liF~I~~:r~~~'IIll~~, . !If&~$'!f _ ,~i]t;i~,~~~,i$~~~~~~~:i,,~~~~~ThII~[~yg%d Physical State' and Liquid, Appearance Odor Color pH Specific Gravity Boiling/Condensation Point MeltingIFreezing Point Solubility in water Citrus. Orange. 7.2 to 7.8 [Basic.l 1.0 100"C (212"F) O"C (32"F) Complete; Stability and Reactivity The product is stable. Conditions of Instability None known. Incompatibility with Various None known. Substances . Hazardous Decomposition . Products , Hazardous Polymerization ) When exposed to fire: Produces normal products of combustion. Date Receivec : Will not occur. jAN I t D08-- Original Sub!'Y1iltal Continued on Next Page" Page: 2/3 .~~~~. 23-3 joh1l5on lUilX PROFESSIONAL Material Safety Data Sheet STRIDE CITRUS. ~ Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Effects of Chronic Exposure None known. Other Toxic Effects None known. DOT Classification Not regulated TDG Classification Not regulated Reporting in this section is based on ingredients disclosed in Section 2 US Regulations ) This productis not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not controlled under WHMIS (Canada). WHMIS Icon Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. ~7PtiO'~:6!l;Qtli~'ft1li'ffl}!iljW:tiaQ'~"\'$lij!I1<:~~~~~f~~~lI11i~'~l'lj.j-~'~'ll!;"f;;~J ~4;'0k'9f@';*"^~\:tiU~';0Sjfa&'m;W0:nM1~f;I!~%Jfw~rII~~~1l~'{~iRlli't~~-,~r~~~~~~;:~~~ Other Special Not ayailable. I - Consideratio"ns Version 1.01 Nnti("f' to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warra~ty, express or implied, . as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL User is responsible to _ evaluate all available information when using productfor any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Date Received: ) .J JAN t t 2008 Original submittal_ 25-1 l/\'.~4... Date Received: john!ion WiD( PROFESSIONAL ) Material safeJ~A !JqQ8 TRIAD II DISINFECTANT CLEANER>riginaISubmittF' National Fire Protection Association (NFP A) Fire Hazard ~ Healtb ~ Reactivity Hazardons Material Information System (HMIS) Specific Hazard Emergency Overview Clear Green. Liquid. See Section 9. DANGER. CORROSIVE. CAUSES EYE AND,SKIN BURNS. HARMFUL IF SWALLOWED. ' , j Product Name Product Use MSDS# TRIAD \I DISINFECTANT CLEANER Industrial/Institutional: Disinfectant. This product is intended to be diluted prior to use. 113962001 Code 3963 441031 PMS# Validation Date 2/21200 I 2/212001 N~ Previous :Validation. u.s. Headqu"arters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com Canadian Headquarters Johnson Wax Professional '100'Matheson Blvd. East. Suite 203 Mlssissauga, Ontario L4Z 2G7 . Phone: (905) 755-0913 or (888) 746-5971 .. ' Print Date Supersed.es Tn Cll~e n~ Emerl'encv (tlOO) tl51-1145 J Ingredients n-Alkyl Dimethyl Benzyl Ammonium 68424-85-1 1.52 Chloride Di,N-Alkyl Dimethyl Ammonium 68424-95-3 2.28 . Chloride Not available. LC50tiDSO ORAL (LD50): Acute: 426 mglkg [Rat]. ' Not available. Not available. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes Corrosive. May cause'permanent damage including blindness. Skin Corrosive. May cause permanent damage. Inhalation May cause irritation and corrosive effects to r:Jose.throat and_re~Eir~tory tract. Ingestion Corrosive. May cause burns to mouth, throat, and stomach. Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may Aggravated by Overexposure: be more susceptible to irritating effects. See Toxicological Information (section 11) :'I~~h:fij~BPSt~j!jiM'e"a~e~~~I~YI-4l'~~&~~~W4l'-\F'!It~' :!iM'''.IW1~_J.f''#_0~,,1ThW~iliIW~'';fub'%iTjig>,,<*&itJ'IWi#_.JFi\\~~i ,"~..,j~\;ll",u_ ,. ~";4fw~~\jjj~~~j1Ja~~ Eye Contact Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention immediately. Flush immediately with plenty of water for at least 15 min~tes--=- Get_ medical attention immediately. If breathing is difficult: Remove to fresh air. Get medical attention immediately. Do not induce vomiting! Drink milk. egg white or gelatin solution. If these are not available, drink large quantities of water. Never give anything by mouth to an unconscious person~ Get medical attention immediately. Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsion may be needed. - Skin Contact _ Inhalation , : Ingestion , i 'j Notes to Physician Contiiwed on Next Page' Page: 114 25-2 Date Received: '':N:','rj ~~. Malerial safetJAN 4etl2008 ,. 'I john5on WilX PROFESSIONAL TRIAD II DISINFECTANT. CLEANER ,." Flammability of the Prod~ct Flash Points l Products of Combustion' Fire Fighting Media and Instructio'ns Protective Clothing (Fire) _ Special Remarks on Fire and _ Explosion Hazards Personal Precautions Environmental Precautions and Clean-up Methods \ None known. None known. None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. . Put on appropriate personal protective equipment (see Section 8). Corrosive material (See sectionsB and 10). Pulan appropriate personal protective equipment (see Section 8). In the event of major spillage: Use appropriate containment to avoid environmental cOntamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a wa~er rinse for final clean-up. Handling . Storage . ~ngineering Controls ) Personal Protection Avoid cOfltact with eyes, skin, and clothing. Do not taste or swallow. Avoid breat~,ing vapors or spray mists. Wash thoroughly after handling. Remove and wash contG!minated clothing and footwear before re-use. Product residue may remain'on/in empty c6ritainers. All precautions for handling the product must be used in handlinQ the empty container and residue. FOR INDUSTRIAL USE ONLY!' ' 'S16n~~'iri"a'dry;'cool and well-ventilated area. Protect.from freezing. Keep container ~ightly closed., KEEP OUT OF REACH OF CHilDREN.' . 'u.... . Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not reauired if Qood ventilation is maintained. ( ) Eyes Chemical splash goggles. Face shield. Hands Chemical resistant gloves. Includes: Rubber gloves. Neoprene gloves. Respiratory If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection progra~ that meets OSHA's 29 CFR 1910.134 and ANSI ZBB.2 reauirements must be followed whenever workplace conditions warrant a respirator's'use. Feet No special requirements under normal use conditions. Bo.dy If major exposure is possible, wear suitable protective c1othi,ng and footwear. Physical State and Appearance Odor -Color pH Specific Gravity MeltingfFreezing Point Vapor Pressure Solubility in water ) Minty. Clear Green. 13 [Basic.l 1.0 O"C (32"F) 17 mm of Hg Complete. Continued on Next Page' Page: 2/4 Date Received: ~t; ,~~.;: JAN t I 2008 25-3 ~\ john!ion WilX PR.OFESSIONAL TRIAD JrDISINFECTANT CLEANER MateriM>~&mmittal :: Stability and Reactivity Conditions of Instabilitv The product is stable. None known. . Incompatibility withyarious Avoid mixing with: acids Substances Hazardous Decomposition When exposed to fire: Produces normal products of combustion. Products Hazardous Polymerization Will not occur. Acute toxicity Corrosive. Effects of Chronic Exposure None known. Other Toxic Effects None known. PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Locai'/Municipal ordinances regarding disposal of pesticide wastes. Waste Information DOT Classification , I ,~ DOT Proper Shipping Name DOT Class Corrosive liquid, basic, organic, n.D.S. ( Quaternary ammonium coumpond. ,Tetrasodium ~alt of EDTA ) Class 8: Corrosive material UNINA Packing Group DOT Special Considerations UN3267 III Limited Quantity TDG Classification TDG Class PININIP TDG Special Considerati{)ns Reporting in this section is based on ingredients disclosed in Section 2 US Regulations Federal CERCLA: Hazardous substances.: Ethyl Alcohol State New Jersey: Ethyl Alcohol Massachusetts spi1llist: Ethyl Alcohol Massachusetts RTK: Ethyl Alcohol Pennsylvania RTK: Ethyl Alcohol This prodUct is not subject to the reporting requirements under California's Proposition 65. Registered Product EPA Registration Number: 6836-73-70627 Information ....icanadian Regulations I Canadian NPRl Not applicable. WHMIS Classification Not applicable. WHMlS ICon. Continued on Next Page Page: 314 Date Received: 25-4 ~~:>':J.~'~, JAN t 1 2008 john'!ion WilX PROFeSSIONAL TRIAD II DISINFECTANr CLEANER Material Safety Oa'ta Sheet Original Submittal' , " ~) Registered Product Not' applicable:' Information All Ingredients ofthis product are listed or are excluded from listing on the U.S. Toxic Substahces Control Act (TSCA) Chemical Substance Inventory. Chemical Inventory Status Other Special Consideration,s Not available. Version Nntil'P to Rel'lder This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy afthe information conta;~ed within. Actual conditions o/use and Iland/ing are beyond seller's control. User is responsible to evaluate all available information 'when using product for any particular use and to comply with all Federal, State, Provincial and 'Locollaws and regulations.' -. . - . .. ) ) ) johH!iOn WilX PROFESSIONAL ~!!~l!__ IF-ire Haz_,!~d 1ReactiVitv HMIS L_L' I 0 I 0 .,;i,-;~, Date Received: 29-1 JAN t t 2008 , MATERIAL s:A.FETY,'_DATP.. S,HEET Orjgma S'ubniitta GLANCE SC (SUPER CONCENTRATE) JI NFPA _ /I Personal protective equipment JI-r-....J ..-....:.;..,..........._.,. II 0 1. q;;,~,t'" II 0 I .""':" Version Number: 1 Prep?Jration date: 2006-0~15 1lW~~~\\1l'lt~!%&-'{~1i'-f~t~egl\\l.m:I1J~j1;<~I'JI:)1.e:0I'VJt!~tilff#r~E:Nim.l5m~J'(~1iIlit"A~~~~~~~4~~11 Product name: MSDS #: Product code: Recommended use: Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th 51. Sturtevant. Wisconsin 531 77-0902 Phone: 1-888-352-2249 MSDS Internet Adaress: www.johnsondiversey.com . Emergency telephone number: GlANCE SC (SUPER CONCENTRATE) 114700004 114700X.114700004.04701,04305.Q4159 Creanin_9 product. This product is intended'to be diluted prior to US~. ( Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle OakviJIe, Ontario L6H 6P1 Phon~: 1-800-668.3131 1-800-851-7145 (Prosarl: 1-651-917-6133 (Inl'iProsar); 01-800-710-3400 (lyIexico)" '"",-,.m"'"""""'~""""~~"^-"'-",''''''''''-'''''''''''''''''A;'''''",B'''S''''''''''''''I''J'h;'''''''H""'_~__""'"'~-;W_~~"__i'-""'l f!'~.w~4iiwio~.ffi1t~'""r~ '~~~..@;'1it~~~~'l>~~'l:;l~~\xL!!,,~~u;"~J)lIIn8,J~'~'~tru.l.:!~I~;"'~f"~~~~_~i'~~~ ~MERGENCY OVERVIEW . 'OANGER. CORROSIVE. CAUSES SKIN AND EYE BURNS, HARMFUl. OR FATAL IF SWALLOWED. .' i ....Principle routes of exposure: Eye contact: Skin contact: Inhalation: Ingestion: ~~"'-~Jl<'l(!ll\llg\;tSliJilr,Jr;rlIN~RMA'ili[!l!:~~)3'!~:elli!)i!ili~'-~jjj HAZARDOUS COMPONENTS I Ingredient(s) Sodium lau!y1 sulfate I Ammonium hydroxide I 2-butoxyethanol Eye contact. Skin contact. Inhalation. Corrosive. Causes permanent eye damage, including blindness. Corrosive. Causes permanent damage. May cause irritation'and'corrosive effects to nose, throat and respiratory tract. ,'Corrosive. Causes'bums to mouth, throat and stomach. . ~ CAS # Weight % LOSO Oral - Rat LOSO Dennal . Rabbit Not available Not available = 220 mglkg ILeso Inhalation. Ra, I > 3900 mo/m' (1h) I I Not available I .,= 221 mgll. (4h) I = 450 ppm (4h) 151-21-3 1336-21-6 111'76-2 1-5% 1-5% 20 - 30% = 1288 mg/kg = 350 mglk.9 = 470 mg/kg Eye contact: ~~~~;l;_ffi<~~~~"'~\mIg:Sif~IDIM6~(:i'r:gl;:'sgg;i1~' c. ';'~J Skin contact: Inhalation: Ingestion: Aggravated Med~cal Conditions: Immediately flush eyes with running water for at least 15-20 minutes, keeping eyelids open. Get medical attention immediately. Flush immediately with plenty of water for at least 15-20 minutes. Get medical attention immediately. If breathing is:affected, remove to fresh air. Get medical attention immediately. , If swallowed, give a cupful of water or milk. THEN IMMEDIATELY CONTACT 'A PHYSICIAN OR POISON CENTER. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious pe'rson. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be more susceptible to irritating effects. . . ~1~~'\lt~~m~~&r~~~511lF.!B.E:2r;;tG..f;JJ1UlilG'!ME~~:llJ8ES~i~~:r;;~~~1l1~!);~~t~~J Suitable extingUiShing media: Specific hazards: "'1usual hazards: \cific methods: j GLANCE SC (SUPER CONCENTRATE) nie product is'not flammable. Extinguish fire using agent suitable for sur~ounding fire None known. Corrosive material (See sections 8 ana 10). No special methods required 10f4 Date Received: 29-2 . . . . - . .... ..-.. ..~~ . 1.&j~:;f:agJEft\\t~~~,~i,(jWAWJ€~1~t[f~~1~~.m~~S'tEIRE,~GJGRr/NGi'MEASllRES~t~~}~~~~ii1fu~!Z~ib~~~~1i~iil~~ik~?t~M~liU\]tr~mt~I Sp~ciar'prote.ctjve e.qui~~ent for firefighters: As in any fire, wear self.conlained breathing apparatus pressure-de!'1<!nd, MSHAlNJqSH \apprOVed or , eqUivalent) and full profecllve gear' Onglnal Submltta ) Extinguishing media which must.not be.used for safety reasons: No information available "l;':;:'l.~;:. , Fi~~-fu;~~m~~~};~~1'Wi.b-1;tij,,~~~6WP;G:G,I]D-EN1A~gE12E~SE:*MEAS.oRE:~~~i;1t~;~~f,t~~~~\~~~~~'fi~~~;1 Personal precautions: Environmental precautions and clean~'up methods: Put on appropriate personal protective equipment (see Section 6.). Absorb spili with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final cl~a.n.up. 1~ll:\,~m='~'-""'~j;;,"'''''!f'''''''J>''''''*'''''ill';'''!)'I'_''l~""U'^''''''''''I.''''''''A''ND"S.;o;13"""'G'.. .E..J""",'''\~'''''''!ff'!'''l"(~~'''''''''''''''''''~'1''"\<-''''~1 If!'?'<f~""t""~*-4j1[,~~3j~:r,.,,,,-,,,;;'~~:@,~J-~;lSJ.!tlt,,.,.~~~Lj'f":a:.'.'t8~t".L:I'.L:; ,l..P,l~, __.. ...', .~IL ,O;,tj.,.. ,,,""&_~.r:...~'-\!;-~ziit'fW..J!l'i!,,,~~'<ffif'..;U~h."~3tG~'S(i~'1f,1:~ Handling: Avoid contact with skin, eyes and clothing. Do not taste'or swallow. Avoid breathing vapors or mists. Use only with adeqLfate ventil~tjon. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product res.,idue may remain onlin empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.. Storage: ' Protect from freezing. Keep tightly dosed in a dry, cool and well.ventilated place. KEEP OUT OF THE REACH OF CHILDREN.. . . I~"~'__""""__"""~_""""""'l;'" ~E'X" " " ." "d' '" 'S~'l''''''cS'''N- ""R"''''''''''"''I'''N' ""''''''''''''''_<c'''~''''''j'''''''_~'~_1 EMKkI~llm;i:'~.f\lPlm~!i~ilW~~~~~,a;~ 2,"'m-,e~S.WI:\E~y:e.Nmg~^g.~, j{r:;Jt:.:n~~~,~u~e .\lI)..tI;,~(lt.~, ~;id_~~~.Jk,",.:i'l~~i;f,JI,;m~;r;~'Nt.$.~1i~~€~ Engineering measures to reduce, exposure: , Good general ventilation should be "sufficient ~o control airborne re~els., Respiratory protectjonis not required if good ventilation is maintained.. Pp.ffional Proter.:tive Eauiilment Eye protection: Hand protection: Skin'and body protection: Respjrato.ry pro~ectlon: Chemical splash goggles. Chemical 'resistant gloves Protectivefootwear../f major exposure is possible, wear suitable protective c;lolhing and footwear. In case of insufficient ventilation wear suitable respiratory equipment. A respiratory protection program that 'f'heets" OSHA's "29 CFR .191 0.1'34 arid 'ANSI Z88.2 'requirements must be followed whenever wor~place conditions warrant a respirator's use.. Ha~clle in acCordance wlth'good Industrial hygiene and safety.practlce Hygiene measures:' , ) -"" Physical State: pH: Appearance: Color: Odor: Specific gravity: Density: VOC: Flash point: Solubility: Viscosity: InQredientlsl 2-butoxyethanol ACGIH 20 ppm [TWA) . OSHA Skin 240 mg/m' (TWA) SO ppm [TWA) CAS # 11.1-76-2 Mexico 75 ppm (STEL) 360 mg/m' (STEl) 120 mg/m' [TWA) 26 Dpm (TWA) , ....n~9.lmIi{Ii!SJWhim'A'NfilIe;fi!6MI~~'I!iI8Iif<1l.~g~itlil$"',dt~~~_jt~l!l ',;". "i,i" Liquid 11.5 Aqueous solution Blue Ammoniacal' 0.995 8.3 Ibslgal 20.0% . >200 (OF) >93.3 ("C) Soluble No information available Bulk density: No information available Dilutio'n pH: No information available: Vapor density: No inform"ation available Evaporation Rate No info!lTlation available Bolling point/ra'nge: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Partition c"oefficient (n-octanoUwater): No information available Solubility in other solvents: No information available Elemental Phosphorous: 0 %P . - Title 17,.California Code of Regulations. Divisio~ 3, Chapter 1, Subchapter 8..5, Article 2, Consumer Products, Sections 94508 1l!>.~_~'&_,~.,'~~~~t:~:OlliSjIfhiBJ.If/ffi)';1b:'N9mE1.\':€ktl\lI~.~",~IJ1!M~>1~~i'.:&'iil!lll\~lf~~~~1 Stability: Polymerization: Hazardous decomposition products: Materials to avoid: Conditions to ayoid: The product is stable.. Hazardo!Js polymerization does not occur.. None reas'onably foreseeable. Strong oxidising agents. Do not mix with any other. product or chemical. Do not freeze. IJ~~~"i!W!~~4~:~ilili\ll,:t;;;;r'0XJe:0I1EfGi~A'Il~rNfi0~M~iI:I(;jN~~y,'\li;~'~-~'1!i<"'''''".~J ~ ,. ,., "'.""""~.. - ,,_.,...'"'1.. ....'. .',~ "t.. ,.. ,~,........,,",.,._., '_,._',... ,.--,_~,.,_..",..'.."_"''''''',..'^'k.",~". ."-......,'-...,. ", .'. .. ,t. ,'>,~1i..~1f"""",~!M'i_~.;H(\,;' Acute toxicity ')mponent Information: / Oral LOSO estimated to be between 500 - 5000 mg/kg See Section 3 GLANCE SC (SUPER CONCENTRATE) 2 of 4 '~~'t;:P",,-' 29-3 , ~~4~~1t~ii~~fii.~j~~"~~~~~~~i.':ijf~~iM~1\'tl[OXlc.'orrQ_G_ICA'I~tIN'Fit}RMA'I!(;),'~'lt~~Ml!~t~~~!~~?t'~4~~~~1tf!?t~~~tr.01 Chronic toxicity: None known Uate KeCelVea: -J ,S.nedfic effects Ca'rcinogenic effects: Mutagenic effects: R.eproductive toxicity: Target organ effects: Original Submittal l'IJr~""'~~"'_r~I'!"'\)"'~tiWJ,l!ill~"",,".'2''''E'>''''''''G'I'''''''',WrN. ""R..,"^;;"I.O,.N.:_.".....,"!_"""''''''''''--"'''''''''-~..'''#''''''''''f<''"..1 :..~jj:~f~~\Wilf~~.e:":;"M~'l,';:,.,,..- ..- iS~~l 'ff _V~UL:;\:.? ,~i::\L::,__,~\;J.__.IV.l~!!~___,~.~'lli.~:,.!~~~'m~~~~1;~-;N:~~1fa~t':~ None known None known None known None known JAN t t 2008 Environmental Information: No data available ~~klI\~~~~!tB~i;\1I;1'a*[)t$J~J)$A'mct.tjf-l.$IEl.E~mlJJ.N$~~~~~!1il~~ Waste from residues I unused products: Dispose of according to all federal, state and local applicable regulations n_""''''-'''''~t_'''''''''''''''''''''''''''",'.'''''''11C''''''~'.''''''''-AiN-S'''''''''''C'I'N''''''''''M' ''''."I'''.,-;O'-......\\W''---,''''';~'m'~''''''''''~~;iII ~r';:~~1ij;;*,~~J;'r;t~",-",7ir~~~';!;~::-~-!lt'ii;.'.ij,."Ww.wt;{1l.jt;.<+_.-";J,\I;V;:\.'. ,r?^u:JXi-I_~,_,['4.\'l.,:).: ,,~')I: .~UmiI'iC\o~i-~m-79z.:;-m-~n1:~, ""', j,H')~~~~~'-if-ie~~~"~ DOTITDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information . . , ''''''_''''~''!!",''''''FI!l\'$,_''''''l1l.''''''''''''''''.'5'''''''E'''I)'''''''''''''D'!l1IN''''''R''M"'leN' '-~""~'~~""-"""""':~-"''' "'1;i-ti~;:~~"-~""-",il.:I<...""'~1ti",-,,~,,,,m;;:;~~aiiiO'!~~m;'t_'~:fQ- ,'~u,~h~,",",J,~i ,._M~,~; JVIt:\ll)" .. ~~,*,->J.: "'.. ,u;g>";;~J!;1!j~--,m!i~~w;L _ ,: _"~~~~~ Internatinnallnventnril'!!'ll All components of this product are listed on the following inventories: U.S.A (TSCA), Canada (DSUNDSL). U.S. Requlltfinn!'ll California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW I Inaredientlsl I Sodium laurvl sulfate Sodium xylene sulfonate \ I Ammonium hydroxide ,I . 2-buto_ryelhanol /1 Water , J I I I CAS # 151-21-3 1300-72-7 1336-21-6 111-76-2 7732-18-5 MARTK: NJRTK: P ARTK: I' I I I x RIRTK: x X x X x CERClAJ SARA I InQ'redientfs) I Ammonium hydroxide I 2-butoxvethanol CAS # 1336-21-6 111-76-2 WelQ'ht % 1.5% 20 ~ 30% I CERClAISARA RQ lIbS)! 1000 I Section 302 TPQ lIbS): ! Section 313 x InQ'redlent(s) 2.butoxvethanol CAJ>;'HAP X CAA ODS CWA Priority Pollutants SARA 311/:\12 J.-l:!,..:lrrf C:lbmnril'!!'I: Immediate: Y Delayed: N Fire: N Reactivity: N Sudden Release of Pressure: N Canada WHMIS hazard class: E Corrosive material. Inqredj~.mtls) 2-butoxvethanol CAS#_ 111-76-2 NPRI X l)!:i"i'qJ1:-~'!Ii1~"';"""'AW"""""-""""~""';~~.'6""""":'E"R'l'I""''''''"R..'M"-'^""[''''N'Wk\'"~1l!t''l''_ii_''''-'''lj!'"'''-\W;~ ,M!;~lff~_<'~~~~'4[,";:;'-'f,&il'~::1ij#~~'mt~"""\'!<>>""''''i.,,",,..._;.m,lJi.,''4--'W''/''''''''"'I.;, :j,\~.iM;]. ",;..< J~UJf.,",.' .. r.:~;,r_I.~__~ .. ,",_~."~"",,, __ - ____~~~~W-.JrLTft'::.~~~;m~J".l!!- ,..._~:!!~. lason for reviSIon: ,{spared by: Not applicable NAPRAC GlANCE SC (SUPER CONCENTRATE) 30f4 ~:;t..;.~ 29-4 '$~rif~i~t'i,:d~~~~Bivr~~~~~~~lii~~1:6IQJTHERnN_nO:RM~II-Q~~i~1A~-!~,~~~~~J.11t]~~~~\1fl~jf~.iWi~,~F~~~~:t{1 Additional advice: None - ") Notice to Reader: This document has been prepared using data from sources considered technicafly reliable. It does not constitute a warranty, express or implied, -as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate a/l available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. . , . Date Received: JAN \ t 2008 Original submittal. \ I / I ..J GLANCE SC (SUPER CONCENTRATE) 40f4 FROM FAX NO. ..v,.~j,.~ . Jun. 182007 01:05PM P1 I SupPlJ(~ AlVRrss 34-1 ) JON DON PRODUCTS 400 MEDINAN ROAD ROSELLE, IL 60172 jTLU:_ l 630-893-4747 MA TERIAL SAFETY DATA SHEET HAZARD ~Al'ING lJ!Jl<&-- ".UTlflll! :, ).""ON 1 0 ,....""..'rI . '-tLrCOUJ" ~ O.'NS:IO~I.rjC"'1lIj"T I ~-SS[ GECTIO~ IV' . ~ - ~ .~ Q) b I TRAO( NAIl: lOll L1oB(t) SPOT OUT I CfEHICAL FORH.llA MIXTURE SECTION I , 2-86 , PRlllOCT TYPr . ~o:;v.:;;ved: LIQUJ:D CLEANING COMPOUND CIt::HJcJU. NAIoI; OR Sl'loOH DETEllGENT - CO....POS'rTION . . lor"',~itt"'l c.o.s R!:C.N.. APPROx. ~ 1fT. :i15ii4 JLV 0/:[;]/1 TlV JAN 1 12008 CDWOI.ENT 151-21-3 25035-81-8 1-2 10-15 N/E NIE NIE NITl I Alkyl Sulfate Anionic Surfactant Acrylate Cnpolymer I SECTION II - paYSICAL PROPERTIES w/mild ,odor /Sff":J':n(2n718::'.-' ..L.:.;\....8.::/ aIu1.LJ,"'; ,..in,""," I. '",. I __ I.M1 . nr,....~n... _"'" 212. P, water VOLAT Ice ~~Atif-; ~+ .' . l.m . SEC~ION.III - PIRE AND EXPLOSION HAZARD .1 . LA"" ro"","" J AUTO IGNlTIllN TEMP. (.r} lLOWER EXPlOSION LINIT Il:) 'jUPPOl EXPl05liiN UHlT ! None. water' solution NIA '" N/^.. .. , II/A . (~:~UISHI'IC l1I'roAH fi] :~~HOL [] C02 fKJ gri/'llCAL QJ ~:~ 0 OTIJ:R SPrCIAL fIRE FIGijllNC PROC(OURt~ . M'f'[A/lA/j(( - !lXlR Clear.. blue liquid .REEW.:; POINT \"f I 32'F. waCer I SlJLlJ!lIUJr J~ ~AWI' . Comnlete Lv ~ =iC..U,SJ I r;' U,:ys.) 1 (rD. (""-" ~~HY (A.l~ = 1) I I ~vJv..~~""t.UWJYl AL.:t,.IAll z:: l)j (J.. . (:} Con!. and IIse caution when approaching fire-exposed containers. I UMJSUAL FIRE ~ EXPLOSlDol /iAlAAllS Containers may, burst in hea t of {:ire,. I T4!>J'.:"~l.f'm_n t,fp.lrT \'AtJ.f:S SECTION IV - HEALTH RAZARD PRIMARY ROUTES or ElPOSURE o =IH 0 O$llA IxJ (yE [K] SKill [] MN:: ESTt..cU tH::D CARCINOGENS OR SUSPECTED CARCINOGENIC INGREOIENTS 0 NTP 0 IAR!: 0 05fV\ []) HO;C E..ECTS Of' oVERexPo5uRE If in Eyes: Undiluted product splashed in eyes will cauSe irritation. If on 'Skin: Brief contaCt with prnducC should not produce any harmful effects, buc p.tolonged contaet. as from clothing wet with produce, may cause iTTieation. I.f Inhaled: No harmful effects as ordinarily used. If spray misted. may ecuse chest discomforC and coughing.. ff Swallowed; Hay cause nausea, vomiting, diarrhea. UE:RGEM:Y Ale FIRST Aiu PRiLi,t.tr<t:; If 1n gyes; Flush thoroughly wi.th water for at least 15 minuees. If discomfort persists~ See a doctor. . on Slt=in: Rinse th6rouRhly wir:.h water. ...LInhaJf?d-:.. .-Go--to--f'Fesn- a.l-r~...