HomeMy WebLinkAboutMiscellaneous APPLICANT 6/19/2009
IzTA
1\ Professional Enviro
rvice 'corporation
.
KT A Associates, Inc.
8005- Avenue
Suite 4100
Seattle, WA 98104
206-447-1450
WNW.ktainc.net
. June 16, 2009
City of Springfield
Planning Division
Altn: Andy Limbird
225 Fifth Street
Springfield, OR 97477
Re: REVISED FINAL HMMP for the Walgreens Clinical Pharmacy in Springfield, OR
Dear Andy,
We are pleased to provide you with three complete sets of the REVISED FINAL HMMP for the
Walgreens Clinical Pharmacy in Spri~gfield, OR (located on the 1 st Floor of the Riverbend Medical
Pavilion). ..,~." . .<4~
All comments made by SUB and the City have been addressed in the REVISED FINAL HMMP
Additionally, I have provided you, SUB, and Walgreens with an electronic copy of this entire document
via E-mail on June 16, 2009.
If you have any questions, issues, or concems, please do not hesitate to contact me directly.
Sincerely,
KTAAssociates, Inc.
~71~
John M. Souza, PE
Senior Environmental Engineer
Cc: Ami Shah, Walgreen Company
SEATTLE
PORTLAND
DENVER
OLYMPIA
BOISE
Date, Received: f/~/~'f
Planner: AL
KfA Associates, Inc.
KT A Associates, Inc. Phone 206.447.1450
800 Fifth Avenue, Suite 4100 Fax 206.374.2279
Seattle, WA 98104 www.KTAinC.nel
Hazardous Material Management Plan
Walgreens Clinical Pharmacy
Located in the Peace Health Riverbend
Medical Pavilion
Springfield, Oregon
REVISED FINAL, June 2009
KTA
Date Received: {,/I~/,#o'J
Planner: AL I I
APr0fessional Em6ronmental Service Corp9r~tion
TABLE OF CONTENTS I
1.0 HAZARDOUS MATERIAL MANAGEMENT PLAN PURPOSE AND OBJECTiVES................... 1
2.0 PLAN REVIEW AND REVISIONS ................................................................................................... 2
3.0 HAZARDOUS MATERIAL INVENTORY STATEMENT AND STORAGE.................................... 3
4.0 HAZARDOUS MATERIAL SECONDARY CONTAINMENT AND SPILL PREVENTION ........... 5
5.0 CHEMICAL EMERGENCY I SPILL RESPONSE.......................................................................... 8
6.0 PERSONNEL TRAINING FOR HAZARDOUS MATERIAL MANAGEMENT............................. 10
7.0 MONTHLY INSPECTIONS OF HAZARDOUS MATERIAL MANAGEMENT AND
CORRECTIVE ACTION SySTEM........................ .................................... ........................ ..... ........ 11
8.0 RECORDKEEPING ........................................................................................................................ 12
LIST OF APPENDICES
APPENDIX A HAZARDOUS MATERIAL INVENTORY STATEMENT
APPENDIX B MATERIAL SAFETY DATA SHEETS FOR PRODUCTS IDENTIFIED IN HMIS
APPENDIX C HAZARDOUS MATERIAL STORAGE LOCATION DRAWING
APPENDIX D DNAPL LIST
APPENDIX E HAZARDOUS MATERIAL STORAGE MONTHLY INSPECTION FORM
Date Received: Sj~/t/tro1
Planner: AL
1.0 HAZARDOUS MATERIAL MANAGEMENT PLAN PURPOSE AND I
OBJECTIVES
The Hazardous Materiai Management Plan ("Plan") for the Waigreens Clinical Pharmacy ("Facility")
located in the Peace Health Riverbend Medical Pavilion in Springfield, Oregon seNes several
objectives.
The Plan establishes responsibilities, policies, prevention measures, and procedures for the storage
and usage of hazardous materials at the Facility. Requirements for hazardous materials have been
established by the City of Springfield Drinking Water Protection (DWP) Overlay District and rely on the
Springfield Fire Code. One purpose of the Plan is to meet DWP requirements and protect the
groundwater used as a city drinking water supply from contamination by discharges of hazardous
material or other materials that pose a risk to groundwater. The Plan addresses the following
hazardous material management processes (the applicable section of the Plan is identified in
parentheses):
. Allowable hazardous materials to be stored and used at the Faciiity (Section 3.0);
. Hazardous material storage locations (Section 3.0);
. Secondary containment for hazardous material containers and spill prevention measures
(Section 4.0);
. Spill control, collection, and disposal procedures (Section 5.0);
. Personnei training for hazardous material management (Section 6.0);
. Inspection and maintenance of containment devices and emergency equipment (Section
7.0);
. Recordkeeping (Section 8.0); and
. Hazardous Material Inventory Statement (Appendix A).
This Plan addresses requirements for the environmental regulation areas described above. Although
there are several hazardous material safety and use guidelines induded within this Plan, Health and
Safety and Hazard Communications are covered by a separate program at the Facility.
Additionally, this Facility is unlikely to generate regulated hazardous waste at this time; therefore,
hazardous waste management is not addressed within this Plan.
WAlGREENS CLINICAl PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
DaL, i";ciceived:
Planner: AL
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2:0 PLAN REVIEW AND REVISI~NS' I
The Facility will ensure the PlEin is kept current and updated as necessary to reftect any change in the
storage of hazardous materials. It is anticipated that the list of hazardous materials submitted to the
City of Springfield is comprehensive and wouid only occasionally require updating for additional
materiais. Hazardous material storage, management, and spill response procedures1in this Plan will
be reviewed periodically and updated as necessary.
2.1 Facility Staff Designated to Implement the HMMP and Its Requirements
The following Walgreens personnei have been identified to implement the HMMP and all of its
requirements.
. Ginny McDaniel
Pharmacy Manager
Walgreens Clinical Pharmacy, Springfield, OR
541-736-9895
541-736-9903 Fax
E-mail: rxm.13016(Q)store.waloreens.com&ainnv.mcdaniel(Q)walareens.com
. Teresita Ceja
Senior Pharmacy Technician
Walgreens Clinical Pharmacy, Springfield, OR
541-736-9895
541-736-9903 Fax
E-mail: rxm.13016(Q)store.walareens.com
. Wendy Burg
District Manager
Walgreens Portland South
971-230'{)555
E-mail: wendv.buro<aJwaloreens.com
WALGREENS CLINICAL PHARMACY HMMP -JUNE 2009 - REVISED FINAL
KT A ASSOCIATES, INC.
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Date Received:
Planner: AL
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3.0 HAZARDOUS MATERIAL INVENTORY STATEMENT AND STORAGE
,
The hazardous material management requirements include maintaining an inventory of hazardous
materials used at the Facility and identification of the storage locations. The hazardous materials
covered by this Plan are a unique subset of the broad classification of "hazardous material", it is
important to understand the definition of hazardous material as it applies to this Pian.
3.1 Definition of Hazardous Material
Hazardous materials are substances, as defined in City of Springfield Land Use Development
Code, Chapter 3.3-200 for the Drinking Water Protection (DWP) Overlay District, which may
be stored, handled, treated, used, or produced at the Facility. As the Facility is located in an
area specified to be a drinking water wellhead Time of Travel Zone (TOTZ) of 1-5 years,
restrictions apply to hazardous materials to protect groundwater. The Springfield Development
Code defines hazardous materials as those substances (liquid or solid) which pose a risk to
groundwater quality (Chapter 3.3-205 A.1.). The class of hazardous materials is based on
the Springfield Fire Code, which has been as adopted and amended by the City, including
materials in both usable or waste conditions.
City of Springfield Land Use Development Code, Chapter 3.3-230 exempts several types of
Springfield Fire Code hazardous materials, these exemptions include: (1) Hazardous
materials in fuel tanks and fluid reseNoirs attached to (i) a private or commercial motor vehicle
and used directly in the motoring operation of that vehicle, or (ii) machinery, induding but not
limited to fuel, engine oil and coolant; (2) Fuel oil used in existing heating systems; (3)
Hazardous materials contained in properly operating sealed units (transformers, refrigeration
units, etc.) that are not opened as part of routine use; (4) Local natural gas distribution lines; (5)
Fuel for emergency generators located at facilities that provide essential community seNices
(hospitals, fireMe safety, police, public shelters, telephone systems, etc.); and (6) Any
commonly used office supply - such as correcting fluid for typewriters, toner for computer
printers or cleaners for windows and bathrooms - where the supplies are purchased off-site for
use on-site.
3.2 Hazardous Material Inventory Statement
The Facility has developed a comprehensive Hazardous Material Inventory Statement (HMIS)
that lists all hazardous materials used at the Facility, maximum quantity, and storage location.
This list accompanies the Plan and is located in Appendix A. The Material Safety Data Sheets
(MSDSs) for all products identified in the HMIS are located in Appendix B.
3.3 Hazardous Material Storage Locations
The hazardous material storage locations are listed in the Hazardous Material Inventory
Statement in Appendix A. Additionaily, locations most likely to store hazardous material and
pharmaceutical items within the Facility are identified and outlined in red on the detaiied floor
plan drawing in Appendix C.
The HMMP with the HMIS and facility drawing identifying hazardous material and
pharmaceutical item storage locations are to be submilted to the City of Springfield along with
the DWP Overlay Development Application.
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
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Planner: AL
3.4 Hazardous Material Man",,,,,,.. .",.1.
All hazardous materials defined above will be stored, handled, treated, used, or produced at
the Facility according to the guidelines outlined in this Plan. Hazardous materials will be
purchased only where necessary and used only for the intended purpose. Hazardous
materials will only be stored indoors with appropriate secondary containment. Hazardous
materials will not be stored outdoors. Hazardous materials will only be used outdoors with
precautions to prevent hazardous material from entering stormwater or infiltrating into the
ground. Facility personnel will take precautions to prevent releases of hazardous materials
during storage and use, and any releases that do 'occur wiil be controlled, cleaned up promptly,
and disposed of appropriately.
Individual containers of products that are not highly hazardous or toxic, and which are
frequently used may be kept at the use location without secondary containment. Examples
would be househoid products such as dish detergent or hand soap placed beside the Facility
sink or under the sink within the sink cabinet.
Pharmaceutical items may be hazardous materials and will be managed appropriately.
The Facility will not purchase, store, use, or sell any products containing Dense Non-Aqueous
Phase Liquids (DNAPLs). A DNAPL is one of a group of hazardous materials that is
denser than water, has a iow solubility rate, and degrades slowly to other compounds
that are even more of a health hazard. A list of DNAPLs regulated within the City of
Springfield's DWP Overlay District is maintained by the Springfield Utility Board (SUB)
and included in Appendix D. Examples of DNAPLs are Perchlorethylene and 1,1,1-
Trichloroethane.
Material Safety Data Sheets (MSDSs) for new hazardous materials proposed to be stored,
handled, treated, used, produced, or sold at the Facility must be reviewed by the SUB before
purchase to ensure the product does not contain any DNAPLs. The Facility will maintain a log
of all products reviewed for potential DNAPLs.
The HMIS will be updated with new products as they are approved. The Facility will submit an
updated HMIS to the SUB in electronic format, when new hazardous materials are added or
removed from the HMIS or upon request by the SUB.
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
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Date Received:~//6/~L.
P'imnf>r: AL / '('
Hazardous materials will be stored, handled, and used with precautions to avoid spills.
4.1 Secondary Containment
The City of Springfield requires that all hazardous malerial containers must have secondary
containment regardless of type, quantity, or size. Secondary containment for hazardous
materials that pose a risk to the groundwater will be provided in accordance with the applicable
regulatory requirements (Chapter 3.3-235 B.2. of the DWP Program). This requirement
specifically states that: "Unless exempted, all hazardous materials or other materiais that pose
a risk to groundwater shall be stored in areas with approved secondary containment in place
(Springfield Fire Code 2702.1 and 2704.2.2)". Secondary containment may be provided by
one of the following means:
. Liquid-tight sloped or recessed floors;
. Liquid-tight floors with raised or recessed sills or dikes;
. Sumps and coliection systems;
. Drainage systems leading to a controlled location; or
. Secondary containment devices, such as spill pallets, decks, tubs, or trays for containers.
Secondary containment systems will be sized to accommodate a spill from the largest
container. In addition, the sizing needs to accommodate fire-protection water (20-minute
discharge volume). The materials of construction of the secondary containment system must
be compatible with the hazardous materials to be stored. Incompatible hazardous materials
will be separated from each other in the secondary containment system. The secondary
containment system will have a monitoring method, such as visual obseNation. Materials
should be stored away from doorways and drains to prevent spills or leaks from leaving the
secondary containment area.
