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Home My WebLink AboutApplication APPLICANT 9/25/2020City of Springfield - Development & Public Works 225 Fifth Street Springfield, OR 97477 Drinking Water Protection Overlay District RProject Information "74i Applicant Name: � (Applicar t. complete this section)equired on Company: -ax: Address: 0,0 IlD W Applicant's Rep.: PCM4 0 Ita, hon ' Company: ax: Address: 4- -PO Y7Gx 266 1 4 I -W" (. - Property Owner: hon 24 Company: 'ax; Address: IM & ASSESSOR'S MAP NO: TAX LOT - Ill, 2'Li:0r"0^ Property Address: yH' Size of Property: Ac es ❑ Square Feet ^/ Ly" Zoning: Existing Use: Description of If you are filling in this form by hand, please attach your proposal d Proposal: cription m thiy application, Si natures: Please sign and Print your Required Property,Aj'' Information Associated Cases: / J name and date in the apqroil box do the next pacle. Case No.: O\`6`l - Date: '�-'Z`O D evlewed',h : Application Fee: $ Z` -\Z Technical Fee: �ti.i Postage Fee: $0 TOTAL FEES: I MoLA I PROJECT NUMB R: Revised 1/15/09 ddk 1 of 5 Signatures The undersigned acknowledges that the information In this application Is c rrect and accurate. Applicant: nn '��((// aYm' O' , Dat �'S55'''IIggnaturL �77R-('tdPJ �fhRP��tXFt� �`dWN€-�� Owner: owner, Signature I Revised 1/15/09 ddk 1 1 2 of 5 Drinking Water Protection Application Process 1. Applicant Submits a Drinking Water Protection Applicatio i to the Development $ Public Works Department tena and/or development The application must conform to the Drinking Water P otection Submittal Requirements Checklist on pages 4-5 of this applicatic i packet. Applications may be approved, approved with conditic Planning Division staff screen the submittal at the fror L counter to determine whether all required items listed in the Drinking Wateo Protection Submittal Requirements Checklist have been submitted. calendar days to the Hearings Official. Applications missing required items will not be accept d for sub ittal. 2. City Staff Conduct Detailed Completeness Check Planning Division staff conducts a detailed completen - ss check wjthin 30 days of submittal. The assigned Planner notifies the applicant in writing garding the completeness of the application. I An application is not be deemed technically complete intil all information necessary to evaluate the proposed development, its impacts, a. d its compliance with the provisions of the Springfield Development Code and c her applicable codes and statutes have been provided. Incomplete applications, as well as insufficient or unc ar data, will delay the application review process and may result in denial. 3. City Staff Review the Application and Issue a Decision This is a Type I decision and thus is made without pul lic notice and without a public hearing since there are clear and objective approval c tena and/or development standards that do not require the use of discretion. Decisions address all the applicable approval criteria E nd/or development standards. Applications may be approved, approved with conditic ns, or denied. The City mails the applicant and any party of standin a copy of the decision, which is effective on the day it is mailed. The decision issued is the final decision of the City bu may be appealed within 15 calendar days to the Hearings Official. Revised 1/15/09 ddk 1 3 of 5 DWP Overlay District Development Submittal Requirem nts Checklist NOTE: If you feel an item does not apply, please state the reason v by and att$ch the explanation to this form. rials in aggregate quantities 141A [?' Submitted Concurrently with Site Plan Review or Minimurr Development Standards devices proposed, and, if applications,: where applicable. drain to the sanitary sewer ❑ Application; Fee - refer to the Development Code Fee Schee to for the appropriate fee 4 of 5 calculation formula. A copy of the fee schedule is available a the Development & Public Works Department. The applicable application, technology, d postage fees are collected at the time of complete application submittal. [� DWP Overlay District Development Application Form ❑ Copy of the Deed ay ❑ copy of a Preliminary Title Report issued within the paste 10 days documenting and listing all encumbrances. MI/ownership M Narrative explaining the proposal and any additional informtion that rTay have a bearing in determining the action to be taken, including findings dem' nstrating compliance with the Standards for Hazardous Materials within Time of Travel ones (TOTZ) listed in SDC 3.3-235. NOTE: Before the Director can approve a DWP Overlay Dist r t Development request, information submitted by the applicant must adequately supi ort the request, All of the Standards for Hazardous Materials within TOTZ must be addi assed. In mplete applications,las well as insufficient or unclear data, will delay the applic tion review process and ;may result in denial. In certain circumstances, i, is advisable to hire a professional planner or land use attorney to prepare the reqL ired findings. ISI Three (3) Copies of a Plot Plan reduced to 8 lh" by 11'outlining the applicable TOTZ boundaries in relationshipto the property boundaries Three (3) Copies of theFollowing: Iii N 1p ❑ Use of hazardous materials that pose a risk to groundwat r that existed on the property prior to May 15, 2000, if applicable ❑ Hazardous Material Inventory Statement and Material SaP ty Data Sheet for all materialsentered on the Statement. Hazardous material- eights shall be converted to volume measurement for purposes of determining amou - s (i.e. 10 pounds shall be considered equal to one gallon) N A ❑ List of chemicals to be monitored through the analysis of roundwat(Ir samples and a monitoring schedule if groundwater monitoring is anticipe ed to be required [Detailed description of the activities conducted at the faci ty that involve the storage, hand ling;'.treatment, use, or production of hazardous mal rials in aggregate quantities greater than 500 gallons Description of the primary and any secondary containmer devices proposed, and, if V V'W' applicable, clearly identified as to whether the devices wil drain to the sanitary sewer or stormwater system III Revised 1/15/09 ddk 4 of 5 u ProposedHazardous Material Management Plan for the procedures to be followed to prevent, control, collect, a release of a hazardous material ly Description of the procedures for inspection and mainte Q Dnd emergency equipment escription of the plan for disposition of unused hazard material waste products over the maximum allowable a transportation and proposed routes that indicates pose of any unauthorized I of containment devices iterialslor hazardous s, including the type of Revised 1/15/09 ddk I 5 of 5 P R S P C T Drinking -Water Protection for the City of Springfield Property: 790 30" St. bid C Springfield, OR 97478 Date: 9/23/2020 Use of hazardous materials that pose a risk to groundwater that existed on the property prior to May 15, 2000. ' -Of these there are none to our knowledge. The property owner states the property ground has been inspected since this date to verify there are no hazardous materials in the ground or on or around the property that would pose a risk to groundwater. Groundwater safety for our community is a high concern and there no contaminants. Hazardous Material Inventory Statement and Material Safety Data Sheet for all materials entered on the Statement. Hazardous material weights shall be converted to volume measurement for purposes of determining amounts. 10 pounds shall be equal to 1 gallon. Hazardous Material Inventory Statement 1. Ethanol never exceeding 500gal 2. Acetone never exceeding lgal 3. Heptane never exceeding 270gal 4. Toluene never exceeding 55gal Hazardous Material Safety Data Sheet Attached in separate pdf, Date Amount of Material Safety Precautions Employee Accessing Used Needed Materials mm/dd/yyyy # of gallons Gloves, mask needed, Employee time etc. A detailed description of the activities conducted at the facility that involve the storage, handling, treatment, use, or production of hazardous materials in aggregate quantities greater than 500 gallons. -The Ethanol, Acetone, and Toluene on-site would never exceed a few bottles or 10 gallons. This is stored in a cabinet inside the facility that employees need to sign the datasheet for when using the material. Ethanol would be stored outside the building in flame retardant polyethylene tote. Each tote is UN/DOT approved meeting specification 31 HA1 N. A galvanized steel cage surrounds the tote for further safety. This is also not expected to exceed 500 gallons. Each Tote and/ or Barrell will have a spill containment platform Features high-density polyethylene construction for excellent chemical resistance. Will not rust or corrode. Grating is easily removed and has 1-3/4" square openings for effortless cleaning. Allows 2 -way forklift fork access for easy maneuverability. Meets EPA requirements for secondary spill containment of hazardous materials. 40 CFR 264.175. Description of the primary and any secondary containment devices proposed, and, if applicable, clearly identified as to whether the devices will drain to the sanitary sewer or stormwater system. -The containment devices areas listed above in the last paragraph. Standard bottles for the isopropyl alcohol that will be used for cleaning. The UN/DOT approved totes meeting specification 31 HA1N for the ethanol that will also be used primarily for cleaning. Neither of the substance will ever have any contact with groundwater whatsoever. After they are used for cleaning towels will be disposed of properly in a garbage can that meets industrial specifications and then therefore the alcohol will never have contact with groundwater. It is of our utmost priority to keep the groundwater of our city safe and without contamination from materials used. The materials will never be drained into a sewer or stormwater system ever. They will be closely monitored inside the building and then disposed of property so as to never have contact with groundwater and therefore pose no risk of contamination. Proposed Hazardous Material Management Plan for the facility that indicates procedures to be followed to prevent, control, collect and dispose of any unauthorized release of hazardous material. -We will have rigorous procedures for handling any potentially hazardous materials so as to keep our business, employees, and groundwater all safe. Some procedures are mentioned above in the previous paragraph. Employees will sign, track, and log any potentially hazardous materials. Any potentially hazardous materials will be disposed of properly through the proper disposal system and never under any circumstances be drained into sewer or storm drains on-site. A spill containment tray will be located under UN/DOT approved totes meeting specification 31 HA1/Y. This will ensure that if there was every any spill no ethanol would ever have the chance to get into the groundwater. However, even if the ethanol did spill from the tote, it is extremely unlikely/impossible that the ethanol would ever get into the groundwater because it would evaporate long before that happened. Description of the procedures for inspection and maintenance of containment devices and emergency equipment. -UN/DOT approved totes meeting specification 31 HAf/Y will be inspected frequently to ensure there are no leaks or cracks. It is very unlikely that there ever would be because of the specifications that they meet. Isopropyl alcohol bottles will be inspected and signed off by an employee to ensure the integrity of the containers as well. These containers do not require any maintenance. If there was ever an issue with the structural integrity of the containers, we would purchase new ones so that we would not risk any spills or contamination to groundwater. Description of the plan for the disposition of unused hazardous materials or hazardous material waste products over the maximum allowable amounts, including the type of transportation and proposed routes. -It is very unlikely that this would occur as both ethanol and isopropyl alcohol have an exceptionally long maximum allowable time for storage. If the occasion did arise, a professional would be called to the site to take possession of any expired materials