~.. If Swallowed: Give two glasses of \JaLer. Get medical attention irrunediately. o ORAl. o INlfALAIlON 1 FROM : FAX NO. 'f,;;t\.~; Jun. 18 2007 01:06PM STAllILlfl, ,', wVITIONS ro .1/010 IB ST~ 0 ~ST-'BLE ~, . HAZAROoUS OCCQiPOSITION PHWOCTS-- . '. None knO\Jn. ) I ~ZAJlOOUS POll'It::'RHArION ,I ciwlI HONS TO AVOID UHAY 0CI:Lf/Gi} ~ILL HOT DCClJ!lJ' None, ,m,c(JolPATlBll,!!,Y (ilATClilAlS TO A~jjiLij , U WATER ' LxI OTH::A Avoi<!. stronLoxididng and reducing agen E:S. SECTION VI '- SPILL OR LEAK PROCEDURE , ' , STEPS TO ai. iAJCLN IN CASE: HATERIAl IS Il(LEASlll DR SF'llL!;P For small sp:i.lls that can be handled routinely; wipe up and flush area "i~h wster. P2 34-2 I I t Date Received: JAN I 1 26C~ Onginal~Ubmittal For large spills, coUect' product with suitable .absorbent and collect fOr disposal. Floo~s may be slipperYi use care to avoid falling. wASTE Plll>'OSAl IlETlms For large 'spills ~ landfill absorbed matedal in accordance 'lith local. stl'te and federal regulations, SECTION VII - SPECIAL PROTECTION VENrILAHlIH TYPE: Normatrop~venti~ation unPer normal use where mistin8 unlikely. ~l~rLKAlunt r~~ltC'jUri' None needed- under no,mal use conditions. " . IVher~ sub:5tantial misting likely. use .NIOSH>;1pproved I:es~ifato"., JPROTE~TIYE. CLOVES ~I\bi;;"req., n6rnw.lY/ in: ~~mErla. ., , .~~CU9 far Jlro~ed <:>:ntacE. , Safety glasses if splas,hing l1kel~., I PTHtR 'PRoTeCTlve (QUIPHENT , . None. SECTION VIII - STORAGE AND HANDLING .Keep from freezing. Store at SO.F - 110"F. SECT tON IX - SHIPPING PAOPER StHfP1Nll "''''''', Compounds, Clean:i.ng Liqu'id, NO! U.S. OOT HAZARD CLASS, u.s~ DOT 1..0.' No.. ~ LASEL REOUIREHD/TS, SECTION X - MISCELLANEOUS This product contains no ingredients tbat are listed in the SARA III, Section 313 ;I:n'Ventoiy. AB8RevIATlDI/S' N/A N/D NIE lM:t.U.,. lESS Ytwj CREATER THAN \ , \ I NOT APPlICABLe NOT OCTERHll<tP I<<lT ESTA.8l1S1f:D UNK ( ) I. i"REPARW aT DA TE SUPER.CEOCS l Phil Gariboldi 7/10/02 9/30/99 )1nfo.Jmilt..11Y1 CI71t.ained her-.,,lO i!!l, lo tr.., best or OUJ" Ir.:~l~~a nod ~l'lcr. 8CCUUt.II!I.. I-IDIlrCVC't") alru;!e \. .~. c:onditiCJ1"\5 or hartd)'ing Dnd UB.\!: Qr!! be)'CW'ld OIJr ca"lt.r"Ql, )fO nal(l!! no g.Jtl.rJlOtse Dr fll':J\Jlts. arfd U:li~ rJQ liability (I:U.d.....gog inClJr.r-C!d by tnl.8Qf t.t\j5' fl'oBt~riIJ1. It. is t.he re9po;:r1.SibilHr 0' the U$er 'too cOh"'q)l)' with all IlWHr:able rf!!deraJ, (itate end loC'~] lows and t"eguhUona.. I J J I I I 1 I I johll!ion UJiJX PROFESSIONAL \ l .:,':~.;., '. PART 1 1-1 Material Safety Data Sheet II , BRAVO HEAVY DUTY LOW ODOR STRIPPER oil ' National Fire Protection Association (NFPA) Fire Hazard Health Reactivity Specific Hazard ~ Protective Clothing .~ ^. Hazardons Material Information System (HMIS) II Emergency Clear Liquid. See Section 9. J[ Overview 'DANGER. CORROSIVE. CAUSES'EYE AND SKIN BURNS. HARMFUL OR FATAL IF SWALLOW~D. MSDS# Indusfr;alllnslitufional: Floor care. This product is intended to be diluted prior to use. 114585004 I Validation Date, " 433448 II 7/1 ?/2000 Product Use . V.S. Headquarters . Johnson Wax Professional 8310 16th Street Sturtevant. Wisconsin 53177~0902 Phone: (888) 352'2249 MSDS Internet Address: www.jwp.com I Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East. Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Print Date ,Supersedes 1n r:!~e of EmerPencv ~7!Ct/o~~""?if!ll~~lfilflfo"F'tlia~M'ik1lfl!{!1i:;rtJ.V1. ,,'. m:!:ht.~\ttii$~~,-,~W~_~_"8i#;~~~mJ~I~\1Wfuro~~J!~~ ___._ Exposure-Urn.its . "ngredients , "c-:'Monoethanolamine CAS# % by Weight 141-43-5 1-5 Sodium Hydroxide 1310-73-2 1-5 Sodium silicate _ Water 1344-09-8 7732-18,5 5-10 60-100 ~ TWA: 8 STEL: 15 (mg/m') from OSHA(PEL) [United States] TWA: 7.5 STEt: 15 , (mg/m') from ACGIH (TLV) [United States] CEIL: 2 (rng/m') from OSHA (PEL) [United States] STEL: 2 (mg/m') from ACGIH (TLV) [Uniled Stales] Not available. Not available. , 7119/2000 No:Previous Validation. ! (800) 851-7145 ORAL (LD~O): Acute: 1720 mg/k9 [Rat]. DERMAL (LD50): Acute: 1018 mglkg [Rabbit). II Not available. 'I: Not available. Not Applicabie. Routes of Entry Inhalation. Skin contact-Eye contact. Potential Acute Health Effeds Eyes Corrosive. May cause permanent damage including biindness. . Skin Corrosive. May cause permanent damage. Inhalatiott May cause irritation and _ corrosive effects to nose, throat and respiratory tract. Ingestion Corrosive. May'cause burns to mouth, throat, and stomach. Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, e1h,physema, etc., may Aggravated by Overexposure: be more susceptible to irritating effects. II : See ToxicoJogicallnformation (section U) 1 na:t',.=._Recei1 ed: ) -"'" Continued an Next Page JAN 1 1 2008 Original Submittal Page: 1/4 1-2 ' Date Received: \;"I\;'~ ! IAN 1 1 2008 Material Safety Data~eet , Johnson wax PROFESSIONAL BRAVO HEAVY DUTY LOW ODOR STRIPPER ~ Eye Contact Skin Contact Inhalation Ingestion Immediately flu.sh ey.as with' running water for at least 15 minutes, keeping ey'eIids open. Get medical attention immediatelv. . F'lush !mmediately wjth plenty of water for at least 15 minutes. Get medical ~ttentio~' immediately. If bre-athingis difficult: Remove to fresh air. Get-medical attention immediately. 00 not-induce vomiting!' Immediately drink plenty of water. Never give anything by ,mouth to an I unconscious person. Get medical attention immediately. . JI ' . , Products of Combustion Fire Fighting Media and Ins'tructions Protective Clothing (Fire) Special Remarks on Fire and Explosion Hazards No~e known. None known. None known. II " Ex~ingujsh with water spray or carbon dioxide, dry chemical powder or appropri~te foam. Normal fire fighting procedure may be used. ~I Put on appropriate personal protective' equipment (see Section 8). . Corrosive material (See sections 8 and 10). Personal Precautions Environmental Precautions and Clean-up Methods Storage Put on appropriate perSonal-protective equIpment (see~'ection 8). . In.the event of-major spillage: Use appropriate containment to avoid environmental cbntamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a w~ter rinse for final c1e~n-up.. _ . " l. .~. Avoid contact.with eyes, skin,' and' clothing. Do not taste 'or swallow. Avoid mists. Wash thoroughly after, handling. Remove and wash contaminated re;use. Product residue may remain on/in empty containers. All precautions for be used 'In handling the empty container and residue;iFOR INDUSTRIAL USE Store in a dry, cool and'well-ventilated area. Protect from freezing. Keep container tightly closed. KEEP OUT OF REACH OF CHILDREN. " I , I Engineering Controls Good g~neral ventilation should be sufficient'to control airborne levels. required if good ventilation is maintained. ' Personal Protection ~ Eyes Chemical splash'goggles, II. Hands Chemical resistant gloves. Includes; Neoprene groves. R.ubber gloves. ii Respiratory If.mistslvapors are not adequately controlled 'by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's 'use. Feet Protective footwear: Body If major exposure. is possible, wear suitable protective ~ot~ing and footwear. Physical State and Appearance Odor Color pH Specific Gravity ;'iling/Condensation Point .J , I:MeltingfFreeZing Point Continued on Next Page: Liquid. I Bland. Clear 12.7 [Basic,] (Undiluted.) 1.1 1000C (2120F) O'C (320F) Page: 214 }ohn50n WilX PROFESSIONAL ~""I Solubility in water 1-3 'J;, .',~ Date Received: BRAVO HEAVY DUTY LOW ODOR STRIPPER Materlall Safety Dj~~e,t 1 jl 2008 , Complete. Conditions of Instability Incompatibility with Various. Reactive with oxidizing agents, acids. Substances Hazardous Decomposition Products Hazardous Polymerization When exposed to fire: Produces normal products of combustion. Will not occur. Effects of Chronic Exposure None known. Other Toxic Effects None known: Not available. Waste Information Undiluted product is regulated. under environmental'and transportation laws as a co'l'rOsive waste. Dispose of according to all federal, state and local regulations. II . - , DOT Classification ) DOT Proper Shipping Name DOT Class UNINA Packing Group TDG Classification IDG Proper Shipping Name IDG Class PININIP Packing Group Corrosive liquid, basic, inorg'anic, n.o.s. ,( Sodium hydroxide , Class '8: Corrosiv~ material UN3266 /I Corrosive liquid, basic, inorganic, n.o.s. ( Sodium hydroxide . ,I , Monoethanolamine ) II 'I ! II II Class B: Corrosive material UN3266 /I Reporting in t~is section is based on ingredients disclosed in Section 2 US Regulations Registered Product Information ~I)an.dian Regulatinns WHMIS Classification Federal Clean Water Act (CWA) 311: Sodium Hydroxide CERCLA: Hazardous substances.: Sodium Hydroxide State New Jersey spill list: Sodium Hydroxide New Jersey: Monoethanolamine, Sodium Hydroxide Massachusetts spill list: MonoethanoJamine, Sodium Hydroxide Massachusetts RTK: Monoethanolamine, Sodium Hydroxide Pennsylvania RTK: Monoethanolamine, Sodium Hydroxide This product is not subject to the reporting requirements under California's Proposition 65. II Not applicable. CLASS E: Corrosive liquid. Continued on NextPage, fags: 314 1-4 ".' ;. il Material Safety Data Sheet II JAN 1 1 2008 Da~e Received: john5on WilX PROFESS/ONAl BRAVO HEAVY DUTY LOW ODOR STRIPPER - . ) .' WHMIS Icon @ , qriginal submittal_ Registered Product Not applicable. In{ormation II Chemical Inventory Status: All ingredients of this p'roduct are listed 'or are excluded from listing on "the U.S. Tox'ic Substances Control Act (TSCA) Chemical Substance Inventory. Version 1.01 .Nnti(,l'tnR(>ade~. . .. . . .' --, " ,11 This document has been prepared using data from sources' considered technically reliable. 1/ does not constitute a warraiitj.o~ express or implied, as to the accuracy of the information contained 'within. Actua/conditions of IIse and handling are beyo~'dseller's contr~i.' User i~ r~spollsible to evaluate all available information when using productf~'" a';y particular use and to comply with" all Federal," Siille, Provincial and:Locallaws and regulations. " ." " " . " II ..." . ) ? " " - ) 2-1 johu!!ion WiIX PROFESSIONAL Date Received: Materialllsafety, Dat,~l'f' I 2008 DEODORIZER UQUID - FRESH II . , ,) r- National Fire Protection Association (NFP A) Health Reactivity Hazardous Material Information System (HMIS) Fire Hazard 11 Emergency Clear Oft-white. liqUid. See Sectionl9. Overview C.AU.T10N: May be mild.IY irritatingho.'!>kin. May cause eye in:itation. . . ] . l%i:<:S'.-r"*"",' '~,'l\l~. r._""'fpN*,V4'0~, ',''1Pe''',-''ft"'~'''~iti.&1*tffl''At'''''~~~..~ *'is.. ... _\!Il~,_". ,_if.m __.' mi~~&r~~li~~~~~~~~~,llibJ~~~i~J~J&1Ji!ilJ~~~~~~~-~~~.~t&1J Product Name DEODORIZER LIQUID. FRESH Code' 3~84 Product Use Industrial/Institutional: Carpet care. This product is'intended to PMS# 433348 be diluted prioi to use. . II . 126349001 I Validation Date 01/19/2000 Specific Hazard Protective None required. Clothing MSDS# U.s. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin,53177-0902 Phone: (888) 352-2249 MSDS Interhet Address-: www.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mjssissa~gC3,,9ntario L4Z 2G7 Phone: (905) 755-0913 or (888)746-5971 Print Date Superse~es " . 04120/2000 04112/2000. " (800) 861-714; In r.a!i:eof RmerJJe"ju;v f!!i("'S~ti[lf1'i2~'tmt1l1ftlti!J'f1i1IffIfiTri8,",rHf!1fi!!f{ff:1r{ilifgltrlrllffi--Tfi1l1Z.'"ffj!jf!'~\"_~_'r~~ ~4c'M-it;HitlWffiWJRW11;tiM0_liii%i?k;.jW&:iM5Y'AA&tf:?4iiii"~:t~f~~wEj;;w~~;~.~.~#A"~4!lljII.:E:~~ ., lngredients CAS # % by Weight .. . E~posureLi.mi~ - > "I' '.1 JI LC5~ILDSO" ! . " __ 'Alcohol Ethoxylates 68439-46-3 1-5 Not available, ORAL (LD50): Acute: 1378 mglkg [Ra.tj. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. 'oRAL (LD50): Acute: 404 mglkg [Rat].. II Not availaple. Not available. ,Not applicable. Sodium Alkyl Aryl Sulfonate 68411-30-3 1-5 Not available. _ Alkyloxypolyethyleneoxyethanol Fragrance Water 68131-40-8 1,,5 1-5 60-100 Not available. Not available. Not available; 7732-18"5 Potential Acute Health Effects Eyes May be moderately initating to eyes. Skin May be mildly irritating to skin. Inhalation None known. Ingestion None kn?~n, Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11) Flush immediately with plenty of water. If irritation persists, get medical attention. Flush immediately with plenty at water. Get medical attention if irritation occurs. It breathing is difficult: Remove to fresh air. No specific first aid measures are required. Skin Contact - Inhalation - ..hgestion /:~' Continued on Next Page Page: 1/3 2-2 ' johll!ion wax PROFESSIONAL DEODORIZER LIQUID - FRESH. " Date Received: II Material ~afety Data Sheet JAN t I 2008 . Flammability of the Product Flash Points Products of Combusti~ii-':' Fire Fighting Media . ~. and Instructions Special Rem~rks on Fire and Explosion Hazards ( None-known;' Extin'guish. with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighti"ng,procedure may be used. . !! None known: Personal Preca~ti!lns Environmental Precautions' and Clean-up Methods Put "on appropriate" personal protective equipment (see'Section 8)." .~~ - . . " .-.-. ,',"-,-"" -. _' c, . '," II '-.' . Intheevenl of major spillage: Use appropriate oontainmentto avoid envilunmental contatninatich Sweep: or scrape up material. Place in suitable clean, dry containers for disposal by approve"d methods. .Use a water 'ri,ns~ for final clean-up,. It Handling Storage Avoid contact with eyes, skin, and clothing, Wash- thoroughly after handling, FOR INDUSTRIAL USE ONLY. " ,. II Store in a dry, cool'and-well-ventilated area,'Protect from freezing. KEEP d'UT OF REACH OF 'CHllDREN: . , '.' , II Engineering Coiiirols . No special ventilation requireme'nts:.General'room ventilation is adequate, II 11-' I. II II il ) " Eyes No'sp~cial protective clothj~g is''required. . . "'. Hands No special protective clothing is required: Re~piratory No_special'pr~tkctive clothing is required. Feel No special'protective clothing is required. Body No special'protectiye clothing is required. Personal Protectilm ) " Color pH Specific Gravity Boiling/Condensation Point MeltingIFreezh,lg Point Solubility in water Fruity. Apple-like, Clear Off~white. 3.1 [Acidic.) 1 1000C (2120F) DOC (320F) Complete. Stability and Reactivity Conditions oflnstabilitv Incompatibility with Various Substances Hazardous Decomposition Products : Hazardous Polymerization ;i Continued an Next Page The product is stable. None known. None known. Produces normal products"ofcombustion. Will not occur. Page: 2/3 ~ ." Date Received: 2-3 john5on wax PROFESSIONAL DEODORIZER LIQUID - FRESH Malerlal:safe~~f 'h'f12008 _ Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Effects of Chronic Exposure None known. Other Toxic Effects Not avai!able, Not available. No speCial precautions. Dispose of according to all federal, state and local regulati?cns. DOT Classification Not regulated TDG Classification Not regulated Reporting,in this section is based on ingredients disclosed in Section 2 us Regulations" This'product isnat subject to the reporting requirements under California's Proposition 65. "llI Registered Product Not applicable. 1\ Information Canadian Regulations WHMIS Classification CLASS 0-28: Material causing other toxic effects (TOXIC). WHMIS Icon (I) Registered Product No~ applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Other Special Considerations MSDS Selial Range: 001-002. Version Nnticp tn Rp::arlpr This document has been prepared using dataftom sources considered technically reliable. It does not constitute a warra~ty, express or implied, as to tlte accul'acyoflhe information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provikcial and Local lows _ and regulations. I ,,/ Date Received: 3-1 ,'. john5on WilX PROFESSIONAL JAN 1 1 2008 Material iSaf.l:,tv Data..$heettt I ' Ur'lgmal ::;ubml a .\, ) EXTRACTION RINSE Health Reactivity Hazardous Material Information System (HMIS) National Fire Protection Association (NFP A) Fire Hazard Specific Hazard CPr,othe~tive ~ 111 ot mg ~.~ Emergency Clear Amber, Liquid:' See Section 9.:: Overview CAUTION: May cause eye and skin irritation. II Product Name EXTRACTION RINSE Code 3130 436894 Ii 04!1912000 Product Use Industrial/Institutional: Carpet care. This product is intended to PMS# be diluted prior to use.; 126353005 Validation Date MSDS# 1n C~IIlP n~ Emerpencv " 0412012000 04/12/2000. :r (890) 851-(145 U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address:' \oVWW.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888)'746-5971 I Print Date Supersedes r;~~"0nJW;~""IG'Jti~q:;w:W}"'~;_0?X$?\t'71\7:mV'\'jFio/?2P't"~Si1J~m;**:~~7~!:I~ ' . '(\lV"'b &~,JIJ''?!Jil,t~fPi~~VlRB~~~f1JrI~~JJl!JolillJJJJt!JJlJA!lJJtJJllllll!Jlm&'~=~i ',,,_~ -. ..' . ."11 ,'11'11"".. _.~ \Ingredients CAS # % by Weight. Exposu~e. Limits JAlkyl Naphthalene Sodium 1-5 Not availabie. ~ Sulfonate . Surfactant (NJTRS # 489909-5020-P-PC) Sodium Xylene Sulfonate Hydroxyacetic acid' . I. ii LCSOILDSO Not available. II Not available. Not avaifable. ORAL (LD50): Acute: 1950 mglkg [Rat]. Not applicable. 1-5 Not av;ailable. 1300-72-7 79-14-1 1-5 1-5 Not available. Not'ayailable. ,Water 7732-18-5 60-100 Not available. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes May be moderately irritating to eyes. Skin May be moderately irritating to skin. Inhalation None known. Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section ll) Eye Contact Skin Cont~ct 'nhalation )gestion Flush immediately with plenty of water. If irritation persists, get medical attention. Flush immediately with plenty of water. If irritation persists, get medical attention. No specific first aid measures are required. No specific first aid measures are required. ~ Continued on NextPage Page: 1/3 3-2 joh1l5on WilX PROFESSIONAL Date Received: EXTRACTION RINSE Ii 'I , Material 'Safety Data Sheet , JAN 1 1 2008 Flammability of the Product Flash Points None known. CLOSED CUP: >930C (199A'F). Ji ~-I'l!1i;g.'."," ill.lllr 'Ctl;i1~iJ .>j:; 01. " ". lLY, jj- ~'~'''0;ta ,M"",. "",.' , I' " W' ""'W;;:, " ", '. '1'" Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Haurds None known: -"I Extinguistl'with water spray or carbon dioxide, dry chemical powder or 'approp~iate foam. Normal fire fightin'g procedure may be used. . jl' , None known. Personal Precautions Environmental Precautions and Clean-up Methods Put on appropriate personal protective equipment (see Section 8.). . hi'the event,of major spillage: Use appropriate contai'nment to -avoid environment'al '~ntamjnation. Sweep or scrape up material. Place in suitable clean, dry con~ajners for disposal by approved methods. Use a" water rinse for final clean-up. " lr . .' . . Handling Storage Avoid con'tact wlth- eyes, skit:J, and clothing. Wash thoroughly after handling. FOR INDUSTRIAL USE ONLY. " . I . Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. . . Ii Eyes Safety glasses recommended.' " Hands No special requirements under normal use conditions. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body If major exposure is possible, wear suitable protective clothing. " Engineering Controls," Personal Protection , ) No special ventilation requirements. General room ventilation is adequate. -.\ , Color pH Specific Gravity Boiling/Condensation Point Melting/Freezing Point Solubility in water Apple-like. Clear Amber. 2.85,[Acidic.j 1.01 1000C (2120F) O'C (32'F) Complete. Stability and Reactivity Conditions of Instabilitv Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization I .,~ Continued on Next Page The product is stable. None known. , Reactive with:alkalis. When expose:d to fire: Produces normal products of combustion. " J II II II II Will not occur. Page: 2/3 3-: joh1l5on WilX PROFESS/ONAL EXTRACTION RINSE . " r ! , Material:Safety Data Sheet " JAN 1 1 2008 Date Received: Acute toxicity Not available. Effects of Chronic Exposure None.known. Other Toxic Effects Not available. Not available. No special precautions. Dispose of according to all federal, state and local DOT Classification Not regulated TDG Classification Not.regulated Reporting:in this section is based on ingredients disclosed in Section 2 us Regulations This product is not subject to the reporting requirements under California's Proposition 65. . Registered Product Not applicable. '" I . Information __.01 Canadian Regulations WHMIS Classification CLASS 0-28: Material causing other toxic effects (TOXIC). WHMIS Icon (T) Registered Product Not applicable. Information Chemical Inventory,Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. II Version NntiC'P tn Rpadpr This document has been prepared using data from sources considered technically reliable. It does not constitute a warra,!ty. express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL- User is responsible to _ evaluate all available information when using product for any particular use and to comply with all Federal, State, Provi~cial and Local laws and regulations. '1 ) J 4-1 johU!iOnWilX PR.OFESSIONAl bate Received: ) Material Safety DaJANhtet 2008 HEAVY DUTY PRESPRAY National Fire Protection Association (NFP A) Fire Hazard Health ~ Reactivity Specific Hazard Hazardous Material Information System (HMIS) Protective~, ~~'. Clothing ~. Emergency Clear Colorless. Viscous liquid. Apple-like. Odor. Overview WARNING: CAUSES EYE IRRITATION. MAy'cAuSESKIN IRRITATION. Product Name Product Use HEAVY DUTY PRESPRAY Code Industrial/Institutional: Carpet care. This product is intended to PMS# be diluted prior to use. 4266 433336 MSDS# 126327003 u.s. Headquarters , Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 - MSDS Internet Address: www.jwp.com Canadian Headquarters Jo'hnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z-2G7 . Phone: (905) 755-0913 or (888)'746-5971 Validation Date I Print Date Supe~~.edes In ('a~p ~nf Emerp'encv 0411912000 0412012000 04IiZIZOOO. (8U~) 851-1145 CAS # . LC50ILD50 - -.' Ethyl Alcohol 64-17-5 0.1-1 TWA: 1900 (m9Im') from ORAL (LD50): Acute: 7060 OSHA (PEL) [United Statesl mg/kg [Rat]. VAPOR (LC50): TWA: 1880 (m9Im') from Acute: 20000 ppm 10 hours ACGIH(TL V) [United States] [Rat]. Diethylene Glycol Butyl Ether 112-34-5 1-5 Not'available. ' ORAL (LD50): Acut~: 5660 m9/k9 [Rat]: DERMAL (LD50): Acute: 2700 mg/kg [Rabbit]. Dioctyl Sodium Sulfosuccinate 577-11-7 5-10 Not available. ORAL (LD50): Acute: 1900 mg/k9 [Rat]. Alcohol Ethoxylates 68439-46-3 10-30 Not available. ORAL (LD50): Acute: 1378 mg/k9 [Rat], DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. Water 7732-18-5 160-100 Not available. Not aoolicable. Routes of Entry , Skin contact. Eye contact. Potential Acute Health Effects Eyes May be severely irritating. to eyes. Skin May be moderately irritating to skin. Inhalation May be irritating to nose, throat, and respiratory tract. Ingestion May be irritating to mouth, throat and stomach. Medical Conditions Persons with pre-existing skin disorders may be more susceptable to irritating effects. Aggravated by Overexposure: See ToxicoJogic:lllnformation (section 11) / Continued on Next Page, Page: 1/4 4-2 Date Receiv(3d: john5on wilx PROFESSIONAL HEAVY DUTY PRESPRAY Material Safety Data Sj).1I 1 1 2008 Eye Contact Skin Contact Inhalation Ingestion . ) .Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention. Fr~sh'immediately with plenty of water. If irritation persists, get medical attention. If brea~hing:is d~fficult: Remove to fresh.air. Get medical attention. Immediately drink plenty of water. 'Never give anything by 'mouth to an unconscious person. Get medical attention. Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire and Explosion Hazards None known. CLOSED CUP: >930C (199.40F). None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. Put on appropriate personal prote~tive equipment (see Section B). None known. Personal Precautions Environmental Precautions and Clean.up Methods Put on appropriate personal protective equipment (see Section'B). In the event of major spillage: Use appropriate containment t~ avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water ri~se for final clean-up. Storage Avoid contact with eyes, skin, and clothing. Wash thoroughly ONLY. Store ill a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. , ) Engineering Controls Personal Protection No special ventilation requirements. General room ventilation is adequate. Eyes Safety glasses with side shields. Hands NO,special. requirements under normal use conditions. For prolonged or repeated contact with skin: Neoprene Qloves. Rubber q[oves. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body If major exposure is possible, wear suitable protective clothing. Physical State and Appearance Odor Color pH . Specific Gravity Boiling/Condensation Point Melting/Freezing Point Viscosity Solubility in water liquid. (Viscous) Apple-like. Clear Colorless. 6 to 7 [Acidic.] 1 1 DDoC (2120F) DOC (320F) 72 cP (Dynamic). Complete. ) Continued,on Next Page Page: 2/4 4-3 Date Received: -., ;," john5on WiIX PROFESSIONAL HEAVY DUTY PRESPRAY Material Safety rAWf"\ 2008 .' Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization Not available. .When exposed to fire: Produces normal products of combustion. Will not occur. ORAL (LDSO) Greater than 5000 mg/kg (rat). INHALATION (LCSO) Greater than 120 mg/L (rat), Effects of CbronicExposure NonEt known. Other Toxic Effects Not available. Acute toxici!y Not available. Waste Information No special p~ecautions. Dispose of accordjn~ to. all federal, state and local regulations. DOT Classification Not regulated , _ ...l'TDG Classification Not regulated Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal CERCLA: Hazardous substances.: Ethyl Alcohol, Diethylene Glycol Butyl Ether State New Jersey spill list: Diethylene-Glycol Butyl Ether New Jersey: Ethyl Alcohol, Diethylene Glycol Butyl Ether Massachusetts spiJIlist:Ethyl Alcohol Massachusetts RTK: Ethyl Alcohol Pennsylvania RTK: Ethyl Alcohol, Diethylene Glycol Butyl Ether This product is not subject to the reporting requirements under California's Propositioh 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification CLASS D.2B: Material causing other toxic effects (TOXIC). WHMIS Icon CD Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. ' I , ~ Continued on Nextpage . Page: 3/4 4-4 john5on WiD( PROFESS/ONAL' HEAVY DUTY PRESPRAY Material Safety Data Sheet Other Special Considerations . Not available. Version Nntil"i> tn Rf'IUif't This document has heen prepared using dala from sources considered technically reliable. It does not constitu/~ a warranty, express or implied, as /0 the accuracy of the information contained within. Actual conditions ofllse and handling are beyond seller's controL User is responsible to evaluate all available information when using product for any par/icular use and to comply ",ilh a/J Federal, State, Provincial and Loco/laws and regulations. . Date Received: JAN 1 1 2008 Original submittal ') ,~ ) " -) '5-1 ]ohn5ou'waX PROFESS/ONAL :j:,}l"t Date Received: ".." .' " Material SafetjAHt~ '11lOO8 ) IODINE SPOTTER Health Reactivity Hazardous Material Information System (HMIS) Original Submittal. I I o i I National Fire Protection Association (NFP A) Fire Hazard Specific Hazard Protective Clothing Emergency Clear Colorless. Liquid. See Section 9. . I Overview CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www;jwp.com' C3;nadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 I Code IPMS# I Validation Date Print Date Supersedes in ('SHIP,of Emerpencv 3849 433352 04/28/2000, 04/28/2000 04119/2000. (8UU) 851-7145 Product Name Product Use' IODINE SPOTTER Industrial/Institutional: Carpet ~re. 126358003 MSDS# Sodium Sulfite /Sodium Bisulfite I CAS# 7757-83-7 7631-90-5 '% by Weight Exposure Limits U1 LCSOILDSO Ingredients '. 1-5 10-30 Not available. . TWA: 5 (mglm') IromOSHA (PEL) [United States] TWA: 5 (mg/m') from ACGIH (TLV) [United States] Not available. Not available. ORAL (LD50): Acute: 2000 mg/kg [Rat], ' Water 7732'18-5 60-100 Not available, Routes of Entry Inhalation: Skin contact. Eye contact. Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly, irritating to skin. Inhalation May be irritating to nose, throat, and respiratory tract. Ingestion None known. Medical Conditions Persons with pre-existing sensitivity to sulfites may be more susceptible to allergic,reaction. Individuals Aggravated by Overexposure: with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be more susceptible to irritating effects. See Toxicological Information (section 11) Eye Contact Skin Contact Flush immediately with plenty of water. Get medical attention jf irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. If breathing is diffic~lt: Rer:nove to fresh air. Seek medical attention. NO'specific first,aid measures are required. Inhalation Ingestion ) Continued on Nextpage, Page: 1/4 5-2 )ohn!iOnWilX- PR.OFESSIONAL I")ate Received: Mat.riJAWJDltAllL~t , IODINE SPOTTER FlammabiIity.of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards ) -None known. Not available: Products of combustion: Oxides of sulfur. Oxides of sodium. Ex.tinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. ' None known. PersonaJ Prec,8utions Environmental Precautions and Clean-up Methods Put on appropriate personal protective equipment (see Section'8). In the event of major spillage: Use appropriate containmeritto avoid environmental Contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disp'osal by approved:methods, Use a water rinse for final clean-up. ., Handling Storage Avoid contact with skin and eyes. Avoid breathing vapors of fhls product. After handling, always wash hands thorouQhlV with soap and water. . Do not use if allergic to sulfites, FOR INDUSTRIAL USE ONLY Store in a dry, cool and well-ventilated area. Protect from freezing;.'Keep away from heat, sparks and ftame. KEEP OUT OF REACH OF CHILDREN, . Engineering Controls Personal Protection No special ventilation requirements. General room ventilation is adequate. Eyes No'special protective clothing is required. Hands Neoprene gloves, Respira'oryNo special protective clothing is required. Feet No special protective clothing is required. Body No special protective clothing is required. , ) Physical State and Appearance Odor Color pH Specific Gravity Solubility in water Liquid. Odorless. Clear Colorless. 7 [Neutral.l 1.16 Complete, Stability and Reactivity Conditions of Instabilitv Incompatibility with Various Substances . Hazardous Decomposition Products Hazardous Polymerization The product is stable. Excessive heat Reactive with acids. Oxides of sodium. Oxides of. sulfur. Will not occur. ,\ Continued on Next Page Page: 2/4 Date Received: 5-3 ,."'t'."'<. JAN 1 1 2008 Material Safety Data Sheet }oh1l5on wax PROFESSIONAL IODINE SPOTTER Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). DERMAL (LD50) Estimated to be Qreater than 2000 mQ/kQ (rat). None known. May cause sensitization by skin contact. May cause allergic skin reactions with repeated exposure. Effects of Chronic Exposure - Other Toxic Effects Waste Information No s~ecialwecautions. Dispose of according to all federal, state and local regulations. DOT Classification Not regulated TDG Classification Not regulated Reporting in this section is based on ingredients disclosed in Section 2 us Regulations ) ,j Federal Clean Water Act (CWA), 311: Sodium Hydroxide, Sodium Bisulfite CERCLA: Hazardous substances.: Sodium Hydroxide, Sodium Bisulfite State New Jersey spill list: Sodium Hydroxide. Sodium Bisulfite New Jersey: Sodium Hydroxide, Sodium Bisulfite Massachusetts spill list: Sodium Hydroxide, Sodium Bisulfite Massachusetts RTK: Sodium Hydroxide, Sodium Bisulfite Pennsylvania RTK: Sodium Hydroxide, Sodium Bisulfite This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not controlled.under WHMIS (Canada). WHMI8 Icon @ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Other SpeCial Considerations Not available. Version '1otiel'" to Rl'"lIder f Continued on Next Page: Page: 3/4 5-4 john5on wax PROFESSiONAL Material Safety Data Sheet IODINE SPOTTER -, . This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to _ evaluate all ~vai1able information when using product/or any particular use undlo comply with all Federal, State, Provincial and.Locallaws . and regulations. > ! Date Received: JAN 1 1 2008 Original submitt~ I , , ) -) "" John~onwilX PROFESSIONAL" ". ..'. ) OVER & UNDER National Fire Protection Association (NFP A) . Fire Hazard Hazardous Material Information System (HMIS) Health Reactivity Specific Hazard 6-1 Date Received: Material SaJ.A~OaJa Ut Original Submittal Protective None required. Clothing Emergency . White. Opaque Emulsion. See Section 9. Overview CAUTION: May be mildly irritating to eyes. 'May be mildly irritating to skin. Product Name OVER & UNDER Industrialllnstitutional: Floor care. 114150033 I Code IPMS# Product Use MSDS# Validation Date u.s. Headquarters Johnson Wax Professional B310 161h Street Sturtevant, Wisconsin 53177-0902 Phone: (BBB) 352-2249 MSDS Internet Address: www;jwp.cOm Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East. Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (BB8) 746-5971 In Case of EmerJlencv Print Date Supersedes 4151 432584 04/1912000 04/1912000 041.12/2000, (BUU) Bb1-fHb Ingredients ) Dipropyiene Glycol Methyl Ether f CAS # 34590-94-B 1-5 TWA: 600 STEL: 900 (mg/m') from. OSHA (PEL) [United Statesl SKIN TWA: 606 STEL: 909 (mg/m') from ACGIH (TLV) [United States) SKIN 1-5 Not available. % by Weight Exposure Limits Tributoxyethyl Phosphate 78-51-3 Diethylene Glycol Ethyl Ether Acrylic Polymers Water 111-90-0 1-5 Not available. 7732-18-5 10-30 Not available. 60-100 . Not available. LCSOILDSO ORAL (LD50): Acute: 5119 mglkg [Rat]. DERMAL (LD50): Acute: 9480 mglkg[Rabbit]. ORAL (LD50): Acute: 3000 mglkg [Ratl. DERMAL (LD50): Acute: 16000 mg/kg [Rabbit]. ORAL (LD50): Acute: 5540 to 9740 mglkg [Rat]. Not available. Not applicable. Routes of Entry Inhalation. Skin contact. Eye contact: Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly irritating to skin. Inhalation None known; Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11) ) ./ Continued,on,NextPage Page: 1/4 6-2 uate ~ecelveu. JAN 1 1 2008 john5on wax PROFESSIONAL OVER & UNDER Material Safety Data Sheet Original Submittal Eye Contact Skin Contact Inhalation Ingestion ) Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. No specific first aid measures are required. Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. Not available. None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Personal Precautions Environment.al Precautions and Clean-up Methods Put on appropriate personal protective equipment (see Section 8). In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a' water rinse for final clean-up. Handling Storage Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY. Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. ) '- Personal Protection No special ventilation requirements. General room ventilation is adequate. Eyes No special protective clothing is required. Hands No special protective clothing is required. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body No special protective clothing is required~ Physical State;and Appearance Odor Color pH Specific Gravity Boiling/Condensation Point Melting/Freezing Point Solubility in water Continued on Next Page Liquid. (Opaque Emulsion.) Mild. Ammoniacal. White. 9 to 9.6 [Basic.) 1.03 100"C (212"F) O"C (32"F) Complete. ) Page: 2/4 ,," Date Received: 6-3 john5on wax 'PROFESSIONAL OVER & UNDER Material Safety OatafANl! 1 2008 Stability and Reactivity Conditions of Instabilitv Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization The product is stable. None known. Not available. When exposed to tire:iProduces normal products of combustion. Will not occur. Acute toxicity ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Effects of Chronic Exposure None.known~ Other Toxic Effects Not available. Not available. Waste [nfonnation No special precautions. Dispose of according to all federal, state and local regulatiol'1s. DOT Classification Not regulated , fDG CI:::::;:I::ed 'J 1 Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal SARA 313 toxic chemical notification and release reporting: Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether CERCLA; Hazardous substances.: Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether State New Jersey spilt list Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether New Jersey: Tributoxyethyl Phosphate, Dipropylene Glycol Methyl Ether, Diethylene Glycol Ethyl Ether Massachusetts RTK: Dipropylene Glycol Methyl Ether Pennsylvania RTK: Tributaxyethyl Phosphate, Diprapylene Glycol Methyl Ether, Diethylene Glycol Ethyl Ether This product is nat subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not controlled under WHMIS (Canada). WHMIS Icon @ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. ToxicSubstan~es Control Act (TSCA) Chemical Substance Inventory. ) I , Continued on'Next:Page_ Page: 314. 6-4 '. , }OhU50UWilX PROFESSIONAL Material Safety Data Sheet OVER & UNDER Other Special Considerations Not available. Version ,Nt)ti('('to~ This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL User;s responsible /0 evaluate all available information when using productfor any particular use and to comply with all Federal, State, Provincial and Loco/laws and regula/ions. Date Received: JAN \ 1 2008 Original Submittal ') , ) , ) .... johil5on UJilX PROFESSIONAL ') National Fire Protection Association (NFP A) . . PLAZA PLUS Fire Hazard Health ~ Reactivity Specific Hazard Hazardous Material Information System (HMIS) 7-1 Date Received: Material Safety Da~lt,e, 2008 Oriainal Sul:!mitt2' 1 ~J Emergency Milky-white. Emulsion. See Section 9. Overview CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. ' . rfJ~7~li5p11~"@ffJiiF~1{ji~qfl9i!1mllqQ}!te~l)ylf{iet1'fjfifaiiE:~~!f:g;lia~~.~~_.~ .;.?JA_,~J2$iit'"iW*",~0liim~%.,iifi""A'iJif?~il\tfi9#Wr&;Bjlffi%,~#l&1;I)Jt9fA'jJii\~J1~~~~ill;1IL~~~. Product Name PLAZA PLUS jcode 4168 Product Use Industrial/Institutional: Floor care. PMS# 437634 MSDS# 114170012 ,IValidalionDate 10/12/2000 Protective None required. - Clothing U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 _ MSDS Internet Address: www.jwp.com Print Date ~upersedes Canadian Headquarters Johnson Wax Professional 100 Matheson 'Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905),755-0913 or (888) 746-5971 In Case of RmerfJencv 10/12/2000 10/\212000. (8UU) 851-7145 Ingredients . )Tributoxyethyl Phosphate Zinc Ammonium Carbonate Dipropylene Glycol Methyl Ether Diethylene Glycol Ethyl Ether Ethylene Glycol Phenyl Ether Acrylic Polymers Water CAS# 78-51-3 % by Weight Exposure Limits Not available. Not available. TWA: 600 STEt.: 900 (mg/m') from OSHA (PEL) [United ' Stales] SKIN TWA: 606 STEL: 909 (m9/m') from ACGIH (TLV) [United States] SKIN Not available. Not available. Not available. Not available. LCSOILDSO ORAL' (LD50): Acute: 3000 mglkg [Rat]. DERMAL (LD50): Acute: 16000 mg/kg [Rabbit]. Not available. . ORAL (LD50): Acute: 511'9 mg/kg [Ratj. DERMAL (LD50): Acute: 9480 mglkg [Rabbit]. ORAL (LD50): Acute: 5540 to 9740 mg/kg [Rat]. ORAL (LD50): Acute: 1260 mglkg [Rat]. Not available. Not applicable. Routes of Entry 1-5 40861-29-8 34590-94-8 ' 1-5 1,5 111-90-0 1-5 122-99-6 1-5 7732-18-5 15-40 60-100 Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly'irritating to skin. Inhalation None known. Ingestion None known. Medical Conditions None known. Aggravated by,Overexposure: - See TQxicologicallnformation (section 11) ) Continued on Next Page Page: 1/4 7-2 "Or Jfjhn50n uiax PROFESSIONAL Date Received: Material Safety DatJANett t 2008 PLAZA PLUS Eye Contact , Skin Contact Inhalation Ingestion ( ~) ,Flush immediately with plenty of water. Get medical attention if irritation occurs. Flush imlT1ediately with plenty of water. Get medical attention if irritation" occurs. No specifi~ ~r~t aid measures are required. NO.5'pecific fir~t aid measures are required. Flammability oCthe Product Flash Points Products of Combustion Fire fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. None. None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Personal Precautions Environmental Precautions and Clean-up-Methods Put on appropriate personal protective equipment (see Section 8.). In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place"in suitable clean, dry containers for disposal by approved methods. Use a. water rinse for final clean-up. Handling Storage Avoid contact with skin and eyes. FOR INDUSTRIAL: USE ONLY. Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN, " ) Engineering Controls Personal Protection No spedal ventilation requirements. General room ventilation is adequate. Eyes No special requirements under normal use conditions. Hands No special requirements under normal use conditions. Respiratory No special requirements under normal use conditions. Feet No special requirements under normal use conditions. Body No special protective clothing is required. Physical State and Appearance Odor Color pH Specific Gravity Solubility in water Liquid. (Emulsion.) Mild. Ammoniacal. Milky-white. 8 to 8.6 [Basic,] 1.03 Dispersible. ) Continued on,Next Page. Page: 2/4 7-3 JohTl5onwiJX PROFESSIONAL PLAZA PLUS Date Received: Materlal:Safety Data Sheet 2008 Stability.and Reactivity Conditions ofIristability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization The product is stable. None known. Reactive with oxidizing agents. Urlginal Submitt< I When exposed to fire: Produces normal products of combustion. Will not occur. Acute toxicity Effects of Chronic Exposure Other Toxic Effects ORAL (L050) Greater than 5000 mglkg (rat). None known. None known. J Not available. Waste Information No special precautions. Dispose of according to all federal, state and local regulations. DOT Classification Not regulated )TDG Classification , Not regulated - Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal SARA 313 toxic chemica-I notification and release reporting: Diethylene Glycol Ethyl Ether, Tributoxyethyl Phosphate, Zinc Ammonium Carbonate, Clean Water Act (CWA) 307: Zinc Ammonium Carbonate CERCLA: Hazardous substances.: Diethylene Glycol Ethyl Ether, Tributoxyethyl Phosphate, Zinc Ammonium Carbonate State New Jersey spill list: Diethylene Glycol Ethyl Ether, Tributoxyethyl Phosphate, Zinc Ammonium Carbonate New Jersey: Diethylene Glycol Ethyl Ether, Tributoxyethyl Phosphate, Oipropylene Glycol Methyl Ether, Zinc Ammonium Carbonate Massachusetts spill list: Zinc Ammonium Carbonate Massachusetts RTK: Dipropylene Glycol Methyl Ether, Zinc Ammonium Carbonate Pennsylvania RTK: Diethylene Glycol Ethyl Ether, Tributoxyethyl Phosphate, DipropyJene Glycol Methyl Ether, Zinc Ammonium Carbonate This product is not subject to the reporting requirements under California's Pro'posiUon 65. Registered Product Not applicable. Information Canadian Regulations Canadian NPRI Canadian NPRI: Zinc Ammonium Carbonate WHMIS Classification Not controlled under WHMIS (Canada). WHMIS Icon @ I) Registered Product Not applicable. Inrormation Continued.on Next Page. Page:.314 7-4 johTl5on WiJX PROFESSIOlVAL Material Safety Data Sheet PLAZA PLUS Chemical Inventory Status All ingredients of this product are listed or are excluded fro'm listing on the U.S. Toxic Substances Control . Act (TSCA) Chemical Substance Inventory. , ) Other Special Considerations ,MSOS Serial Range: 012-013. Version 1.01 Nntirp to Rl'~rJe~ . This d(Jcumenf has been prepared using data from sources considered technically reliable. It does not constitute a warranty. express or implied, as to the accuracy of the information contained within. Actual conditions o/use and handling are beyond seller's control. 'User is responsible to evaluate all available information when using productfor any particular use and to comply with all Federal, State. Provincial and Local laws and regulations. Date Received:. jAN \ \ 1006 Original submlttal-- ) '. ]ohn!iou WiJX PR.OFESSIONAl ,.. . .:.:\ ) PRO-STRIP National Fire Protection Association (NFP A) Fire Hazard Health ~ Reactivity Specific Hazard Hazardous Material Information System (HMIS) 8-1 Date Received: " JAN 11 2008 Material Safety Data Sheet " . II Origipal Submittal I .. Protective Clothing ~~ ~~ Emergency Clear White to yellowish. Liquid. See ~ection 9. Overview OANGER. CORROSIVE. CAUSES EYE ANO SKIN BURNS. HARMFUL OR FATAL IF SWALLOWED. Product Name Product Use. PRO-STRIP Industrial/Institutional: Floor care. MSDS# 114156003 Code PMS# Validation Date U.s. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (8BB) 352-2249 MSDS Internet Addres:s: www.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga. Ontario L4Z 2G7 Phone: (905) 755-0913 or (BBB) 746-5971 Print Date I Supersedes In C:lI<O:P n~ Eme~p"encv 3700 413946 04~712000 , 0412712000 041i'912000. I (800) 851-7145 Ingredients CAS# % by Weight )Sodium Hydroxide 1310-73-2 1'5 Ethylene Glycol Phenyl Ether 122-99-6 1'5 Sodium Xylene Sulfonate 1300-72-7 1-5 Monoethanolamine 141-43-5 10-30 2-Butoxyethanol 111-76-2 10-30 Water 7732-18-5 30-60 Exposure Limits CEIL: 2 (mglm') from OSHA (PEL) [United States] STEL: 2 (mgim') from ACGIH (TL V) [United States] Not available. Not available. TWA: B STEL: 15 (mglm') from OSHA (PEL) [United States] TWA: 7.5 STEL: 15 (mglm') from ACGIH (TL V) [United States] TWA: 120 (mglm') from OSHA (PEL) [United States] TWA: 97 (mglm') from ACGIH (TLV) [United States] Not available. ~rLC501LD50 " Not avaHab'ie. I II ORAL (L050): Acute: 1260 mgikg [Ratj'. Not available. ORAL'<L050): Acute: 1720 mgikg"[Rat]: OERMAL (L050): Acute: 1018 mgikg [Rabbit]. ., ORAL (L050): .Acute: 506 mglkg [Rat]. OERMAL (L050): Acute: 406 mglkg [Rabbit]. . VAPOR (LC50): Acute: 450 ppm 4 hours [Rat]. ~i 'I Not available. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects. Eyes Corrosive. May cause permanent damage including blindness. Skin Corrosive. May cause permanent damage. Inhalation May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion Corrosive. May cause burns to mouth, throat, and stomach. _ Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, e'J,Physema, etc., may ,Aggravated by Overexposure: be more susceptible to irritating effects, II: , JSee Toxicological Information (section 11) t' Continued on Next Page . Page: 1/4 8-2 Date Received: john5on'wax PROFESSIONAL PRO-STRIP JAN 1 1 2008 Material Safety Data Sheet Eye Contact Skin Contact _ Inhalation Ingestion 'j Immediately flush eyes with running water for at least 15 minutes. keeping eyelids open. Get medical attention immediately. . Flush:'immediately with plenty of water for at least 15 minutes. Get medical attention immediately. If breathing is difficult: Remove to fresh air. Get medical attention immediately. Do not induce vomiting! Immediately drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Flammability of the Product Flash Points . Products of Combustion Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire and Explosion Hazards None kn.own. Not available. None.known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate' foam. Normal fire fighting procedure may be used. Put on appropriate personal protective equipment (see Section 8). Corrosive material (See sections 8 and 10). Personal Precautions Environmental Precautions and Clean-up Methods Put on appropriate personal protective equipment (see Section 8). . In the event of major spillage: Use'appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse'for final c1ean:up. - . '.. Handling Storage 'i j Avoid contact with eyes, skin. and clothing. Do not taste or swallow. Avoid,br~athirig vapors or spray mists. Wash thoroughly after handling. Remove and wash contaminated clothing and footwear before re-use. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handlinQ the empty container and residue. FOR INDUSTRIAL USE ONLY. Store in a ~ry, cool'and well-ventilated area: Protect from freezing. Keep container tightly closed. KEEP OUT OF REACH OF CHILOREN. Engineering Controls Personal Protection Good general ventilation should be sufficlemt to control airborne levels. Respiratory protection is not reQuired if Qood ventilation is maintained. Eyes Chemical splash goggles, Hands Ghemical re'sistant gloves. Incll!des: Neoprene gloves. Respiratory If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI 288,2 reauirements,must be followed whenever workplace conditions warrant a respirator's use. Feet Protective footwear. Body If major exposure is possible, wear suitable protective clothing and footwear. Physical State and Appearance Odor Color pH Specific Gravity Boiling/Condensation Point _ MeltingfFreezing Point liquid.' Mild. Clear White to yellowish. >13 [Basic.] 1.02 >82'C (179.60F) <DOC (320F) ) Continued on.Next Page: Page: 2/4 ;+' .Date Received: 8~3 john5on WiJX PROFESSIONAL PRO-STRIP Material 'Safety Data JAN 1 1 2008 _ ~ Solubility in water Complete. " " II Original Submit*1 Stability and Reactivity Conditions of r nstabilitv Incompatibility with Various Substances Hazardous Decomposition Products Hazardous ~olymerization The product is stable. None known. Reactive with.oxidizing agents, acids. II 'I II Toxic decomposition products include: Oxides of nitrogen. II . II Produces normal products of combustion. Will not occur. Acute toxicity Corrosive. . Effects of Chronic Exposure None known. Other Toxic Effects Not available. Waste Information Undiluted product is regulated under environmental and transportation laws as a corrosive waste. Dispose of according to all federal, state and local regulations. !: DOT Proper Shipping Name DOT Class VNINA Packing Group TOG Classification Corrosive liquid, basic, organic, n.o.s. (Monoethanolamine, Sodium hydroxide) Class 8: Corrosive material UN3267 II TOG Class PININIP Not applicable. Reporting in this section is based oit ingredients disclosed in Section 2 us Regulations Federal Clean Water Act (CWA) 311: Sodium Hydroxide ' CERCLA: Hazardous substances.: Sodium Hydroxide, 2-Butoxyethanol State New Jersey spill list; Sodium Hydroxide, 2-Butoxyethanol New Jersey: Monoethanolamine, Sodium Hydroxide, 2-Butoxyethanol Massachusetts spill list: Monoethanolamine, Sodium Hydroxide, 2-Butoxyethanol Massachusetts RTK: Monoethanolamine, Sodium Hydroxide, 2-Butoxyethanol Pennsylvania RTK: Monoethanolamine, Sodium Hydroxide, 2-Butoxyethanol This product is not subject to the reporting requirements under California's propositior 65. Registered. Product Not applicable. Information Canadian Regulations Canadian NPRI Not applicable. WHMIS Classification Not applicable. WHMIS Icon I Continued on NextPage !, Page: 3/4 8-4 john!ion uiiJX PROFESSIONAL. _ ~RO:STRIP Registered"ProduCt Not applicable. . Information Material Safety Data Sheet Chemical Inventory Status "All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Other Special Considerations Not available. Version Notice to Rf'llder This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied. as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using productfor any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Date Received: JAN 1 1 2008 Original submittF'1 ) , .I ) MATERIAL SAFElY DATA SHEET MANUFACTURED FOR: TRIPLE S Billertca, MA 01862 EMERGENCYTELEPHONE: 1-888-779-1339 SECTlDN 1 - PRODUCT NAME: Trtple S Product No: Product Type: SHOP CLEAN 13059,13060,13061 High Powered Degreaser ) SECTION 2 - HAZARDOUS INGREDIENTS 2-butoxyethanol CAS#111-76-2 1fv\%=6.0 Sodium Hydroxide CAS #131 0-73-2 \M'!o=1.24 SECTION 3 - HEALTH HAZARD & FIRST AID 1. Acute Health Effect Minimal 2. Chronic Health Effects Yes 3. Carcinogen No 4. prtmary Entry Routes: a) Skin & Eyes: 2-butoxyethanoi readily penetrates skin. Significant volume may result.in red blood ceiL destruction. .May.cause eye irritation. b) Ingestion: May be harmfuL c) Inhalation: Inhalation of vapor or mist may be irritating. 5. First Aid: a) Skin: Remove contaminated clothing-wash skin with soap and water. If irrttation persists get medical attention. b) Eyes: Wash eyes with large volumes of water for at least 15 min- utes while lifting the upper and lower eyelids and rotating the eye- ball. Get immediate medical attention. c) Ingestion: Give large volumes of water. Do not induce vomiting. Get medical attention. d) Inhalation: Move to fresh air. If symptoms persist seek medical attention. SECTION 4 - PHYSICAL & CHEMICAL CHARACTERISTICS 1. Physical State Liquid 2. Coior Dark Red 3. Odor Glycol ether 4. Solubility in water Complete 5. Specific Gravity (H20=1.O) 1.037 6.pH 13 7. Freezing Point N/A 8. Flash Point None (will not bum) 9. Vapor Pressure N/A SECTION 5 - FIRE AND EXPLOSION HAZARD 1. Flash Point None 2. Extinguishing Media N/A 3. Special Fire Flghling Procedures None 4: Unusual Fire & Explosion Hazard Fire fighters should observe all precautions that apply to any fire where chemicals are stored. Date Received: 9-1 JAN 1 1 2008 4rVl/01 1-800-323-2251 VI i~illi:li .;,uurrutlal HMIS HAZARD RATING HEALTH SALUD .FLAMMABILlTY INFLAMABILlOAD REACTIVITY REACTIVIDAD PERSONAL PROTECTION I B PROTECCION PERSONAL O-LEAST I MiNIMO 2 l-SlIGHT/LlGERO 2-MDOERATEJ MODERADO o 3-HIGH/SERIO 4-EXTREMEI o MUYGRAVE 8 - glasses Ilentes + gloves/guantes SECTION 6 - REACTIVITY DATA 1. Stability Stable 2. Conditions to Avoid None known SECTION 7 - SPILL OR LEAK PROCEDURES 1. If product leaks or spills - Flood area with water-mop up dispose to sanitary sewer. 2. Abide by Federal, State, and Locai regulations. SECTION 8 - PERSONAL PROTECTION 1. Wear goggles. 2. Wear rubber gloves. SECTION 9 - SPECIAL PRECAUTIONS 1. Store containers tightly closed and in an upright position. 2. Do not destroy or deface the label. SECTION 10 -SECTION 313 SUPPLIER NOTIFICATION (SARA) This product contains the following toxic chemicals subject to the reporting requirements of Section 313 ofthe Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372: 2-butoxyethanol CAS #111-76-2 1fv\%=6.0 SECTION 1.1- TOXICOLOGICAL INFORMATION None SECTION 12 - ECOLOGICAL INFORMATION None SECTION 13 - DISPOSAL CONSIDERATIONS 1 . See Section 7 above. SECTION 14 - DOTTRANSPORT INFORMATION 1. This product is Not Regulated. SECTION 15 - OTHER REGULATORY INFORMATION All ingredients appear on the TSCA Inventory List. SECTION 16 - OTHER INFORMATION 1. N/A = Not Applicable 2. PMCC = Pensky Martin Closed Cup The health hazards given on this Materiat Safety Data Sheet apply to this product In Its concentrated form (as supplied) and may differ significantly at use dilution. The signs and symptoms of overexposure apply only to negligence in handling or misuse of the concentrated product and not to the routine exposure of the diluted product under conditions of ordinary use. .1. '~'..' .." . ", , ....i John50n wax . PR.OfESSIONAl Date Received: 10-1 JAN 1 I 2008 \ -, , Material16f~ll1:g@j~!i1 SNAPBACK UHS RESTORER Fire Hazard Health ~ Reactivity Specific Hazard Protective None required. Emergency Blue. Opaque Emulsion. See Section 9. Clothing Overview ~VIJ7ir,~1jiffjr;;;f69Jj}?iQ.fjfctt'1l@rCg'f:n'PATff)}a:~*/ririii!tfjJiffl~~~~JJ",ir~'fIj.~~~~.l","1l!l.~_fi!ili ,~.~:~n~__._,3B'!_:;ffifi~_\iilliiklTJl1.1""\'"l-;W&I!iW,%",;.,;mk0&.;eJp1t.'$fij}\"*,%~",,,"_-""~~~4%Ttfu&L~,W:'",,"b1PB~?lL~~~.~~ Product Name SNAPBACK UHS RESTORER ICode . 4134 . Product Use Industrial/Institutional: Floor care. I PMS# 462012 MSDS# 114135009 Validation Date 0411912000 National Fire Protection Association (NFP A) Hazardous Material Information System (HMIS) U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East. Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Print I!ate Supersedes 'In Case of Rmerpen€;v 0411912000 041t2l2000. (800) 851-7145 Ingredients I CAS# 78-51-3 Not available. % by Weight Exposure Limits . Tributoxyethyl Phosphate ) ~ 1-5 ~ Not available..' ., TWA: 600 STEL: 900 (mglm') from OSHA (PEL) [United States] SKIN TWA: 606 STEL:.909 (mglm') from ACGIH (TL V) [United States] SKIN Not available. Not available. Oiethylene Glycol Ethyl Ether Oipropylene Glycol Methyl Ether 111-90'0 1-5 34590-94-8 1-5 Acrylic Polymers Water 7732-18-5 10-30 .60-100 LCSOILDSO ORAL (LD50): Acute: 3000 mglkg [Rat]. OERMAL (L050): Acute: 16000 mglkg'[Rabbit]. ORAL (L050): Acute: 5540 to 9740 mglkg [Rat]. ORAL (L050): Acute: 5119 mglkg [Rat]. OERMAL (L050): Acute: 9480 mglkg [Rabbit]. Not available. Not applicable. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes None known. Skin None known. {nha/ation None known. Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11) ) Continued on Next Page Page: 1/4 "', ; 10-2 Date Received: john5on WiJX PROFESSIONAL SNAPBACK UHS RESTORER Material Safety Data sJAN 1 1 2008 Eye Contact Skin Contact Inhalation Ingestion _Co) Rinse with plenty of running water. Rinse with plenty of running water. No.specific first- aid measures are required. No specific first aid measures are required. Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. CLOSED CUP: >93"C (199.4"F). None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Personal Precautions Environmental Precautions and Clean-up Methods Put on appropriate personal protective equipment (see Section 8.). In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-uj:? Handling Storage Use appropriate hygiene measures when handling product. FOR INOUSTRIAL USE ONLY Store in a dry, cool and well-ventilated ~rea. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. , ) Engineering Controls Personal Protection No special ventilation requirements. General room ventilation is adequate. Eyes No special protective clothing is required. Hands No special protective clothing is required. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body No special protective clothing is required. Physical State and Appearance Odor Color pH Specific Gravity Solubility in water Liquid. (Opaque Emulsion.) Mild. Citrus. Blue. 8.4 to 8.9 [Basic.] 1.02 Complete. ) Continued oncNext Page; , Page: 2/4 'I D~te Receivedto-3 :r~:I,j~\4. . ,., :~ Jt.N 1 1 2008 Material Safety Data Sheet john50i,wiJX . PROFESSIONAL. SNAPBACK UHS RESTORE~ Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous POlymerization The product is stable. None known. Not available. When exposed to fire: Produces normal products of combustion. Will not occur. Acute toxicity ORAL (L050) Estimated to be greater than 5000 mglkg (rat). Effects of Chronic Exposure None known. Other Toxic Effects Not available. Not available. Waste Information No special precautions. Dispose of according to all federal, state and local regulations. DOT Classification Not regulated .~ )TDG Classification , Not regutated Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal SARA 313 toxic chemical notification and release reporting: Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether CERCLA: Hazardous substances.: Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether State New Jersey spill list: Tributoxyethyl Phosphate, Diethylene Glycol Ethyl Ether New Jersey: Tributoxyethyl Phosphate, Dipropylene Glycol Methyl Ether, Diethylene Glycol Ethyl'Ether Massachusetts RTK: Dipropylene Glycol Methyl Ether Pennsylvania RTK: Tributoxyethyl Phosphate, Dipropylene Glycol Methyl Ether, Diethylene Glycol Ethyl Ether This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not a WHMIS controlled material. WHMIS Icon @ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. ) I Continued on Next Page Page: 3/4 10-4 Date Received: john5on WiJX PROFESSION/\L Material safJMta\ste~008 SNAPBACK UHS RESTORER Other Special Considerations Not available. Version ~t.,,"R"'llilpr This document has been prepared using da/alrom sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL User is responsible to evaluate all available information when using product/or any parlicu/ar use and /0 comply with all Federal, Slate, Provincial and Loco/laws and regulations. ) ) ~ 11-1 johu5on WiIX PROFESSiONAL :':(/(;;;;:,: Date Received: , ) Material Safety M 1>]~e.go08 . , SOIL RELEASE/BONNET BUFF Original. Submittal National Fire Protection Association (NFP A) Health Reactivity Hazardous Material Information System (HMIS) Fire Hazard Specific Hazard Protective None required. Clothing Emergency Clear Colorless. Liquid. See Section 9. Overview CAUTION: May be mildly irritating to eyes. May be mildly irritating to skin. Product Name Product Use SOIL RELEASE/BONNET BUFF Industrial/Institutional: Carpet care. 126325002 Code PMS# 3682 433335 04/1912000 0412012000 04/1212000. ("UU) "51-7145 MSDS# Validation Date V.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 . Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com , Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga.,Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) .746'5971 Print Date Supersedes In Case of Emerpcnev I Ingredients )Acrylic Polymers (NJTSR# .. 00897100-50217) Sodium Lauryl Sulfate CAS # % by Weight Expo'sure Limits LC50ILD50 1-5 Not available. Not available. 151-21-3 1-5 Not available. ORAL (L050): Acute: 1288 mglkg [Rat]. OUST (LC50): Acute: >3900 mg/m3 1 hours [Rat]. ORAL (L050): Acute: 5660 mglkg [Rat]. OERMAL (L050): Acute: 2700 mglkg [Rabbit]. Not available. Diethylene Glycol Butyl Ether 112-34-5 !).;10 Not available; Water 7732-18-5 60.100 Not available. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes May be mildly irritating 'to eyes. Skin May be mildly irritating to skin. Inhalation None known. lngestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section tl) } , Continued on 'Next Page Page: 1/4 11-2 john5on wax' PROFESS!l!NAL ~ ': " . o~' Received: M.~Jre~6~~\heet . SOIL RELEASE/BONNET BUFF Eye Contact Skin Contact Inhalation Ingestion Flusn immediately with plenty of water. Get medical attention if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No !,pecific first aid measures are required. No.specific first aid measures are required. Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. Not available. None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. None known. Personal Precautions Environmental Precautions and Clean~up Methods Put on appropria~epersonal protective equipment (see Section 8). In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep ar scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for finaJ clean-up. Handling Storage Avoid contact with skin and eyes. FOR INOUSTRIAL,USE ONLY. Store in a dry, caol and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHiLDREN. ) " "I Engineering Controls. Personal Protection No special ventilation requirements. General room ventilation is adequate. Eyes No special protective clothing is required. Hands No special protective clothing is required. Respiratory No special protective clothing is required. Feel No special protective clothing is required. Body Na special protective clothing is required. S;sr."''1S1};#'';''iiP;'W*'Jrtlf7*1ili\icli;,'!''Si';~i'';;S'@t\;",,~''e';iiq,~.l0+'';''~=Y:0j'&'r)$Jl90';*'1J:~->>8''''.M"r;m''''.''''';.,rs+r;1mml1fl;'' .,.y, ~~~IIIl';'~; "~ifl0k~~P~W4 ~;~.- ~0f0_'<""'''' ';n"w , Sectio '"9;!f'Jjys"q,aIana!c.hem}ca11f'{oeedl~l'A '10111 '-,}, '",.cl~"'Jjl ,c~r tilt' . ..r:. .' {,err . :", . v ,i!S ~ ' ,~'IE""''t$'YfYJ~~M;~_a."-,",';ffi,",,,;)%;;,~~Jii1;;;m?'W$,,~_~ftr~~M;ttlh!t:~~1lili,,,,. ,,",,,", 1%.'4;.' '10i&j"",/~.., ,0;,,' nSW~;;.." ,.;;;' *,J'~,'1i""'''_'.:r. -\0'S,,",...rilit,"'~4;;JJ~ Physical State and Liquid. Appearance Odor Color pH Specific Gravity Boiling/Condensation Poin~ Melting/Freezing Point Solubility in water Continued on Next Page Citrus. Clear Colorless. 7.5 to 8.5 [Basic.] 1.01 1000C (2120F) DoC (320F) Complete. Page: .214 Date Received: 11-3 ~"'l~~ john5on liiiJX PROFESSIONAL SOIL.RELEASE/BONNET BUFF Materia,,fftfNY j>ala!OO8 Stability and Reactivity Conditions of Instability Incompatibility with V Brinus Substances Hazardous Decomposition Products . Hazardous Polymerization The product is stable. None known. Not available. When exposed to fire: Produces normal products of combustion. WHlnot occur. ORAL (L050) Estimated to be greater than 5000 mglkg (rat). OERMAL (LD501 Estimated to be qreater than 2000 mqlkq (rat). Effects of Chronic' Exposure None ~,nown. Other Toxic Effects Not available; Acute toxicity Not available. Waste Information No special precautions. Dispose of according to all federal.. state a~d local ~eguJatio~s. DOT Classification " Not regulated , .,,'TDG Classification Not regulated Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal CERCLA: Hazardous substances.: Diethylene Glycol Butyl Ether State New Jersey spill list: Diethylene Glycol Butyl Ether New Jersey: Diethylene Glycol Butyl Ether Pennsylvania RTK: Diethylene Glycol Butyf Ether This product is not subject to the reporting requirements under California's. Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not controlled under WHMIS (Canada). WHMIS Icon @ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic'Substances Control Act (TSCA) Chemical Substance Inventory. Continued on NextF'agec Page: 3/4 1-1-4 I.. john5on WiJX PR.OFESSIONAL Material Safety Data Sheet SOIL RELEASE/BONNET BUFF ,. ..;.' -) Other Special Considerations , Version Not available. Nntil'P to Rp!l..lkr This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied. as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's controL User is responsible to evaluate all available information when using product/or any particular use and to comply with all Federal, State, Provincial and Local laws and regula/ions. ' Date Received: JAN 1 12008 Original Submittal ~ ) Date Received: 12-1 i~~;::;i' JAN 1 1 2008 johu5on WilX PROFESSIONAL ., -- ) M.ateriD~ySub01itlaJp' TANNIN STAIN REMOVER National Fire Protection Association (NFP A) Fire Hazard ~ Health ~ Reactivity Specific Hazard Hazardous Material Information System (HMIS) . Protective None required. Clothing Emergency Overview Clear Colorless. liquid. See Section 9. CAUTION: May be mildly irritating to eyes, May be mildly irritating to skin. U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 . Phone: (888) 352-2249 MSDS Internet Address: www.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 I Code PMS# I Validation Date I Print Date I Supersed~s 1" r"'lf> nf Emerp'cncv . 4253 436897 lit 712001 111712001 111012001. (BUU) B51-714b Product Name Product Use , MSDS# TANNIN STAIN REMOVER Industrial/Institutional: Carpet care. 126333004 Ingredients ')Sodium Xylene Sulfonate 01 Surfactant (NJTSR# 489909-5020-P-PC) Oiethylene Glycol Butyl Ether CAS # % by Weight Expos'ureLimits LC50ILD50 1300-72-7 1-5 Not available. 1-5 Not aV~lilable. Not available. Not available,. 112-34-5 1-5 . Not available. ORAL (L050): Acute: 5660 .mglkg [Rati. OERMAL (LD50): Acute: 2700 mglkg [Rabbit]. .oRAL (L050):" Acute:. 3000 mglkg (Rat]. . . Not available. Citric Acid 77-92-9 5-10 Not available. Water 7732-18-5 60-100 Not available. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly irritating to skin. Inhalation None known. Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11) Eye Contact Skin Contact Flush immediately with plenty of water. Get medical attef"!tion if irritation occurs. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. No specific first aid measures are required. Inhalation ingestion -' Continued on Next Page. Page: 114 12-2 -' johTl5on WiJX PROFES~/C!.N~L Date Received: TANNIN STAIN REMOVER ;" " Material Safety oa~~N"'l 1 2008 Flammability of the Product Flash Points Products of Combustion Fire Figbting Media and Instructions Special Remarks on Fire and Explosion Hazards' None known. None'; . :.'~)"6n~-known. , " r, Exiin'~lli.~ii'wi!h water spray or carbon dioxide, dry chemical powder or'appropriate foam. Normal fire fightin'g 'procedure maybe used. None known. Personal Precautions ,. Environmental Precautions and Clean-up Methods Put on appropriat~ personal p'roteCtive equipment (see Section 8). In the event of ~ajor spillage: Use appropriate containment to avoid environ'mental contamination. Sweep or scrape material. Place in suitable clean, dry containers for disposal by approved methods. Use a Storage Avoid contact with skin and eyes. FOR Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. ,'. .' - Engineering Controls Personal Protection N'o special ventilatiori"requifeinemts:General room ventilation is adequate. Eyes No ~pecial requirem~nts under normal use 'conditions'. Ha'nds No spedal requirements"under normal use conditions. ( ) . ' . . Respiratory No special requirements under normal use conditions. Feet No sped?!1 requirements under normal use conditions. Boay No speciai protective clothing is required. Physical State and Appearance Odor Color pH Specific Gravity MeltingfFreezing Point Solubility in water Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization < Liquid. Fruity. . Clear Colorless. 