Most of the hazardous materiais to be stored and used at this Facility are alcohols,
alcohol-based products, and cleansers and disinfectants in less than one quart plastic
containers. All liquid hazardous materials and hazardous materials that could be
dissolved in water (e.g., powdered products) will be stored in secondary containment.
The secondary containment trays will allow easy access and quick inspection to
determine if any release of hazardous materials has occurred. The secondary
containment trays will have sufficient depth to contain at least 110% volume of the largest
container.
Additionally, all pharmaceutical items and medicines that will be stored and used at this
Facility will have appropriate secondary containment. Pharmaceutical items and
flledicines will be stored on secondary containment trays that will be physically altached
to the phamnaceutica/ shelving. All pharmaceutical shelving will be physically secured to
the Facility walls. The secondary containment trays will allow easy access and quick
inspection to determine if any release of hazardous materials has occurred. The
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
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secondary containment trays will have sufficient depth to contain at least 110% volume of
the largest container.
In hazardous material use areas where products are used frequenUy and easily visible,
individual containers of products that are not highly hazardous or toxic do not need to be kept
in secondary containment. Examples wouid include a sma Ii container of dish detergent or
hand soap placed beside the Facility sink or under the sink within the sink cabinet. Materials
not in current use should be retumed to storage in secondary containment.
Hazardous materials that are individually packaged in sealed foil or plastic packets will not
require storage in secondary containment, unless the material poses a high risk to
groundwater.
Storage devices such as Pixis medication dispensing units and drawer carts, such as a crash
cart provide adequate secondary containment.
LasUy, this Facility is unlikely to generate regulated hazardous waste at this time. However, in
the event that such waste is generated and stored at the Facility, it will be stored in appropriate
secondary containment (Le., secondary containment trays) until it is collected by an approved
waste material vendor and disposed in accordance with State and local requirements. The
secondary containment wili have sufficient depth to contain at least 110% volume of the
largest container.
4.2 Spill Prevention
In addition to secondary containment, Facility personnel will follow precautions in hazardous
material storage and use to prevent spills. The following measures will be used for spill
prevention:
. Containers of hazardous materials will be stored in designated areas within the Facility.
Safe storage and use of hazardous materiais will only occur in conjunction with Facility
safety procedures.
. Hazardous materials should not be left in doorways, hallways, bathrooms, beside drains,
outside areas, or any other unrestricted or unprotected locations.
. All containers of hazardous materials will be labeled with the identity of contents and
chemical components.
. Hazardous material containers must be in good condition, compatible with the material
stored therein, and not in danger of leaking. Containers should be kept ciosed except
when the material is in use. Non-compatible materials should not be stored next to each
other.
. Containers stored in cabinets, closets and on shelves should be at eye-level or below.
. Storage areas should be well-lit. Hazardous material storage areas should be secured or
locked, if appropriate, to protect against unauthorized access.
. Hazardous material storage areas should have signs to provide safety information and
spill cleanup procedures.
. Spill cleanup kits should be readily available near hazardous material storage areas.
WAlGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
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Date Received:
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. Floor drain mats should be maintained in all hazardous material storage areas with
ftoor drains to prevent accidental spills from reaching the sanitary sewer system.
. Hazandous material containers must not be opened, handled, or stored in a manner that
may nupture the container or cause them to leak.
. Proper handling and storage information is explained in MSDSs, available for all
hazardous materials stored and used at the Facility.
. Empty containers previously used for storage of hazardous materials will be free of
residual material before appropriate disposal.
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
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Date Received: YYdtnir
Planner: AL
5.1 General
Personnel who work with or around chemicals wili be trained in these procedures. Hazardous
material container storage areas will be managed to minimize the possibility of fire, explosion,
or any unplanned release of chemicals to the environment.
52 Emergency Requirements
The Facility maintains an emergency plan, which includes the following'elements required for
hazardous material management:
. Communications and fire control equipment, including periodic testing to ensure
equipment will operate properly in time of emergency.
. Arrangements with local authorities.
. An Emergency Coordinator for the Facility has been designated with the responsibility for
coordinating ali emergency response measures.
. Spili response procedures: the level of response to a hazardous material spili will depend
upon the physical characteristics and volume of material being handled, its potential
hazards, and the potential for release to the environment. The following are general
guidelines to be followed for a hazardous material spill:
o The individual who caused or discovers the spili is responsible for immediate
response and containment until the Emergency Coordinator arrives.
o Immediately alert area oCcupants and supeNisor, and evacuate the area, if
necessary.
o If a volatiie, flammable material is spilled, immediately wam everyone, control
sources of ignition and ventilate the area.
o If there is a fire that cannot be extinguished with a portable fire extinguisher,
cali the local Fire Department at 911.
o Altempt to contain the spili (with absorbent material) to the smallest practicai
area.
o As appropriate, spills should be cleaned up by chemical treatment,
absorption, or neutralization. If the spill is too large for the responsible
individual or Emergency Coordinator to handle, or may pose a risk to
groundwater:
. Call911 to contact:
. Fire Department Hazardous Material Unit,
. Police Department, and
. Springfield Utility Board (SUB).
WAlGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FiNAl
KT A ASSOCIATES, INC.
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. Contact the Peace Health Riverbend Medical Pavilion
Emergency Coordinator.
o Wear personal protective equipment, as appropriate to the hazards. Refer to
the Material Safety Data Sheet (MSDS) for appropriate personal protective
equipment.
o Protect floor drains or other means of environmental release. Floor drain
mats, spill socks, and absorbents may be placed around drains.
o Bulk absorbents and multiple spill pillows do not work with acids.
POWERSORB (3M) products and their equivalent will handle acid. Acids
should be neutralized if possible.
o When spilled materials have been absorbed, use brush and scoop to place
materials in an appropriate container. Polyethylene bags may be used for
small spills. Five-gallon pails with poiyethylene liners may be appropriate for
larger quantities.
o For spills of hazardous material, the waste product and spill control materials
might be classified as a hazardous waste. For a spill of hazardous material,
label the container to identify the material as Spill Material Involving "XYZ
Chemical". Contact the Emergency Coordinator for advice on storage and
packaging for disposal.
o Decontaminate the surface where the spill occurred using a mild detergent
and water, when appropriate.
. The Emergency Coordinator will complete or assign necessary reporting to authorities and
agencies. The Emergency Coordinator will assess the need for any required
environmental reporlng. The Emergency Coordinator may contact or coordinate with
the Peace Health Riverbend Medical Pavilion Emergency Coordinator and
Environmental Coordinator for assistance.
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
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Date Received:
Planner: AL
6/;6~'
/ / .
In general, Facility personnel will receive direction or training from their supeNisors, as necessary for
each position, in hazardous material management. General training given to all employees in their
group does not need to be documented.
Facility personnel who handle hazardous materials may need basic training and direction if their
position has responsibility for:
. Awareness of the sensitive area that the Facility occupies and special precautions needed to
protect the drinking water.
. General hazardous material storage and use guidelines.
o Responding to spills or other hazardous material related emergencies.
At a minimum, all Facility staff will be trained on the following: HMMP requirements, Emergency Plan
procedures, and DWP awareness.
WALGREENS CLINICAL PHARMACY HMMP -JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
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Date, r~eceived:
Planner: AL
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,'- AND CORRECTIVE'ACTldN ~YSTE:M" ' I':
Monthly inspections of hazardous material storage areas will be conducted. As necessary,
documented periodic inspections of storage areas are required for hazardous material management
at the Facility.
This Facility is unlikely to generate regulated hazardous waste at this time. However, in the event that
such waste is generated and stored at the Facility, it will be inspected monthly as stated in Plan
Section 7.2.
7.1 Hazardous Material Storage Monthly Inspections
Monthly inspections of hazardous material storage areas will be performed using the standard
Hazardous Material Storage Monthly Inspection Form. Appendix E includes a copy of this
inspection form.
The inspection form includes a list of items to be checked at each area. In particular,
secondary containment devices (tubs, trays, and cabinets), and emergency equipment must
be inspected. The inspector will look for events or practices that could lead to an unintended
release of hazardous material. The inspection form must also be reviewed and si9ned by the
Facility Manager. Completed inspection forms will be maintained in a binder or file.
When an inspection identifies a compiiance issue, a corrective action will be performed. The
Facility Manager will track both preventative and corrective maintenance activities in a log
book.
7.2 Hazardous Waste Storage Monthly Inspections
As previously stated, this Facility is unlikely to generate regulated hazardous waste at this
time. However, in the event that such waste is generated and stored at the Facility, it will be
stored in an appropriate secondary containment device (i.e., secondary containment tub, tray,
or cabinet) until it is collected by an approved waste material vendor and disposed in
accordance with State and local requirements. These containment devices will be
inspected for compliance just like those for hazardous material and pharmaceutical items
and recorded on the Hazardous Material Storage Monthly Inspection Form.
WALGREENS CLINICAl PHARMACY HMMP - JUNE 2009 - REVISED FINAL 11
KTAASSOCIATES.INC.
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Planner: AL
8.!! 8,ECORDKEEPING . . I I
8.1 Recordkeeping
The Facility Manager will establish and maintain a hazardous material management file. As a
best management practice, all hazardous material management files should be maintained for
a minimum of 3 years. As necessary, the filing system should include:
. Hazardous Material Management Plan (HMMP),
. Hazardous Material Inventory Statement (HMIS) and 10caUon drawings,
. Correspondence with agencies, consultants, etc. (must maintain for 3 years),
. Reports submilted to environmental, fire, and safety agencies,
. Personnel training records, and
. Completed hazardous material storage monthly inspection forms.
82 Reporting
Any new hazardous material must be approved by the SUB and added to the HMIS prior to
storage within the Facility. The new material's MSDS should be reviewed to ensure that it
does not contain any DNAPLs (refer to the DNAPL List located in Appendix D).
In addition, the HMMP should be reviewed and updated regulariy to refiect current hazardous
material management within the Facility.
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES. INC.
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Date f{eceived:_~.J~OPvL
Planner: AL /
APPENDIX A - HAZARDOUS MATERIAL INVENTORY STATEMENT
WALGREENS CLINICAL PHARMACY HMMP- JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
Date, rteceived: iOf. /~Clo-z>L
Planner: AL
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NFPA 704 Classification
Name of Hazard
Health
Flammability
Instabil itY/Reactivity
Special Hazards
Code in Words
None or Minima) or Least
Slight
Moderate
High or Serious
Severe
Color on Sauare on Point.
Blue
Red
Yellow
White
Corresoondina Numerical Code
o
1
2
3
4
Combustible Liauids
Unified Fire Code Definitions
Flammable Liauids
I
I
Flammable Solid
pxidizer
PvroDhoric
Unstable (reactive)
(but not exolosivej
Water reactive material
I
I
I Toxic
IHiahlv Toxic
I
IUse
I
Class 2
Class3A
Class3B
1A
1B
1C
4
3
2
1
4
3
2
1
3
2
1
Spatial Location
9-Q'Clock
12-Q'Clock
3-Q'Clock
6-0'Clock
COde
o through 4
o through 4
o tnrough 4
Only use W (Water reactive) or OX (Oxidizer)
100F <: or = FP < 140F
140F < or= FP <: 200
FP > or: 200F
F2
F2
F1
FP <: 73F. SP <: 100F
FP < 73F. BP:> 100F
73F < FP < 100F
F4
F3
F3
IIqnition temp < 212F
I
IExolosive reaction from COntamination, thermal or ohv~i(;al shock
I Causes severe increase in bum rate of combustibie materials or viqorous decomposition
ICauses moderate increase in burn rate or spontaneous kmition of combustible materials
ISliqhllv increa~es burn rate. does not cause spontaneous 'jQnition
I .
ISoontaneous JQnj!jonin air beJow 130F
Caoable of detonation or exolosive decomoosition or reaction at normalil'!lTlo/nrASS
Cao,able of detonation or exoiosive decomoosition or reaction from hiqh temp or heating
Unstable and caoable of violent chemical reaction at normaltempfpress, but does not detonate or explode
Normallv stable. but can become unstable at hiah tema
I Reacts exolosively with water without heat or confinement
Potentiallv explosive when mixed with water
I.Release enerqv when mixed with water, but not violentlv
I
I Lethal dose to rats LD50
I Lower IAthal dose to rats LD50
I
IUSE {Materiall is: 1. Placini1.. a material into action, includins solids. liguids and ,gases. or
12. Making a material available for service by Opening or connecting anvthinq utilized for confinement of material inclUding solids, liquids and gases.