and they would then properly dispose of them. Our business would not engage in the transportation of any potentially hazardous materials. We would have a professional make sure everything was disposed of properly and safely. For more information on our practices please reference our attached sds and waste material SOP's. 6 PRSPCT CHEMICAL SPILL CLEANUP PROCEDURES Chemical Spill Cleanup Procedures You should NOT clean up a spill if: • You don't know what the spilled material is • You lack the necessary protection or equipment to do the job safely • The spill is too large to contain • The spilled material is highly toxic • You feel any symptoms of exposure Instead contact one of the following: x3194 EH&S (24 hr assistance line) May have to wait up to 15 min for call back Call 9-911 if spill is immediately health -threatening Spill Response Scheme: Evaluate and Notify • Assess the toxicity, flammability, or other properties of material (see label and MSDS) • For flammables, remove or mm off all ignition sources such as motors, pumps, fridges. • Determine if there is an immediate health threat to you or your neighbors If so, alert neighbors, isolate the area an call for help using the numbers above. • If spill is minor, begin cleanup following steps below Containment/Cleanup • Don gloves, eye protection, lab coat, etc. • Contain and absorb spill using absorbents appropriate for the material • Protect floor drains from contamination, by putting absorbents or barriers around them • Package and label waste. Include contaminated clothes, rags, equipment, etc. • Store temporarily in a fume hood is material is volatile Followup • Send Hazardous Materials/ Waste Pickup Request form to EH&S • Reorder and restock cleanup materials used • Inforrn EMS if there were any personnel exposures, or release to the drain system P R S P C T ......................................................................... EMERGENCY ACTION PLAN ......................................................................... Prepared by: Dalton Baarstad And Dain Farah March 2019 1.0 INTRODUCTION PRSPCT LABS LLC is committed to ensuring the health, welfare and safety of all aur employees. This Emergency Action Plan (EAP) was created with this in mind. A well designed EAP saves lives as well as property damage. Emergency conditions are rare, but there must be a concise plan in place in the event that an emergency does happen. This document is available to all PRSPCT employees, temporary employees, and contracted employees. Familiarity with the procedures in this plan will help reduce the possibility of an emergency, while limiting its impact if an emergency occurs. This plan will be implemented only in an emergency or during a simulated emergency to evaluate the performance of this plan. It is the responsibility of all our employees to be alert to conditions and to try and remedy potentially dangerous situations before they become emergencies. Preventing an emergency is less costly to life and property than reacting to one. With constant attention and careful actions, this plan may never be implemented. 2.0 LINES OF COMMUNICATION In order to properly coordinate the myriad of activities during an emergency, PRSPCT LABS LLC. has designated an employee to be the emergency response coordinator (ERC). This individual will coordinate emergency actions between PRSPCT employees, management, and the outside emergency response agencies (police, fire, etc.). By designating one individual to be the communication pipeline, confusion and the potential for error will be reduced. The Emer_encv Response Coordinator (ERC) is not a rescue worker. The ERC is a trained individual whose primary role is to assess a situation, gather information and provide recommendations to emergency personnel. 2.1 DESIGNEES The designated Emergency Response Coordinator is: Name Title Role Dain Farah Environmental Manager Primary Dalton Baarstad President Alternate Charlie Philip Shop Superintendent Alternate 2.2 ACTIONS In the event of an emergency, the witnessing individual must notify someone in the main office (ext. 211) who will call or page the Emergency Response Coordinator (ERC). The ERC will coordinate the necessary emergency activities including: • Employee evacuation • Requesting emergency response • Notifying the proper regulatory agencies (if required) including; Department of Environmental Protection, the Occupational Safety and Health Administration and/or the Coast Guard. • Notifying the proper levels of management. • Providing the required information to emergency response agencies including, but not limited to: chemical inventories and MSDS sheets. • Consolidating employee verification information. The Emergency Response Coordinator (ERC) will also perform necessary duties as required in the PRSPCT Hazardous Waste Contingency Plan. In the event that it has been verified that the primary Emergency Response Coordinator (ERC) is not on site, the alternate ERC will perform the actions described herein. The alternate ERC will notify the primary ERC as soon as possible. In the event that neither the primary nor the alternate ERC is on site, the witnessing individual will notify the proper emergency response agencies as directed on the emergency telephone list (Appendix A). The witnessing individual will notify the proper level of management who will notify an Emergency Response Coordinator. Once an evacuation is signaled, all employees will exit the facility as directed in the Evacuation Plan (Section 4.0). 3.0 EMERGENCY RESPONSE The most important action for an employee who witnesses an emergency is to assess the situation and to react quickly and properly for the situation at hand. Since it is not possible to train every employee in the proper actions for each separate and unique event, employees are directed to notify the Emergency Response Coordinator (ERC) of the emergency. This individual is responsible for providing the necessary response to address the emergency and bring the situation under control. In any emergency, the witnessing individual should be prepared to give the following information to the Emergency Response Coordinator: • The nature of the emergency: fire, chemical spill, severe injury • The exact location of the emergency • The number of individuals involved in the emergency and the extent of any injuries: specify if anyone is immobilized or trapped in the area. • The duration of the emergency: how long has it been since encountered. The following information provides specific details for cerin emergency conditions. Since each emergency is a unique event and may encompass any combination of emergency conditions, individuals are requested to use common sense and be as accurate as possible when notifying the Emergency Response Coordinator. A fire's greatest immediate danger is usually the smoke emitted from the fire. Smoke can affect personnel in remote locations minutes before the actual fire reaches that area. Small fires need to be controlled quickly by trained individuals. Anyone not directly associated with the fire suppression activity should leave the immediate area. Lager fires which cannot be contained with one fire extinguisher require a facility evacuation and immediate response by a professional fire fighting team. In all fire situations, of any size, the Emergency Response Coordinator must be notified. The ERC must inform the fire department of the fire even if it has been contained and appears to be properly suppressed. Any individual who chooses to tackle a small fire using a fire extinguisher should not perform this task alone. The extinguisher user should quickly designate one employee to stand near the escape route and monitor them. In the event that the fire spreads in a manner which. could trap the extinguisher user, the monitoring individual should notify the extinguisher user to stop and evacuate the area. The monitor is not to rescue the extinguisher user if trapped or rendered unconscious. He/she should inform the Emergency Response Coordinator who will provide the necessary services to secure the user's rescue. The extinguisher user should be properly trained in small fire suppression including the use and limitation of portable fire fighting equipment. This individual should designate another employee to inform the Emergency Response Coordinator while they extinguish the fire. An individual should not attempt to fight a fire using portable fire fighting equipment in the following situations: • If the individual has not been trained in extinguisher fire fighting • An evacuation has been ordered • The fire is producing large amounts of choking smoke • The fire is blocking an escape route • The fire is burning on or near flammable chemicals or compressed gases • The fire is burning chemicals in bulk containers • The fire is spreading quickly • The fire is too large to be handled with one extinguisher Any person who witnesses a fire should perform the following tasks: • Notify individuals in the immediate area of the fire • Contact the Emergency Response Coordinator. Inform the ERC of the fire's location, extent, materials burning and the nature of any injuries. • Based on the information given from the witnesses, the Emergency Response Coordinator may signal a general evacuation from the facility. (1) The Emergency Response Coordinator will contact the local fire department and will provide them with the information received from the witnessing individual. (2) The Emergency Response Coordinator will meet the fire department outside the building and provide them with information on the fire and Material Safety Data Sheets for the materials burning inside (if possible). (3) The Emergency Response Coordinator will provide the proper actions and information requested by the fire department or additional emergency agencies (if warranted). The ERC will provide necessary information to management on the situation and abatement activities as required. (4) The fire area will be designated safe for re-entry only after authorization from the emergency agency and inspection by the Emergency Response Coordinator. 3.2 CHEMICAL SPILL In any situation which involves a chemical spill, every effort should be made to maximize protection and to gain as much information about the chemical as possible. Reading the Material Safety Data Sheet (MSDS) is the first step in handling any spill. The MSDS informs the reader about the hazards of the chemical, the effects of exposure and the types of personal protective equipment which must be worn during chemical use and spill cleanup. Every individual who encounters a spill of any size should read and understand the MSDS for that particular chemical from a safe distance before proceeding with cleanup activities. Upon encountering an uncontrolled chemical spill of any hazardous material, the witnessing individual should perform the following activities: (1) Notify individuals in the immediate area of the spill. All individuals in the immediate area of the spill should stop work activities and leave the spill area. Do not throw any electrical switches or unplug any electrical equipment. (2) From a remote location, determine what chemical(s) that have spilled. (3) Contact the Emergency Response Coordinator and inform him of the spill including the location, material and quantity. Follow any special instructions given by the ERC. (4) The Emergency Response Coordinator will perform procedures to mitigate the effects of the spill and contact the appropriate parties as directed in the hazardous Waste Contingency Plan. (5) The Emergency Response Coordinator will determine if an evacuation is warranted. He/she will signal this evacuation. (6) The Emergency Response Coordinator will inform the proper emergency spill response agency to clean up the spill. (7) The Emergency Response Coordinator will inform the proper regulatory agencies if the amount of chemical discharged into the environment is above the reportable quantity for a regulated chemical. (8) If an evacuation is not required, the Emergency Response Coordinator will proceed to the area and isolate the spill using approved spill containment equipment. The ERC will wear proper personal protective equipment as directed by the MSDS when isolating the spill. (9) The Emergency Response Coordinator will provide activities and information as requested by the spill response agency or additional emergency agencies (if warranted). He/she will provide necessary information to management on the extent of the emergency and abatement activities as requested. (10) The spill area will be designated safe for re-entry only after the spill has been completely contained and inspected by the Emergency Response Coordinator. 