3 to 3.4 [Acidic.] 1.03 DoC (32"F) Complete. None known. Avoid mixing with: alkalis When exposed to fire: Produces normal products of combustion. Will not occur. Continued on NextPage Page: 2/4 12-3 .. ~l:'-'" ~."r joh1l5on WiJX PROFESSIONAL TANNIN STAIN REMOVER Material Safety Data Sheet Acute toxicity ORAL (LD50) Greater than 5000 mg/kg (rat). Effects of Chron!c Exposure None known. Other Toxic Effects None known. Not available. Waste Information No special precautions. Dispose of according to all federal, state and local regulations. DOT Classification DOT Proper Shipping Name DOT Class Consumer Commodity ORM-D TDG Classification IDG Proper Shipping Name mc Class Consumer Commodity ORM-O in this section is based. on ingredients disclosed in Section 2 Regulations ., .J Federal CERCLA Hazardous substances.: Diethylene Glycol Butyl Ether . , State New Jersey spill list: Diethylene Glycol Butyl Ether J New Jersey: Oiethylene Glycol Butyl Ether Pennsylvania RTK: Diethylene Glycol Butyl Ether This product is not subject to the reporting requirements u'nder California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not controlled under WHMIS (Canada). WHMIS Icon @ Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Date Received: JAN \ \ 2008 } Original submittal- i Continued on Next Page' Page: 314 12-4 john5on WiJX PROFESSIONAL Material Safety Data Sheet TANNIN STAIN REMOVER Other Special Considerations Not available. Version 1.02 NntiN' tn Rf'~d<< This document has been prepared using dalo from sources considered technically reliable. It does not constitute a warranty, express or implied; as to the accuracy a/the information contained within. Actual conditions of use and handling are beyond seller's control. User;s responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. ( ) \ ) '. rJ ,I }ohw:ion Wil}( PROF.ESSIONAL .., ~.' " ~ / ".)~-~" "'" VECTRA National Fire Protection Association (NFP A) Fire Hazard ~ Health ~ Reactivity Specific Hazard Hazardous Material Information System (HMIS) 13-1 Date Received: Material Saf~~altalsm Original Submittal Protective None required. Clothing Emergency Translucent. Opaque Emulsion. See Section 9. Overview CAUTION: May be mildly irritating 'to eyes. May be mildly irritating to skin. ' Product Name Product Use VECTRA Industrial/Institutional: Floor care. 114070010 MSDS# Code PMS# VaUdation Date Print Date Supersedes U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSDS Internet Address: www.jwp.~om Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Tn f":llIse of Fmentencv 4071 433046 1011212000 10/1212000 411912000. (~~u) .~51-7145 Ingredients '~ .J Tribuloxyethyl Phosphate CAS# 78-51-3 % by Weight 1-5 Oipropylene Glycol Methyl Ether 34590-94-8 1-5 Oiethylene Glycol Ethyl Ether 111-90-0 1-5 Zinc Ammonium Carbonate Acrylic Polymers Water 40861-29-8 1-5 10-30 60-100 7732-18-5 Exposure Limits Not available. TWA: 600 STEL: 900 (mglm') from OSHA (PEL) [United States] SKIN TWA: 606 STEL: 909 (mglm') from ACGIH (TLV) [United States] SKIN Not available. Not available. Not available. Not available. LC50ILD50 ORAL (L050): Acute: 3000 mgikg [Rat]. OERMAL (L050): Acute: 16000 mg/kg [Rabbit]. ORAL (L050): Acute: 5119 mgikg [Rat]. OERMAL (L050): Acute: 9480 mgikg [Rabbit]. ORAL (L050): Acute: 5540 to 9740 mglkg [Rat]. Not available. Not available. Not applicable. Routes of Entry Inhalation. Skin contact. Eye contact. Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin May be mildly irritating to skin. Inhalation None known. Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Tnformation (section 11) ) Continued on Next Page. Page: 114 13-2. john5on WiJX PROFESSIONAL Date Received: JAN 1 1 2008 Material Safety Data Sheet VECTRA Eye Contact Skin Contad Inhalation Ingestion -) Flush immediately with plenty of water. Get medical attention if irritation occurs. .Flustlimmediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. No speci~9, first aid measures are required. Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards None known. CLOSEO CUP: >930C (2000F). None known. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. fighting procedure may be used. None known. Normal fire Personal Precautions Environmental Precautions' and Dean-up Methods Put on aRpropriate personal protective equipment (see Section 8). In the event of major spillage: Use appropriate containment to avoid environmental conta'mination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Handling Storage Avoid contact with skin and eyes. FOR INOUSTRIAL USE ONLY. Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILOREN. ~ 'I j Engineering Controls Personal Protection .'No special ventilation requirements. General room ventilation is adequate. Eyes No special requirements under normal use conditions. Hands No special requirements under normal use conditions. Respiratory No special requirements under normal use conditions. Feet'No spedal requirements under normal use conditions. Body No speci~l protective clothing is required. Physical State and Appearance Odor Color pH Specific Gravity Solubility in water Liquid. (Emulsion.) Ammoniacal. Translucent. Opaque 8.5 to 9 [Basic.] 1.03 Dispersible. j Continued on Next Page' Page: 214 Date Received:_ 13-3 ., ., JAN 1 1 2008 Material Safety Data Sheet Original Submittal '. ~~"..vL joh1l5on WiJX PROFESSIONAL VECTRA Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization The product isstabJe. None known. None known. When exposed to fire: Produces normal products of combustion. Will not occur. Acute toxicity ORAL (LD50) Gieater than 5000 mglkg (iat). Effects of Chronic Exposure None known. _ Other Toxic-Effects ~None known. I .. Not available. Waste Information No special precautions. Dispose of according to all federal, state and local regulations. DOT Classification Not regulated J TDG Classification -, Not regulated ~~ ,l . Reporting in this section is based on ingredients disclosed in Section 2 us Regulations Federal SARA 313 toxic chemical notification and release reporting: Diethylene Glycol Ethyl Ether, Zinc Ammonium Carbonate Clean Water Act (CWA) 307: linc Ammonium Carbonate CERCLA: Hazardous substances.: Diethylene Glycol Ethyl Ether, Zinc Ammonium Carbonate State Ne'w Jersey spill list: Diethylene Glycol Ethyl Ether, Zinc Ammonium Carbonate New Jersey: Dipropylene Glycol Methyl Ether, Diethylene Glycol Ethyl Ether, Zinc Ammonium Carbonate Massachusetts spill list: Zinc Ammonium Carbonate Massachusetts RTK: Dipropylene Glycol Methyl Ether, Zinc Ammonium Carbonate Pennsylvania RTK: Oipropylene Glycol Methyl Ether, Diethylene Glycol Ethyl Ether, Zinc Ammonium Carbonate This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable, Information Canadian Regulations Canadian NPRI Canadian NPRI: Zinc Ammonium Carbonate. WHMIS Classification Not controlled under WHMIS (Canada), WHMIS Icon @ , { Registered Product Not applicable. Information , Continuedon.NextPage Page: 314 '. 13-4 john5on WiJX . .. ..... . PROFESSIONAL'.. VECTRA Material Safety Data Sheet Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Other Special Considerations MSDS Serial Range: 010-012. Version 1.01 Nntll'l' tn Rl'~de.I This document has been prepared using "data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the acc~racy of the' information contained within. Actual conditions of use and handling are beyond seller's controL User is responsible /0 evaluate all available information when using product/or any panicu/ar use and to comply with all Federal, State, Provincial and Loco/laws and regulations. Date Received: JAN 1 1 2008 Original Submittal_ ) ....,,.'",-';.-.,, " ".i."~~ Date Received: 14-1 JAN f I 2008 . JOhU50ii'wax PROFESSIONAL ~. 'i ~' ..~ . ' Material Sef/'itJIrRifaUHffiMal ---" J ~ RUST REMOVER Fire Hazard Healtb .~ Reaelt\ity Specific Hazard Protective ~1(;1!" ~ Emergency Clear Yellow. Liquid. See Section 9. Clotbing ~'-C;q;..::;.,.... .. - . ~;;g;..: Overview OANGER. CORROSIVE. CAUSES EYE ANO SKIN BURNS. = HARMFUL OR FA TAL IF SWALWWED. . .- T' ',.,-",.,-, '''';-,',-.'e'', .:_....'...--: .",..,.,.:~....,.. """,,"-",'""'Ii.f''-'''_'.-.'.~_''_:'''_''<'''_',,~;,''''.-,.- "'_, ,',:' ".. 1;'-,,,.._,..:.~.,,, ~ ...." .9<5:f!.fJf~rtL1;!c;h,~'!!!i:f1;{:RfJ?J!~f!~'J.!!;,qlJmp~n~.tft~~P!!P~,tiefl.. :/;.:', ,'.c. ProdnetName RUST REMOVER Code 3697 National Fire Protection Association (NFP A) Hazardous Material Information System (HMIS) earth\!;' ifJ#;.i ~ ..~"~- 'i~~ W.El::':,..,A-;;:Jr~_;ifl::_I' 'iI.~~~ .: """"" ,..' . '.t. ~.;. ~lfe !iazarg ).: f~i1 ~.:;t...:. . " . .' ","" n ~:I, 1M.- 3 o ilJ Reactivity MSDS# Industrial/Institutional: Carpet care. 126337001 PMS# 432311 04/1912000 0412012000 04/12/2000. (800) 851-7145 - Product Use Validation Date U.S. Headquarters Johnson Wax Professional 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 MSOS Internet Address: www.jwp.com Canadian Headquarters Johnson Wax Professional 100 Matheson Blvd. East, Suite 203 Mississauga, Ontario L4Z 2G7 Phone: (905) 755-0913 or (888) 746-5971 Priot Date Supersedes In Ca!ie of EmerPencv . Section 2, Composition and Information on Ingredients. /". --,' ."---. '.- ,.-. ".' --'-'. "..:' . . . ", . I Ingredients r CAS # Hydrochlartc Acid 17647-01-0 :.water 7732-18-5 % by Weight Exposure Limits I LCSOILDSO 5-10 60-100 Not available. Not available. I Not a~ailab!e. Not apolicable. '-:/ ~ectio.n 3,. Ifazards!!!.':r~;i;ifat@!,;. ... Routes of Entry Inhalation. Skin contact. Eye cOntact. Potential Acute Health Effects Eyes Corrosive. May cause pennanent damage including blindness. Skin Corrosive. May cause permanent damage. Inhahrtion May cause irritation and corrosive effects to nose, throat and respiratory tract. Ingestion Corrosive..May cause bums to mouth, throat, and stomach. Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may - Aggravated by Overexposure: be more susceptible to irritating effects. See Toxicological Information (section 11) ;;; siiCiio'n''4i "j=iiit 'Aid Meil~iJ'es' 'XC:;:,.. ',."C.,-,'" .~.'o ". .r..,', "-._.~. ~ye Contact Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open, Get medical attention immediatelv. - Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately. If breathing is difficult: Remove to fresh air. Get medical attention immediately. Do not induce vomiting! Immediately drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. ' Skin Contact Inhalation Ingestion Continued on Next Page Page: 1/4 14-2 jcih1l5onwiJX P1I.OITS5/0lVA! --..- . ...---... --- M. ,I Safety Data ~A~t 1 1 2008 , . RUST REMOVER Oria;nal Submilt~,_ Section 5..Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions L. __~~":.. Clotbing (Fire) Special Rem~rks on Fire and Explosion Hazards -'-'-) None known. Not available. None .krtOwn. Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting. procedure may be used. Put on'appropriate personal protective equipment (see Section 8.). Corrosive material (See sections 8 and 10). Section 6. Accidental Release Measures Personal Precautions Environmental Precautions and Clean-up Methods Put on appropriate personal protective-equipment (see Section B.). In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Section 7. Handling air", Storage ,. Handling Storage Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash thoroughly after handling. Remove and wash Contaminated clothing and footwear before. re-use'- Product residue mayx-emain on/in empty containers. Aflprecautions for handling the product must be used in handlinQ the empty container and residue. FOR INDUSTRIAL USE ONLY. Store in a dry, cool and well-ventilated area. Protect from freezing. Keep container tightly closed. KEEP OUT OF REACH OF CHILOREN. Engineering Controls ;'Section 8. Exposure ControlS/Personal Protection ",." . . ..--' .,; Good.general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if Qood ventilation is maintained. Personal Protection /.-- ~ 'I Eyes Chemical splash goggles. Hands Chemical resistant gloves. Includes: Neoprene gloves. Rubber gloves. Respiratory If mistslvapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 reauirements must be followed whenever workplace conditions warrant a respirator's use. ~ection,9.- Physical and .Ch~mical Properties. , ' ' . r Physical State and Uquid. Appearance . Odor Acrid. Color Clear Yellow. plI <1 [Acidic.] Specific Gravity 1.05 Solubility in water Complete. . Feet Protective footwear. -!lolly If major exposure is possible, wear suitable protective clothing and footwear. ....,' ',."!;. "~;'::,. ';'.:'", ;-".......- !L~~,~tt~[j 1,p". ~talJilitY!,ij~.B~~~!ivitY Stability and Reactivity The product isstable~ I Conditions of Instability IncompatibUity with Various Substances Hazardous Decomposition' Products . Hazardous Polymerization None kno'Wn. Avoid mixing with: Chlorine products. Mixing with other cleaning products may produce toxic gas." Ventilate if possible. When exposed to fire: May form an acid mist. Will not occur. 'I .' Continued on Next Page Page: 214 .' uate Kecelved: 14-3 john5on WiJX I'fUJFESSlONIU RUST t<EMOVER ". Material Safety Data sdAN 1 1 2008 " I' " Section 11. Toxicological Information .,~ .." , ,..."(~s.. .., -..~~..........l... 'I Acute toxicity ORAL (L050) Between 1000 and 2500 mglkg (rat). CorrosiveJ. j Effects of Chronic EIposure None known. _ Other Toxic Effects Not 8,,:ailable. Section 12. Ecological Information Not BvaDable. . Section 13. Disposal Considerations 'Waste Information Undiluted product is regulated under environmental and. transportation laws as a corrosive waste. Dispose of according to all federal, state and local regulations. JI . . Section 14. Transport Information DOT Classification DOT Proper Shipping Name DOT Class COf'!~umer Commodity ORM-O '" TDG Classification .';; TDG Proper Shipping Name TDG Class Consumer Commodity ORM-O ; Section 15. Regulatory Information ,,;.' " , Reporting in this section is based on ingredients disclosed in Section 2 .... ., US Regulations , .) Federal SARA 313 toxic chemical notification and release reporting: Hydrochloric Acid Clean Water Act (CWA) 311: Hydrochloric Acid Clean air act (CM) 112 accidental release prevention: Hydrochloric Acid CERCLA: Hazardous substances.: Hydrochloric Acid State New Jersey spill list: Hydrochloric Acid New Jersey: Hydrochloric Acid New Jersey toxic ........a<:>u uphe prevention act: Hydrochloric Acid Massachusetts RTK: Hydrochloric Acid Pennsylvania RTK: Hydrochloric Acid This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not appliCable.' 1! . Information Canadian Regulations WHMIS Classification CLASS 0-28: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid. WHMIS Icon <I)@ Registered Product Not applicable. Information I: JI All ingredients of this product are listed or are excluded from listing on the U.S. Toxicl'Substances Control Act (TSCA) Chemical Substance Inventory. II I Cbemical Inventory Status ) ) Continued on Next Page Page: 3/4 14-4 johTl5on WiJX PROFESSiON/U M, ~I Safety Data Sheet RUST REMOVER Section 16. Other Information Other Special ConsideratioDs Not available. ".~\ ,) Version Notll'P to Rp~uter This document has been prepared using data from sources considered. technically reliable. It does not constitute II wa;ranty, express or implied, as to the accuracy ojthe informadon contained within. Actual conditions of use and handling arc beyond seller's control. User is responsible to eva/uale 011 available informadon when using product for any particular use and to comply with all Federal, State, Provincial and Local laws . and regulations.. Date Received: JAN 1 12008 Original submit~1 , ) ( ) ) j ) -....' Date Received: 15-1 .>. ., JAN 1 1 2008 11 Original SJbmittaJ " " ,;. AMAZ Har~,Water ~tain Remover MATERIAL SAFETY DATA SHEET ============================================================================= d '. r:' .'J."l; ;" General Information ==============================================================7============== Company's Name: PACIFIC SUN MAKERS, Inc. :: Company's Street: 671 E1 Camino " Company's City: Sacramento Company's State: CA Company's Country: US Company's Zip Code: 95815 Company's Emerg Ph #: 916-921-6861 Company's Info Ph #: 800-921-6861 Date MSDS Prepared: 17 July 01 Preparer's Name: Roger Curry Preparer's Company: Nevada Ecotec Preparer's City: Reno P!eparer's State: NV HMIS Information: Health: 1 Flammability: 0 Reactive: 1 Protection: A Unit Of Issue: Various ~=~_~~~~_~=~~~~~_~::~~~:______________________________________1______________ -----------------------~~;~~~~~~~~/~~~~~~ t Y In~~~~~~~~~---- .11 ------------ ~~~~~=~====~~~~~~~=======~~-----===~~======~=~~~~~=~=~=----_.==~==~~=~~~~~~==~ Proprietary: NO Ingredient: SILICA,CRYSTALLINE QUARTZ Ingredient Sequence Number: 01 Percent: 60-70 NIOSH (RTECS) Number: VV7330000 CAS Number: 1408-60-7 OSHA PEL: 8 hr. time-weighted average limit as stated in 29 CFR 1910.1000 Table Z-l-A (for dry powder only)) ACGIH TLV: 0.1 MG/M3 (Respirable Crystalline Quartz) TSCA No. Crystalline Silica appears on the EPA TSA inventory under the CAS No. 1408-60-7 OSHA Carcinogen: Crystalline Silica not listed WHIMS Classification: 0-2A Other Recommended Limit: None Specified Proprietary: NO Ingredient: Naptha ,Petroleum ,Heavy Alky1ate Ingredient Sequence Number: 02 Percent: 5-10 NIOSH (RTECS) Number: Unavailable CAS Number: 84741-65-7 OSHA PEL: NOT ESTABLISHEO ACGIH TLV: NOT ESTABLISHED TSCA: This material is listed on the EPA/TSCA Inventory of Chemical Substances Other Recommended Limit: None Specified Proprietary: NO Ingredient: 9-0ctadecenoic Acid Ingredient Sequence Number: 03 Percent: 5-10 NIOSH (RTECS) Number: Unavailable 15-2 Date Received: CAS Number: 112-80-1 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHEO Other Recommended Limit: None Specified JAN 1 1 2008 ') Original Submittal ---------------------------------------~---------- Proprietary: NO Ingredient: Triethanolamine Ingredient Sequence Number: 04 Percent: 5-10 NIOSH (RTECS) Number: Unavaliable CAS Number: 000102-71-6 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABILSHED WHIMS Classification: 0-2B Other Recommended Limit: None Specified ============================================================================= physical/Chemical Characteristics ==============~============================================================== Appearance And Odor: GREEN PASTE WITH MILD LEMON OOOR Boiling Point: 2l50F,1020C Melting Point: less than 400F Vapor Pressure (MM Hg/70 F): -17.0 @ 200C Vapor Oensity (Air~l): N/A Specific Gravity: Unavailable Evaporation Rate And Ref: >1 (BUTYL ACETATE) Solubility In Water: Dispersable Percent Volatiles By Volume: 7-13 ) ============================================================================= Fire and Explosion Hazard Data ============================================================================= Flash Point: >200oF Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: C02, FOAM, DRY CHEMICALS. Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA & FULL. PROTECTIVE EQUIPMENT. Unusual Fire And Expl Hazrds: NONE; ============================================================================= Reactivity Data ======--~.._-- .-.---- ============================================================ Stability: YES Cond To Avoid (Stability): NONE SPECIFIEO Materials To Avoid: DO.NOT MIX WITH OTHER CHEMICALS Hazardous Oecomp Products: CO, WITH INCOMPLETE COMBUSTION. Hazardous Poly Occur: NO Conditions To Avoid (polymerization I : Not Relevant ============================================================================= Health Hazard Oata ============================================================================= Route Of Entry - Inhalation: NO Route Of Entry - Skin: NO Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACTUE: OEFATS SKIN; MAY IRRITATE EYES. PROLONGED EYE CONTACT MAY CAUSE EYE DAMAGE. CHRONIC: SAME AS ACUTE. ) I , " ) ) / 15-3 _, o. pate Received: JAN 1 1 2008 Carcinogenicity - NTP: YES (Silica Powder) Carcinogenicity - IARC: YES (Silica Powder) . ." b.tt I Carcinogenicity -.-OSHA: NO Ong1ral Su ml a Explanation Carcinogenicity: SILICA;CRYSTALLINE-QUARTZ:IARC MONOGRAPHS,SUPP.VOL 7,Pg 341 Signs/Symptoms Of Overexp: SEE HEALTH HAZARDOUS Med Cond Aggravated By Exp: SENSITIVE SKIN AND EYES. II Emergency/First Aid proc: INHALATION: REMOVE TO FRESH AIR. EYES: .FLUSH , THOROUGHLY WITH FRESH WATER, FOR AT LEAST 15 MINUTES. GET MEOICAL ATTENTION. SKIN: FLUSH WITH FRESH WATER, WASH WITH SOAP ANO WATER REMOVE CONTAMINATEO CLOTHES ANO SHOES. INGESTION: GIVE WATER, DO NOT INOUCE VOMITING. GET MEOICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN iI UNCONSCIOUS PERSON. :1 ~~==~~~~~~~====~~~~~====~~~===~~~~~==~==~=~~~=====~==~~~~=====I'I~~~=======~~== Precautions for Safe Handling and Use ===========================~==================================~============== Steps If MatI Released/Spill: WIPE UP SMALL AMOUNTS OR FLUSH TO ORAIN; COLLECT ANO RETURN LARGE AMOUNTS TO CONTAINER. II ,!I Neutralizing Agent: NONE SPECIFIED Waste Oisposal Method: OISPOSE OF AS A SANITARY WASTE. DISPOSAL MUST BE IN ACCOROANCE WITH FEOERAL,STATE&LOCAL REGULATIONS. Precautions-Handling/Storing: KEEP CONTAINER CLOSEO WHEN NOT IN USE. KEEP OUT OF THE REACH .OF CHILDREN. II Other Precautions: DOT CLASS: NOT REGULATEO. -- ----------- --------------------~-- ----~- - ---- ----------- ----- ------------------ , , ---============================= Ii Control Measures I' ==~~====~~=~~~~~===~~~=====~~~~===~====~~~~===~~~~~~~=~~===+===~~~~~~~~~~ Respiratory Protection: NONE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN. .. .. Ventilation: MECHANICAL NORMAL. AIR OILUTION. Protective Gloves: RUBBER OR CHEMICAL RESISTENT. Eye Protection: ANSI APPROVEO CHEM WORKERS GOGGLES. Other Protective Equipment: EYE WASH FOUNTAIN & OELUGE SHOWER WHICH MEET ANSI OESIGN CRITERIA (FP N) . Work Hygienic Practices: KEEP FOOD Suppl. Safety & Health Oata: WASTE ACCORDANCE WITH FEOERAL, STATE AND AWAY. WASH HANOS AND OISP METH: DISPOSAL LOCAL REGULATIONS. FACE BEFORE EATING. MUST BE IN ===================------===================================================== Transportation Data -----~================================================================== ==========~===========================================~================~===== Additional Information ===================~========================================================= Biodegradablility: Surfactants and wetting agents are biodegradable.May be disposed of as a sanity waste ,check with local authorities. ============================================================================= ". , Oisposal Oata =================-~------==================================================== See Above: Control Measures and Safe Handling Precautions 'I ~~=~~~~~~~=~~=~==========~~~===~==~=====~====~==========~==~~~i============== ~~======~~=~~=====~======~~~====::~::~~:::~~=====~====~~====~=J=~=~~~~~=----- Label Required: YES i ----- 15-4 Date Received: Label Status: G Common N~me"Mildly Alkaline, Abrasive Compound Chronic Hazard: NO Signal Word: CAUTION ! KEEP OUT OF THE REACH OF CHLIDREN Acute Health Slight: X Contact Hazard-Slight: X Fire Hazard-Slight: X Reactivity Hazard-None: X Special Hazard Precautions: ACTUE: DEFATS SKIN; MAY IRRITATE PROLONGED EYE CONTACT MAY CAUSE EYE DAMAGE. CHRONIC: SAME AS Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: AMAZ'HARP WATER STAIN REMOVER Label City: Sacramento Label State: CA Label Zip Code: 95815 Label Country: US Label Emergency Number: 916-921-6861 JAN 1 1 2008 ) Original Submittal EYES. ACUTE. Disclaimer =======:o;=:o;::=~========= -------.