1:10
are
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~(l)
)> ~.
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::::::--.
,~
0-.
~
~
EPCRA Hazard Codes (Table 6\
EPCRA Hazard Codes UFC Hazard Name
1.1 Class A Explosives
1.2 crass B Explosives
1.3 Class C Explosives
1.4 Blasting Agents
1.5 Very Insensitive Explosives
1.6 Extremely Insensitive Explosives
2.1 Flammable Gas
2.1 Flammable Gas
2.2 Non-Flammable Gas
2.2 Non-Flammable Gas
2.3 Poisonous Gas
3.1 Flammable Liquid (FP < 0 F)
3.2 Flammable Liquid (0 F < FP < 73 F)
3.3 Flammable liquid (73 F < FP < 141 F)
3.1f3.2 Combination Flammable Liquid
4.1 Flammable Solid
4.2 Spontaneously Combustible Material
4.2 Spontaneously Combustible Material
4.3 Dangerous When Wet
4.3 Dangerous When Wet
4.3 Dangerous When Wet
4.4 Reactive Material
4.4 Reactive Material
4.5 Combustible Liquid
4.5 Combustible Liquid
4.5 Combustible Liquid
4.5 Combustible Fiber
4.5 Combustible Fiber
5.1 Oxidizer
5.1 Oxidizer
5.1 Oxidizer
5.1 Oxidizer
5.2 Organic Peroxides
6.1 Poisonous Material
6.2 Etiologic Material
6.3 Acute Health Hazard
6.4 Chronic Health Hazard
6.5 Pesticide
7.3 Radioactive Material
8 Corrosive
9 Miscellaneous Hazardous Material
UFC Hazard Cfass
Div 1.1
Div 1.2
Div 1.3
Div 1.4
Div 1.5
Div 1.6
Gaseous
liquefied
Gaseous
liquefied
Gaseous
lA
18& 1C
18& 1C
4
3
3
2
1
2
1
"
IliA
IlIB
Loose
Baled
4
3
2
1
-00
ora
::JIJ)
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0-
't
IEPCRA Storaae Conditions (Tables 4 & 5\
TABLE IV . STORAGE CODES'
-~ r~oISt...a
A.... ..._..Abowgl'Ound tank
B.... ...............Undergrouncltank
C..... ,.......Tank Inside building
D.... ...........St.., drum
E.... "Pla$(k; or non-metallic drum
F............un.....Can
G. ............,...... .Carboy
H...,.........n..n..Silo
I....,.."".........., Fiber drum
J.. .............Bag
K..............".....Box
l.....................CVlinder
M ....................Glua tlottto., jug.ar buckete
N ".............,..... Plastic bottles, jugt or buckets
O.....................Totebin
P..................... Tankwagon
a.....................Rallcar
R.....................Clthor
s..... .,...~r
TABLE V - TEMPERATURE AND PRESSURE CONDITIONS
AND STO,RAGE cgD~
~ Stl)faae CendiUor.s
(PRESSURE)
. . . .Normal pressure
.Graat., thtln nonTllll 'Pm.ure
.less than norrnal pl'8ssuro
1
2 ..........
3
4
.
B
7
(TEMPERATURE)
.. .Nonnaltempendure
. .Groal:orthan normaltompor.ture
. .less th;!n normal temperature but not ctyogen!c
, .Cryogenic conditions
ONAPL Definina Reauirement~
Definition
Dense Nan-aqueous Phase Liquids (DNAPLs) are:
Heavier than water (specific gravity >1)
Have a low solubility rate (<10g/1 or 1%)
Degrade to other compounds that are (wen more of a health hazard
Far the pUrposes of Drinking Water Protection, DNAPL chemicals are defined as "all chemicals displaying the characteristics of a ONAPL chemical
or a material containing a substance considered a DNAPL chemical".
DNAPL CI'U"mir.~I!;.
DNAPL chemicals are commonly used as cleaners, de-greasers, coolants, pesticides, and for treating wood. The following DNAPL chemicals are
identified specifically but are not a comprehensive list of chemicals considered DNAPLs. If a chemical meets the Definition above it is regulated
and prohibited.
APPENDIX B - MATERIAL SAFETY DATA SHEETS FOR PRODUCTS IDENTIFIED IN HMIS
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES.INC.
Date f-tHCeived:2,.L6p,mr
Planner: AL
Humeo Holding Group, Inc.
7400 Alumax Drive
Texarkana, TX 75501
903-83] - 7808
Item #0395-0467
CAMPHOR SPIRITS USP
DATE PREPARED: 0311410]
SECTION I
PRODUCT IDENTIfiCATION
PRODUCT NAME: Camphor Spirits USP
SECTION II
HAZARDOUS COMPONENTS
Component
Percent
CAS No.
Ethyl Alcohol
Camphor
84.0%
10.0%
64-17-5
76-22-2
SECTION III
PHYSICAL DATA
Boiling Point: 1700F
Specific Gravity: (H20 ~ I) 0.824
Solubility: (In water) Insolubie
Vapor Pressure: (mmHg) NA
Vapor Density: (Air=l) NA
Evaporation Rate: NA
Appearance and Odor: Clear water white liquid with camphor odor.
% Volatiles by Volume: NA
SECTION III A
DEGREE OF HAZARD
Degree of Hazard
4 - Extreme
3 - High
2 - Moderate
I - Slight
o - Insignificant
Flammability
Health
Reactivity
Special Hazard
3
3
o
o
Date, Heceived:
Planner: AL
{,/; 6/ ;JtrP/
/ I
CAMPHOR SPIRITS USP
Page 2
SECTION IV
FIRE AND EXPLOSION HAZARDS
Flash Point: 66'F
Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, water spray.
Special Firefighting Procedures and Precautions: When heated, material emits flammable and
explosive vapors. If it can be safely done, remove containers from fire area.
Unusual Fire and Explosion Hazards: Firefighters should use self-contained breathing apparatus
and full protective clothing.
SECTION V
HEALTH HAZARD DATA
First Aid Instructions for Accidental Exposure:
If on Skin: Wash with soap and water. Get medical help if any irritation persists.
If in Eyes: Flush with running water for 15 minutes. Get medical attention immediately.
IfInhaled: Remove victim to fresh air. Get immediate medical assistance.
If Swallowed: Immediately give 3 to 4 glasses of water. Do Not induce vomiting. If vomiting
occurs, give fluids again. Have physician determine if patient's condition allows induction of
vomiting or evacuation of stomach. Do not give anything by mouth to an unconscious or
convulsing person.
SECTION VI
REACTIVITY DATA
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to a void: Strong oxidizing agents such as Potassium Pcnnanganate & Chromic
Anhydride.
Decomposition Products: Partial oxidation products and carbon monoxide from therma~oxidation
degradation.
Date t'teceived:
Planner: AL
,ff./~9
I I
CAMPHOR SPIRITS USP
Page 3
SECTION VII
SPILL AND DISPOSAL PROCEDURES
Steps to be taken in the event of a spill or discharge: Provide adequate ventilation. Remove
sources of heat or ignition. Protect against inhalation of vapors and skin contact. Cover spill with
dry sand or vermiculite and mix well prior to transferring to a disposal container. Keep container
tightly closed.
Disposal Procedures: Scrap can be burned in a safe place or approved incinerator. Follow
Federal, State and local regulations.
SECTION VIII
INDUSTRIAL PROTECTIVE EQUIPMENT
Ventilation: To meet TL V requirements.
Respiratory Protection: Full face chemical cartridge respirator with an organic vapor cartridge to
200 mglmg3
Eye Protection: Chemical safety goggles, eye wash station.
Skin Protection: Protective clothing for prolonged or repeated exposure.
SECTION IX
SPECIAL PRECAUTIONS
Precautions to be taken in handling and storing: Store in a cool, dry, well ve ntilated area away
from oxidizing agents and sources of heat or ignition.
Date Received:~/ 0'*>7
Planner: AL .
Cc5Cc5
MSDS for Hydrogen Peroxide, 3%
Catalog # 1202E
Medical chemical Corp.
19430 Van Ness Ave.
Torrance, CA 90501
Customer Service: Phone (310)787-6800
FAX (310)787-4464
CHEMTREC Emergency Response Telephone Number: (800)424-9300
Notc: The CHEMTREC phone number is only for cmcrgencies involving spills, leaks, fire, cxposure or accident. Please
dircct all other inquiries to our customer service phonc numbcr.
Section 1 - Product Identification
A stabilized, aqueous solution of hydrogen peroxide.
Section II - Composition/Information on Components
Ingredients
CAS#
OSHA Pel
1 ppm TWA (air)
ACGIH TLV
1 ppm TWA (air)
Other Limits
%
hydrogen peroxide 7722-84-1
3%w/v
Section III . Hazards Identification
OveNiew: May be harmful if swallowed. May be irritating to skin eyes and respiratory tract.
Safety Ratings
Health: Slight Flammability: None Reactivity: None
Recommended safety equipment: safety goggles, lab coat and proper gloves
Storage: General storage
NFPA Ratings
Health = 0 Flammability = 0 Reactivity = 1
Potential Health Effects
Contact: Slight
The toxicology of this compound have not been completely examined. It is presumed that the toxicity of this item is
similar to other dilute peroxides. 3% hydrogen peroxide is not expected to present health problems under normal
circumstances
Inhalation: Not likely to be an issue. May be irritating
Ingestion: While the toxicity of this compound is low, large doses may cause nausea, vomiting, diarrhea, etc.
Skin contact: Not normally a problem
Eye contact: May be irritating
Chronic Exposure: Unknown
Aggravation of preexisting conditions: Unknown
Section IV - First Aid Measures
Inhalation: Unlikely to be an issue. Remove from source of exposure and get medical altention for any breathing
difficulty.
Ingestion: Unlikely to be an issue. Get medical advise for exceptional cases.
MSDS for 3% Hydrogen Peroxide, page 1 of 3
Date Received:#rl<r07
Planner: AL
Skin Contact: Unlikely to be an issue. Wash affected area with soap and water. Get medical advice if irritation develops.
Eye Contact: Rinse thoroughly with running water. Get medical advice if irritation develops.
Section V - Fire Fighting Measures
Flash point:: Not applicable.
Flammable Limits: Not applicable.
Fire: Not normally a fire Hazard,
Explosion: Not Normally an explosion hazards.
Fire Extinguishing Media: Any means suitable for surrounding fire.
Special information: Pyrolysis will release corrosive oxides.
Section VI - Accidental Release Measures
Absorb with a suitable inert absorbent and store in a suitable container for disposal. Waste disposal is usually not restricted but local
ordinances vary. Insure compliance with all government regulations.
Section VII - Handling and Storage
Store in a closed container, protected from freezing.
Section VIII - Exposure Control/Personal Protection
Airborne Exposure Limits: See section II
Ventilation System: Usually not required. When required, Refer to the ACGIH document, "Industrial Ventilation, a
Manual of Recommended Practices" for details about ventilation.
Personal Respirator: Usually not required. In case of emergency, or when exposure levels are unknown, use a positive
pressure, full face piece, air supplied respirator.
Skin protection: Protective gloves are not required but recommended as part of good laboratory practice.
Eye Protection: Laboratory safety goggles or similar products are not required but recommended as part of good
laboratory practice.
Section IX - Physical and Chemical Properties
Boiling Point: 100'C
Vapor pressure (mm Hg): 18 @ 20'C
Vapor Density (air = 1): 0.6
VOC: 0 g/l
Appearance and Odor: A clear, colorless, odorless liquid.
Density: About 1.0 g/ml
Evaporation Rate (water = 1): 1
Solubility: Infinitely miscible with water
Section X - Stability and Reactivity
Stability: Freezes at low temperature.
Hazardous Decomposition Products: Will liberate large amounts of oxygen.
Hazardous polymerization: Will not occur.
Incompatibilities: Nothing unusual.
Conditions to avoid: Excessive cold/heat and light.
Section XI . Toxicological Information
Cancer lists
Ingredient
Hydrogen Peroxide
Known Carcinogenicity?
No
NTP?
No
Anticipated?
No
IARC Category
3
MSDS for 3% Hydrogen peroxidJ';. ~e 2 of 3
Date Received:_.{'//~a-9
Planner: AL I .