3.3 SEVERE INJURY A person with a severe injury is one that demands immediate medical attention; examples include: excessive bleeding, heart attack, asphyxiation, or engulfment. In most cases the first five minutes are critical. On encountering a severely injured individual the witnessing individual should: (1) Assess the situation form a safe distance and determine the extent of injuries. Determine if there are any conditions which could put others in danger such as leaking gas pipes, tanks or cylinders, broken electrical lines, or other hazards. (2) Dial 911 and request an ambulance. Alert the emergency agency of the facility location and the extent of the injuries. (3) Inform the Emergency Response Coordinator of the situation and that an ambulance has been called. The Emergency Response Coordinator will proceed outside to meet the ambulance and escort responders to the injured individual. Witnessing individuals should properly protect themselves from blood home pathogens by avoiding blood and blood products and by wearing impervious gloves. In no case should injured individual be left alone for any extended period of time. IMPORTANT Persons with severe injuries should not be moved unless present conditions could cause greater injury to the victim, e.g., a fast spreading fire. If person must be moved, isolate the victim's neck and back to prevent movement as much as possible. IMPORTANT Individuals should not attempt to rescue an injured employee inside a confined space. Persons inside a confined space should be retrieved from outside of the space using winches and/or lifelines only if they are in imminent danger. 4.0 EVACUATION PLAN This section details evacuation procedures for any PRSPCT LABS LLC, building. All PRSPCT personnel, contractors, and visitors are expected to follow this plan in the event of an evacuation. H101rJeFlIf Employees will be notified to evacuate the building. This signal can only be authorized by the Emergency Response Coordinator or appropriate level of management (e.g., President, Vice President). If commanded to evacuate, all employees will comply regardless of the individual announcing the evacuation. 4.2 ESCAPE ROUTES All employees shall immediately leave the work area using the shortest route to the outside. If this route is blocked, employees will use the next shortest route. Escape routes are provided in the attached site drawings (Appendix B). All employees should be trained in the evacuation routes for their work area. 4.3 ASSEMBLY AREAS The designated assembly area is across the steel bridge next to the Metaleraft building. The exact location is indicated on the attached site drawing (Appendix B). Once in the assembly area, be sure to identify yourself to your supervisor or the Emergency Response Coordinator. The ERC and department supervisors in cooperation with the ERC will ascertain if any employees are remaining in the building. Stay clew of the road, trucks or equipment. Do not leave the assembly area unless instructed to do so. Do not proceed to your automobile or any other area. Any individuals not accounted for are assumed to be trapped inside the building. There may be more than one roll call to assure that everyone is safe. Your assistance in this manner will prevent emergency responders from attempting an unnecessary and dangerous rescue. 4.4 CONDUCT Once an evacuation has been signaled, all employees should follow these instructions to ensure the safe evacuation of themselves and their fellow employees: (1) Shut down operating machinery if it can be done quickly without endangering personnel. If a flammable chemical has spilled, do not shut down any electrical equipment. (2) Leave the building using the identified escape routes. If the primary route is blocked, use a secondary route. (3) Do not carry any food, drinks, chemicals, product, or tools while evacuating. Place these items on the nearest available raised surface (NOT THE FLOOR!). (4) Walk briskly but do not nm. Use handrails in stairways. (5) If the smoke becomes thick, crawl on the ground. Be sure to avoid spilled chemicals or sharp objects. (6) Check doors for heat prior to exiting. (7) Proceed directly outside. Do not go to other areas to retrieve personal items. (8) Once outside, proceed to the designated assembly area by walking along the edge of the road. Stay clear of the building. Be aware of emergency vehicles and equipment. (9) At the designated assembly area, meet with your work group and identify yourself to your supervisor and the Emergency Response Coordinator. Be sure this individual commns your presence. (10)Do not re-enter the facility or leave the designated meeting area unless told to do so by a member of an emergency agency (e.g., fire, police) or by the Emergency Response Coordinator. 4.5 SUPERVISORS Supervisors play a key role in an evacuation by assuring that all personnel have been trained in evacuation conduct and that personnel follow these procedures in the event of an evacuation. Once at the designated assembly area, supervisors must ensure that all of the employees in their work group as well as contract personnel under their responsibility are accounted for. Supervisors should select at least one alternate individual to take over their duties should they be absent or injured during an evacuation. This alternate individual should be fully informed of the required duties of this function. 110 IMPORTANT Supervisors are not instructed to perform rescue operations or assist in emergency procedures. Their primary purpose is to inform and coordinate personnel in their department in an emergency evacuation. Supervisors are instructed to leave the facility as quickly and as safely as possible and to assist others in doing the same. Duties prior to an evacuation: • Ensure that personnel have been informed and understand the rules governing evacuation conduct. • Ensure that personnel understand their primary and secondary escape routes as well as the location of the assembly area. Duties during an evacuation: • Ensue the orderly evacuation of all personnel in a prompt and safe manner. • Ensure fire and stairwell exit doors are closed following the evacuation of the area. Duties of the designated assembly area: • Account for all department personnel. • Inform the Emergency Response Coordinator of any missing employee. • Report any employees injured during the evacuation to emergency personnel. • Ensure that all personnel stay in the designated assembly area until instructed to do otherwise. 5.0 TRAINING In order for all facets of this plan to be properly executed, all employees of PRSPCT shall be trained in the elements of this plan. Special training is required for Emergency Response Coordinators. 5.1 ALL EMPLOYEES 11 • Each employee shall know the proper response for each type of emergency that they may encounter at PRSPCT. • He/she should know the identity of the Emergency Response Coordinator and how to contact him/her in an emergency. • He/she should be familiar with the lines of communication and the activities of the Emergency Response Coordinator. • Each employee shall know the evacuation procedure and designated assembly area. • Each employee shall know the proper conduct while in the assembly area. • Each employee shall be informed that fire extinguishers are designated for trained individuals only. Employees shall be trained in such procedures on initial hire and refreshed at least once annually. A facility evacuation drill may be executed at management's discretion to fulfill the training requirements. 5.2 SUPERVISORS In addition to being properly trained in all of the elements described in Section 5. 1, Supervisors shall be properly trained in their duties prior, during and after an evacuation as specified in Section 4.5 of this plan. 5.3 EMERGENCY RESPONSE COORDINATORS ,• Each of the Emergency Response Coordinators will be fully trained and familiar with all facets of this Emergency Action Plan. • Emergency Response Coordinators will be familiar with their roles and responsibilities as directed in the Hazardous Waste Contingency Plan. • Emergency Response Coordinators will be properly trained in notifying appropriate agencies, as listed in Appendix A, in response to emergency incidents. • Emergency Response Coordinators will be trained in Hazardous Waste Operations and Emergency Response (HAZWOPER) for a minimum of 40 hours initially and 8 hours annually. • Emergency Response Coordinators will be trained in proper management procedures for handling confrontations with nearby residents or members of the media. • Emergency Response Coordinators will be properly trained in the PRSPCT Respiratory Protection Program. They will undergo the required procedures to wear air purifying respirators. 12 13 CHEMICAL HAZARDOUS WASTE DISPOSAL PROCEDURES DON'T DUMP IT DOWN THE DRAIN! To prevent injury, minimize environmental health hazards, and meet regulatory requirements, campus hazardous waste generators most comply with strict chemical waste disposal procedures. Please read this carefully and become familiar with the information so that campus waste can be disposed of in a safe, efficient, and legal manner. > Do not dispose of chemicals via sink or trash cans. > Do not use fume hoods to intentionally evaporate chemicals. > Do not store waste outside work area. > Do not abandon hazardous materials and waste. > Individuals may be held criminally liable for violations of applicable laws and regulations. HOW TO HANDLE CHEMICAL WASTE Minimize Initial Generation • Review each experimental protocol to assure that hazardous and radioactive reagents are used efficiently and that excess purchases are minimized. • Conduct microscale processes to minimize hazardous materials used and generated. • Use substances which can he neutralized or stabilized, either physically or chemically. Use radioactive materials which can be practically stored for decay (half-lives less than 60 days). • Substitute with less hazardous materials. • Always plan ahead (budget, supplies, storage, etc.) with regard to hazardous waste disposal. • Participate in the campus Surplus Chemical Program. Comply with Requirements for Waste Storage Store chemicals in appropriate containers designed for chemicals. Containers must be completely sealed to prevent spillage (no open -top glassware!). Liquid waste must be in screwtop containers only, and must not be filled over 80%. Outside surfaces of containers must be clean and free of any contamination. Gas cylinders and lecture bottles must have regulators removed. Red Biohazard bags are for Biohazardous waste only. Sharps must be stored in puncture -proof containers. Store chemical waste in a designated location (low traffic, safe, secure, contained, etc.). Label this storage area as "Hazardous Waste Storage Area". Appropriately label Every Container Use the official campus hazardous waste label and provide all the necessary information. All hazardous waste containers must be labeled with the words "Hazardous Waste Do not loose track of container contents! All unknowns must be analyzed and their hazardous components identified at the generator's expense. Waste must be identified by chemical name. Labels such as "Inorganic Waste' and "Organic Waste' are not adequate (no abbreviations). All constituents in solid and liquid mixtures must be identified, and to the extent possible their concenhations stated. Identify the chemical hazard classification(s) of the waste (i.e.: Flammable, corrosive, oxidizer, etc.) Any original/existing labels must be defaced by either removal or lining out. Date containers. Dispose of hazardous waste containers in a timely manner. Under no circumstances store hazardous waste containers for more than 270 days or 9 months. Properly Segregate Hazardous Waste Chemicals Segregate solids, liquids, and gases. Segregate into the following