~ == --~--------========================================= To our actual knowledge,the information contained herein is accurate as of the date of this document.However,neither Nevada Ecotec or its affiliates or employees makes any warranty, expressed or implied, or accepts any liability in connection with this information or its use. This information is for use by technically skilled persons at their own discretion and risk and does not relate to the use of this material in combination with any other substance or process. This is not a license under any patent or proprietary right. The user alone must finally determine suitability of any information or material for any contemplated use, the manner of" .use and whether any patents or intellectual property rights are infringed. , ) . .~ .- 16-1 , . Page 1 of 4 Procter & Gamble Fabric and Home Care Division I Ivorydale Technical Center 5299 Spring Grove A venue Cincinnati,OH 45217-1087 Date Received: JAN 1 I 2008 priginal Submittal I MATERIAL SAFETY DATA SHE1iET !I Issue Date: 04/29102 '! Issue Date: 12/03101 II MSDS #: LDL 0004 Supersedes: LDL 0003 Identity: Liquid Hand Dishwashing Detergents Brands: DAWN (All Variations) IVORY (All Variations) JOY (All Variations) Hazard Rating: Health: [ Flammability: 0 Reactivity: 0 J, 4=EXTREME 3=HIGH 2= MODERATE l~SLIGin 'I ) Emergency Telephone Number: 24hr P&G Operator: DAWN-1-800-725-3296(DAWN) IVORY 1-800-253-2753 (IVORY) JOY - I -800-436-1569 (JOY) or call Local Poison Control Center or your physician .~~i!il!ll!!!:,IIIlJJlJll!"iik~"''''';.Il:'_~~'''''>'r''{'I1m,~~--'"c.....'W"''.''''-'''"~' . ~~~~j;\N~N,I).m:"ll!el..,Dm.i&' ''''1'_= _ Ingredients/Chemical Name: Cleaning and sudsing agents (anionic and nonionic surfaclonts); dispensing aid (ethyl alcohol), water,: stabilizing agents, colorant and'perfume. I ~ Dawn and Joy Antibacterial Hand Soaps also contain the antibacterial active Triclosan. Dawn Hand Care product contains a protease enzyme. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.[200. Chemical I Common I CAS No., Recommended Limits Name Name ' Ethy[ alcohol Ethano[ /64-17-5 Subtilisin Protease I 9014-0 I-I I NIIOSH STEL 0.00006 mglm3 ACGIH TLV: 1880 mglm3 Comnosition RaOlze ;' I, 1-6% I J,D501LC50 I I I I I I <om% Date Received: 16-2 LIQUID HAND D1SHWASHING DETERGENTS MSDS.(Continued) JAN 11 2008 Page 2 of4 ') Health Hazards (Acute aud Chronic): Ingestions: Ingestion may cause transient gastrointestinal irritation. Eye Contact May cause mild, transient irritation. Skin: Transient irritation with prolonged exposure to concentrated material. Signs and Symptoms of Exposure: Ingestion: May result in nausea, vomiting, and/or diarrhea. Eye Contact: May cause stinging, tearing, itching, swelling, and/or redness. Skin: Prolonged contact with concentrated material may be drying or transiently irritating to skin. Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 glasses of water. Eye Contact: Flush thoroughly with water for 15 minutes. Skin: If prolonged contact occurs, rinse thoroughly with water. If spilled on clothing, change clothes. If symptom,s persist or recur, seek medical attention. Other: Consumer product package has a voluntary avoid accidents statement. Flash Point (Method Used): 115-l35'F. Pensky- Explosive Limits: LEL: N/A UEL: NIA Martens (Closed cup) Extinguishing Media: C021 water or dry chemical. Special Fire Fighting Procedures: None. Although this product has a flash point below 200'F (closed cup), it is a >50% aqueous solution that doe~ not sustain combustion. DOT classification is non-hazardous. Unusual Fire Hazar:ds: None ) Stability Conditions to Avoid: None known Unstable: Stable: X Incompatibility (Materials to A void): None known Hazardous DecompositionlBy Products: None known Hazardous Polymerization: May Occur: Conditions to Avoid: None known Will Not Occur: X Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL REGULATIONS. Solutions of the detergents may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. Steps To Be Taken in Case Material is Released or Spilled: Prevent spills from reaching a waterway. Sorbents may be used. Read "Waste Disposal Method" below for further information. ) 2 Date Received: ~) '.-','\:.. . ',," ., j, JAN II 2008 '. LIQUID HAND D1SHW ASHING DETERGENTS MSDS (Continued) P~ge'i3 of 4 , - .' Or" i . 'i!I_~.7!~!!..!!";'lJ-'-'::~ 7...'4ll~."" 7M_.'''''-'!!j-l9'~'3!ff'-m-.iJ "'Zi,G.~>Z"....-M"'=..'.. .,_.77M"3'F.!'!.'llII'lil _.'~I~ ~~~~~~_M'7X~~!inm~~"l~~<:?~--. , ~ 5;.' "",.,"'WiS-\+Y1','~W Precautions To Be,Taken in Handling and-Storing: No unusual p;ecautions necess'ary. II Other Precautions: None known 16-3 II ""!l!lf:~~~,,7iinJT~Wn"'1lfE~OO~W'BEI 'Q"7""eil'sl"J!~~RR~m100a0'l~! ~Li1!l_'_iill!!.,,~g;ar=_"""_"fu,,_,~jUj'L~ifiR,._,"'.k_E.lt~!.>,J:!:ll;l"J!ll,.!llll..,.....,"_~.,,___ Respiratory Protection (Specify Type): None required with norma] use. II' Ventilation Local Eihaust: None required with nonnal consumer use. :; Specia!: None " Mechanical (General): Normallgeneral dilution ventilation is acceptable. !: Other:' None Eye Protection: None required with normal consumer use. :! Industrial Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Protective Gloves: None required with nOrD)a' use.. II Industrial Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Other Protective Equipment: None required with normal use. !I Vapor Pressure (mm Hg): N/A Vapor Density (Air=I): NIA Odor Threshold: N/A Coefficient of Water/Oil Distribution: N/A Scooped Density: NIA ,Appearance and Odor: Purple, Blue, Green. Yellow, Pink or Orange liquids. All products are perfumed. Specific Gravity (H20=I): ca. ] Percent Volatile by Volume Evaporation Rate (nBuOAc=I): Freezing Point: - 30 F pH (I % solution): - 8 Solubility in Water: Comp]etely" , Reserve Alkalinity: N/ A ) Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to A void: None Hazardous Decomposition Products: None known Other Recommendations: None LD50 (rats oral): approx]2 mL/kg ED50 approx 2.3 mL/kg Liquid hand dishwashing detergents bave a relatively low order of toxicity. They may be irritating, but they are not expected to be corrosive. They arc expected to be emetic. 3 Date Receivel~6_4 JAN 1 1 2008 . LIQUID HAND DISHW ASHlNG DETERGENTS MSDS (Continued) Page 4 of 4 I~!::!~=~~~?~~:~~!~~~i!!~~!~~_~.& ) Waste Disposal Method: Disposal is to be performed in compliance with Federal, state and local regulations. Household product is safe for disposal down the drain' during use or in the trash. . Industrial Setting: Solutions of diluted detergent in the course of use, may be allowed to be flushed down sewer. First check with your local water treatment plant. Recycling is recommended for undiluted scrap product. Do not landfill. All components are listed on the US TSCA No components are affected by Significant New Use Rules (SNURs) under TSCA 95. No compol}ents of Dawl1. Ivory or Joy are subject to California Proposition 65 labeling. All ingredients are CEPA approved for import to Canada by Procter & Gamble only. This product has been classified with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required by the Canadian Products Regulation. \ ) The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous w~en used in accordance. with proper safety practices and nonnal handling procedures. Data supplied is for use only in connection with occupational safety ~nd health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company's knowledge. The infonnation relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the. recipient or third persons. for any damage to any property resulting from misuse of the controlled oroduct. ' 4 CEDAR RAPIDS; IOWA 52405-0848 17-1 Date Received: u.s. Dep~rtlllent of labor .~~ O:~uPation~1 SafetY.and Heallh AdministraJ~f4 1 1 2008 <-..~ (I'on-Mandatory Form) For"; Approved OM B No. Q18-0072 Original Submittal I'JotQ: Blank :'PictU &rB no( perrnitfi-d. d ~y,f1em is not ;;.ppSc~(J. c..- no . 6lfonndOon i~ :l~/ab/8. tt;() ,spC!C9 mu~t ba mSl'ked fo ind:ca:o thijt 'I II Emergency Totephon. N"mber II U U - 5 53 -::! 13 1 . 319/363-3591 INIIOWA 800-33~-S204 T efephona ~'urnber for tn(otma!i~n ~ . SAME AS Ll~TED ABOVE I Dalo Prep<l.red 1r 10/1.5/86 EX::rENDED JANUARY 2005 I Sisnc.ture. of Ptep2ter (opt)'ofl.;9 Matefial Safety Data. Shee. , May b'e used lo comply wil" OSHA's Hazard Communicalio~ Standard, . . .29 CFA 1910.1200. Sland.,.d"n1uSI ba . ) consulled for s'p~.ific ~equjreme~t~. . lDE.NnTY IA< U<...d on I..;!xJ itnd Ust) \'II NODH I.IASH ING COMPRESSED DETERGENT TABLETS See lion f ., ~af'\\Jf;!.l::iu(e{'S Nama TUCKER. MANUFACTURING CO" INC. Acdll'::.s.s (Number, ..$lIeet,. C/:y, S18/e, and, ZlP Cod!!) 613 2N~ AVENUE S.E. Sec~ion " - Hazardous Ingredients/Identity Inlormation H~::rdou$ Corr.p?Mnls (S~j"c; ChemlC2J I~enlity: ea..nmon Ndm~:;;)) OS:-iA PEL ACGtH TLV Ot;)er UlT\ils Re-;ommsnded tl/o (cpffuna~ NONE. "\-- , \ ~...:-. -. .~ Sed/on III - Physical/Chemical Charac\erlsli~s Boir:r.g Pci'nt I Speelfie Gr<ilvity(H'zO - 1) .. N/A V2~ Prl!:.s.sUle. (mm Hg~l .1 Me:fllng Point N/A V.;<< Denoiry(AlFl ~ 1) I EVclp,ration RelIc N/A (E!vryf "",elat. - 1) NIp.. N/A N/A SollJbifi.ry In W.eter N/A N/A SecHon 1'1 - Fire and Explosion Hazerd Data Fl..., PoInl.lMe'Nd Use-d) N/A ~pe:atanclJ and Odor I Fl;;.mma~ifJ UmiLS N/A !"tEL N/A IlJEL N/A E..zUnglJishing Media N/A Spectal r1l'9 Fighting PIoc~ule:s N/A ". ;..... II .'1 '1 .11 i: II II I OSHA 174.,5....01; lfJ\,-'i', )u,suaJ flrB .and 8cplo.skln H:.zards . .. NONE' lflejlrodvca I~all)'). ."REPRODUCED LOCALL -.:':. 17-2 ... .~ " , . S.ectjan V - Reactivity Oar.." S\>b;r.ty / UnSl2hl. I. ro,nditio"" laA~.. ._ N/A ISlobl... ~ <. -_. Inc?mpatibillly 'Mar~n'J115 10 Avoi'" . H,.,.,dou> Deo:>m~, or S11'ro;vru --" . Date Received: JttN 1 12DOS ') ,. Original Submittal /-'l'ud.tdous l-"'IcIYr.1enution lAoy=ur I Conditio.1:3 10 Avold I N/A WIU toot O=ur Sec:lion VI - Health Haz.ord Data R"":~s) 01 En.ry: loh,"",ion? NlA He4/l1'1 Ha...22lCS (At:::i:e lU1d C/1.-::.-:;C) . NONE r -. SJ.:;ln? IRRrTATTO~ INDEX = 0 lr.geS'tiOtl? LD~O/KG. = 4.0 GM C2Jcinogenici:y: . NONE NTP? N/A. lARC r.f,onos,aph,? / __... N A OSHA P."l;Ulal.',n. N j A Si~ns and Symp:crr.,s 01 E:..p.::suro , .N/A' . I.~ec:icil CC!'Icitlons G2nef3T:y hs;r8va:ed by EYpos,-"a NONE Ei11e'S2rq c;n:j Fjrs1 AJd Prcc~1J(es .. I=VI= lINn/n.R SKIN. IRRITATTO'" "'.11<::... ~JTTH HATFR. r:ONTACT PHYSICIAN IF IRRITATlON.PERSISTS. IF INGESTED - CONTACT PHYSrCIAN.. .Section VIl - Precautions for Safe Handling and Use SI.eps 1Q Be Tar-en Tn C~a M~ledii"ls - Re!e35.c.d or Spined . . SWEEP UP MATERIALS INTO CONTAINERS AND DISPOSE_OF'PRO~ERL~. FLUSH AREA IH TH I'IATER Tn RFMOVE TRAtE MATERtALS AND. OTS.POSE OF PROPE.RLY I I Wa$te. Ojspos~J MelhOd PROPER DfsPOSAL METHOOS P:e<:.vti""S:CENJ'.'~piE~YfLg P~fc~tTlONS NECESSARY - KEEP CONTAINERS TIGHTLY CLOSED WITHIN AN APPROPRIATE STORAGE AREA. Cihet prCC~!l.rl!on3 N/A. SaJ;:lion VIII - cormoi Measures f1e3pntcry ?rott"C".ion (~ Typa; . N/A Ve.n1rr'btion I" Lc.cal Eih:.u~t N/A I Mec!:-:n'Ql (GfY,"}(t(:J1) Pro~edlye Glave~ . N/A O'~r Prote(."l;...e .-ClOttUng Of Equipin~~ . HAVE RUNNING HATER AVAILABLE. \VQr~Ybhi~nie Pr.3Clic'E'.3 'NORMAL/STANDARD HYGIENIC PRACTICES . Sped", O'.hor I Eyo profe<tion AVOID Eye-CONTACT ) .' P:age~ . fill usc.'o:\u.__(,.h..:\U/C.~l1" N/A - NOT_APPLICABLE Date Rec~ived: JAN 1 1 2008 Diesel. generator Se!ri9inalSUbmittal QSB7.series engine EPA emissions Description Cummins. Power Generation commercial generator sets are fully integrated power generation systems, providing optimum performance, reliability, and versatility for stationary power applications. (\ . Jp~C ......... .' '~ ~~ @ u.s. EPA Modol DSOAA DSGAB DSGAC This generator set is designed in facilities certified to 1809001 and manufactured in facilities certified to 1809001 or 1809002. The Prototype Test Support (PTS) program verifies the performance integrity of the generator set design. Cummins Power Generation products bearing the PTS symbol meet the prototype test requirements of NFPA 110 for Levell systems. All low voltage models are CSA certified to product class 4215-01. The generator set is available Usted to Ul220a. Stationary Engine Generator Assemblies. Engine certified to U.S. EPA Nonroad Source Emissions Standards, 40 CFR 89. Tier 3. I Standby rating 160 Hz 50 Hz 'l'w..J..kV.I1 IrWfk\/A\ 100 (125) 125 (1S6) 150(188) Prime rating 80 Hz 150 Hz IIrW MIA' kW fkVAl 90 (1131 113(1411 135(1691 (1');2006 ICummins Power Generation I Specifications Sobiect to Ctianga Without Notice Cummin!l and PowElfCommand are registered lrademarks 01 Cummins Inc, S.1544b (12106) Features Cummins heavy-duty engine. Rugged 4-cycle generator-drive diesel delivers reliable power, low emissions, and fast response to load changes. Alternator. Several alternator sizes offer selectable motor starting capability with low reactance 2/3 pitch windings; low waveform distortioniwith non-linear loads; fault clearing short-circuit capability. Permanent magnet generator. (PMG) (available on most models) - Offers enhanced motor starting and fault clearing short circuit capability. Control system. The PowerCommand"eiectronic control is standard equipment and provides total genset system integration, including automatic remote starting/stopping and precise frequency and voltage regulation, Optional features inclu:de alarm and status message display, output metering; auto-shutdown at fault detection, and NFPA 110 Level 1 compliance. Cooling system. Standard integral set-mounted radiator system, designed and tested for high ambient temperatures, simplifies facility design requirements for rejected heal. Fuel tanks. Dual wall sub-base fuel tanks are also offered. Warranty and service. Backed by a comprehensive warra,nty and worldwide distributor network. Continuo.... rating Data aheet. 60Hz .kl/l.1klI,A' I I I 50 Hz 'Yl.JklU' 60 Hz 50 Hz I D-3349 I D-3350 ID-3351 Generator set specifications Governor regulation class Voltage regulation, no load to full load Random voltage variation Frequency regulation Random frequency variation Radio frequency emissions compliance Engine specifications Desiqn Bore Stroke Displacement Cylinder block Battery capacity Battery charginq alternator Starting voltage Fuel system Fuel filter Air cleaner type Lube oil filter type(s) Standard cooling system Alternator specifications Design Stator Rotor Insulation system Standard temperature rise Exciter type Phase rotation Alternator coofinq AC waveform total harmonic distortion Telephone influence factor rrrF) Telephone harmonic factor (THF) Available voltages 60 Hz Three phase line-neutral/line.!ine . 110/190 . 115/230 Delta . 120/240 Delta . 110/220 . 120/208 . 1271220 . 115/200 . 139/240 . Note: Consult factory for other voltages. . 220/380 . 230/400 .2401416 Generator set options and accessories Engine o 120 V, 150 W lube oil heater o 1201240 V, 1500 W coolant heater Alternator o 1 050C rise alternator o 1250C rise alternator o 120 V, 100 W anti.condensation heater o Pt..1G excitation o Single phase Fuel System o 24 hour dual wall sub-base tank Date Received: JAN 1 I 2008 :tl% :to.5% Isochronous :to.25% 8rlgiAal Sllbmitt~l- 4 cycle, turbocharged and Charge air after-cooled 107 mm (4.21 in.) 124.0 mm (4.88 in.) 6.69 litres (408 in1 Cast iron, In~ljne, 6 cylinder 1100 amps minimum at ambient temperature of O~F to 32"F (-laDe to OOCl 100 amps 12 volt, negative ground Direct Inlection: number 2 diesel fuel Single element, 10 micron filtration, spinton fuel filter with water seoarator Dry replaceable element One spin-on, full flow filter High ambient radiator Brushless, 4 pole, revolvinQ field 2/3 pitch Single bearing, flexible disc Class H 1500 C standby @ 40 0 C ambient Torque match (shunt) standard, PMG optional A (UI. B M. C IWl Direct drive centrifugal blower fan < 5% no load to full linear load, <3% for any single harmonic <50 per NEMA MG1 -22.43 <3 . 255/440 ; 277/480 .347/600 60 Hz Single phase line-neutraVline-line . 110/220 . 115/230 . 120/240 Exhaust system o Heavy duty exhaust elbow o Slip on exhaust connection Generator set o Battery o Battery charger o Ul2200 Usted o Main line circuit breaker o PowerCommand Network Communications Module (NCM) o Remote annunciator panel o Spring isolators o 2 year prime power warranty o 2 year standby power warranty o 5 year basic power warranty * Note: Some options may not be a,vallable on all models. consult factory for availability. Our energy working for you. ™ Yl:,'i'.'~LUL!XlJ!iJ;iD;2Y-i.~~U;Qru <<:12006 I Cummins POW8f Generation I Specifications Subject to Change Without Notice Cummins and PowerCommand are registered trademark~ 01 Cummins Inc. 5-15440(12/06) c. Power Generation Control system Operator panel features PowerCommand Control. An integrated generator set control system providing voitage regulation, engine protection, generator protection, operator interface, and isochronous governing (optional), Control provides battery monitoring and testing features, and Smart-Starting control system. InPower PC-based service tool available for detailed diagnostics PCCNet RS485 network interlace (standard) to devices such as remote annunciator for NFPA 110 appiications. Control boards are potted for environmental protection. Suitable for operation in ambient temperatures from _ 40C to +70C, and altitudes to 13,000 feet (5000 meters) Prototype tested; UL, CSA, and CE compliant AC protection . Over current warning and shutdown o Over and under voltage shutdown o Over and under frequency shutdown o Over Excitation (loss of sensing) fault o Field Overload Engine protection o Overspeed shutdown . Low oil pressure warning and shutdown o High coolant temperature warning and shutdown . Low coolant level warning or shutdown . Low coolant temperature warning o High, low, & weak battery voltage warning o Fail to start (overcrank) shutdown o Fall to crank shutdown o Redundant start disconnect o Cranking lockout . Sensor failure indication . Low fuel level warning or shutdown . FueHn-rupture-basin warning or shutdown Operator/Display Panel o Manual off switch. o Alpha-numeric display with pushbutton access, for viewing engine and alternator data and providing setup, controls, and adjustments (English or international symbols) o LEO lamps indicating genset running, not in auto, common warning, common shutdown, manual run mode, remote start o Suitable for operation in ambient temperatures trom -20'C to + 70'C Alternator Data o Line to neutral AC volts o Line to line AC volts o 3-phase AC current o Frequency o Total kVA Our energy working for you. ™ 'iV,:Y.\'o'.l;t J I r,n!I!~ s r:'(i ';'i'~[ . ';~.21! I ................."...-.--..--..------......---...."....-......".....".- (\)20061 Cummins Power Generation I Specifications Subject to Change Without Notice Cummins and PowerCommand are registered trademarks 01 Cummins Inc. S-15-44b(12/06) , Date Received: JAN 1 12008 Standard control functions Original Submittal Engine Data o DC voltage . Lube oil pressure . Coolant temperature Other Data o Genset mOdel data o Start attempts, Starts, running hours o Fault history o RS485 Modbus interlace o Data logging and fault simulation (requires InPower service tool) Digital Governing (optionalj . Integrated digital ~Iectronjc isochronous governor . Temperature dynamic governing Digital Voltage Regulation o Integrated digital electronic voltage regulator . 2-phase Iin~ to line sensing o Configurable Torque Matching Control Functions . Time delay start and cool down o Glow plug control (some models) o Cycle cranking o PCCNat Interlace o (2) Configurable inputs o (2) Configurable outputs o Re",ote Emergency Stop Options o Auxiliary output relays (2) " 120/240 V, 100 W anti-condensation heater . Remote annunciator with (3) contigurable inputs and (4) configurable outputs PMG alternator excitation o PowerCommand for Windows. remote monitoring software. (direct connect) o Auxiliary, configurable signal inputs (8) and configurable relay outputs (8) o AC output analogue meters Standard PCC1302 control operator/display panel Optional AC output analog meters c. Power Generation _Date Received: JAN 1 1 2008 Ratings definitions Standby: Applicable for supplying emergency power for the duration of normal power interruption. No sustained overload capability is available for this rating.(Equivalent to Fuel Stop Power in accordance with IS03046, AS2789, DIN6271 and 8S5514). Nominaliy rated. Prime (unlimited running time): Applicable for supplying power in lieu of commercially purchased power. Prime power is the maximum power available at a variable load for an unlimited number of hours. A 10% overload capability is available for limited time. (Equivalent to Prime Power in accordance with IS08528 and Overload Power in accordance with IS03046, AS2789, DIN6271, and 8S5514). This rating is not applicable to all generator set models. Base load (continuous): Applicable for suppiying power continuously to a constant load up to the full output rating for unlimited hours. No sustained overload capability is available for this rating. Consult authorized distributor for rating, (Equivalent to Continuous Power in accordance with IS08528, IS03046. AS2789, DIN6271, and 8S5514). This rating is not applicable to all generator set models. Original Submittal [ Dlm.B" oj ~~ I ,-. Olm.C" . / /, , , ~I'~- I Dim "A- This outline drawing is to provide representative . configuration details for Model series only. See respective model data sheet for specific model outline drawing number. Do nDt us~ fo,. installatlDn d~s;"n I Dim "A" I Dim "B" I Dim "C" I Set weight' wet I Set. weight Vi/tank wet Model !"m~n.) ,mm1in,) mmlin.l kq llbst kllllbs\ DSGAA '.!l656 (104.61 11100143.3! 