Section XII - Ecological Information
Environmental Fate: Biodegradable
Environmental Toxicity: None
Section XIII - Disposal
Not normaiiy restricted but ultimate authority resides with local government agencies. Insure compliance with all
government regulation
Section XIV - Transportation information
Not Regulated
Section XV - Regulatory Information
Chemical Inventory Status
Ingredient
Hydrogen Peroxide
TSCA
Yes
EC
Yes
Federal, State and International Regulations
Ingredient
Hydrogen Peroxide
SARA 302
RQ TPQ
No No
SARA 3 I3
List Category
No No
RCRA
261.33
No
TSCA
SeD)
No
Chemical Weapons Convention: No
TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes, Chronic: No, Fire: No, Pressure: No
Section XVI . Other Information
This information is believed to be correct but is not waranteed as such, nor does it purport to be aii inclusive.
Revision Date: Feb. 16,2006
MSDS for 3% Hydrogen Peroxide, page 3 of 3
Date Received:~Y-m,4
Planner: AL
httpS:11fscimage.fishersci.comjmsdsj45416.htm
Material Safety Data Sheet
Iodine Solution, Tincture
ACC# 45416
II Section 1 - Chemical ~r~o..duct and Company Identification Jl
MSDS Name: Iodine Solution, Tincture
Catalog Numbers: 571951, 571952, 593267
Synonyms: Tincture of Iodine
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
II
~
Section 2 - Composition, Information on Ingredients
CAS#
7732-18-5
64-17-5
7681-82-5
7553-56-2
Chemical Name
Percent
49.77
45.85
2.39
1.99
EINECSjEUNCS
231-791-2
200-578-6
231-679-3
231-442-4
Water
Ethyl alcohol
ISOdium iodide
Iodine
II
II
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: amber liquid. Flash Point: 12.8 deg C.
Warning! Causes severe eye irritation. Flammable liquid and vapor. Causes respiratory tract
irritation. This substance has caused adverse reproductive and fetal effects in humans. May cause
central nervous system depression. May cause liver, kidney and heart damage. Causes moderate skin
irritation. Possible sensitizer.
Target Organs: Blood, kidneys, heart, central nervous system, liver, respiratory system,
cardiovascular system, bone marrow, thyroid.
Potential Health Effects
Eye: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical
conjunctivitis and corneal damage. . .
Skin: Causes moderate skin irritation. May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May be absorbed through the skin. May cause cyanosis of
the extremities.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause
systemic toxicity with acidosis. May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory failure.
Date Received: ~!!~/,}n!f
".;'vf 7 Planner: AL 15-Mar-0919:59
https:j1fscimage.fishersci.com/msds/45416.htm
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized
by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May
cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation. May cause
respiratory sensitization.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. Chronic exposure can
lead to iodism characterized by headache, excess salivation, nasal discharge, conjunctivitis, laryngitis,
bronchitis, stomatitis, enlarged submaxillary glands, and skin rashes. May cause reproductive and fetal
effects. Laboratory experiments have resulted in mutagenic effects. Chronic exposure can affect thyroid
function. Animal studies have reported the development of tumors. Prolonged exposure may cause
liver, kidney, and heart damage.
~-
II
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so
by medicai personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively. Persons with skin or eye disorders or
liver, kidney, chronic respiratory diseases, or central and peripheral nervous sytem diseases may be at
increased risk from exposure to this substance. Activated charcoal does not reduce ethanol absorption.
Antidote: Ethanol may inhibit methanol metabolism.
II
Ij
Section 5 - Fire Fighting Measures
General Information: Ethanol may inhibit methanol metabolism. As in any fire, wear a self-contained
breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Flammable Liquid. Can release vapors that form explosive mixtures
at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Wear
appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing
apparatus (SCBA) to prevent contact with thermal decomposition products. Containers may explode in
the heat of a fire.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-
resistant foam. For large fires, use water spray, fog, or alcohol-resjstant foam. Use water spray to cool
fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Flash Point: 12.8 deg C ( 55.04 deg F)
Autoignition Temperature: 362.8 deg C ( 685.04 deg F)
Explosion Limits, Lower:3.3 vol %
Upper: 19 vol %
NFPA Rating: (estimated) Health: 0; Flammability: 3; Instability: 0
II
IJ
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/LeakS: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable
container. Remove all sources of ignitjDn. Use a spark-proof tool. Provide ventilation. A vapor
Date Received: ~t'i~/Jn>.'"
Planner: AL
~ of 7
15-Mar-09 19:59 i
https:llfscimage.fishersci.com/msds/45416.htm
suppressing foam may be used to reduce vapors.
~-~~""-
-JI
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use
only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof
tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool
place in the original container and protect from sunlight. Store in a tightly closed container. Keep from
contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible
substances. Flammables-area. Keep away from reducing agents. Do not store near perchlorates,
peroxides, chromic acid or nitric acid.
II
Section 8 - Exposure Controls, Personal Prot~ction
Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this
material should be equipped with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
I Chemical Name
I Water
ACGIH
none listed
NIOSH
OSHA - Final PEls
none listed
Ethyl alcohol
1000 ppm TWA
none listed
1000 ppm TWA; 1900
mg/m3 TWA 3300 ppm
IDLH
none listed
Iodine
Jnone listed
10.1 ppm Ceiling
2 ppm IDLH
1000 ppm TWA; 1900
mg/m3 TWA
none listed I
0.1 ppm Ceiling; 1 mg/m31
Ceiling
Sodium iodide
OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Ethyl alcohol: 1000
ppm TWA; 1900 mg/m3 TWA Sodium iodide: No OSHA Vacated PELs are listed for this chemical. Iodine:
No OSHA Vacated PEls are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye
and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin e'xposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements or European Standard EN 149 must be followed whenever workplace conditions warrant
respirator use.
II__~___- -
u~1
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Appearance: amber
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 40 mm Hg
oj of 7
Date Received: t1o/J.<n:l9
Planner: AL
15-Mar-09 19:59
httpS:/1fscimage.fishersci.comfmsds/45416.htm
Vapor Density: 1.6
Evaporation Rate: > 1
Viscosity: Not available.
Boiling Point: 73-79 deg C
Freezing/Melting Point:-80 deg C
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity / Density:O. 79
Molecular Formula:Mixture
Molecular Weight:Not available.
L
Section 10 - Stability and Reactivity
II
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Stable under normal temperatures and pressures., incompatible materials, light,
ignition sources, excess heat, oxidizers.
Incompatibilities with Other Materials: Strong oxidizing agents, peroxides, acids, acid chlorides,
acid anhydrides, alkali metals, ammonia, permanganic acid, ruthenium (VIII) oxide, bromine
pentafJuoride, nitrosyl perchlorate, chromyl chloride, uranium hexafluoride, iodine heptafiuoride, uranyl
perchlorate, acetyl bromide, silver nitrate, disulfuryl difluoride, magnesium perchlorate, platinum,
potassium-tert-butoxide, silver oxide, hydrazine, tetrachlorosilane + water, acetyl chloride, calcium
hypochlorite, mercuric nitrate, perchloric acid, potassium dioxide, sodium, magnesium, zinc, aluminum,
steel, antimony, acetaldehyde, bromine trifluoride, reducing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, toxic fumes of sodium oxide, hydrogen iodide, (odine.
Hazardous Polymerization: Will not occur.
~~~l
~
Section 11 - Toxicological Information
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 64-17-5: KQ6300000
CAS# 7681-82-5: WB6475000
CAS# 7553-56-2: NN1575000
LDSO/LCSO:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mljkg;
CAS# 64-17-5:
Draize test, rabbit, eye: 500 mg Severe;
Draize test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 20 mg/24H Moderate;
Inhalation, mouse: LC50 = 39 gm/m3/4H;
Inhalation, rat: LC50 = 20000 ppm/10H;
Oral, mouse: LD50 = 3450 mg/kg;
Oral, rabbit: LD50 = 6300 mg/kg;
Oral, rat: LD50 = 7060 mg/kg;
Oral, rat: LD50 = 9000 mg/kg;
CAS# 7681-82-5:
Draize test, rabbit, eye: 100 mg/24H Moderate;
Date Received: ~jYJrrof
Planner: AL
. ')f 7
15-Mar-09 19:59
https:/lfscimage.fishersci.comjmsdsj45416.htm
Draize test, rabbit, skin: 500 mgj24H Moderate;
Oral, mouse: LD50 = 1000 mgjkg;
Oral, rat: LD50 = 4340 mgjkg;
CAS# 7553-56-2:
Oral, mouse: LDSO = 22 gmjkg;
Oral, mouse: LD50 = 1000 mgjkg;
Oral, rabbit: LD50 = 10 gmjkg;
Oral, rat: LD50 = 14 gmjkg;
Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 64-17-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7681-82-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7553-56-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: Ethanol has been shown to produce fetotoxicity in the embryo or fetus of laboratory
animals. Prenatal exposure to ethanol is associated with a distinct pattern of congenital malformations
that have collectively been termed the "fetal alcohol syndrome".
Teratogenicity: CAS# 64-17-5: Oral, Human - woman: TDLo = 41 gmjkg (female 41 week(s) after
conception) Effects on Newborn - Apgar score (human only) and Effects on Newborn - other neonatal
measures or effects and Effects on Newborn - drug dependence.
Reproductive Effects: CAS# 64-17-5: Intrauterine, Human - woman: TDLo = 200 mgjkg (female 5
day(s) pre-mating) Fertility - female fertility index (e.g. # females pregnant per # sperm positive
females; # females pregnant per # females mated).
Mutagenicity: CAS# 64-17-5: DNA Inhibition: Human, Lymphocyte = 220 mmol/L.; Cytogenetic
Analysis: Human, Lymphocyte = 1160 gmjL.; Cytogenetic Anaiysis: Human, Fibroblast = 12000 ppm.;
Cytogenetic Analysis: Human, Leukocyte = 1 pphj72H (Continuous).; Sister Chromatid Exchange:
Human, Lymphocyte = 500 ppmj72H (Continuous).
Neurotoxicity: No information found
Other Studies:
II
Section 12 - Ecological Information
Jl
Ecotoxicity: Fish: Rainbow trout: LC50 = 12900-15300 mgjL; 96 Hr; Flow-through @ 24-24.30CFish:
Rainbow trout: LC50 = 11200 mgjL; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium
phosphoreum: EC50 = 34900 mgjL; 5-30 min; Microtox test CAS# 64-17-5: When spilled on land it is
apt to volatilize, biodegrade, and leach into the ground water, but no data on the rates of these
processes could be found. Its fate in ground water is unknown. When released into water it will
volatilize and probably biodegrade. It would not be expected to adsorb to sediment or bioconcentrate in
fish.
Environmental: CAS# 64-17-5: When released to the atmosphere it will photodegrade in hours
(polluted urban atmosphere) to an estimated range of 4 to 6 days in less polluted areas. Rainout should
be significant.
Physical: No information available.
Other: No information available.
II
~l
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemicai is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to ensure
Date Received: ,/;~ / dVP'f
Planner: AL / I
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15-Mar-09 19:59
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complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
II
L
Section 14 - Transport Information
Shipping Name:
Hazard Class:
UN Number:
Packing Group:
Additional Info: !
US DOT
ETHANOL SOLUTION
3
UN1170
II
Canada TOG
FLAMMABLE LIQUID NOS (ETHANOL)
3
UN1993
II
FLASH POINT 8 C
II
Section 15 - Regulatory Information
-~
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 7681-82-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 64-17-5: Immediate, delayed, fire.
CAS # 7681-82-5: immediate.
CAS # 7553-56-2: immediate, delayed, fire.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Poliutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7732c18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 64-17-5 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
r ')f 7
Date Received:
Planner: AL
~/;r~ '1
15-Mar-09 19: 59
httpS:llfscimage.fishersci.com/msds/45416.htm
CAS# 7681-82-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7553-56-2 can be found on the fOllowing state right to know lists: Caiifornia, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
WARNING: This product contains Ethyl alcohol, a chemical known to the state of California to cause
developmental reproductive toxicity.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 7 Keep container tightly closed.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 64-17-5: 0
CAS# 7681-82-5: 1
CAS# 7553-56-2: 1
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 64-17-5 is listed on Canada's DSL List.
CAS# 7681-82-5 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 64-17-5 is listed on the Canadian Ingredient Disclosure List.
CAS# 7681-82-5 is listed on the Canadian Ingredient Disclosure List.