categories: Halogenated organics - Strong oxidizers Non -halogenated organics - Peroxide -forming chemicals Acids of pH <2 (do not mix) - Cyanides Alkaline solutions of pH > 12.5 (do not mix) - Chemical carcinogens Alkali metals and other water reactives - Unstable chemicals Heavy metal solutions and salts - Other toxic materials Bmhazardous material Contact EH&S at ext. 8894 or your supervisor for more information. Proper Disposal • To arrange for a chemical or radioactive waste pickup, please fill out a UCSB Waste Pickup Request Form and send it to EH&S via campus mail or fax it to 893-8659 (please do not call EH&S). To electronically send a waste pickup request visit EH&S' web site at www.ehs.ucsb.edu. Note: Although a continuation sheet is provided, one-page pickups are desired. • EH&S cannot accept responsibility for improperly labeled, packaged, and/or segregate chemicals, and will not pick them up. • Transferring waste into appropriate containers is the generator's responsibility. • Waste containers become the property of EH&S and will not be returned. • To discuss disposal procedures, options, and/or projects related to hazardous waste disposal contact EH&S at extension 3293/7705. WHAT TO DO IN THE EVENT OF A SPILL For emergencies involving chemical spills, call 911. For technical assistance in non -emergencies involving chemical spills, call EH&S at ext. 3194 (24 -hr. Hazardous Material Technical Assistance Line). For chemical spills in which technical assistance is not needed, EH&S must be notified immediately for compliance purpose and to arrange pickup of the spilled materials. Please contribute to a safe working environment. Your cooperation is appreciated. STORM WATER QUARTERLY VISUAL EVALUATION PRSPCT INSTRUCTIONS Visual examination for storm water quality must be performed before the last day of the following months: March, June, September and December. Sampling must be performed during a qualifying rainfall event as follows: • Event must produce at least 0.1 inches of rainfall (steady rain, not a sprinkle) to be considered a Qualifying Event. • Qualifying Event must be at least 72 hours from a previous rainstorm meeting the conditions of a Qualifying Event. • Samples must be collected within 30 minutes from the start of the Qualifying Event or as soon as practicable (not to exceed 60 minutes). • Samples shall be collected at the outfalls (01, 02) as indicated on the evaluation form and associated drawing. • Examination of the samples shall be conducted in a well -lit area. • Personnel shall examine the sample visually for color, odor, suspended solids, foam and sheen. Unusual conditions or further description should be indicated on the form. A small amount of rainbow -like sheen is indicative of minor gasoline and/or oil contamination from vehicles in the puking lot. A milky, white or significant rainbow sheen is an unusual condition that requires further investigation. • Conditions observed must be marked on the visual evaluation form. • After the visual evaluation is complete, samples may be discharged (dumped) into the receiving water. Laboratory analysis is not required for this quarterly visual examination. • The form must be kept on-site with the Storm Water Pollution Prevention Plan. STORM WATER QUARTERLY VISUAL EVALUATION PRSPCT Person: Title: Description: Date: Start Time: ❑ Foam ❑ AM PM Outfall Condition Description: Number: 01 1 ❑ Unusual Color ❑ Foam Description: I ❑ Unusual Odor I Lj Oil Sheen ❑ Suspended Solids I ❑ Other Description /Notes Signature: Number: 02❑ Unusual Color LJ Foam Description: EI 'a! Odor Oil Sheen ❑ Suspended Solids I ❑ Other Description / Notes Signature: Poly - Metal Finishing FIRST AID KIT INSPECTION ❑ 1. Ammonia Inhalant ❑ 2. Eye Dressing ❑ 3. Bandages ❑ 4. Scissors / Tweezers ❑ 5. Wet Pruf Pads ❑ 6. CPR Shields ❑ 7. Finger Cots ❑ 8. Band-Aids ❑ 9. Cold Pack ❑ 10. Burn Cloth / Water Gel ❑ 11. Thermometers ❑ 12.Gloves ❑ 13.Antiseptic Wipes ❑ 14. Eyewash Solution ❑ 15.Antiseptic Spray ❑ 16. Hydrogen Peroxide ❑ 17. Calcium Gluconate Gel Inspected By: PRSPCT LABS LLC INSPECTION 1. Inventory OK. No items depleted. ❑ Yes ❑ No 2. No chemical leaks from containers or dressing. ❑ Yes ❑ No 3. No materials damaged or deteriorated ❑ Yes ❑ No 4. Cabinet secure to wall and door secure ❑ Yes ❑ No 5. Spill kits in place ❑ Yes ❑ No 6. Hearing Protector Inventory ❑ Yes ❑ No 7. List additional inventory needed By: Date: Please Print Signature Monthly Safety Inspection Form 1 of 5 SHOWER AND EYEWASH INSPECTION Area 1. A -Line 2. A -Line 3. C -Line 4. B -Line 5. B -Line 6. C -Line 7. C -Line 8. E -Line 9. E -Line (A&P) 10. F -Line 11. G -Line 12.WWTP 13.MEK Room 14 -Chemical Storage 15.WWTP 16.WWTP 17.E -Line Notes: Inspected By: Eauiumen OK t Shower ❑ Yes ❑ No Eyewash ❑ Yes ❑ No Bottle ❑ Yes ❑ No Shower ❑ Yes ❑ No Eyewash ❑ Yes ❑ No Eyewash ❑ Yes ❑ No Shower ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Bottle ❑ Yes ❑ No Eyewash ❑ Yes ❑ No Shower ❑ Yes ❑ No Eyewash ❑ Yes ❑ No Please 0 Signature PRSPCT LABS LLC Comments Date: Monthly Safety Inspection Forth 2 of 5 FIRE EXTINGUISHER INSPECTION PRSPCT LABS LLC Area Equipment OK Comments 1. Priming ABC Dry Chemical ❑ Yes ❑ No 2. Curing BC Carbon Dioxide ❑ Yes ❑ No 3. SS Etch 1 BC Std. Dry Chemical ❑ Yes ❑ No 4. Lab BC Halon ❑ Yes ❑ No 5. Vapor Blast ABC Dry Chemical ❑ Yes ❑ No 6. C -Line ABC Dry Chemical ❑ Yes ❑ No 7. Boiler (E) BC Halon ❑ Yes ❑ No 8. WWTP ABC Dry Chemical ❑ Yes ❑ No 9. WWTP BC Halon ❑Yes ❑ No 10. Masking ABC Dry Chemical ❑ Yes ❑ No 11. Masking BC Dry Chemical ❑ Yes ❑ No 13. CC Inspect ABC Dry Chemical ❑ Yes ❑ No 14. Loading Bay BC Carbon Dioxide ❑ Yes ❑ No 14A. Mask Hall ABC Dry Chemical ❑ Yes ❑ No 14B. B -Line ABC Dry Chemical ❑ Yes ❑ No 15. Men's Room ABC Dry Chemical ❑ Yes ❑ No 16. Alodine BC Carbon Dioxide ❑ Yes ❑ No 17. Boiler (W) ABC Dry Chemical ❑ Yes ❑ No 18. Compressor ABC Dry Chemical ❑ Yes ❑ No 19. Compressor BC Std. Dry Chemical ❑ Yes ❑ No 20. MEK Room BC PK Dry Chemical ❑ Yes ❑ No 21. MEK Room BC PK Dry Chemical ❑ Yes ❑ No 23. Maintenance ABC Dry Chemical ❑ Yes ❑ No 24. Acid Shed ABC Dry Chemical ❑ Yes ❑ No 25. Women's RR ABC Dry Chemical ❑ Yes ❑ No 26. Warehouse ABC Dry Chemical ❑ Yes ❑ No 27. Rectifiers ABC Dry Chemical ❑ Yes ❑ No Inspected By: Date: By: Please Print Signature Inspection GAS CYLINDER INSPECTION PRSPCT LABS LLC 1. Propane Cylinders (Warehouse) Number of Cylinders: _ Full _ Empty Secured ❑ Yes ❑ No Non -leaking ❑ Yes ❑ No Good condition ❑ Yes ❑ No 2. Freon Cylinders (Wastewater Treatment) Number of Cylinders: _ Full _ Empty Secured ❑ Yes ❑ No Non -leaking ❑ Yes ❑ No Good condition ❑ Yes ❑ No 3. Freon Cylinders (Utility Room) Number of Cylinders: _ Full _ Empty Secured ❑ Yes ❑ No Non -leaking ❑ Yes ❑ No Good condition ❑ Yes ❑ No 4. Acetylene Cylinders (Maintenance Area) Number of Cylinders: _ Full _ Empty Secured ❑ Yes ❑ No Non -leaking ❑ Yes ❑ No Good condition ❑ Yes ❑ No 5. Oxygen Cylinders (Maintenance Area) Number of Cylinders: _ Full _ Empty Secured ❑ Yes ❑ No Non -leaking ❑ Yes ❑ No Good condition ❑ Yes ❑ No Inspected By: Date: By: Please Print Signature Monthly Safety Inspection EMERGENCY EQUIPMENT INSPECTION PRSPCT LABS LLC Equipment OK Emergency Response Cabinet 1. Gloves ❑ Yes ❑ No 2. Respirators ❑ Yes ❑ No 3. Respirator Cartridges ❑ Yes ❑ No 4. Boots ❑ Yes ❑ No 5. Aprons ❑ Yes ❑ No 6. Face Shields ❑ Yes ❑ No 7. Goggles ❑ Yes ❑ No 8. Duct Tape ❑ Yes ❑ No 9. Protective Clothing ❑ Yes ❑ No Emergency Response Equipment Spill Control Kits ❑ Yes ❑ No Drum Pumps ❑ Yes ❑ No Mobile Haywood Pump ❑ Yes ❑ No Pallet Jack ❑ Yes ❑ No Drum Truck ❑ Yes ❑ No Notes: Comments Inspected By: Date: By: Please Print Signature Monthly Safety Inspection Form 5 of 5 Date: 3/1/2D19 �(�f 5UILDINO VISION AND Product CodeO SAFETY DATA SHEET 1. Identification Product Name: lAcetone Product Code: SDS Date: 3/1/2019 Use: Industrial Address: BW 1251 Frontenac Rd. Ste 150 Naperville IL 60563 Phone: (331)281-0154 CHEMTEL: (gee) 255-3924 2. Hazard(s) Identification GHS Classification Flammable liquids, (Category 2) Eye irritation, (Category 2A) Specific target organ toxicity fallowing single exposure, )Category 3) Pictogram /� 1/1%, V J Signal Word jDanger Hazard Statement Highly flammable liquid and vapor Causes serious eye irritation May cause drowsiness or dizziness or eye protection/face protection. Avoid breathing vapors. IF IN EVES: Rinse cautiously with water for several minutes. act lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. In case of carbon dioxide, water spray mist or foam, dry chemical. If inhaled: Remove person to fresh air and keep comfortable for II a poison center/doctor if you feel unwell. Store in a well -ventilated place. Keep container tightly closed. Dispose of stainer to an approved waste disposal plant. Hazards Not Otherwise Classified: Not available 3. Composition/Information On Ingredients 4. First-aid Measures General Advice: Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. If Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In Case of Skin Contact: Wash off with soap and plenty of water. Consult a physician. In Case of Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Ca nsu It a physician. Most Important Symptoms and Effects, Both Acute and Delayed: The most important known symptoms and effects are described in the labelling. Indications of Any Immediate Medical Attention and Special Treatment Needed; No data available 5. Fire -fighting Measures Eginguishing Media: jUse water spray, alcohol -resistant foam, dry chemical or carbon dioxide. Special Hazards: jNo data available Advice for Firefighters 1wear self-contained breathing apparatus for firefighting if necessary. Further Information: Use water spray to cool unopened containers. 6. Accidental Release Measures Personal Precautions, Protective Equipment, and Emergency Procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. Environmental Precautions: lPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and container an electrically protected vacuum 7. Handling and Storage Safe Handling: Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Use explosion -proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. Safe Storage: Keep container tightly closed i n a d ry and welfventi lated place. Containers which a re opened no ust be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Flammable liquids 8. Exposure Controls/Personal Protection Name CAS Acetone 67-64-1 Engineering Control: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EUI. Skin Protection: Handle with butyl rubber gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection: Impervious clothin& Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory Protection: Where risk assessment shows air -purifying respirators are appropriate use afull-face respirator with multipurpose combination (US) or type AXBEK (EN 1438]) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full -face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of Environmental Exposure: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 9. Physical and Chemical Properties Appearance: Acetone Colorless, clear, liquid Odor: Acetone INo Data Available Odor Threshold: jAcetore No Data Available pH: jAcetone I IN. Data Available Melting/Freezing Point: Acetone -94°C (4377) Initial Soiling Point/Range: jAratone 56-C (133°) at 1,013 hPa (760 mmHgl Flash Point jAcetore -16.99°C(1.4YF)-Closed Cup Evaporation Rate: jAratone lNo Data Available Flammability: Acetone INO Data Available Upper Explosion Limit Acetone 13% Lower Explosion Limit jAcetone 2% Vapor Pressure: JAcetona 1245.3 hPa (184.0 mmHg) at 20°C (68°F) Vapor Density: Acetone jNo Data Available Relative Density: Acetone 0.791 g/mL at 25-C (77-F) Water Solubility: Acetone lCompletely Miscible Partition Coefficient: jAcetone jLow Pow: -0.24 Auto Ignition Temp: Acetone 465.0"C(8697) Decomposition Temp: Acetone No Data Available Viscosity: Acetone No Data Available 10. Stability and Reactivity Reactivity: INo Data Available Chemical Stability: Stable urxl.,mcommended storageconditions. Possibility of Hazardous Vapors may form explosive mixtu re with air. Reactions: Conditions to Avoid: JH.L flames, and Sparks Incompatible Materials: Bases, Oxidizing agents, Reducing agents, Acetone reacts violently with phosphorous oxychloritle. Hazardous Decomposition No Data Available Products: 11. Toxicological Information Name: CAS: Acetone 67-64-1 LD50 Oral -Rat- 7,060 mg/kg LC50 Inhalation - Rat -10 h - 20000 ppm Dermal: No data available Skin Corrosion/Irritation: Result: No skin irritation -24h Serious Eye Damage/Eye Irritation: Result: Mild eye irritation -24 h Respiratory or Skin Sensitization: NO Data Available Germ Cell Mutagenicity: No Data Available Carcinogenicity: Not identified as probable, passible or confirmed human carcinogen by IARC, NTP, or OSHA Reproductive toxicity -Human -female -Oral Effects on Newborn: Apgar score (human only). Effects on Newborn: Other neonatal measures or effects. Effects on Newborn: Drug dependence. Information: Central nervous system depression, narcosis, Damage to the heart. 