1549 1611 1160 (26021 1761 (3882) DSGAB 1 2656 1104.6) 11100 143.~ 11549161/ , 1225 (27001 1 1 B06 (39801 DSGAC I 2656 1104.61 11100 (43.31 I 1549 (61) 11263 (27841 11 B44 (40641 . Note: Weights represent a set with standard features. See outline drawings for weights of other configurations. Dim "'D" available only on models with sub-base fuel tank option. Cummins Power Generation 1400 73rd Avenue N.E. Minneapolis, MN 55432 USA Telephone:.1 (763) 574-5000 U5A Toll-free: 1-800-888-6626 Fax:.1 (763) 574-5298 Our energy working for you. TN '~"''.r',y..r:;!J..mr:ni!.~'iP.Q'..Y9..!.,"(,g!Jl c. Power Generation rD2006 I Cummins Power Generation I Specifications Subjeclto Change Wilhout Notice Cummins and PowarCommand are registered trademarks 01 Cummins Inc. S'1544b(12106) ;' I / " / / / , TABLE IV. STORAGE CODES Code TyoA of StorB;oe . A ~ Aboveground tank B . - Underground tank C - . Tank inside building 0 Steel drum E. ~ Plastic or non-metallic drum F Can G ~ Carboy H. Silo I Fiber drum J ~ Bag K Box L Crclinder -. . M ~ G ass bottles or jugs N ~ Plastic bottles or jugs 0 ~ latabin . . P Tarik wagon Q Railcar R ~ Other S Dewar TABLE V - TEMPERATURE AND PRESSURE CONDITIONS.. . AND STORAGE CODES Codes .Storaqe Condition~ 1 2 3 (PRESSURE) Normal pressure Greater than normal pressure . Less than normal pressure . (TEMPERATURE). . . Nonn~1 temperature. . . . Greater than normal'temperature - . Less than normaJ temperature but not cryo9.enlc Cryogenic conditions 4 5 6 7 EXAMPLE: Antifreeze in the 'main building is kept in a tank inside the building, at nonnaJ pressl,Jre and nonnal temp~rature. . ." . Table IV shoWS you that the code .for a" tank inside B- building is C. Table V shoWs you that ~e code for normal pressure i~.1 and the cod~ for nor:mal temperature is 4. You enter. ~ OJ -0 . TABLE VI"- HAZARD CLASSIFICATION CODES Code 1.1 1.2 1.3 1.4 1.5 2.1 2.2 2.3 3.1 3.2 3.3 4.1 4.? Code. Class 4.3 . Dangerous When Wet 4.4 Reactive Material 4.5 ,Combustible Materials 5~ 1 Oxidizers 5.2 Or~anic Peroxides 6.1 POisonous Materials 6.2 Etiologic Materials 6.3 Acute Health Hazard 6.4 Chronic Health Hazard 6.5 Pesticide 7.3 Radioactive Materials 8.0 Corrosives q.o Misc. Haz~ous Matenals Class Class A Explosives Class B Explosives Class C Explosives Blasting Agents Insensitive Explosives Aammable Gases . Nonflammable Gases Poison Gases . Flammable Uq.jFP less than O'F) Flammable Liq. FP between O'F & 73'1], Aammable Uq. FP between 730F & 141 F) Aammable Soli s . . ~nnl"!.t~eo-!!slv Co,!,:b!js~jble Mate,rial . Date Received: JAN 11 2008 Original submittFli Date Received: ".' " JAN 1 1 2008 COMMERCIAL LEASE AGREEMENT (NNN)Original Submittal This Agreement is made and entered into this 1st day of Qctoher. 2007 by and between .Hawes Investments LLC, ("Lessor") and Samnle Tennant LLC ("Lessee"). I. Oescrintion of Premises & Term of Lease. Lessor (eases to Lessee that certain space known as 400 International Way. Suite 100. S!lrinl'field OrelJon 97477 ("Premises") to be used, occupied, and operated as a general office as set forth in Paragraph 10, for an initial term of 60 months. commencing on .Tanuarv 1. 200!! and ending on Decem her 31. 2012. 1.1 Lessor agrees to use its best commercially reasonable efforts to deliver possession of the Premises to Lessee by the commencement date. If, despite said efforts, Lessor is unable to deliver possession as agreed, Lessor shall not be subject to any liability therefore, nor shall such a failure affeCt the validity of this Lease. Lessee shall not, however, be obligated to pay Rent or perform its other obligations until it receives possession of the Premises. If possession is not delivered within 30 days after the commencement date, Lessee may, at its option, by notice in writing within 10 days after end of such a 30 day period, cancel this Lease, in which event the Parties shall be discharged from all obligations hereunder. 2. Rental. Lessee shall pay to Lessor base rent for the initial 60 month lease term as follows: January 1, 2008-December 31, 2012 $2,500.00 The agreed upon leaseable space totals annroximatelv 1.200 square feet. "All:' rent shall be due and payable on the first day of each month commencing on .Tanuarv 1. 20011. 2.1 As additional rent, Lessee shall pay to Lessor $360.00 ($.30 !ler SQuare foot) as Lessee's initial share of common area maintenance el\penses ("CAM") until receipt of further notice of change from Lessor. CAM shall be due at the same time base rent is due. l 2.1.2 CAM charges shall include those costs incurred by Lessor in operating and maintaining the building and Premises not specifically attributable to anyone tenant, including the cost of HV AC maintenance, trash removal, maintaining the common areas and in keeping said areas clean and free of debris, snow removal, landscaping and irrigation, common lighting, maintaining all fire detection and suppression devices, utility costs including gas, water, electric, sewage and telephone service to service common areas, (real property taxes), management fees, building maintenance including painting, and exterior window cleaning and fire and casualty insurance covering the Premises and building attached to or appurtenant to the Premises. Annual increases to the expense pass-throughs for property management, accounting/legal, and reserves for replacement shall be capped at 4%. 2.1.3 Lessor shall deliver to Lessee within 90 days after the expiration of each calendar year a reasonably detailed statement showing Lessee's share of the actual CAMs incurred during the preceding year. If Lessee's payments during the preceding year exceed Lessee's share as indicated on such statement, Lessor shall refund the amount of such over-payment against Lessee's next month's CAM charges. If Lessee's payments during the preceding year were less than Lessee's share as indicated on such statement, Lessee shall pay to Lessor the amount of the deficiency within 15 days after delivery of Lessor's statement. 2.2 Upon execution of this lease, Lessee shall pay to Lessor the second month's rent and CAM charge together in the amount of $2,860 ($2,500.00+ $360.00 plus a security deposit of $2,500.00 for a total of $5,360.00. In the event Lessee subleases the space, Lessor reserves the right to require a security deposit as a condition of its approval. The security deposit may be used by Lessor to ensure Lessee's faithful performance of Lessee's obligations underthis.lease and to. 1- COMMERCIAL LEASE AGREEMENT! Initials I Lessor_/_ T P.SSf',f". Date Received: JAN 1 1 2008 , ., . '; .. Original Submittal 'remedy any lack of such performance, including without limitation, the payment of rent or CAM. If Lessor should use the security deposit, Lessee shall replace said deposit within 15 days of notice of such use from Lessor. If Tenant is not in default at the expiration or termination of this Lease, Landlord shall return the entire security deposit to Tenant. 3. Utilities. Lessee shall pay each Month as part of the CAM charges: All utilities as described in paragraph 2.1.2. 3.1 All other utility charges related to Lessee's occupation of the Premises and the operation of Lessee's business thereon shall be billed to Lessee by the utility companies or by Landlord to pay for those utilities on common meters. These common meters shall be billed to all tenants on the utility on a prorata basis by square footage of the Project. 3.2 Lessee shall at all times keep the Premises lien free and shall promptly pay when due all legitimate bills associated with Lessee's use of the Premises, including all bills arising out of the construction contemplated under paragraph 5 below and which are to be paid by Lessee thereunder. . 3.3 Lessee shall be responsible for all telephone, electronic data transmission, and security devices to and within the premises. If existing cabling in the premises can be utilized by the Lessee, Lessor will reasonably allow such use. 4. Renewal Ontion. If Lessee is not then in default, Lessee shall have the option to renew this Lease for One (1 \ additional term of sixtv (/iO\ months each, as follows: 4.1 The renewal option(s) may be exercised by written notice given by Lessee to Lessor not later than ninetv (90"\. days prior to the expiration of the then existing term. 4.2 Each renewal term shall commence upon the expiration of the then existing term and shall end 60 months thereafter; 4.3 The base rental rate shall be $2.08 per square foot per month for the first year of the first option and shall escalate by 3% (three percent) per square foot per month annually for each of the renewal years and terms. 4.4 Unless specifically provided herein, or hereafter agreed to by the parties in writing, all terms and conditions under the Lease for the renewal term shall be identical with those applicable during the original term. 5. Lessee ImnrovementsfFixtures/Alteration~. Lessee shall make the following improvements to the leased space at Lessee's sole cost: I. Turn office with the fireplace into a kitchen/conference room. These items will be located on the common bathroom/coffee bar wall. a. Add sink b. Add dishwasher c. Add counter space d. Add upper cabinets 2. Add counter space to windowed conference room to the left of the front door. 3. Add freestanding work areas to the windowed conference room to the left of the front door. 4. Change out doors to doors with windowed inserts. 5. Remove shelving in front of old receptionist's office. Possibly remove the glass front to that office and turn it into a solid wall so that it can be used as a regular office, with Landlord's approval,or insert windows in existing doors. 2- COMMERCIAL LEASE AGREEMENT Initials LessOf_/_ Ipc:::c;;:p.f". Date Recelvea: ~ JAN 11 2008 . Original Submittal 6. Be allowed to remove the glass partition that is now between the entry and conference room. Lessee shall agree to return the glass wall to its' original location and coridition at the termination of the lease, or pay the amount of $1,000 to Lessor in consideration of a wall replacement. . 7. Premises will be professionally cleaned, including carpeted areas and windows - inside and out. ' 8. All fixtures, outlets, window coverings, and exterior door locks will be in working condition. Lessee shall obtain Lessor's written approval of contractor, materials and design before proceeding with work. Any materials that are removed from premises and are reusable shall be stored at a predetermined location for Lessor's possible future use. If any costs are incurred in the storage of the materials, that cost shall be borne by Lessor. 5.1 Except as set forth in Section 32, Lessee shall not make any material changes, alterations, or additions to the Premises without the prior written consent of Lessor, which consent shall not unreasonably be withheld. Any alteration or improvement undertaken by Lessee shall be completed in a good and workmanlike manner and within the term of this Lease. 5.2 Fixtures, installed by Lessee that cannot be removed without doing material damages to the premises shall, upon the expiration of this Agreement, become the property of Lessor. Material damage is defined as any removal activity that would require cutting and patching of the floor, walls or ceiling. All other such fixtures installed by Lessee shall remain the property of Lessee and shall be removed within five days of the expiration of this Agreement. , 5.3 Lessor represents and warrants that aIr utilities now extended to the Premises, will at the start of this Lease, be in good and proper working order including HV AC, water, sewer, and" electrical systems. 6. Coml!liance with Laws. Lessee shall keep the Premises in a clean, sanitary condition during the lease and shall be at all times in conformity with applicable building and fire codes. Lessee shall fully and promptly comply with all federal, state, and local laws, statutes, rules, regulations, and ordinances applying to the operation of Lessee's business. Lessee shall not engage in any conduct or activity on the Premises which is contrary to the laws, rules, regulations, or ordinances of any governmental authority having jurisdiction over the Premises or Lessee's business conducted thereon. 7. Maintenance and Renair. 7.1 It shall be the responsibility of Lessor to maintain and repair the following items: The Premises' roof and gutters, exterior walls (including windows, paint or other appropriate covering), bearing walls, foundation, floors and common areas per Section 2.1.1. 7.2 It shall be the responsibility of Lessee to maintain and repair the following items: The Premise.s' interior walls, ceilings, doors, electrical fixtures and lights, interior plumbing from point of entry, all repairs necessitated by the negligence of Lessee or Lessee's invitees, and all other repairs to the Premises which are not the responsibility of Lessor. 8. Sigm. Lessee may post, at its sole cost and expense, one (1) building standard sign on the existing sign. Signage shall match the building signage standard and may include the business name and logo. All signage designs must be reviewed and approved by Lessor and meet all City of Bend signage requirements prior to construction and installation. Lessee shall receive a prorata share of the sign space according to the square footage of the project leased 3- COMMERCIAL LEASE AGREEMENT Initials Lessor_ 1_ J .P.~~P:P: Date Received: JAN 1 1 2008 (approximateIf31.58%) in the position of Lessor's choice. Lessee may also place a sign near their front en~rance, with Landlord's written approval of design. Original SUbmittal 9. Lessor's Access. Lessee shall allow Lessor reasonable access to the Premises for the purpose of inspection to assure Lessee's compliance with this Lease, to ascertain that the Premises are in good repair and in clean and sanitary condition and to show the Premises to prospective tenants. Lessor's access shall be during business hours or at such times as may be agreed upon by Lessor and Lessee. Lessor's entry shall be done in a manner which does not adversely affect Lessee's use or occupancy. Lessor may enter the premises in the event of emergency requiring the immediate protection of property or person(s) without notice and at anytime. 10. Use of the Premises. Lessee shall use and occupy the Premises as general office use, and for no other purpose without the prior written consent of Lessor. 11. Insurance. Lessee shall obtain and keep in force a Commercial General Liability policy of insurance protecting Lessee and Lessor as an additional insured against claims for bodily injury, personal injury and property damage based upon or arising out of the ownership, use, occupancy or maintenance of the Premises and all areas appurtenant thereto. Such insurance shall be on an occurrence basis providing single limit coverage in an amount not less than $1,000,000 per occurrence with an annual aggregate of not less than $2,000,000, an "Additional Insured-Managers or Lessors of Premises Endorsement" and contain the "Amendment of the Pollution Exclusion Endorsement" for damage caused by heat, smoke or fumes from a hostile fire. The policy shall not contain any intra-insured exclusions as between insured persons or organizations, but shall include coverage for liability assumed under ihis Lease as an "insured contract" for the performance of Lessee's indemnity obligations under this Lease. All insurance carried by Lessee shall be primary to and not contributory with any similar insurance carried by Lessor. . 11.1 Lessor shall at all times during this Lease keep and maintain a policy of fire and casualty insurance with an extended coverage endorsement, insuring the Premises and attached building against fire and other casualties in an amount of not less than the full replacement cost of the Premises, attached building and appurtenant premises. If the annual cost to Lessor for such property insurance exceeds the standard rates because of the nature of Lessee's operations, or as a result of any activity of Lessee, Lessee shall, upon receipt of appropriate invoices, reimburse Lessor for such increased cost. 11.2 Lessee shall obtain and keep in full force and effect all risk property insurance on all of Lessee's fixtures and personal property in the Premises for the full replacement cost thereof. Lessee shall use the proceeds from such insurance for the replacement of fixtures and personal property for the Premises. 11.3 Except as caused by Lessor, Lessee shall indemnify, protect, defend, and hold. harmless the Premises, Lessor and its agents and partners from and against any and all claims, loss of rents and/or damages, liens, judgments, penalties, attorneys' and consultants' fees, expenses and/or liabilities suffered directly or from a third-party claim arising out of, related to or caused by the use and/or occupancy of the Premises by the Lessee. If any action or proceeding is brought against Lessor by reason of any of the foregoing matters, Lessee shall upon notice defend the same at Lessee's expense by counsel reasonably satisfactory to Lessor and Lessor shall cooperate with Lessee in such defense. Lessor need not have first paid any such claim in order to be defended or indemnified. 4- COMMERCIAL LEASE AGREEMENT Initials Lessor_I_ I .f'..~!;:P.P. Date Received: . JAN 1 1 2008 . . 11.4 ~either party shall be li~ble to the other (or to the other's succesl!5li~iW8!1~lttal for any loss or damage caused by fire or any of the risks insured against under any Insurance policy required by this Lease, and in the event of insured loss, neither party's insurance company shall have a subrogated claim against the other. Each of Lessee and Lessor covenants that, to the fullest extent permitted by law and by their respective insurers, no insurer'shall hold any right of subrogation against the other. Lessee shall advise its insurers of the foregoing and request such waiver be permitted under any policies maintained by Lessee pursuant to this Section 11. 12. Liens; Ron(ls. Except for work completed pursuant to paragraph 5, Lessee shall pay, when due, all claims for labor or materials furnished or alleged to have been furnished to or for the Lessee at or for use on the Premises, which claims are or may be secured by any mechanic's or materialmen's lien against the Premises or any interest therein! Lessee shall give Lessor not less than 10 days notice prior to commencement of any work in, on or about the Premises. If Lessee shall contest the validity of any such lien, claim, or demand, then Lessee shall, at its sole expense defend and protect itself, Lessor and the Premises against the same and shall pay and satisfy any such adverse judgement that may be rendered there\ln before the enforcement thereof. If Lessor shall require, Lessee shall furnish a surety bond in an amount equal to 150% of the amount of such contested lien, claim, or demand, indemnifying Lessor against liability for the same. 13. Waste. Lessee will not commit or suffer any waste or strip of the Premises and shall at the expiration of the lease return the Premises to Lessor in substantially the same condition as when the contemplated tenant improvements are completed, in broom clean condition, subject to reasonable wear and tear. 14. rovenants nfLessee & Exclusion of Warranties. Lessee certifies that this Lease has been executed by Lessee on the basis of Lessee's own examination and personal knowledge of the Premises; that no representations have been made by Lessor or anyone on Lessor's behalf as to the condition or state ofrepair ofthe.Premises except as stated herein; that neither Lessor nor anyone on Lessor's behalf has made any promise or agreement to alter, repair, or improve the Premises, except as specifically set forth herein. 15. Condemnation. Condemnation shall mean any taking of any "interest in the Premises by right of eminent domain or any purchase of any such interestin lieu of condemnation. Lessor shall promptly notify Lessee of any notice of taking by any authority. 15.1 In the event the whole of the Premises is taken by condemnation or such portion of the Premises so as to make the Premises unsuitable for its primary intended use as stated herein, then this lease shall terminate as of the date title to the demised Premises vests in the condemning authority. In the event only a portion of the Premises are taken such that the space is not unsuitable for the intended use contemplated herein, this Lease shall terminate as to the portion of the Premises taken, and Lessor, at Lessor's expense, shall promptly restore the remaining portion of the Premises to a self-contained architectural unit reasonably suitable for Lessee's use. 15.2 Lessor and Lessee shall each be entitled to receive the proceeds resulting from any condemnation as is ascribed to it in such proceeding or as is agreed to by the condemning authority, Lessor and Lessee. 16. Default. Occurrence of any of the following shall constitute a default: (a) Lessee's failure to pay any rent or other charge required hereunder within 10 (ten) days after it falls due; (b) Failure to cure a default relative to the required insurance coverage within fifteen (15) days after written notice has been given by the non-defaulting party spec:ifically informing the defaulting party of the nature of the default; or (c) failure of either party to comply with any 5- COMMERCIAL LEASE AGREEMENT Initials Lessor_ /_ T .f"..~.t:.P.p. Date Received: JAN 1 1 2008 termorco~dlt;8.n or fulfill any obligation of this Lease (other than the paymQftmi'%~ittal maintenance of insurance) within thirty (30) days after written notice has been given by the non- . defaulting party to the defaulting party specifying the nature of the default with reasonable particularity. If the default is of such a nature that it cannot be completely remedied within such thirty (30) day period, this provision shall be complied with if the defaulting party begins correction of the default within said period and thereafter proceeds with reasonable diligence and in good faith to effect the remedy as soon as practicable. 16.1 Penalties for Late Payment. If Lessee fails to make timely rental payments, the Lessor reserves the right to assess a late fee of $200.00 and 1.5%/month interest on any unpaid balance. 17. Remedies. In the event of a material default by Lessee, Lessor may immediately or at any time thereafter while said neglect or default continues, without further notice or demand, terminate this Lease and enter into and upon the Premises, or any part thereof in the name of the whole, and restore the same to its former estate without prejudice to any right or remedy which may be available to Lessor for arrears in rent or breach of contract. The preceding sentence is not a limitation on nor shall it preclude either party from any other remedy which may be available at law or in equity, including damages for a party's breach. 