CAS# 7553-56-2 is listed on the Canadian Ingredient Disclosure List.
I[
II
Section 16 - Additional Information
MSDS Creation Date: 9/02/1997
Revision #7 Date: 10/30/2007
The information above is believed to be accurate and represents the best information currently available to us. However. we make no
warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting
from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no
event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirec~ incidental,
consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of. such damages.
, ')f 7
Date Received: ~/5/J.n,9
Planner: AL
15-Mar-09 19: 59
http://fscimage.fishersci.com/msds/89530. htm
Material Safety Data Sheet
Isopropyl alcohol 70% in water
ACC# 89530
II Section 1 - Chemical Product and CompCjny Id~~~fication
:-
JI
MSDS Name: Isopropyl alcohol 70% in water
Catalog Numbers: AC613190040, AC613245000, A459-1, A459-20, A459-4, A459-500, NC9290641,
NC9405257, NC9524653, NC9761180
Synonyms: Isopropanol; Dimethylcarbinol; sec-Propyl alcohol; Rubbing alcohol; Petrohol;
l-Methylethanol; 1-Methylethyl alcohol; 2-Hydroxypropane; 2-Propyl alcohol; Isopropyl alcohol;
Propan-2-01; IPA; 2-Propanol.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201- 796- 7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
~
Section 2 - Composition, I nformation on Ingredients
II
CAS#
67-63-0
7732-18-5
Chemical Name
I sopropyl alcohol
Water
Percent
70
30
EINECS/ELlNCS
200-661- 7
231-791-2
II
IL_~..u
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: colorless liquid. Flash Point: 18 deg C.
Warning! Flammable liquid and vapor. Breathing vapors may cause drowsiness and dizziness.
Causes eye and respiratory tract irritation. Aspiration hazard if swallowed. Can enter lungs and cause
damage. Prolonged or repeated contact causes defatting of the skin with irritation, dryness, and
cracking. May cause central nervous system depression.
Target Organs: Central nervous system, respiratory system, eyes, skin.
Potential Health Effects
Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and
possible corneal injury. May cause transient corneal injury. In the eyes of a rabbit, 0.1 ml of 70%
isopropyl alcohoi caused cof1junctivitis, iritis, and corneal opacity.
Skin: May cause irritation with pain and stinging, especially if the skin is abraded. Isopropanol has a
low potential to cause allergic skin reactions; however, rare cases of ailergic contact dermatitis have
been reported. May be absorbed through intact skin. Dermal absorption has been considered
toxicologically insignificant. The cases of deep coma associated with skin contact are thought to be a
consequence of gross isopropanol vapor inhalation in rooms with inadequate ventilation, rather than
being attributable to percutaneous absorption of isopropanol per se.
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Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney
damage. May cause central nervous system depression. characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness,
coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause
chemical pneumonitis, which may be fatal. The probable oral lethal dose in humans is 240 ml (2696
mg/kg), but ingestion of only 20 ml (224 mg/kg) has caused poisoning.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized
by nausea, headache, dizziness, unconsciousness and coma. May cause narcotic effects in high
concentration. Causes upper respiratory tract irritation. Inhalation of vapors may cause drowsiness and
dizziness.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis.
11-
..--........,
__ 0-"_"
II
Section 4 - First Aid Measures
Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get
medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get
medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion: Potential for aspiration if swallowed. Get medical aid immediately. Do not induce vomiting
unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
If vomiting occurs naturally, have victim lean forward.
Inhalation: if Inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid.
Notes to Physician: Urine acetone test may be helpful in diagnosis. Hemodialysis should be
considered in severe intoxication. Treat symptomatically and supportively.
II
J
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHAlNIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture
with air. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors are
heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the
ground and collect in low or confined areas.
Extinguishing Media: Water may be ineffective. Do NOT use straight streams of water. For large fires,
use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. For small fires, use carbon
dioxide, dry chemical. dry sand, or alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
Flash Point: 18 deg C ( 64.40 deg F)
Autoignition Temperature: 399 deg C ( 750.20 deg F)
Explosion Limiis, Lower:2.0 vol %
Upper: 12.7 @ 93.30C
NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0
11_-
-'
II
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermicuiite, sand or earth), then piace in suitable
container. Use water spray to dilute spill to a non-flammable mixture. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
~ ')f7
Date Received:
Planner: AL
~;lt./~L
09-Dec-0819:52
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11__-
Section 7 - Handling and Storage
~
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep
container tightly closed. Do not pressurize, cut. weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Use only with adequate ventilation. Avoid breathing vapor or
mist.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Keep from contact
with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Ie
Section 8 - Exposure Controls, Personal Protection
~I
Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this
material should be equipped with an eyewash facility and a safety shower. Use adequate general or
locai exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
I Chemical Name
ACGIH
NIOSH
400 ppm TWA; 980 mg/m3
TWA 2000 ppm IDLH (10%
. LEL)
none listed
OSHA - Final PELs
Isopropyl alcohol
200 ppm TWA; 400 ppm
STEL
400 ppm TWA; 980 mg/m3
TWA
Water
Inone listed
none listed
OSHA Vacated PELs: Isopropyl alcohol; 400 ppm TWA; 980 mg/m3 TWA Water; No OSHA Vacated
PELs are listed for this chemical.
Personal Protective Equipment
Eyes; Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANS I Z88.2
requirements or European Standard EN 149 must be followed whenever workplace conditions warrant
respirator use.
II
-II
Section 9 - Physical and Chemical Properties
Physical State: Liquid
Appearance: coloriess
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 33 mm Hg @ 20 deg C
Vapor Density: 2.1 (Air=1)
Evaporation Rate: 1.7 (n-butyi acetate= 1)
Viscosity: 2.27 mPas @ 20 deg C
Boiling Point: 82 deg C @ 760 mm Hg
Freezing/Melting Point:-88 deg C
Decomposition Temperature: Not available.
Solubility: Miscible.
Specific Gravity/Density:0.7850 (water= 1)
Molecular Formula:C3H80
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Molecular Weight:60.09
t~-
Section 10 - Stability and Reactivity
~.~.....~- -~
~
Chemical Stability: Stable.
Conditions to Avoid: Ignition sources, excess heat.
I ncompatibilities with Other Materials: Strong oxidizing agents, strong acids, strong bases, amines,
ammonia, ethylene oxide, isocyanates, acetaldehyde, chlorine, phosgene, Attacks some forms of
plastics, rubbers, and coatings., aluminum at high temperatures.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Wili not occur.
If
Section 11 - Toxicological Information
~I
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 67-63-0:
Draize test, rabbit, eye: 100 mg Severe;
Draize test, rabbit, eye: 10 mg Moderate;
Draize test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, skin; 500 mg Mild;
Inhalation, mouse: LC50 ~ 53000 mg/m3;
Inhalation, rat: LC50 ~ 16000 ppm/8H;
Inhalation, rat: LC50 = 72600 mg/m3;
Oral, mouse: LD50 ~ 3600 mg/kg;
Oral, mouse: LD50 = 3600 mg/kg;
Oral, rabbit: LD50 = 6410 mg/kg;
Oral, rat: L050 = 5045 mg/kg;
Oral, rat: LD50 ~ 5000 mg/kg;
Skin, rabbit: L050 ~ 12800
CAS#.7732-18-5:
Oral, rat: LD50 ~ >90 mL/kg;
Carcinogenicity:
CAS# 67-63-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: A rat & rabbit developmental toxicity study showed no teratogenic effects at doses
that were clearly maternaiiy toxic. In a separate rat study, no evidence of developmental neurotoxicity
was associated with gestational exposures to IPA up to 1200 mg/kg/d.
Reproductive Effects: See actual entry in RTECS for complete information.
Mutagenicity: See actual entry in RTECS for complete information.
Neurotoxicity: In rats exposed to isopropanol by inhalation, acute neurotoxicity was noted at 1 and 6
hours at 5000 ppm, but only minimal effects were seen at 1500 ppm and the animals recovered within
5 hours. No toxicity was noted at 500 ppm.
Other Studies:
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Planner: AL
~II
Il
Section~~_~~c9Io9ical Information
09-Dec-0819:52
http://fscimage.fishersci.com/msds/895 30. htm
Ecotoxicity: Fish: Fathead Minnow: >1000 ppm; 96h; LC50Daphnia: >1000 ppm; 96h; LC50Fish:
Gold orfe: 8970-9280 ppm; 48h; LC50 IPA has a high biochemical oxygen demand and a potential to
cause oxygen depletion in aqueous systems, a low potential to affect aquatic organisms. a low potential
to affect secondary waste treatment microbiai metabolism, a low potential to affect the germination of
some plants, a high potential to biodegrade (low persistence) with unacclimated microorganisms from
activated sludge.
Environmental: No information available.
Physical: THOD: 2.40 g oxygen/gCOD: 2.23 g oxygen/gBOD-5: 1.19-1.72 g oxygen/g
Other: No information available.
II
Section 13 - Disposal Considerations
II
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to ensure
complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Jl
t__
Section 14 - Transport Information
Shipping Name:
Hazard Class:
UN Number:
Packing Group:
US DOT
ISOPROPANOL
3
UN1219
II
Canada TOG
ISOPROPANOL
3
. UN1219
II
II
Section 15 - Regulatory I nformat~on
J
US FEDERAL
TSCA
CAS# 67 -63-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 67 -63-0: Effective 12/15/86, Sunset 12/15/96
Chemical Test Rules
CAS# 67-63-0: 40 CFR 799.2325
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 67-63-0: immediate, deiayed, fire.
Section 313
- 'If '7
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09-Dec-0819:52
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This materiai contains Isopropyl alcohol (CAS# 67-63-0, 70%),which is suQject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 67 -63-0 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL or NJ.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.
European/ I nternationa I Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI F
Risk Phrases:
R 11 Highly flammable.
R 36 I rritating to eyes.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 7 Keep container tightly closed.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 7732-18-5: No information available.
Canada - DSL/NDSL
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHM I S
This product has a WHMIS classification of B2, D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 67-63-0 is listed on the Canadian Ingredient Disclosure List.
II
Section 16 - Additional Information
MSDS Creation Date: 7/27/1999
Revision #11 Date: 2/18/2008
The information above is believed to be accurate and represents the best information currently available to us. However, we make no
r ')17
Date Received:~/J<rz> f
Planner: AL
09-Dec-0819:52
http://fscimage.fishersci.com/msds/89530.htm
warranty of merchantability or any other warranty, express or implied. with respect to such information, and we assume no liability resulting
from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no
event shall Fisher be liable for any claims, 105ses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
- ')f 7
Date Received: t/;(Jd-tJL
Planner: AL / '
09-Dec-0819:52
Item Number: 804
04/29/2008
Page I
of 5
Material Safefy'DataSh~et
Section 1: PRODUCT AND COMPANY IDENTIFICATION
Vi-Jon Incorporated
8515 Page Avenue
Saint Louis, MO 63114
Product Name: 91% WG Isopropyl Alcohol
Product Code: 804
Product Use: Various
Issue Date: 04/29/2008
Supersedes Date: None
Phone: 314-427-1000
In Case of Spill Emergency Contact:
Chemtrec: 1-800-424-9300
'Section 2: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Keep out of reach of children.
Appearance/Odor: Clear, colorless, mobile liquid with a characteristic odor.
WARNING:
Flammable (isopropyl alcohoi)
Target (isopropyl alcohol) respiratory system, skin, eyes, CNS, liver, blood and reproductive
system.
Potential Health Effects: See Section 11 for more information.
Symptoms of Exposure:
Inhalation: May cause irritation of the respiratory tract.
Ingestion: May cause nausea, vomiting and diarrhea.
Eyes: May cause irritation to the eyes.
Skin: May cause irritation to the skin.
This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC
orNTP.
This material contains a component that is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Potential Environmental Effects: See Section 12 for more information.
Date Received: ~/;b/.:No9
Planner: AL
Item Number: 804
04/29/2008
Page 2
of 5
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
,i'
Comoonent CAS#
Isopropyl Alcohol 67-63-0
%byWl.
91%
.Section 4: FIRST AID MEASURES
Emergency first aid procedures by route of exposure:
Inhalation:
If symptoms are experience, remove source of contamination or move victim to
fresh air. If affected person is not breathing, appiy artificiai respiration. If
breathing is difficult, give oxygen. Get medical altention.
Do not induce vomiting. If the material is swallowed, get medical altention or
advice.
If irritation is experienced, flush with water. If irritation persists, get medical
altention.