12. Ecological Information Name CAS Toxicity Acetone 67-64-1 Toxicity to fish LC50-Oncorhynchus mykiss (rainbow trout) - 5,540 mg/I - 96 h, Toxicity to daphnia and LC50- Daphnia magna (Water flea) - 8,800 mg/I - 48 h 13. Disposal Considerations Dispose of contents/container in accordance with local/regional/national/international regulations 14. Transportation Information Proper Shipping Name: )Acetone Hazard Class 13 Identification Number: JUN1090 Packing Group: III Label Flammable Ship: UN1090 ACETONE CLASS 3 PG 11 15. Regulatory Information ie CAS 4302/304 No Components Were Identified 4313 No Components Were Identified :LA RQ=5,0001bs 71 4311/312 Immediate(Acute) Health Hazard, Fire Hazard P66 INo Components Were Identified product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory, 16. Other Information, Including Date of Preparation or Last Revision SDS Date: 3/1/2019 Disclaimer: information and recommendations contained in the Safety Data Sheet (SDS) are supplied pursuant to 29 CFR .0.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. The information and ommendations set forth herein are presented in good faith and believed to be correct as ofthis date hereof. BVV, veveq makes no representation as to the completeness or accuracy thereof, and information is supplied upon the rens condition that the persons receiving the information will be required to make their own determination as to its :ability for their purposes prior to use. In no event will BVV be responsible for any damages of any nature atsoever resulting from the use of, reliance upon, or the misuse of this information. User assumes all risk of use, rage and handling of the product in compliance with applicable federal, state and local laws and regulations. NO WESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A 1TICULAR PURPOSE, OR OF ANY OTHER NATURE, ARE MADE BY BVV HEREUNDER WITH RESPECT TO INFORMATION THE PRODUCT TO WHICH THE INFORMATION REFERS. The information as supplied herein is simplyto be rmative and intended solely to alert the user of the substance which is the subject matter of this SDS. The ultimate opliance with federal, state or local regulations concerning the use of this compound, or compliance with respect to duct liability, rests solely upon the purchaser thereof. This information relates to the material designated and may be valid for such material used in combination with any other materials nor in any process. Date: 3/1/2019 �� BUILDING VISION AND VARIETY Product Code(s): E -200 -OT, E -200.6,E-200-2 5, E-200-5, E -200-55G SAFETY DATA SHEET 1. Identification Product Name: Ethanal 200 Proof Product Code(s): E-20041', E-200-6, E-200-2-5, E-200-5, E-200556 SDS Date: 3/1/2019 Use: Industrial Address: BW 1251 Frontenac Rd. Ste 150 Naperville IL 60563 Phone: (331)281-0154 CHEMI 1800)255-3924 2. Hazard(s) Identification GHS Classification Flammable liquids (Category 2) Pictogram Signal Word Danger Hazard Statement Highly flammable liquid and vapor. ly flammable liquid and vapor. autionary statement(s). Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. and/band container and receiving equipment. Use explosion proof electrical/ ventilating/ lighting/ equipment. Use only non -sparking s. Take precautionary measures against static discharge. Wear protective gloves/ protective clothing/ eye protection/ face action. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. In case of fire: dry sand, dry chemical or alcohol -resistant foam for extinction. Store in a well ventilated place. Keep cool. Dispose of contents/ diner to an approved waste disposal plant. Hazards Not Otherwise Classified: Not Available 3. Composition/Information On Ingredients Concentration Name Cas Ethanal 6417-5 80-100 4. First-aid Measures General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. If Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In Case of Skin Contact: Wash off with soap and plenty of water. Consult a physician. In Case of Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If Swallowed: Do NOT induce vomiting. Never give a nything by mouth to a In u nconscious person. Rinse mouth with water. Consult a physician. Most Important Symptoms and Effects, (loth Acute and Delayed: mustimportant known symptoms and effects are described in the labelling (see section 2.2) and/or n 31 Indications of Any Immediate Medial Attention and Special Treatment Needed: No Data Available 5. Fire -fighting Measures Extinguishing Media: jUse water spray, alcohol -resistant foam, dry chemical or carbon dioxide. Special Hazards: ICarbon oxides Advice for Firefighters jvvear self-contained breathing apparatus forfirefighting if necessary. Further Information: lUse water spray to cool unopened containers. 6. Accidental Release Measures Personal Precautions, Protective Equipment, and Emergency Proaduras Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. Environmental Precautions: 1prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and Materials for Containment and Clean Up: Ca main spillage, and then collect with an electrically protected vacuum cleaner or by wet -brushing and place in container for disposal according to local regulations. 7. Handling and Storage Safe Handling: Avoid contact with skin and eyes. Avoid inhalation ofvopor or mist. Use explosion -proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Safe Storage: Keep container tightly closed in a dry and well -ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Hygroscopic 8. Exposure Controls/Personal Protection Name CAS Ethanol 64-17-5 OSHATWA OSHA STEL ACGIH TWA ACGIH STEL 1000 ppm Not Available 1000 ppm Not Available Engineering Control: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin Protection: Handle with butyl rubber gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection: Impervious clothing. Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory Protection: Where risk assessment shows air -purifying respirators are appropriate use a full -face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full -face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of Environmental Exposure: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 9. Physical and Chemical Properties Appearance: lEthanol I Colorless, clear liquid Odor: jEthanol I IN. Data Available Odor Threshold: lEthanol IN. Data Available pH: 117thanol INo Data Available Melting/Freezing Point: Ethanol 1-143.99-C (-227.18-F) Initial Boiling Point/Range: Ethanal 178.0- ROD -C(172.4-176.0°F) Flesh Point Ethanol 114.0-C(57.2°F)-closed cup Evaporation Rate: Ethanol NO Data Available Flammability: jEthanol I IND Data Available Upper Explosion Limit I Ethanol 19% Lower Explosion Limit: lEth.n.1 13.30% Vapor Pressure: lEth.n.1 59.5 hPa(44.6 mmHg) at 20.0-C(69.0 T) Vapor Density: lEthanol lNo Data Available Relative Density: Ethanol O7974 g/cm3 Water Solubility: Ethanol Completely Soluble Partition Coefficient: Ethanol No Data Awl lable Auto Ignition Temp: Ethanol I 363.0 Decomposition Temp: Ethanol IND Data Available Viscosity: Ethanol INo Data Available 10. Stability and Reactivity Reactivity: INo Data Available Chemical Stability: Stable under recommended storage conditions. Possibility of Hazardous Vapors may form explosive mixtu re with air. Reactions: Conditions to Avoid: I Heat, flames a no sparks. Extremes of temperate re and d irect sun light. Incompatible Materials: lAlkali metals, Oxidizing agents, Peroxides Hazardous Decomposition NO Data Available Products: 11. Toxicological Information e: CAS: nol 64-17-5 I Oral - Rat - 2,743 mg/kg adorn No Data Available 1 Dermal - Rabbit -> 2,000 mg/kg Corrosion/Irritation: Result Mild skin irritation -24h ms Eye Damage/Eye Irritation: Result: Irritating to eyes. -24h story or Skin Sensitization: No Data Available Cell Mutagenicity: No Data Available Not identified as probable, possible or confirmed human carcinogen by naenidty: IARC, NTP, or OSHA No Data Available Information: Drying, cracking of the skin, Skin irritation Liver -Irregularities 12. Ecological Information Name CAS Toxicity Ethanol 64-17-5 Net Available 13. Disposal Considerations Dispose of contents/container in accordance with lora l/regional/national/international regulations. 14. Transportation Information Proper Shipping Name: Ethanol Hazard Class 13 Identification Number: JUN1170 Packing Group: III Label Flammable Ship: I UN1170 ETHANOL CLASS PG 11 15. Regulatory Information Ethanol 64 -IJ -5 SARA 302/304 INo Components Were Identified SARA 313 No Components Were Identified CERCLA lNo Components Were Identified SARA 311/312 IFire Hazard, Chronic Health Hazard PROP 65 INo Components Were Identified This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. 16. Other Information, Including Date of Preparation or Last Revision SDS Date: 3/1/2019 Disclaimer: e information and recommendations contained in the Safety Data Sheet SDS' are supplied pursuant to 29 CFR 1910.1200 the Occupational Safety and Health Standards Hazard Communication Rule. The information and recommendations set th herein are presented in good faith and believed to be correct as of this date hereof. BW, however, makes no )resentation as to the completeness or accuracy thereof, and information is supplied upon the express condition that the rsons receiving the information will be required to make their own determination as to its suitability for their purposes or to use. In no event will BW be responsible for any damages of any nature whatsoever resulting from the use of, iance upon, or the misuse of this information. User assumes all risk of use, storage and handling of the product in mpliance with applicable federal, state and local laws and regulations. NO REPRESENTATIONS OR WARRANTIES, EITHER PRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE, ARE %DE BY BVV HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. The ormation as supplied herein is simply to be informative and intended solely to alert the user of the substance which is the alect matter of this 5DS. The ultimate compliance with federal, state or local regulations concerning the use of this mpound, or compliance with respect to product liability, rests solely upon the purchaser thereof. This information relates the material designated and may not be valid for such material used in combination with any other materials nor in any LW BVV 7/28/2016 03255 SAFETY DATA SHEET 1. Identification Product Name: Heptanes 195-208 Product Code: 03255 SDS Date: 7/28/2016 Use: Industrial General Information: 314-644-1300 CH EMTREC: 800-424-9300 2. Hazard(s) Identification GHSClassification FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 TOXIC TO REPRODUCTION (Fertility) - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 ASPIRATION HAZARD - Category 1 Pictogram O O Signalword Danger HazardStatement Highly flammable liquid and vapor. Causes skin irritation. Suspected of damaging fertility or the unborn child. Maybe fatal if swallowed and enters airways. May cause drowsiness and dizziness. Precautionary Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye orface protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion -proof electrical, ventilating, lighting and all material -handling equipment. Use only nonsparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well -ventilated area. Avoid breathing vapor. Wash hands thoroughly after handling. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. If skin irritation occurs: Get medical attention.Store locked up. Store in a well -ventilated place. Keep cool. Dispose of contents and container in accordance with all local, regional, Page 7/28/2016 03255 national and international regulations. Hazards not otherwise classified: Not available 3. Composition/information on ingredients Name CAS Concentration Distillates (petroleum), light distillate 68410-97-9 >90 hydrotretaing process, low boiling Cyclohexane 110-82-7 1-3 4. First-aid measures General Advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. If Inhaled Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In Case of Skin Contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. In Case of Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. If Swallowed Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms and effects, both acute and delayed Acute: Eye contact: no known significant effects or critical hazards. Inhalation: Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Skin contact: Causes skin irritation. Ingestion: Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Over exposure: eye contact: pain or irritation, watering, redness. Inhalation Nausea or vomiting, headache, drowsiness/fatigue, dizziness/vertigo, unconsiouness, reduced fetal weight, increase in fetal deaths, skeletal malformations. Skin Contact: irritation, redness, reduced fetal weight, increase in fetal deaths, skeletal malformations. Ingestion: nausea or vomiting, reduced fetal weight, increase in fetal deaths, skeletal malformations Page 7/28/2016 03255 Indications of any immediate medical attention and special treatment needed Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. 5. Fire -fighting measures Extinguishing Media Use dry chemical, CO, water spray (fog) or foam. Do not use water jet. Special Hazards Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Advice for firefighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire -exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SOBA) with a full face -piece operated in positive pressure mode. Further Information No data available 6. Accidental release measures Personal precautions, protective equipment, and emergency procedures NON EMERGENCY PERSONNEL: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do nottouch orwalk through spilled material. Shut off all ignition sources. No Flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. EMERGENCY RESPONDERS: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Methods and materials for containment and cleaning up Small Spill: Stop leak if without risk. Move containers from spill area. Use spark -proof tools and explosion proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water -insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large Spill: Stop leak if without risk. Move containers from spill area. Use spark proof tools and explosion -proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the Page 7/28/2016 03255 same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Handling and storage Safe Handling Put on appropriate personal protective equipment (see Section 8). Avoid exposure- obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion -proof electrical (ventilating, lighting and material handling) equipment. Use only non -sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Safe Storage Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection 11 Name CAS Distillates (petroleum), light distillate hydrotretaing pr 68410-97-9 OSHA TWA OSHA STEL ACGIH TWA ACGIH STEL Not Available Not Available 200 ppm Not Available Cyclohexane 110-82-7 OSHA TWA OSHA STEL ACGIHTWA ACGIH STEL 300 ppm Not Available 100 ppm Not Available Engineering Control Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion -proof ventilation equipment. Eye/Face Protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment Page 4 7/28/2016 03255 indicates a higher degree of protection: chemical splash goggles. Skin Protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body Protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Respiratory Protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Control of Environmental Exposure Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modificationsto the process equipment will be necessary to reduce emissions to acceptable levels. L Physical and chemical properties Appearance Distillates (petroleum), light distillate Liquid hydrotretaing process, low boiling Odor Distillates (petroleum), light distillate Characteristic. Hydrocarbon. hydrotretaing process, low boiling Odor Threshold Distillates (petroleum), light distillate Not available, hydrotretaing process, low boiling pH Distillates (petroleum), light distillate hydrotretaing Not available. process, low boiling Melting/Freezing Point Distillates (petroleum), light Not available. distillate hydrotretaing process, low boiling Initial Boiling Point/Range Distillates (petroleum), 90.556 to 97.778"C (195 to 208°F) light distillate hydrotretaing process, low boiling Flash Point Distillates (petroleum), light distillate Closed cup: -8°C (17.6°F) [Tagliabue.] hydrotretaing process, low boiling Evaporation Rate Distillates (petroleum), light distillate 4.24 (butyl acetate = 1) Page 5 hydrotretaing process, low boiling Flammability Distillates (petroleum), light distillate hydrotretaing process, low boiling Upper Explosion Limit Distillates(petroleum), light distillate hydrotretaing process, low boiling Lower Explosion Limit Distillates (petroleum), light distillate hydrotretaing process, low boiling Vapor Pressure Distillates (petroleum), light distillate hydrotretaing process, low boiling Vapor Density Distillates (petroleum), light distillate hydrotretaing process, low boiling Relative Density Distillates (petroleum), light distillate hydrotretaing process, low boiling Water Solubility Distillates (petroleum), light distillate hydrotretaing process, low boiling Partition Coefficient Distillates (petroleum), light distillate hydrotretaing process, low boiling Auto Ignition Temperature Distillates (petroleum), light distillate hydrotretaing process, low boiling Decomposition Temperature Distillates (petroleum), light distillate hydrotretaing process, low boiling Viscosity .Distillates (petroleum), light distillate hydrotretaing process, low boiling 7/28/2016 03255 Not available. Not available. Not available. 6 kPa (45 mm Hg) [room temperature] Not available. 0.708 Insoluble in the following materials: cold water and hot water. Not available. Not available. Not available. Kinematic (40°C (104°F)): <0.01 cm2/s (<1 c5t) 10. Stability and reactivity _ Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical Stability The product is stable. Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to Avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, Page 6 7/28/2016 03255 solder, drill, grind or expose containers to heat or sources of ignition. Incompatible materials Reactive or incompatible with the following materials: oxidizing materials Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 11. Toxicological information Name CAS Distillates (petroleum), light distillate hydrotretaing pro 68410-97-9 LD50 Oral Rat 5.17 g/kg LC50 Inhalation Vapor Rat>5.2 mg/I-4h L050 Dermal Rabbit > 2000 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive Suspected of famaging the unborn child. Suspected of damaging fertility. Additional information Aspiration hazard. Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Page 7 7/28/2016 03255 Name CAS Cyclohexane 110-82-7 LD50 Oral- Rat -12,705 mg/kg LC50 Inhalation - Rat - 4 h - 34,000 mg/I LD50 Dermal - Rabbit -> 2,000 mg/kg Skin corrosion/irritation Result: No skin irritation Serious eye damage/eye irritation Result: Mild eye irritation Respiratory or skin sensitization No data available Germ cell mutagenicity, No data available Carcinogenicity Not identified as probable, possible or confirmed human carcinogen by IARC, NTP, or OSHA Reproductive No data available Additional information Central nervous system depression, Drowsiness, Irritability, Dizziness, Gastrointestinal disturbance, Lung irritation, chest pain, pulmonary edema 12. Ecological information N me CAS Distillates (petroleum), light d 68410-97-9 Toxicity Algae Acute EC50 1 to 10 mg/I - 72 hours, Acute EC501 to 10 mg/I Daphnia 48 hours, Acute LC501 to 10 mg/I Fish 96 hours Cyclohexane 110-82-7 flow-through test LC50- Pimephales promelas (fathead minnow) - 4.53 mg/I -96 h, Immobilization EC50-Daphnia magna (Water flea) - 0.9 mg/I - 48 h, EC50 - Pseudokirchneriella subcapitata (green algae) - 3.4 mg/I - 72 h 13. Disposal considerations Dispose of contents/container in accordance with local/regional/national/international regulations. 34. Transport information Proper Shipping Name Petroleum Distillates, n.o.s., RQ (Cyclohexane) Hazard Class 3 Identification Number UN1268 Packing Group II Page 8 7/28/2016 03255 Label Flammable !15. Regulatory information Name CAS Distillates (petroleum), light distillate hydro 68410-97-9 SARA 302/304 No components were identified SARA 313 No components were identified CERCLA No components were identified SARA 311/312 Fire Hazard, Acute Health Hazard, Chronic Health Hazard PROP 65 No components were identified This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. Name CAS Cyclohexane 110-82-7 SARA 302/304 No components were identified SARA 313 313 CERCLA RQ=10001bs SARA 311/312 Fire Hazard, Acute Health Hazard PROP 65 No components were identified This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. Page 9 7/28/2016 03255 16. Other information, including date of preparation or last revision SDS Date: 7/28/2016 Disclaimer: The information and recommendations contained in the Safety Data Sheet (SDS) are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. The information and recommendations set forth herein are presented in good faith and believed to be correct as of this date hereof. BVV, however, makes no representation as to the completeness or accuracy thereof, and information is supplied upon the express condition that the persons receiving the information will be required to make their own determination as to its suitability for their purposes prior to use. In no event will BVV be responsible for any damages of any nature whatsoever resulting from the use of, reliance upon, or the misuse of this information. User assumes all risk of use, storage and handling of the product in compliance with applicable federal, state and local laws and regulations. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE, ARE MADE BY BVV HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. The information as supplied herein is simply to be informative and intended solely to alert the user of the substance which is the subject matter of this SDS. The ultimate compliance with federal, state or local regulations concerning the use of this compound, or compliance with respect to product liability, rests solely upon the purchaser thereof. This information relates to the material designated and may not be valid for such material used in combination with any other materials nor in any process. Page 10 ® Toluene I[ ' LabCheM Safety Data Sheet pMorews. droll accanchn, to Federal Banister /Vol, 77, No. 58/Montle, March 26,2012/ Rules and Regulations Data of issue: 0 3121/2 014 Revision date. 02127/2018 Su,medes: 0 312112 01 4 Version: l.1 1.1. Identification Product farm Substance Substance name Toluene CAS -No. 108-88-3 Product code LC26170 Formula C7H8 Synonyms benzyl hydnda / methylbenzene / phenylmethane / tolunol / toluol oil l tcluole 1.2. Recommended use and restrictions on use Use of the substance/mixture : Solvent 1.3. Supplier LabCham Inc Jackson's Pointe Commerce Parr Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-82E-5230 - F 724473-0647 infoRlabchem.com-www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC:1-800-4249300 or 011-701 _. 