18. Termination (Jnon Lessee's Bankruotcy. In the event that Lessee becomes insolvent, a receiver is appointed to take charge of the affairs and property of Lessee, or if Lessee makes a voluntary assignment for the benefit of creditors, files a voluntary petition in bankruptcy, or is the subject of an involuntary petition in bankruptcy which is not dismissed within ninety (90) days, this Lease shall immediately terminate. 19. Dama~e to or Destruction of Premises.. The following shall apply if the Premises are damaged or destroyed during the initial or any renewal term of this Lease: 19.1 Dama~. If the leased Premises are partly damaged and paragraph 19.2 below does not apply, the Premises shall be repaired by Lessor at Lessor's expense. If damage is caused by Lessee, Lessee shall reimburse Lessor for all costs of repairs. Repairs shall be accomplished with all reasonable dispatch, subject to interruptions and delays resulting from labor disputes or other occurrences beyond the control of Lessor, and all repairs shall be performed in a good and workmanlike manner in compliance with all applicable building codes and other regulations of any governmental unit having jurisdiction. 19.2 Destruction. If the leased premises are destroyed or damaged to the extent that the cost of repair exceeds forty percent (40.0%) of the value of the cost of the Premises before the damage, either party may elect to terminate this Lease as of the date of the damage or destruction by notice given to the other in writing not more than thirty (30) days following the date of damage. In the event that such notice is given, all rights and obligations of the parties shall cease as of the date of termination, and Lessee shall be entitled to reimbursement of any prepaid amounts paid by Lessee. If neither party elects to terminate, Lessor shall proceed with all reasonable dispatch to restore the leased Premises to substantially the same form and condition as prior to the damage or destruction. Work shall be commenced as soon as reasonably possible, and thereafter shall proceed without interruption except for work stoppages resulting from labor disputes or other occurrences not under the control of Lessor. 19.3 Rent Abatement. Rent shall be abated during the repair of any damage which renders the Premises untenable, except that there shall be no rent abatement where the damage occurred as the result of the fault of Lessee. 6- COMMERCIAL LEASE AGREEMENT Initials Lessor_I_ T .P:~_<;:P:f': Date Received: JAN 1 1 2008 ,. . 20.. Ha7..ardous Material. Lessor represents and warrants that to theQ)rigioalIStsbDnlttat knowledge no storage, treatment, leakage, or spillage of any hazardous material has occurred on L the Premises. Hazardous material as used herein means any substance listed in the Hazardous - Material Table, 49 CFR 172.10 or as hazardous under 40 FR part 302. In the event hazardous materials have been leaked, spilled, released, discharged or disposed ("Discharged") upon the Premises, such that environmental remediation of such is required, Lessee at Lessee's option, may terminate this lease, so long as the said discharge was not caused or materially contributed to by Lessee. Each party shall indemnify, defend, and hold harmless the other from any and all claims, judgments, damages, penalties, fines, costs, liabilities, or losses, including, without limitation, diminution in value of the Premises, damages for the loss or reconstruction of rentable or usable space or of any amenity on the Premises, damages arising from any adverse impact on marketing of the space, and sums paid in settlement of claims, damage to business, attorney's fees, consultant fees, and expert fees, which arise during or after the lease term as a result of contamination by hazardous material or as a result of Lessee's use or activities, or of Lessee's agentsorcontractors. This indemnification includes,without limitation, costs incurred in __I connection with any investigation of site conditions or any cleanup, remediation,J:e.mQY.~L_or I restoration..worbeq!ljJ.e(LbY._<!QY_f~deral, state, O!jQS!!Lgo.v~lfieri.!ii.1 agency or political subdivision because of hazardous riiaieriiirjireSent in the soil or grolliio water on or under the__ Premises. Without limiting the foregoing, if the presence of any hazardous material on the Premises caused or permitted results in any contamination of the Premises, the party causing such shall promptly return premises to the condition existing prior to the release of any such hazardous material. The foregoing indemnity shall survive the expiration or termination of this lease. 21. Parkin~. Lessee shall have the use of the parking spaces adjacent to its Premises on the upper level parking lot and a prorata share of all parking spaces in the Project. Vehicle parking spaces are all considered unreserved and in common. 21.1 Lessee shall not permit or allow any vehicles that belong to or are controlled by Lessee or Lessee's employees, suppliers, shippers, customers, contractors or invitees to be loaded, unloaded, or parked in areas other than those designated by Lessor for such activities. Lessee shall not service or store any vehicles in the common parking areas. If Lessee permits or allows any of the prohibited activities described above, then Lessor shall have the right, without notice, to remove or tow away the vehicle involved and charge the cost to the Lessee. 22. Rules and Rel!ulations, Lessee will comply with the Rules and Regulations of the Building adopted by Lessor that are set forth in Exhibit C attached hereto. Lessor shall have the right at all times to change and amend the Rules and Regulations in any manner as may be deemed advisable by Lessor for the safety, care, cleanliness, preservation of good order, and operationof use of the Premises or the Building. 23. Strict Performance. Non-waiver Lessor's acceptance of any late or partial payment hereunder, or either party's failure in any other respect or to insist on strict and prompt performance of any of the other party's covenants, agreements, or obligations herein contained, or any other leniency on the part of either party as to the terms or provisions of this Lease, shall not be deemed or construed to be, and shall not constitute, a waiver of any subsequent default, non-compliance, or failure of performance by the other party. 24. Time of Essenc... Time is of the essence with respect to the performance of all obligations to be performed or observed by the Parties under this Lease. , 25. Succession and Assil'nm..nt~ This Lease and the parties' rights hereunder shall be binding upon and inure to the benefit of the parties and their respective heirs, legal representatives, successors, and assigns. Lessee shall not assign this Lease nor Lessee's rights or 7- COMMERCIAL LEASE AGREEMENT. Initials Lessor_I_ T .f':$.<;;:P.P. Date Received: JAN 1 1 2008 d . . h . d. . h h .. f L h. h ()riainalSubmittal utIes ereun er WIt out t e pnor wntten consent 0 essor, w IC consenrsnall no1 be unreasonably withheld. The relationship between Lessee and independent contractors working for Lessee shall not be considered a sublease or assignment. Lessee and Lessor shall share equally in any excess consideration received. . 26. ComQlete Agreement. This document contains the entire, final, and complete agreement of the parties and supersedes all other representations, discussions, negotiations, understandings, and agreements, whether oral or written, heretofore made or existing between the parties or their representatives as to the Premises. 27. No PartnershiQ. Lessor is not by virtue of this Lease Agreement or any provision hereof a partner or joint venture with Lessee and shall have no obligation with respect to Lessee's debts or other liabilities, and no interest in Lessee's profits. 28. Notices. Any notice under this Agreement shall be faxed or in writing and shall be effective when actually delivered to the addressee or 96 hours after it is deposited in the United States mail, registered or certified receipt requested, with postage prepaid, addressed to the appropriate party at that party's address set forth below,or at such other address as either party may designate by written notice to the other. Lessor: Hawes Investments. LLC P.O. Box 7548 Eue-ene. Oree-on 97401 Fax: 541-335-21-30 Attention: Scott Penrod Lessee: Samnle Tennant LLC 400 International Wav Suite 100 Eue-ene. Oree-on 97477 29. Attornev's Renresentatioq. The parties acknowledge that each party has had a part in the drafting of this Agreement and the opportunity, if so desired, to consult with their respective attorneys before signing this Lease. As such, this Lease may not in any way be construed against either party as drafter in the event of ambiguity. 30. HolrliDl! Over. In the event Lessee holds over after the term of this Lease, including the two renewal periods, then Lessee shall remain bound by all terms, conditions, and covenants of this Lease, except that the holding over shall be construed to create a tenancy from month to month, and the rental shall be equal to 120% of the monthly rental payable by Lessee unto Lessor during the term of the this lease. As an unassignable concession to Lessee, after the initial term, the hold over base rent shall be the same as that at the end of the original term for the first three (3) months and then 115% of that at the end of the original term for the next three (3) months. 31. T ,atent Defect.s. Lessor, at its sole cost and expense, shall repair any latent defect of any structural element of the Building that is discovered during the Lease Term. Structural elements consist of all footings, foundations, floor slabs, columns, girders, load bearing interior or exterior walls. 32. Alterations to the PremisesfRestoration. After Lessee takes occupancy, Lessee shall have the right to make non-structural improvements to the premises costing less than $5,000 without first obtaining Lessor's consent provided: 32.1 Lessee shall provide Lessor with plans and notify Lessor thirty (30) days prior to commencement of tenant improvements. 8- COMMERCIAL LEASE AGREEMENT Initials Lessor_I_ T .p._~~p.p. I. Date Received: JAN 1 1 2008 32.2 Lessee indemnifies and holds Lessor harmless. .. I submittal 32.3 Lessor has the opportunity to post notices of non-responsibil~~gma . 32.4 Lessee agrees to restore the Premises to its original condition unless Lessor gives written consent to the contrary. I 32.5 Lessee gets all necessary permits and ~pprovals. 33. Non.Disturhance Apreement. Lessor will use its best efforts to obtain for Lessee non~disturbance agreements from any present or future mortgagee or holders of other superior interests, if any, at the time of lease execution. Lessee's duty to subordinate its right under the lease and attorn to such mortgagee or holder shall be expressly conditioned upon Lessee's receipt of a non-disturbance agreement. 34. Rstonnels. Either party will within twenty (20) days after notice from the other execute, acknowledge and deliver to the other party a certificate certifying whether or not this Lease has been modified and is in full force and effect; whether there are any modifications or alleged breaches by the other party; the date to which rent has been paid in advance, and the amount of any security deposit, prepaid rent, or lease consideration; and any other facts that may reasonably be requested. Failure to deliver the certificate within the specified time shall be conclusive upon the party of whom the certificate was requested that the Lease is in full force and effect and has not been modified except as may be represented by the party requesting the certificate. If requested by the holder of any encumbrance, or any ground Lessor, Lessee will agree to give such holder or Lessee notice of and an opportunity to cure any default by Lessee under this Lease. 35. Arhitration, If any dispute arises between the Parties regarding the Lease, such will be subject to arbitration at the request of either Party. Unless a different method of arbitration is agreed to by the Parties, arbitration will be conducted in accordance with the rules of the Arbitration Service of Portland and will be held in Deschutes County, Oregon. An arbitrator will be selected by mutual agreement of the~ Parties, or if the Parties cannot agree, Lessor will submit a list of three (3) arbitrators to the 'Lessee, who will choose one of the three. If Lessor fails to forward a list 0 f arbitrators to Lessee, of if Lessee fails to select an arbitrator within ten (10) days of receipt of such list, the Party not failing to do so will be entitled to select an arbitrator. 36. Attornev Fees. In the event that action is instituted to enforce this Lease or any provision of it, to determine the parties rights or responsibilities hereunder, to collect rents due from Lessee hereunder, or otherwise arising directly or indirectly from this Lease, the prevailing party in such action shall recover the prevailing party's attorney fees from the losing party, in addition to costs and disbursements, in the trial and any appellate court in which such action, or any issue therein, is tried, heard, or decided. 37. Numher. (;en!ler and Cautions. In construing this instrument and where the context requires, the singular includes the singular and plural, the masculine and neuter each include the masculine, feminine, and neuter, and all grammatical changes shall be implied to make the provisions hereof apply equally to corporations and to individuals. Captions have been inserted solely for convenience of reference, but are not a part of this Agreement and do not limit the scope nor in any respect modify the meaning of the paragraph or section to which each refers. 38. (;overninl'Law. All matters with respect to this Agreement, including but not limited to matters of validity, construction, effect, and performance, will be governed by the laws of the State of Oregon applicable to contracts made and to be performed therein between residents thereof. All disputes concerning this Agreement shall be heard in Deschutes County. Attached Exhibits: 9- COMMERCIAL LEASE AGREEMENT .j , Initials Lessor_ /_ I ,P5~~f>:P. 'J , Date Received: JAN 1 1 2008 Exhibit A- Rules and Regulations Exhibit B- Guaranty Original Submittal IN WITNESS WHEREOF the parties have executed this Lease at Bend, Deschutes County, Oregon on the day and year first set forth above. LESSOR: Hawes Investments I J 'C: LESSEE: Samnle Tennant T J.c: By: By: Jospeh R. Hawes, Member Bill Business, Member 10- COMMERCIAL LEASE AGREEMENT Initials LessDr_ /_ 1.p..c;:.c::p.P. , J Date Received: .... .'. JAN 1 1 2008 EXHIBIT A' Original Submittal RULES & REGULATIONS 1. Lessee shall not suffer or pennit the obstruction of any Common Areas, including driveways, walkways or stairways. 2. Lessor reserves the right to refuse access to any persons Lessor in good faith judges to be a threat to the safety and reputation of the premises and its occupants. 3. Lessee shall not make or permit any noise or odors that annoy or interfere with other lessees or persons having business within the premises. 4. Lessee shall not keep animals or birds within the premises, and shall not bring bicycles, motorcycles or other vehicles into areas not designated as authorized as same. 5. Lessee shall not make, suffer or permit litter except in appropriate receptacles for that purpose. 6. Lessee shall not alter any lock or install new or additional locks or bolts without notifying Lessor and supplying Lessor with new keys. .__..._~ 7. Lessee shall be responsible for the inal'l',v,,,;ate use of any toilet rooms, plumbing or other utilities. No foreign substances of any kind are to be inserted therein. . 8. Lessee shall not deface the walls, partitions or other surfaces of the premises. 9. Lessee shall not suffer or permit anything in or around the premises, or building that ,causes excessive vibration or floorloading in any part of the premises. 10. Furniture, significant freight and equipment shall be moved into or out of the ,building only with the Lessor's knowledge and consent, and subject to such reasonable limitations, techniques and time, as may be designated by the Lessor. Lessee shall be responsible for any damage to the building premises arising from any such activity. 11. Lessee shall not employ any service or contractor for services or work to be performed in the Building, except as approved by the Lessor. 12. No additional window coverings, shades or awnings shall be installed or used by the Lessee, without Lessor's approval. 13. No Lessee, employee or invitee shall go upon the roof of the building. 14. Lessee shall not suffer or permit smoking or carrying of lighted cigars or cigarettes within the building. 15. Lessee shall not use any method of heating or air conditioning other than is provided by the Lessor. 16. Lessee shall not install, maintain or operate any vending machines upon the premises without the Lessor's written consent. 17. The premises shall not be used for lodging or manufacturing. ".-18. Lessee shall comply with all safety, fire protection and evacuation regulations established by Lessor or any applicable governmental agency. 19. Lessor reserves the right to waive anyone of these rules or regulations, andlor as to any particular Lessee, and any such waiver shall not constitute a waiver of any other rule or regulation or any subsequent application thereof to such lease. 20. Lessee assumes all risks from theft or vandalism and agrees to keep its premises locked as may be required. 21. Users of the parking area will obey all posted signs and park only in the areas designated for vehicle parking. 22. Unless otherwise instructed, every person using the parking area is required to park and lock his own vehicle. Lessor will not be responsible for any damage to vehicles, injury to persons or loss of property, all of which risks are assumed by the party using the parking area. ~..23. The maintenance, washing, waxing or cleaning of vehicles in the parking structure or common areas is prohibited. 24. Video or arcade games or machines are prohibited from the premises. 25. Lessor reserves the right to make such other reasonable rules and regulations as it may from time to time deem necessary for the appropriate operation and safety of the premises and its occupants. Lessee agrees to abide by these and such rules and regulations. 11. COMMERCIAL LEASE AGREEMENT Initials Lessor_I_ T ,f':.~.~P:P: " ,. Date Received: JAN 1 1 2008 Original Submittal 12- COMMERCIAL LEASE AGREEMENT Initials Lessor~ /_ 1.p..o;:.o;:p.P, ., Date Received: EXHIBIT B- PERSONAL GUARANTY JAN 1 1 2008 Date: Januarv 1 st. 2008 Original Submittal Hawes Investments LLC ("Lessor") Samole Tennat LLC ("Lessee") Bill Business ("Individual") In order to induce Lessor to enter into this lease, Guarantor hereby unconditionally guarantees the prompt and faithful payment and performance of all present and future debts, liabilities, and obligations of any kind or nature, direct or indirect, of Lessee to Lessor arising under the lease between Lessor and Lessee of even date herewith (the "Lease"), however said debts, liabilities, and obligations may be evidenced and in whatever form they may be. Upon any default of Lessee under the Lease, Guarantor shall, upon demand, cure such default without any obligation on the part of Lessor to endeavor"io collect' from or to proceed against Lessee or to remove Lessee from the premises. Guarantor hereby consents to (i) Lessee exercising its option to renew one or more times the term of the Lease, (ii) any and all modifications of the Lease, and (iii) any and all extensions of time for the payment of the rent or other sums owing under the Lease or for the performance of any other obligations under the Lease. The obligations of Guarantor hereunder are primary and unconditional obligations of Guarantor and apply to all existing and future indebtedness of Lessee to Lessor under the Lease, or arising by reason of any of its provisions, and may be enforced directly against Guarantor without any action against or demand upon Lessee, and Guarantor may be joined as a defendant in any action involving Lessor and Lessee. Guarantor will pay the reasonable attorneys' fees and costs incurred by Lessor in any such action and in any appeal therefrom, all as fixed by the court or courts in which the suit or action is tried or appeal is heard. Guarantor consents to and waives notice of any arrangements or settlements made in or out of court in the event of receivership, liquidation, readjustment, bankruptcy, reorganization, arrangement, or assignment for benefit of creditors of Lessee and anything whatsoever, whether or not herein specified, that may be done or waived by or between Lessor and Lessee. No action or omission by Lessee, with or without the consent of Lessor, shall release either of Guarantor from the obl!gations contained in this Guaranty and hereby assumed by Guarantor. Without limiting the broad application of the preceding sentence, but by way of example only, Guarantor agrees that the Guaranty will continue in effect according to its terms notwithstanding the insolvency or bankruptcy of Lessee, the assignment by Lessee of the Lease and all of its rights therein, and notwithstanding the consent of Lessor to the 13- COMMERCIAL LEASE AGREEMENT Initials LessOf_ /_. T ,P:~,"P:P: .' , ~ assignment and the assumption by the assignee of Lessee's obligations under the Lease. This Guaranty shall apply during any extension, renewal, or modification of the Lease. This guaranty.covers all costs and expenses, including reasonable attorney fees, which Lessor may payor the liability for which it may incur in connection with enforcing its rights against Lessee whether or not legal action is instituted; and in the event any action is instituted against Guarantor based upon this guaranty, Guarantor agrees to pay, in addition to the costs and disbursements provided by statute, such sum as the court may adjudge reasonable as attorney fees therein together with reasonable attorney fees awarded upon appeal. This guaranty shall continue in full force and effect until all obligations to be performed by Lessee under the Lease, including, without limitation, the obligation to pay rent for the initial term and any renewal term, have been fully performed and satisfied. Date Received: AGREED AND ACCEPTED: JAN 1 1 2008 By: Origin~1 submitt"" Name: Bill Business Date: .. \ 14- COMMERCIAL LEASE AGREEMENT Initials Lessor_I_ I .~~~PP