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Home My WebLink AboutPermit Correspondence 1982-10-5 G':){i~" ,..,..~V.. : ';'~~.i':"\~ ~1'~:;" c,",.",..,', C:.~~:..'.. c- . PHIL' A.HUNT CHEMICAL CORPORATION PRODUCT SAFETY DATA SHEET PALISADES PARK. NEW JERSEY 076!50 CABLE ADDRESS: OCHAP NEW YORK TELEPHONE: 201 944.4000 KIS FlLM KIT - DEVELOPER (Consists of Three Parts) PURPOSEOFPRODUCT Photographic Concentrates used to prepare a Working Solution for Developing Color Negatives. DESCRIPTIC>NOFMATERIALS PART A - A proprietary aqueous alkaline solution of inorganic salts and organic chelating agents. CATALOG NO. NAME OF PRODUCT CERTIFIED BY: OR. M. J. KELLEY, Dlreclor of Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I CHEMICAL NAME AND SYNONYMS, N .A,. N.A. I TRADE NAME AND SYNONYMS lNqt Aoolic~b~e) , N A_ FORMULA CHEMICAL FAMILY N.A. SECTION 11- HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS TLV (Unlls) "" TLV (Units) ALLOYS AND METALLIC COATINGS 'llo PIGMENTS BASE METAL CATALYST I VEHICLE SOLVENTS ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS ADDITIVES OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS, OR GASES TLV (Units) 'llo I I I SECTION 111- PHYSICAL DATA o BOILING POINT ( F.) I VAPOR PRESSURE (mm Hg.) I VAPOR DENSITY (AIR=l) I SOLUBILITY IN WATER I APPEARANCE AND ODORcolorless SPECIFIC GRAVITY (H20=1) 2120F Aoorox. 1.45 52 1 11 15 rom ~~RSgtUM~~~fTILE EVAPORATION RATE -1Water = 1) :::omplete pH aqueous solution with little or no odor. Aoorox. SECTION IV . FIRE AND EXPLOSION HAZARD DATA I FLASH POINT (Method Used) I EXTINGUISHING MEDIA N.A. I SPECIAL FIRE FIGHTING PROCEDURES N.A. I I FLAMMABLE LIMITS N.l\. ILel I Uel Nnt- Flrlrarnrlh10 , ' " I UNUSUAL FI RE AND EXPLOSION HAZARDS N.A. I ~ PAGE 1 of 2 J1-1C/mp 10-5-82 Form OSHA.20 Rev. Ma, 72 6&3 ~iJ \N UCE.NSES AND TAX/I5..e-S 7 'I. ~ PHILIP A.. HUNT C~"EMICA.L CORPORA.TION ~ALOG NO, 'NAME OF PRODUCT KIS FILM KIT - DEVELOPER (2;' <2;:;;C) EMERGENCY AND FIRST AID PROCEDURES Spills on Skin: Wash affected areas with soal? and water. ~es: Flush with clear warm ~t~~_J~Q!:, 1l[I to 15 minutes. Get rredical attention. Acc.i}Jent:.~J Ingestion: Give Ja:r:-<!~ (l1J-:.'Int-it-ie2 nf water includinq one ounce of vinea-ar. If c:liRnJ1T1_to!'t nersists. get rredical attention. SECTION VI . REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE rnnt-~~t- w;t-h ~t-rnng ~~;n~ y INCOMPATABILlTY (Matnials to avoid) 1\lnnp HAZARDOUS DECOMPOSITION PRODUCTS !i'011,~ HAZARDOUS POLYMERIZATION' MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR y SECTION VII- SPILL OR LEAK PROCEDURES ('') .' STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush with water to drain. I WASTE DISPOSAL METHOD I I I I RESPIRATORY PROTECTION (Spedfy type) Dilute with water. Biodegradable - no problem in sewerinq. SECTION VIII - SPECIAL PROTECTION INFORMATION VENTILATION Nnnp Re<l"; rpn I LOCAL EXHAUST I MECHANICAL (Ge"eral) I None RecruiTed I PROTECTIVE GLOVES I-EYE PR-6TECTlON Rubber crlov~!S !:,~~()rnmended . Safety goggles or qlasses I OTHER PROTECTIVE EQUIPMENT I I PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING ' , Keep containers closed and plainly marked. I I OTHER PRECAUTIONS None. I' SPECIAL NnnF' 'RF'qllirpn OTHER SECTION IX. SPECIAL PRECAUTIONS Store in a cool, dry area. -..----..-------- , ' PAGE 2 of 2 J!-1Cjrnp 10-5-82 ('" , , , , Form OSHA.20 Rev. May 72 88 · liCENSES AND TAXES -'. --'- C.:," -. ..:-;-.: .'