2.9. Classification of the substance or mixture GHS49S classification Flammable liquids, H225 Highly flammable liquid and vapour. Category 2 Skin conosion/irritation, H315 Causes skin irritation. Category 2 Reproductive toxicity, H361 Suspected of damaging fedility or the unborn child. Category 2 Spei target organ H336 May cause drowsiness or dizziness. toxicity— Single exposure, Category 3, Narcosis Specific target organ H373 May cause damage to organs (central nervous system, liver, head) through prolonged or toxicity — Repeated repeated exposure. exposure, Category 2 Aspiration hazard, H304 May be fatal if swallowed and enters airways. Category 1 Hezamlous to the aquatic H402 Harmful to aquatic life environment — Acute Hazard, Category 3 Full text of H statements : see section 16 2.2. GHS Label elements, Including precautionary statements GHS -US labelling Hazard pictograms(GHS-US) O' O .0, ensm cnsos Signal send (GHS -US) Danger Hazard statements (GHS -US) H225- Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361 -Suspected of damaging fertility or the unbom child. H373 - May cause damage to organs (central nervous system, liver, head) through prolonged or repeated exposure. H402 - Harmful to aquatic life 8&2712018 EN (Ennliehl Page 1 Toluene Safety Data Sheet according to Federal Register/ Vol. 77, No. 58 / Morday, Mamh 26,2012/ Rules and Regulations Precaubonary statements (GHS -US) P201 -Obtain special instructions before use. % GHS -US classification P202 - Do not handle until all safety precautions have been read and understood. scASNoJ1ill P210 - Keep away from heat, sparks, open flames, hot surfaces. No smoking. (Moro ransituent) P233 - Keep container tightly closed. Skin Imlt.2 H315 P240 - GroundOond container and receiving equipment. First-aid measures general P241 - Use explosion -proof electrical, ventilating, lighting equipment. P242 - Use only non -sparking tools. STOT SE 3, H336 P243 - Take precautionary measures against static discharge. P260 - Do not breathe mist, vapours, spray. STOT RE 2, H373 P264 - Wash exposed skin thoroughly after handling. P271 - Use only outdoors or in a well -vent laled area. Mr. Tox. 1, H304 P273 -Avoid release to the environment. First-aid measures after inhalation P280 -Weer protective gloves, protective clothing, We protection, face protection. Aquafic Awls 3. H402 P301+P310 - IF SWALLOWED: Immediately call a POISON CENTERmodor P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. First-aid measures after We contact P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTERIdoctor if you feel unwell. P314 - Get medical advice and attention if you feel unwell. P331 - Do NOT induce vomiting P332+P313 - If skin imitation occurs: Get medical advicemitlention. P363- Wash contaminated clothing before reuse. P370+P378 - In case of Flim: Use carbon dioxide (CO2), powder, alcohol -resistant foam to extinguish. P403+P235 - Store in a well -ventilated place. Keep cool. P405 -Store locked up. P501 - Dispose of contentslcorrtainer to comply with local, state and federal regulations 2.3. Other hazards which do of result in classification Other hazards not contributing to the None under normal conditions. classification 2.4. Unknown acute toxicity (GHS U3)_ Not applicable SECTION 3: osition/information on ingredients 3.1. Sobstancss, Substance type Mono -constituent Name Product Identifier % GHS -US classification Toluene scASNoJ1ill t00 Flan LIg2, H225 (Moro ransituent) Skin Imlt.2 H315 First-aid measures general Ever. 2, H361 amesC artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious STOT SE 3, H336 with laboured breathing: halfseated. Victim in shock: on his back with legs slightly wised. Vomiting: prevent asphyxia/aspiation pneumonia. Prevent cooling by covering the victim (no STOT RE 2, H373 warming up). Keep watching the victim. Give psychological aid. Keep fine victim calm, avoid physical strain, Depending on the victim's condition: doctodhospital. Never give alcohol to Mr. Tox. 1, H304 drink. First-aid measures after inhalation Remove the victim into fresh air. Respiatory problems: consult a doctor/medical service. Aquafic Awls 3. H402 Full text of hazard classes and Hstatements : see section 16 3.2. Mixtures Not applicable SECTION 4: First-aid measures 4.1. Description of first aid measves First-aid measures general Check the vital functions. Unconscious: maintain adequate airway and respiretion. Respiratory amesC artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: halfseated. Victim in shock: on his back with legs slightly wised. Vomiting: prevent asphyxia/aspiation pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep fine victim calm, avoid physical strain, Depending on the victim's condition: doctodhospital. Never give alcohol to drink. First-aid measures after inhalation Remove the victim into fresh air. Respiatory problems: consult a doctor/medical service. First-aid measures after skin contact Wash immediately with lots of water. Soap may be used. Do not apply( chemical) neutralizing agents. Remove clothing before washing. Take victim to a doctor if irritation persists. Take victim to a doctor/medical service if imitation persists. First-aid measures after We contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Dc not apply fantasizing agents. Take victim to an ophthalmologist if imitation persists. Take victim to a doctor/medical service if induction pemists. EN (English) 2/10 Toluene Safety Data Sheet according to Federal Register/ Vol. 77, No. 58 / Monday, Moron 26, 20121 Rules and Regulations First-aid measures after ingestion Rinse mouth with water. Immediatey after ingestion: give lots of water to drink. Do not give milkloil tu drink. Do not Induce vomiting. Give activated charcoal. Call Poison Information Centre (wive big.be/antigithtm). Consult doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. .. 4.2. Most important symptoms and _ effects (aceta and delayed) Symptomsleffects after inhalation EXPOSURE TO HIGH CONCENTRATIONS: Headache. Nausea. Feeling of weakness. Dimness. Central nervous system depression. Narcosis. Mental confusion. Drunkenness. Combination disorders. Disturbed motor response. Disturbances of consciousness. Symptomsleffects after skin contact Tingling/irritation of the skin. Red skin. Symptoms/effects after eye contact Irritation of the eye tissue. Symptoms/effects after ingestion Risk of aspiration pneumonia.Nausea. Abdominal pain. I motion of the gasMc/inteshnal mucosa. Symptoms similar to those listed under inhalation. Chronic symptoms ON CONTINUOUS/REPEATED EXPOSUREICONTACT: Dry skin. Skin mshlinflammation. Impairment of the nervous system. Tremor. Impaired memory. Impaired concentration. Brain affection. Disturbances of head rate. Change in the haemogmmme/blood composition. 4.3. Immediate medical attentio.n and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire�fiijhtlng measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Quick -acting ABC powder extinguisher. Quickapting BC powder extinguisher. Quick -adding class B foam extinguisher. Quick -acting CO2 extinguisher. Class Bfoam (not alcohol -resistant). Unsuitable extinguishing media Water (quick -acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle expansion. 5.2. Specific hazards dosing from the chemical Fire hazard DIRECT FIRE HAZARD: Highly flammable liquid and vapour. Gashopour flammable with air within explosion limits. INDIRECT FIRE HAZARD: May build up electrostatic charges: risk of ignition. May be ignited by spats. Gas/vapour spreads at floor level: ignition hazard. Reactions involving a fire hazard: see "Reactivity Hazam'. Explosion hazard DIRECT EXPLOSION HAZARD: Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD: may be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard". Reactivity Reacts violently with (some) halogens. Reacts violently with (strong) oAdizers: (increased) risk of fm/explosion. Violent to explosive reaction with (same) acids. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heal. Protection during firefighting : HeaVfire exposure: compressed air/oxygen apparatus. _ 6.1. Personal precautions, pmtective equipment and emergency procedures 6.1.1. For non -emergency personnel Protective equipment Gloves. Protective goggles. Head/neck protection. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. Large spillslin enclosetl spaces: gas-tight suit. Emergency procedures Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close dwrs and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark -and explosionproof appliances and lighting equipment. Keep containers dosed. Wash contaminated clothes. 6.1.2. For emergency responders Protective equipment Do not breathe gas, fumes, vapouror spray. Equip cleanup crew with proper protection. Emergency procedures Stop leak if safe to do so. Ventilate area. If a major spill occurs, all personnel should be immediately evacuated and the area ventilated. 6.2. Environmental precautions Prevent soil and water pollution. Toluene Safety Data Sheet according to Federal Register 1 Vol. 77. No. 581 Moral March 26. 20121 Rules and 6.3. Methods and material for containment and cleaning up For containment Contain released prcduct, pump into suitable containers. Plug the leak, cut oft the supply. Dem Direct sunlight. Heat sources. Sources of ignition. up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive gas - KEEP SUBSTANCE AWAY FROM: heat sources. ignition acumen. air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide KEEP SUBSTANCE AWAY FROM: oxidicin, agents. (strong) adds. halogens. equipmentlreceptades with earthing. Do not use compressed air for pumping over spills. Methods for cleaning up Liquid spi ll: cover with foam. Take up liq cid spill into inert absorbent material, e.g.: sand, earth, collect spills. Provide the tank with earthing. Under a shelter/in the open. Stare only in a limited vermiculite. Scoop absorbed substance into closing containers. Carefully collect the quantity. May be shared under nitmgen. Meet the legal requirements. Keep out of dived spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for sunlight. pumping over spills. Take collected spill to manufadurencompelent authority. Wash clothing SPECIAL REQUIREMENTS: closing clean. correctly labelled. meet the legal requirements. and equipment after handling. 6.4. Reference to other sections Packaging materials No additional information available NIOSH REL TWA) di glass. tin. MATERIAL TO AVOID: polyethylene. NIOSH NIOSH REL (STEL)(mglm') 560 mg/m' 7.1. Precautions for safe handling NIOSH REL STEL) (ppri Precautions for safe handling Use spark-lexplosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the concontmtion in the air regularly. Work under local exheusliventilation. Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Handle unplanned empty containers as full ones. Thoroughly clearldry the installation before use. Do not discharge the waste into the drain. Do not use compressed air for pumping over. Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not set, drink or smoke when using this product. 7.2. Conditions for safe storage, Including any incompatibilities Incompatible products Strong oxidizers. Incompatible materials Direct sunlight. Heat sources. Sources of ignition. Heal and ignition sources KEEP SUBSTANCE AWAY FROM: heat sources. ignition acumen. Prohibitions on mixed storage KEEP SUBSTANCE AWAY FROM: oxidicin, agents. (strong) adds. halogens. Storage area Store at emblem temperature. Ventilation at floor level. Fireproof storeroom. Provide for a tub to OSHA PEL (STEL)(ppm) collect spills. Provide the tank with earthing. Under a shelter/in the open. Stare only in a limited OSHA quantity. May be shared under nitmgen. Meet the legal requirements. Keep out of dived 300 ppm sunlight. Special miss on packaging SPECIAL REQUIREMENTS: closing clean. correctly labelled. meet the legal requirements. NIOSH Secure fragile packagings in solid containers. Packaging materials SUITABLE MATERIAL: metal. stainless steel. carbon steel. aluminium. nickel. polypropylene. NIOSH REL TWA) di glass. tin. MATERIAL TO AVOID: polyethylene. 8.1. Control parameters Toluene(1DBA8J) ACGIH ACGIH TWA(ppm) 20 ppm OSHA OSHA PEL (TWA)(ppm) 200 ppm OSHA OSHA PEL (STEL)(ppm) 500 ppm 10 -min peak per 8 hour shift OSHA OSHA PEL (Ceiling)(ppm) 300 ppm IDLH US IDLH (ppm) 500 ppm NIOSH NIOSH REL (TWA) (mg/m') 375 mg/m' NIOSH NIOSH REL TWA) di 100 ppm NIOSH NIOSH REL (STEL)(mglm') 560 mg/m' NIOSH NIOSH REL STEL) (ppri 150 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should he available in the immediate vicinity of any potential exposure. Ensure adequate ventilation. 