Immediately flush eyes with water for at least 15 minutes while holding eyelids
open. If symptoms persist, get medical altention.
Ingestion:
Skin:
Eyes:
'Section 5: FIRE FIGHTING MEASURES
Flash Point: 14'C (57.2'F)
Auto Ignition: (Isopropyl Alcohol) 399'C
Flammability Classification: Flammabie Liquid IB
Extinguishing Media: Use methods appropriate for the surrounding fire. Consider water spray
or fog, carbon dioxide, dry chemicai powder, or alcohol resistant foam.
Products of Combustion: Upon decomposition this product may emit carbon dioxide, carbon
monoxide and/or low molecular weight hydrocarbons.
Fire Fighting Equipment/Instructions: Wear protective clothing and equipment suitable for the
surrounding fire, including helmet, facemask, and self contained breathing apparatus.
NFPA Rating: Health:1 Fire: 3 Reactivity:O
Hazard Scale: 0 = Minimal 1 ='Slight 2 =.Moderate 3 = Serious 4 = Severe
SectlonG: ACCIDENTAL RELEASE MEASURES
Personal Precautions: For large spills wear gioves, safety glasses and when levels exceed
OSHA PEL use appropriate NIOSH approved respiratory protection. Keep unnecessary
personnel away. Eliminate all sources of ignition or flammables that may come into contact with
a spill of this material.
Environmental Precautions: Prevent discharge to open waters.
Method for Containment: Absorb spilled liquid in suitable non-flammable inert material such as
clay, vermiculite or diatomaceous earth.
Methods for Clean-Up: Ventilate area of leak or spill. Use spark-proof tools to sweep or scrape
up and containerize in approved chemical waste container. Wash spill area with water.
Date ~eceived: ~rJ;v1
Planner: AL
Item Number: 804
04/29/2008
Page 3
of 5
Section 7: HANDLING AND STORAGE
,
Jr
Handling: Keep away from heat, sparks and flame. Prevent contact with eyes. Avoid
inhalation.
Storage: Keep the container tightly closed and in a cool, well ventilated place.
:Section'S: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Isopropyl Alcohol (67-63-0)
ACGIH: 200 ppm TWA
OSHA: 400 ppm TWA; 980 mg/m3 TWA
Engineering Controls: Normal room ventilation is usually adequate under normal use.
Personal Protective Equipment (PPE)
Eye/Face Protection: None needed under normal use.
Skin Protection: None needed under normal use.
Respiratory Protection: None needed under normal use.
General Hygiene Considerations: None needed under normal use.
;Section 9: PHYSICAL AND.CHEMICAL PROPERTIES
Appearance/Color: Clear, colorless, mobile liquid
Odor: Alcohol
Physical State: Liquid
pH: Not Available.
Vapor Density: (Isopropyl Alcohol) 2.07 (air = 1)
Boiling Point: (Isopropyl Alcohol) 82.50C [DIN 43171]
Vapor Pressure: (Isopropyl Alcohol) 42 hPa at 200C
Melting Point: (Isopropyl Alcohol) -90oC
Freezing Point: Not Available
Flash Point (see section 5)
Flammability Properties (see section 5)
Solubility (in water): Soluble
Density @ 20oC: 0.784-0.786 g/cm3
Evaporation Rate: Not Available
OctanollWater partition coefficient (Kow): (Isopropyl Alcohol): 0.05 at 250C
Auto-ignition temperature: (Isopropyl Alcohol) 3990C
Decomposition temperature: Not Available
Section 10: STABILITY AND REACTIVITY
Stability: Stable under normal ambient temperatures 700C (210C)
Condition to Avoid: Avoid excessive heat or sources of ignition.
Incompatible Materials: This product reacts with strong acid, strong bases, and oxidizing
agents.
Hazardous Decomposition: upon decomposition, this product evolves carbon monoxide, carbon
dioxide, and/or low weight hydrocarbons.
Hazardous Reactions: Hazardous polymerization will not occur.
Date Received:-#o/';""'L
Planner: AL
Item Number: 804
04/29/2008
Page 4
of 5
Section 11: TOXICOLOGY INFORMATION
ACUTE EFFECTS:
A: General Product information
Product contains isopropyl alcohol.
B: Component Analysis LD50
Isopropyl Alcohol (67-63-0)
Inhalation LC50 Rat: 72.6 mg/L/4H
Oral LD50 Rat: 4396 mg/kg
Dermal LD50 Rat: 12800 mg/kg
Dermal LD50 Rabbit: 12870 mg/kg
CHRONIC EFFECTS:
Component
isopropyl Alcohol (67-63-0)
Carcinogenicity: ACGIH A4 - Not Ciassifiabie as a Human Carcinogen
Neurotoxicity: This product contains isopropyl alcohol, a central neNOUS system target.
Mutagenicity: No information available for product.
Reproductive: No information available for product.
Developmental: This product contains isopropyl aicohol, a developmental hazard.
Target Organs: skin, eyes, CNS, Kidney, Developmental and respiratory system.
:Section 12: ECOLOGICAL INFORMATION
Ecotoxicity: Isopropyl Alcohol (67-63-0)
96 Hr EC50 Scenedesmus Subspicatus: >1000 mg/L
72 Hr EC50 Scenedesmus subspicatus:>1 000 mg/L
96 Hr LC50 Pimephales promelas: 9640 mg/L [flow through]
96 Hr LC50 Pimephaies promelas: 94900 mg/L [flow through] (29 days old)
96 Hr LC50 Pimephales promelas: 61200 mg/L [flow through] (31 days old)
5 min EC50 Photobacterium phosphoreum: 35390 mglL
48 Hr EC50 Daphnia magna: 13299 mg/L
:Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, state, and local regulations.
.Section 14: TRANSPORTATION INFORMATION
Shipping Name: Consumer Commodity ORM-D
Proper Shipping Name for Non-Consumer Commodity: Isopropanol, 3, UN1219, PGII.
Section 15: REGULATORY INFORMATION
Isopropyl alcohol, a component of this product, is on the TSCA inventory.
The following components appear on one or more of the following state hazardous substance
lists:
I Component
I Isopropyl
Alcohol
CAS#
67-63-0
CA
YES
MA
YES
MN
YES
NJ
YES
PA
YES
Date Received: ~;/6'/...bJf
Planner: AL
Item Number: 804
04/29/2008
Page 5
of 5
Section 16: Other Information
Prepared by: Vi-Jon Inc.
Disclaimer:
The information and recommendations contained in the Material Safety Data Sheet (MSDS) are
supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Heaith Standards Hazard
Communication Rule. The information and recommendations set forth herein are presented in
good faith and believed to be correct as of this date hereof.
Vi-Jon, however, makes no representation as to the completeness or accuracy thereof, and
information is supplied upon the express condition that the persons receiving the information will
be required to make their own determination as to its suitability for their purposes prior to use. In
no event will Vi-Jon be responsibie for any damages of any nature whatsoever resulting from the
use of, reliance upon, or the misuse of this information. User assumes all risk of use. storaoe
ilnd handlina of the oroduct in comoliance with aoolicable federal. state and local laws and
reaulations.
NO REPRESENTATIONS OR WARRANTIES: EITHER EXPRESSED OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER
NATURE, ARE MADE BY VI-JON HEREUNDER WITH RESPECT TO INFORMATION OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. The information as supplied herein is
simply to be informative and intended solely to alert the user of the substance which is the subject
matter of this MSDS. The ultimate compliance with federal, state or local regulations concerning
the use of this compound, or compliance with respect to product liability, rests solely upon the
purchaser thereof.
This information relates to the material desionated and mav not be valid for such material used in
combination with anv other materials nor in anv orocess.
Date Received:
Planner: Al
6)i~f
/
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
t9ohnson
A FAMILY COMPANY
,.
g.
Version 1.
WINDEX@ ORIGINAL GLASS CLEANER
Print Date 01/22/2009
Revision Date 01/16/2009
MSDS Number 350000004274
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name
Use of the
Substance/Preparation
Company
Emergency telephone
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance { Odor
Immediate Concerns
Potential Health Effects
Routes of exposure
Eyes
Skin
Inhalation
Ingestion
Aggravated Medical
Condition
WINDEX@ ORIGINAL GLASS CLEANER
Hard Surface Cleaner
S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236
24 Hour Transport & Medical Emergency Phone (866) 231-
5406
24 Hour International Emergency Phone (952) 852-4647
blue {liquid / characteristic
Avoid contact with skin, eyes and clothing.
Eye, Skin, Inhalation, Ingestion.
None known.
None known.
None known.
None known.
None known.
3. COMPOSITIONilNFORMATION ON INGREDIENTS
I.; ChemitaFNarne
I Water
I Isopropanol
I Ethyleneglycol
Monohexvlether
4. FIRST AID MEASURES
Eye contact
CAS-No.
7732-18-5
67-63-0
112-25-4
Weiqht % .
60.00 - 100.00
1.00 - 5.00
0.10- 1.00
Rinse with plenty of water. Get medical attention if irritation
1/7
j
0//6/.Ju-bf
/ / '
Date Received:
Planner: AL
Material Safety Data Sheet
according 10 ANSI Z400.1- 2004 and 29 CFR 1910.1200
<.9ohnson
A FAMilY COMPANY
WINDEX@ ORIGINAL GLASS CLEANER
Version 1.
Print Date 01/22/2009
Revision Date 01/16/2009
MSDS Number 350000004274
develops and persists.
Skin contact
Wash off with soap and water. Get medical attention if irritation
deveiops and persists.
Inhalation
Remove to fresh air.
Ingestion
Never give anything by mouth to an unconscious person. Get
medical attention immediately.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media
Alcohol foam, carbon dioxide, dry chemical, water fog
Specific hazards during fire
fighting
Container may melt and leak in heat of fire.
Further information
Although this product has a flash point below 200 De9 F, it is
an aqueous solution containing an alcohol and does not
sustain combustion. Standard procedure for chemical fires.
Wear full protective clothing and positive pressure self-
contained breathing apparatus.
Flash point
130 OF
Method: Tag Closed Cup (TCC)
Flash point
540C
Method: Tag Closed Cup (TCC)
Lower explosion limit
Note: no data available
Upper explosion limit
Note: no data available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Remove all sources of ignition.
Methods for cleaning up
Soak up with inert absorbent material.
Sweep up and shovel into suitable containers for disposal.
Dike large spills.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
KEEP OUT OF REACH OF CHILDREN AND PETS.
2/7
I
Date Heceived:_~/;f~7
Planner: AL
Material Safety Data Sheet
according 10 ANSI 2400.1- 2004 and 29 CFR 1910-.1200
~ohnson
A fAMilY COMPANY
Version 1.
WINDEX@ ORIGINAL GLASS CLEANER
Print Date 01/22/2009
Revision Date 01/16/2009
Advice on protection
against fire and explosion
Storage
Requirements for storage
areas and containers
MSDS Number 350000004274
Use only as directed.
Keep away from heat and sources of ignition.
Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.
Do not freeze.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
CAS"No,
Isopropanol
Isopropanol
Isopropanol
Personal protective equipment
Respiratory protection
Industrial setting
Household setting
Hand protection
Industrial setting
Household setting
Eye protect/on
Industrial selting
Househoid setting
Hygiene measures
67-63-0
'ACGIH STEL
400 ppm
67-63-0
200 ppm
ACGIH TWA
67-63-0
980 mg/m3
OSHA TWA
400 ppm
No personal respiratory protective equipment normally
required.
No personal respiratory protective equipment normally
required.
not required under normal use
not required under normal use
No special requirements.
No special requirements.
Use only with adequate ventilation. Wash thoroughly after
handling. Substantial amounts of mist/vapors can be
controlled with local exhaust ventilation or respiratory
protection. Wear suitable protective clothing.
3/7
Date Received:_~rdn.L
Planner: AL .
Material Safety Data Sheet
according to ANSI Z4DO.1- 2004 and 29 CFR 1910.1200
...~I
Wohnson
A FAMILY COMPANY
WINDEX@ ORIGINAL GLASS CLEANER
Version 1.