8.3. Individual protection mersureslPersonal protective equipment 4110 Toluene Safety Data Sheet aceording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 20121 Rules and Materials far protective clothing: GIVE GOOD RESISTANCE tetraflmmathylene. short. PVA. GIVE LESS RESISTANCE: butyl rubber. natural rubber, neoprene. nitrile rubber. polyethylene. neopronematural rubber. ruble rubber/PVC. GIVE POOR RESISTANCE: chloroprene rubber Hand protection: Gloves Eye protection: Safety glasses Skin and body protection: Heac/neck protection. Protective c othing Respiratory protection: Full face mask with fitter type A at mnc. in air> exposure limit TV lip 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Liquid. Colour Colourless Odour Odour threshold pH Malting point Freezing point Boiling point Critical temperature Critical pressure Flash point Relative evaporation rate (butylacetate=l) Flammability (solid. gas) Vapour pressure Vapour pressure at 50'C Relative vapour density at 20'C Relative density Relative density of saturated gas/air mixture Density Molecular mass Solubility Log Pow Auto -ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Aromatic occur 0.2 - 69 ppm 0.8 - 276 mg/m' No data available -95'C (1013 hPa) No data available 110.6'C (1013 hPa) 321 -C 41077 hPa 4.4 -C (Closed cup, 1013 hPa) 2.24 No data available 30.89 hPa (21.1 °C) 109 hPa 3.1 0.87 (20 °C) 1.6 870 kg/m' 92.14 g/mol Insoluble in costar. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform. Soluble in carbondisulflde. Soluble in acetic acid. Soluble in elhylaoetate. Soluble in petroleum spirit. Water: 0.057 - 0.059 gill 00ml (25 "C) Ethanol: complete Ether: complete Acetone: > 10 g1100ml 273 (Experimental value, 20 °C) 480 -C (1013 hPa) No data available 0.69 mir is (20 °C) 0.6 meas (20 °C) v10 Toluene Safety Data Sheet according to Federal Register I Val, 77, No. 58 / Monday, March 26, 20121 Rules and Regulations Explosive limits Explosive properties Oxidising properties 9.2. Other information Minimum ignition energy Specific conductivity Saturation concentration VOC content Other properties 1.3-7Vol % 46 - 270 g/m' Lower explosive limit (LEL): 1.3 vol % Upper explosive limit (UEL): 7 vol % No dab available No dab available 0.3 mJ 1pi 0 g/m' 100% Gaslvapour heavier than air at 20-C. Clear. Volatile. Substance has neutral reaction. May generate electrostatic charges. SECTIONI 10.1. Reactivity Reacts violently with (some) halogens. Reacts violently with (strong) oxidizers. (increased) disk of firelexplosion. Violent to explosive reaction with (some) acids. 10.3. Chemical stability Stable under normal conditions. _.... _ 10.3. Possibilityof hazardous reactions No additional information available 10.4. Conditions to avoid Heat. Direct sunlight. Sparker Open flame. 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure Inhalation: Skin and eyes contact Acute toxicity Not classified Toluene (108888) Causes skin irritation. LD50 021 rat 5580 ni bcdyweight (Equivalent or similar to EU Method B.I. Acute Toxicity (Orel), Rat, Male, Experimental value) LD50 dermal rabbit o 5000 mg/kg bodyweight (Other, 24 h, Rabbit, Male, Experimental value) LC50 inhalation rat (cri 1 25.7 mgll air (Equivalent or similar to OECD 403, 4 h, Rat, Male, Experimental value) ATE US (oral) 1 5580 mg/kg bodyweight Skin corrosion/irritation Causes skin irritation. Serious eye damage4rritation Not classified Respiratory or skin sensitisation Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classed Reproductive toxicity Suspected of damaging fertility or the unborn child. Specific target organ toxicity(single exposure) May cause drowsiness or dizziness. Specific target organ toxicity (repeated May cause damage to organs (central nervous system, liver, head)through prolonged or exposure) repeated exposure. Aspiration hazard 0212712018 : May be fetal if swallowed and enters airways. Toluene Safety Data Sheet according to Federal Register I Vol. 77, No. 5e I Monday, March 29, 29121 Rules and Regulations Patential ativerse human health effaces and May be fatal it swallowed and enters airways. Practically non-toxic if swallowed (LD50 oral, rat symptoms > 2000 mg/kg). Causes skin imbiber. Non-toxic in contact with skin (LD50 skin> 5000 mglkg). Ecology - air May cause drowsiness or dizziness. Non-toxic by inhalation (LC50 inh, rat> 20 mg11/4h). 2.52 g Odg substance Moderately irritant for eyes. Caution! Substance is absorbed through the skin, Symptomsleffects after inhalation EXPOSURE TO HIGH CONCENTRATIONS: Headache. Na..... Feeling of weakness. 0.69 Dimness. Central nervous system depression. Narcosis. Mental confusion. Drunkenness. Tclpene(108-08.3) Coordination disorders. Disturbed motor response. Disturbances of consciousness. Symptomsleffects after skin contact Tinglinglirritation of the skin. Red skin. Symptomsleffects atter eye contact Irritation of the eye tissue. Symptoms/e5ethe after ingestion Risk of aspiration pneumonia.Nausea. Mdominal pain. Initafion of the gastrointestinal mucosa. Symptoms similar to those listed under inhalation. Chronic symptoms ON CONTINUOUS/REPEATED EXPOSUREICONTACT: Dry skin. Skin ashllnflammation. Impairment of the nervous system. Tremor. Impaired memory. Impaired concentration. Brain affection. Disturbances of heart rate. Change in the haemogammelblood composition. 12.1. Toxicity Ecology - general Not classif ed as dangerous for the environment according to the criteria of Regulation (EC) No Biodegradable in the soil. Readily biodegradable in water. 12722008. Ecology - air Not included in the list of 0uorinated greenhouse gases (Regulation (EU) No 51712014). Not 2.52 g Odg substance classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Ecology - water Toxic to thundered. Toxic to fishes. Groundwater pollutant, Fouling to shoreline. Inhibits 0.69 photosynthesis of algae. Harmful to bacteria. Taste alteration in fishes/aquatic organisms. Tclpene(108-08.3) LC50 fsh 1 1 5.5 all (96 h, Oncorhynchus kisutch, Flow-through system, Fresh water, Experimental value) 12.2. Peaisteace and degadat ility Toluene (10888.3) Persistence and degatlability Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 2,15 g 01 substance Chemical oxygen demand (COD) 2.52 g Odg substance ThOD 3.13 g 01 substance SOD (%of ThOD) 0.69 12.3. Bioaccumulative potential Toluene(108-BBJ) BCF fish1 90 172 h, Leuciscus idus, Static system. Fresh water, Experimental value) Log Pow 2.73 (Experimental value, 20 °q Bioaccumulative potential Law potential for bioaccumulation (BCF c 500). 12.4. Mobility in soil Toluene (108-884) Surface tension 1 27.73 Night (25 °C) Ecology- soil I Law potential for adsorption in soil. 12.5. Other adverse effects No additional infomedli n available 13.1. Disposal methods Regional legislation(waste) LWCA(the Netherlands): KGA category 03. EN (English) Toluene Safety Data Sheet acceding to Federal Register/ Vol. TT, No. 58 / Monday, March 29, 2012 / Rules and Regulations Waste disposal recommendations Do not discharge into drains or the environment. Remove waste in accordance with local and/or Subject to reporting requirements of United States SARA Section 313 national regulations. Hazardous waste shall not be mixed together with other waste. Different I 100016 types of hazardous waste shall not be mixed together if this may entail a risk of pollution or Health hazard - Skin corosion or Irritation create problems for me further management of the waste. Hazardous waste shall be managed Health hazard - Reproductive toxicity responsibly. All entities that store, transport or handle hazardous waste shall take the Physical hazard - Flammable (gases, aerosols, liquids, or solids) necessary measures to prevent risks of pollution or damage to people or animals. Recycle by Health hazard - Specific target organ toxicity (single or repeated exposure) distillation. Do not lantltill. Incinerate under surveillance with energy recovery. May be Health hazard -Aspiration hazard discharged to company wastewater treatment plant. Additional information Hazardous waste according to Directive 20011 as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 20171997. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description UN1294 Toluene, 3, II UN-Nc.(OOT) UN1294 Proper Shipping Name (DOT) Toluene Transport hazard class(es)(DOT) 3 -Class 3- Flammable and combustible liquid 49 CFR 173.120 Parking group (DOT) II - Madura Danger Hazard labels (DOT) 3- Flammable liquid DOT Packaging Non Bulk (49 GFR 173.xxx) 202 DOT Packaging Bulk (49 CFR 173.xxx) 242 DOT Special Provisions (49 CFR 172.102) 182-Authodzed IBCs: Metal (31A, 31B and 31N); Rigid plastics (31111 and 31H2); Composite (31 HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(4)(2) Normal ............. 178.275(d)(3) Tel -The maximum degree of filling must net exceed the degree of filling determined by the following: Degree of filling =971(1 +a Qr -tU) Where: in is the maximum mean bulk temperature during transport, and ff is the temperature in degrees celsius of the liquid during filling. DOT Packaging Exceptions (49 CFR 173,dol 150 DOT Quantity Limitations Passenger aircraflhail 5 L (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 60 L CFR 175.75) DOT Vessel Stowage Location B - (i) The material may be stowed "on deck" or "under deck" on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) "On deck only" on passenger vessels In which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Other information No supplementary information available. SECTION 15: Regulatory information Toluene(108438J) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 RQ (Reportable quantity, search 304 of EPA's List of Usfs) I 100016 SARA Section 3111312 Hazard Classes Health hazard - Skin corosion or Irritation Health hazard - Reproductive toxicity Physical hazard - Flammable (gases, aerosols, liquids, or solids) Health hazard - Specific target organ toxicity (single or repeated exposure) Health hazard -Aspiration hazard Toluene Safety Data Sheet according to Federal Register/ V.I. 77, No. 58 / Mormil March 26, 2012 / Rules and Regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Ad (TSCA) inventory Chem [calls) subject to the depending requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Toluene CAS -No. 108-88-3 100% 15.2. International regulations EUltegulations No additional information available National regulations 15.3. US State Toluene (188483) U.S. - California - Proposition 65 -Carcinogens No List H315 U.S. - California - Proposition 65 -Developmental Yes Toxicity H361 U.S.- CalBomia- Proposition 65 -Reproductive Yes Toxicity - Female H402 U.S. - California - Proposition 65 -Reproductive No Tonicity - Male No significant risk level (NSRL) 7000 pg/day This product can expose you to Toluene, which is known to the Stale of California to cause birth dialects or other reproductive harm. For more information go to www.P65Wamings.ca.gov. Revision data 0212712018 Full text of H -statements: sea section 16: H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin initation. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fedgiry or the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H402 Harmful to aquatic life NFPA health hazard 2 -Materials that. under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire Inexact 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient 0 temperature conditions. N FPA reacfivity 0 -Material that in themselves are normally stable,even under fire conditions. 02/2712015 Toluene Safety Data Sheet according to Federal Register 1Vol. 71, No. 581 Monday, March 26, 20121 Rules and Regulators Hazard Rating Health 3 Serious Hazard - Major injury likely unless prompt action is taken and medical trodrent is given Flammability 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a Flash point above 200 F. (Class I IIB) Physical 2 Moderate Hazard - Materials that are unstable and may undergo violent chemical changes at normal temperature and pressure with low risk for explosion. Materials may react violently with water or form peroxides upon exposure to air. Personal protection H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator any us hadchem mmmxoo m ma soa a nom—Nbak wmr,.naeaoarnaaandadenneed rom noon ftaramnb, emrese y,#oWsd. a,ranch and taecnkin ma awn— norbla raolang rraa me am orae sos man,ara,a.ma.. aadada, of mia mar. mann nanrrcarby EN (English)