Print Date 01/22/2009
Revision Date 01116/2009
MSDS Number 350000004274
9. PHYSICAL AND CHEMICAL PROPERTIES
Form
liquid
Color
blue
Odor
characteristic
pH
10.5 -11.0
Melting point
no data avaiiable
Boiling point
no data availabie
Freezing point
no data available
Flash point
130 OF
Method: Tag Closed Cup (TCC)
540C
Method: Tag Closed Cup (TCC)
Flash point
Evaporation rate
no data available
Autoignition temperature
no data available
Lower explosion limit
no data available
Upper explosion limit
no data available
Vapour pressure
similar to water
Water solubility
completely soluble
Partition coefficient: n-
octa nol/water
no data available
Specific Gravity
1.0 estimated
10. STABILITY AND REACTIVITY
Conditions to avoid
None known.
Materials to avoid
Strong oxidizing agents
Hazardous decomposition
products
When exposed to fire, produces normal products of
combustion.
4/7
'[
I
~/dlr#o7
Date Received:
Planner: AL
Material Safety Data Sheet
according to ANSI Z400.1~ 2004 and 29 CFR 1910.1200
<t)ohnson
A FAMilY COMPANY
WINDEX@ ORIGINAL GLASS CLEANER
Version 1.
Print Date 01/22/2009
Revision Date 01/16/2009
MSDS Number 350000004274
Hazardous reactions
Stable
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity
LD50
Dose: estimated> 5,000 mg/kg
Acute inhalation toxicity
LC50 rat
Dose: > 2.5 mg/i
Acute dermal toxicity
LD50 rabbit
Dose: estimated> 2,000 mglkg
Chronic effects
Carcinogenicity
no data available
Mutagenicity
no data available
Reproductive effects
no data available
Teratogenicity
no data available
Sensitisation
Not known to be a sensitizer.
12. ECOLOGICAL INFORMATION
Ecotoxicily effects
Not Available
13. DISPOSAL CONSIDERATIONS
Industrial setting
ObseNe all applicable Federal, Provincial and State
regulations and Local/Municipal ordinances re9arding
disposal.
Household setting
Consumer may discard empty container in trash, or recycle
where facilities exist.
14. TRANSPORT INFORMATION
Land transport
5/7
iL
Date Received: f/6/.;;>tn'r
1
Planner: AL
Material Safety Data Sheet
according 10 ANSI Z400.1. 2004 and 29 CFR 1910.1200
<9ohnson
A FAMILY COMPANY
WINDEX@ ORIGINAL GLASS CLEANER
Version 1.
Print Date 01/22/2009
Revision Date 01/16/2009
MSDS Number 350000004274
U.S. DOT and Canadian TOG Surface Transportation:
NA number 1993
Proper shipping name Combustible Liquid, N.O.S.
Class: Combustible liquid
Packaging group: III
Note:
SC Johnson ships this product as "Non-Regulated" per DOT
exception for Combustible Liquids. (49 CFR 173.150)
Sea transport
IMDG:
UN-Number:
Packaging group:
Proper shipping name
Class:
None.
None.
not regulated
None.
Air transport
ICAO/IATA:
Class:
Packaging group:
Proper shipping name
UN/ID No.:
None.
None.
not regulated
None.
15. REGULATORY INFORMATION
Global Chemical Inventories
Notification status
All ingredients of this product are listed or are excluded from
. listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).
California Prop. 65
This product is not subject to the reporting requirements under
California's Proposition 65.
This product has been classified in accordance with hazard
criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products
Regulations.
6/7
I
Date Received' o/to/dd#1
Planner: AL
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
(jJohnson
A FAMILY COMPANY
WINDEX@ ORIGINAL GLASS CLEANER
Version 1.
Print Date 01/22/2009
Revision Date 01/16/2009
MSDS Number 350000004274
16. OTHER INFORMATION
HMIS Ratings
, Health
o
Flammability
2
Reactivity
o
NFPA Ratings
Health
o
Fire
2
Reactivity
Special
o
Further information
This document has been prepared using data from sources considered to be technically reliable.
It does not constitute a warranty, expressed or implied, as to the accuracy of the information
contained herein. Actual conditions of use are beyond the seller's control. User isresponsible to
evaluate all available information when using product for any particular use and to comply with all
Federal. State, Provincial and Local laws and regulations.
I Prepared by:
I SC Johnson Global Safety Assessment &
ReQulatory Affairs (GSARA)
7/7
J
Date Received: f)~~f
Planner: AL
.
. ..
eJil'. :ScienC8' uab,.com
..~) Chemi~als&~~oiat9ry .Eq~ipin~nt
~l- --
: Health 2
Fite . 2
Reactivity 0
I Personal J
Protection
Material Safety Data Sheet
Witch Hazel MSDS
Section 1: Chemical Produc:t and Company Identification
Product Name: Witch Hazel
Contact Information:
Catalog Codes: SLW1105
CAS#: Mixture.
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
RTECS: Not applicable.
TSCA: TSCA 8(b) inventory: Ethyl alcohol 200 Proof
CI#: Not appiicabie.
Order Online: ScienceLab.com
Synonym: Witch Hazel, double distilled extract
Chemical Name: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
- Section 2: Composition and Information on Ingredients
Composition:
Name
Ethyl alcohol 200 Proof
I Witch Hazel Extract
CAS#
64-17-5
% by Weight
14-15
85-86
Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse).
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact
(irritant, permeator).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animaL) by ACGIH [Ethyl alcohol 200 Proof].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria
and/or yeast. [Ethyl alcohol 200 Proof].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohoi 200 Proof]. Classified
Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof].
Date Received' ~/r.J#Y p. 1
Planner: AL
The substance is toxic to blood, the reproductive system, liver, upper respiratory tract, skin, central neNous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. Immediately fiush eyes with running water for at least 15 minutes,
keeping eyelids open. Cold water may be used. Get medical attention.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Cold water may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical altention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Serious higestion: Not available.
Sec!ion5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: The lowest known vaiue is 3630C (685.4 OF) (Ethyl alcohol 200 Proof).
Flash Points: OPEN CUP: 43.3330C (1100F).
Flammable Limits: The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 200 Proof)
Products of Combustion: These products are carbon oxides (CO, C02).
Fire Hazards in Presence of Various Substances:
Flammable in presence of open fiames and sparks, of heat.
Slightly flammable to fiammable in presence of oxidizing materials.
Non-fiammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Slightly explosive in presence of acids.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water.
SMALL FIRE: Use DRY chemical powder.
LARGE FiRE: Use aicohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent
pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel.
Date Received:-#1k9 p. 2
Planner: AL
considerable distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Special Remarks on Explosion Hazards:
Ethanol has an explosive reaction with the oxidized coating around potassium metal.
Ethanol ignites and then explodes on contact with acetic anhydride + sodium hydrosulfate (ignites and may
explode), disulfuric acid + nitric acid, phosphorous(lIl) oxide platinum, potassium-tert-butoxide+ acids.
Ethanol forms expiosive products in reaction with the following
compound: ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane
iodide), magnesium perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver
fulminate) silver nitrate (forms ethyl nitrate) silver(l) oxide + ammonia or hydrazine (forms
silver nitride and silver fulminate), sodium (evolves hydrogen gas).
(Ethyl alcohol 200 Proof)
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container.
Large Spill:
Flammable liquid.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or
confined areas; dike if needed. Be careful that the product is not present at a concentration level above TL V.
Check TL V on the MSDS and with local authorities.
Section ~1: Handling and Storage
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek
medical advice immediately and show the container or the label.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
,SectiofL8: Exposure Controls/l"ersonal Protection!!
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves (impeNious).
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits:
Ethyl alcohol 200 Proof
TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999]
TWA: 1000 (ppm) from OSHA (PEL) [United States]
Date Received:
Planner: AL
6jt~
/ 1
p. 3
TWA: 1900 (mg/m3) from OSHA (PEL) [United States]
TWA: 1000 (ppm) from NIOSH
TWA: 1000 (ppm) [United Kingdom (UK)]
TWA: 1920 (mg/m3) [United Kingdom (UK)]
TWA: 1000 STEL: 1250 (ppm) [Canada]
Consult local authorities for acceptable exposure limits.
Section 9:'Physicaland Chemical Properties
Physical state and appearance: Liquid.
Odor: Characteristic Witch Hazel (Strong.)
Taste: Not available.
Molecular Weight: Not applicable.
Color: Clear Colorless.
pH (1% soln/water): Not available.
Boiling Point: 880C (190AOF)
Melting Point _80C (17.60F)
Critical Temperature: The lowest known value is 2430C (469AOF) (Ethyl alcohol 200 Proof).
Specific Gravity: 0.979 - 0.983 @ 25 C(Water = 1)
Vapor Pressure: 2.5 kPa (@ 200C)
Vapor Density: 1.03 (Air = 1)
Volatility: Not available.
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof)
Water/Oil Dist. Coeff.: Not available.
lonicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water.
Soluble in methanol, diethyl ether, acetone.
Section. 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources (sparks, flames), incompatible materiais
Incompatibility with various substances: Slightly reactive to reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Date Received: ~;'::~Ji".",f- p. 4
Planner: AL
Ethanol rapidly absorbs moisture from the air.
Can react vigorously with oxiders.
The following oxidants have been demonstrated to undergo vigorous/explosive reaction with ethanol: barium
perchlorate, bromine pentafluoride, calcium hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride,
dioxygen difluoride, disulfuryl difluoride, fluorine nitrate, hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl
perchlorate, perchloric acid permanganic acid, peroxodisulfuric acid, potassium dioxide, potassium perchlorate,
potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver peroxide, uranium hexafluoride, uranyl
perchlorate.
Ethanol reacts violenliy/expodes with the following compounds: acetyl bromide (evolves hydrogen bromide)
acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver oxide, chlorate. chromic
anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen peroxide +
sulfuric acid, iodine + methanol + mercuric oxide, manganese perchlorate + 2,2-dimethoxy propane,
perchlorates, permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, siiver & nitric acid,
silver perchlorate, sodium hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water.
Ethanol is also incompatible with platinium, and sodium. (Ethyl alcohol 200 Proof)
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological ihforl1'latiOl1
Routes of Entry: Absorbed through skin. Eye contact. Inhalation.
Toxicity to Animals: Acute oral toxicity (LD50): 23793 mg/kg (Mouse) (Calculated value for the mixture).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof].
Classified A4 (Not classifiable for human or animaL) by ACGIH [Ethyl alcohol 200 Proof].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for
bacteria and/or yeast. [Ethyl alcohol 200 Proof].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 200 Proof]. Classified
Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof].
Other Toxic Effects on Humans:
Hazardous in case of ingestion, of inhalation.
Slightly hazardous in case of skin contact (irritant, permeator).
Special Remarks on Toxicity to Animals: Not avaiiable.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic)
Causes adverse reproductive effects and birth defects (teratogenic) , based on moderate to heavy consumption.
May cause cancer based on animal data.
Human: passes through the placenta, excreted in maternal milk. (Ethyl alcohol 200 Proof)
Special Remarks on other Toxic Effects on Humans:
Section 12: Ecological Information
Ecotoxicity: Not available.
B005 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Date Received' tj'/i>>-Pf
Planner: AL / /
p. 5
I Special Remarks on the Products of Biodegradation: Not available.
. Section .13: DisposCiIConsiderations
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental
control regulations.
Section 14: Transport.lnformatloh
DOT Classification: CLASS 3: Flammable liquid.
Identification: : Ethanol solution (Ethyl alcohol 200 Proof) UNNA: 1170 PG: III
Special Provisions for Transport: Not available.
'Section 15: Other Regulatory Information
Federal and State Regulations:
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl
alcohol 200 Proof
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause cancer which would require a warning under the statute: Ethyl alcohol 200 Proof
Rhode Island RTK hazardous substances: Ethyl alcohol 200 Proof
Pennsylvania RTK: Ethyl alcohol 200 Proof
Florida: Ethyl alcohol 200 Proof
Massachuselts RTK: Ethyl alcohol 200 Proof
New Jersey: Ethyl alcohol 200 Proof
TSCA 8(b) inventory: Ethyl alcohol 200 Proof
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R10- Flammable.
S2- Keep out of the reach of children.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 2
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 2
Date Received: ~fy~'1
Planner: AL .
p. 6
....
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impeNious).
Lab coat.
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent.
Splash goggles.
References: Not available.
Section 16: Other Information
Other Special Considerations: Not available.
Created: 10/10/200512:16 AM
Last Updated: 11/06/200812:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we
assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall ScienceLab. com be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even
if ScienceLab.com has been advised of the possibility of such damages.
Date Received: ~1dH>" ,
Planner: AL
p. 7
APPENDIX C - HAZARDOUS MATERIAL STORAGE LOCA TlON DRAWING
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009 - REVISED FINAL
KTAASSOCIATES, INC.
Date Heceived:--1p~f
Planner: AL .
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APPENDIX D - DNAPL UST
WAlGREENS CLINICAl PHARMACY HMMP -JUNE 2009 - REVISED FINAl
KTAASSOCIATES. INC.
Date ~eceived:--Pp/~_
Planner: AL
Dense Non-Aqueous Phase Liquids (DNAPLs)
Prohibited From Use in the Time-or-Travel Zones
Identified in Springfield City Code
Adopted by the Springfield Utility Board
March 28, 2005
Definition
Dense Non-aqueous Phase Liquids (DNAPLs) are:
. Heavier than water (specific gravity >1)
. Have a low solubility rate (<lOg/lor 1%)
. Degrade to other compounds that are even more of a health hazard
For the purposes of Drinking Water Protection, DNAPL chemicals are defined as "all chemicals
displaying the characteristics of a DNAPL chemical or a material containing a substance considered a
DNAPL chemical".
DNAPL Chemicals
DNAPL chemicals are commonly used as cleaners, de-greasers, coolants, pesticides, and for treating
wood. The following DNAPL chemicals are identified specifically but are not a comprehensive list of
chemicals considered DNAPLs. If a chemical meets the Definition above it is regulated and prohibited.
Common DNAPL chemicals are listed below.
Chemical Name
I, 1,2,2-tetrachloroethane
I Alternative Name
I Acetylene tetrachloride;
Symmetrial tetrachloroethane
Ethane trichloride;
B-trichloroethane; V iny]
trichloride
1,1- DCE; I,I-Dichloroethene;
asym-Dichloroethylene; NCI-
C54262; RCA waste number
U078; Sconatex; VC; VDC;
Vinylidene chloride; Vinylidene
chloride (II); Vinylidene
dichloride; Vinylidene chloride;
I, I ,2-trichloroethane
1,I-dichloroethylene
CAS Number
79-34-5
79-00- 5
75-35-4
Date Received: t/~#Vf
Planner: AL
Chlorinated hydrochloric ether;
],I-Dichloroethane; asym-
Dichloroethane; Ethylidene
chloride; Ethylidenedichloride;
I,]-Ethylidene dichloride; NC]-
C04535; RCRA waste number
U076; UN 2362; Asymmetrical
dichloroethane
1 Propylene dichloride; Dichloro- 178-87-5
1,2-propane
I, I,] - TCA; Aerothene; Aerothene 71-55-6
TT; Baltana; Chloroethene;
Chloroethene NU; Chlorothane
NU; Chloroethene; Chloroethene
NU; Chloroethene VG; ChI orten;
Genklene; ]nhibisol; Methyl
chloroform; Methyltrichloro-
methane; NCI-C04626; RCRA
waste number U226; Solvent III;
- T; I, 1,1- TCE; Trichloroethane;
Tri-ethane; UN 283]
Allyl trichloride; Glycerol
trichlorohydrin; Glyceryl
trichlorohydrin; Trichlorohydrin
I Unsym- Trichlorobenzene;
] ,2,4- Trichlorobenzol
Acetylene dichloride;
cis-Acetylene dichloride;
trans-Acetylene dichloride;
sym-Dichloroethylene
Carbon chloride; Carbon tet;
Freon@ 10; Halon@ 104;
Tetrachloromethane
I Aroclor<ID ]254; PCB;
Polychlorinated biphenyl
I Methane trichloride;
Trichloromethane
bis (2-Chloroethyl)ether; 2,2-
Dichlorodiethyl ether; 2,2-
Dichloroethyl ether
11,2-Dibromoethane; Ethylene
bromide; Glycol dibromide; EDB
II ,2-DichlOro. ethane; Ethylene
chloride; Glycol dichloride
SUB DNAPL chemical lis!
Page 2 of5
I,I-Dichloroethane
11,2-Dichloropropane
I, I , I-Trichloroethane
1,2,3- Trichloropropane
11,2,4-trichlorobenzene
1,2-dichloroethylene
Carbon tetrachloride
I Chlorodiphenyl
I Chloroform
Dichloroethyl ether
I Ethylene dibromide
I Ethylene dichloride
75-34-3
96-]8-4
120-82-1
540-59-0
56-23-5
111097 -69-]
167 -66-3
111-44-4
1106-93-4
1107-06-2
Date Received: fr.l<n>f
Planner: AL
SUB DNAPL chemical iis!
Page 3 of5
Methylene chloride
Aerothene MM; DCM;
Dichloromethane; Freon 30;
Methane dichloride; Methylene
bichloride; Methylene dichloride;
Narcotil; NCI-C50I02; RCRA
waste number U080; Solaesthin;
Somethine; UN 1593
o-DCB; 1,2-Dichlorobenzene;
ortho- Di chi orobenzene;
o-Dichlorobenzol
I Ethane pentachloride; Pentalin
I Halowax@ 1013; 1,2,3,4,5-
Pentachloronaphthal ene
I PCP; Penta; 2,3,4,5,6-
Pentachlorophenol
PCM; PMM; Trichloromethane
sulfenyl chloride;
Trichloromethyl sulfur chloride
PCE; PERC; Perchlorethylene;
Ankilostin; Antisol I; Carbon
bichloride; Carbon dichloride;
Dee-Solv; Didakene; Dow-per;
ENT 1,860; Ethylene
tetrachloride; Fedal-UN; NCl-
C04580; Nema; PER; Perawin;
Perchlor; Perchloroethylene;
Perclene; Perclene 0; Percosolv;
Perk; Perklone; Persec; RCRA
waste number U210; Tetlen;
Tetracap; Tetrachlorethylene;
Tetrachloroethene; 1,1,2,2-
Tetrachloroethylene; Tetraleno;
Tetralex; Tetravec; Tetroguer;
Tetropil; UN 1897
Acetylene dicloride; trans-
Acetylene dichloride; 1,2-
Dichloroethyene; (E)-I ,2-
Dichloroethene; trans-
Dichloroethylene; 1,2- trans-
Dichloroethene; 1,2-trans-
dichloroethylene; sym-
Dichloroethylene; Dioform
o-dichlorobenzene
pentachloroethane
pentachloronapthalene
pentachlorophenol
perchloromethyl mercaptan
Tetrachloroethylene
Trans-l,2-dichloroethylene
75-09-2
95-50-1
76-01-7
1321-64-8
87 -86-5
594-42-3
127-18-4
540-59-0
Date Received: ~1~1
Planner: AL
SUB DNAPL chemical iis!
Page 4 of5
Trichloroethylene
TCE; Acetylene trichloride;
AIgylen; Anamenth; benzinol;
Blacosolv; Blancosolv; Cecolene;
Chlorilen; I-Chloro-2,2-
dichloroethylene; Chlorylea;
Chlorylen; Circosolv;
Crawhaspol; Densinfluat; 1,1-
Dichloro-2-chloroethylene; Dow-
tri; Dukeron;Ethinyl trichloride;
Ethylene trichoride; Fleck-flip;
Flock-flip; Fluate; Gemaglene;
Germalgene; Lanadin; Lethurin;
Narcogen; Narkogen; Narkosoid;
NCI-C04546; Nialk; Perm-a-
chi or; Perm-a-clor; Petzinol;
Philex; RCRA waste number
U228; Threthylen; Threthylene;
Trethylene; Tri; Triad; Trial;
TriasoJ; Trichloran;
Trichloroethene;
1,1,2- Trichlororthene;
1,2,2- Trichloroethene;
1,1,2- Trichloroethylene;
] ,2,2- Trichloro-ethylene;
Tri-clene; Trielene; Trieline;
Triklone; Trilen; Trilene; Triline;
Trimar; Triol; Tri-plus; Tri-plus
M; UN 17]0; Vestrol; Vitran;
Westersol
Halowax@; Nibren wax;
Seekay wax
Chlorethene; Chlorethylene;
Chloroethene; ] -Chlorethene;
Chloroethylene; ] -Chloroetyne;
Ethylene monochloride;
Monochloroethene; Monochlor-
ethylene; MVC; RCRA waste
number U043; Trovidur; UN
1086; VC; VCM; Vinyl C
monomer; Vinyl chloride
monomer
trichloronaphthalene
Vinyl chloride
bromodichloromethane
Dibromochloromethane
Bromoform
Trichlorofl uoromethane
Cis-I,2-dichloroethylene
tribromomethane
79"01-6
132] -65-9
75-01-4
75-27-4
124-48-]
75-25-2
75-69-4
Date t'{eceived: tf~~1
Planner: AL
SUB DNAPL chemical list
Page 5 of5
1 Trans-I,3-dichloropropylene
1 bis (chloro) methylether
Ibis (2-chloroethyl) ether
1 bis (2-chloroisopropyl) ether
I 2-chloroethylvinylether
1 chlorobenzene
1 bromomethane
1 m-dichlorobenzene
1 dibromomethane
I chloroethane
1 hexachloroethane
I tetrachloronapthalene
I Dichlorofluoromethane (in compressed form)
1 1,1, I ,2- Tetrafluoroethane
11,l,l,3,3-Pentafluoropropane
I
S:nancylm/DNAPL2
Ethane; 2-chloroethoxy
1
1 methyl bromide
11,3-Dichlorobenzene
1
1
I Halowax@; Nibren wax;
Seekay wax
I
1111-44-4
I 39638-32-9
/110-75-8
108-90- 7
1 74-83-9
1541-73-1
74-95-3
1 75-00-3
67-72-1
1335-88-2
1112-TFE
PFP
75-71-8
811-97-2
1460-73-1
1
Date f~eceived: 6flJrff"1
Planner: AL
APPENDIX E - HAZARDOUS MATERIAL STORAGE MONTHLY INSPECTION FORM
WALGREENS CLINICAL PHARMACY HMMP - JUNE 2009- REVISED FINAL
KTAASSOCIATES.INC.
Date R~ceived:~hYJe'of
Planner: AL
HAZARDOUS MATERIAL STORAGE MONTHLY INSPECTION FORM
Storage Area(s)
Date/time
Name
Reviewed bv
I
I
I
I
I
I
I
I
I
I Communir.ation SYStem!!.
Phone is accessible.
I Emerqen~ phone numbers are posted next to o.hone.
J Posted safety and waminq sians are evident and orooerlv disolaved.
I MSDSs are accessible and available.
Protective Equiqri1ent
Personnel Protection Eauioment is readily available.
General Work Area
Clinic/storaoe area is maintained secure:
No smokinq in area is oermitted.
doors are locked when unattended.
Secondarv ContainmlO!nt
Haz"lrdous material conlail1ers are stored in aooropriate se(:ondarv containment.
Product containers are nolleakinq, rusted. bulflinll or daman.ed.
The base under containers is in qoodcondilion (clean. dry. l!ouid-liqht, and free of any cracks or defects),
Sumps and collections systems are in (load condition: any drainan8 or release flows 10 controlled location.
Containers of stronn acids are stored in oolvethvlene trays or tubs.
lncomoatible materials are stored seoarateiv.
EmerqencY EauiDment
Fire extinquishers are present and fullv charoed.
Date of ias! fire extinauisher insoection is noted and current.
Spill control equioment (spill kit. neutralizers. absorbent oads) is accessible and available.
Spill PmVlmtinn Ml'!::l!':.lIrl'!S
Hazardous material containers are labeled.
Hazardous material containers are keot closed.
Hazardous material storaQe area has sians with safety and spill resoonse infonnation.
All oersons mananina hazardous material have received cruDer traininQ.
Storaqe areas are clean. well-lit. and in ClClIXJ condition.
No hazardous materials are stored in inappropriate locations.
Emoty containers are manaaed orooerlv.
Area Hazardous Materials Inspection Topic OK Comments
General Work Area
Emergency Equipment
Communications Systems
Protective Equipment
Secondary Containment
Spill Prevention Measures j
General Work Area J
Emergency Equipment I I
Communications Systems I I
Protective Equipment I I
Secondary Containment I I
Spill Prevention Measures _I- I
General Work Area I I J
Emergency Equipment I I I
Communications Systems I I J
Protective .Equipment I I J
I Secondary Containment I I I
-- _--+~Pill Prevention Measur~~I_ ..J
General Work Area I I
I Emergency Equipment I I
I Communications Systems I I
I Protective Equipment I I
I Secondary Containment I I
I Spill Prevention Measures I
Comments:
WALGREENS CUNICAL PHARMACY, SPRINGFIELD, OR
MAY 2009