. '., PALISADES PARK. NEW JERSEY 07650 CABLE ADDRESS: OCHAP NEW YORK TELEPHONE: 201 94.....000 CATALOG NO. NAME OF PRODUCT KIS FILM KIT - DEVELOPER (Consists of 3 Parts) PURPOSE OF PRODUCT Photographic Concentrates used to prepare a Working Solution for Developing Color Negatives. DESCRIPTION OF MATERIALS PART B- Aqueous solution containing Hydroxylamine Sulfate CERTIFIED BY: DR. M. J. KELLEY, Dlreclor 01 Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I CHEMICAL FAMILY N.A. N.A. (Not ITRADENAMEANDSYNONYMS Applicable) I FORMULA N.A. N.A. CHEMICAL NAME AND SYNONYMS, SECTION" - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS I PIGMENTS % TLV (Units) ALLOYS AND METALLIC COATINGS 'lIo TLV (Units) BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS ADDITIVES FILLER METAL PLUS COATING OR CORE FLUX OTHERS SOLVENTS (q OTHERS lOOT CORROSIVE HAZARDOUS MIXTURES OF OTHER LIQUIOS, SOLIDS, OR GASES IHydroxylamine Sulfate Approx. \*NO TLV Established. Toxicity is moderate. I 'lIo TLV (Units) 30 SECTION III- PHYSICAL DATA I BOILING POINT tF.) I VAPOR PRESSURE (mm Hg.) I VAPOR DENSITY (AIR=l) I SOLUBILITY IN WATER I APPEARANCE AND ODOR Clear. water-white. mobile liauid. A.pprox. 21201" SPECIFIC GRAVITY (H2o=1) Aprrn"ll'. PERCENT. VOLATILE 1 c; mm BY VOLUME (%) EVAPORATION RATE (Water = 1) ll.nnrnv 1 ,16 76 1 3.2 completel oH No odor. l I FLASH POINT (Method USed) Not Flammable I EXTINGUISHING MEDIA Solution is not a hazard, but crystals from dried liquid I SPECl,A1,. FJRE FIGHTING PFlOCfOURES COU~d be, especla ~y under disaster conditions. Explosion Hazard for Isuch crystals is moderate when exoosed to heat. This danqer UNUSUAL FI RE AND EXPLOSION HAZARDS would be increased in the presence of excess of alkalies which could SECTION IV - FIRE ANO EXPLOSION HAZARD DATA I FLAMMABLE LIMITS N.A. ILel I Uel liberate free hY~Toxvlamine_ This can ex~lode ~a~;1y AAGE'~2 JMC/mp iO-5-82 Form OSHA-20 Rev. Mal' 72 LICENSES AND TAXES · 89 .'" PHILIP ~. HUNT CHEMICAL CORPORAT~ FILM KIT - DEVELOPER ALOG NO, ,NAME OF PRODUCT ' PART B '(: SECTION V .HEAL TH HAZARO DATA THRESHOLD LIMIT VALUE N'.A. I EFFECTS OF OVEREXPOSURE Liauid is irri tatinq to skin, eves and'mucous membranes" I I EMERGENCY ANDFIRST AID PROCEDURES Affected body areas should be washed with copious quantities of soap land warm water. I In: f:'vf:'!3: Iw~~di~t~!~ flv~h with clean warm water ~ediG~l attf:'~tion. SECTION VI. REACTIVITY DATA for 15 min. and get STABILITY I UNSTABLE I STABLE INCOMPATABILITY (MaTerials To avoid) x CONDITIONS TO AVOID Heat and excess of alkalies. HAZARDOUS DECOMPOSITION PRODUCTS Alkalies free hydroxylamine CONDITIONS TO AVOID HAZARDOUS POL YMERIZATION MAY OCCUR WILL NOT OCCUR x I SECTION VII. SPill OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ( Flush to drain with cooious amounts of water. WASTE DISPOSAL METHOD Flush to drain with copious amounts of water. SECTION VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Sped!\' Type) Not normally needed Recommended MECHANICAL (General) Recommended PROTECTIVE GLOVES I.f:YE;.PROTECT~ON Dry rubber gloves ~atety glasses, goggles or face I OTHER PROTECTIVE EQUIPMENT Whatever is needed to avoid contact with skin or clothinq. VENTILATION LOCAL EXHAUST , SPECIAL OTHER shield. SECTION IX . SPECIAL PRECAUTIONS I' PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING 'KP€.p. ("'nnt-;'li npl::'S closed. St-nre i.n a Gool venti la ted olace. I OTHER PRECAUTIONS -, I 1, I'l',': '".' PAGE 2 of 2 JMC/mp 10-5-82 Form OSHA.20 Rev. May 72 90 · LICENSES AND TAXES -..----- "f""''';.~~' .';. *:'-, ~ .~ ,...;,..""""" ..o:';';",.;...r.o.;;: ,..' 1~"~'/~:>i.'5r'; C..".. '.. .". '., .-. ,~ .....,.. >- ., PALISADES PARK. NEW, JERSEY 07650 CABLE ADDRESS, OCH~P N'EW"'yci~K TELEPHONE, 201, 944.4000 CATALOG NO. NAME OF PRODUCT KIS FILH KIT - DEVELOPER (Consists of 3 Parts) 'PURPOSE OF PRODUCT Photographic Concentrates used to Prepare a Working Solution for Developing Color.Negatives. DESCRIPTION OF MATERIALS PART C A proprietary aqueous acidic solution of inorganic salts and an organic color developing agent. CERTIFIED BY: DR. M. J.'KELLEY, Director of Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I I CHEMICAL NAME AND SYNONYMS, I CHEMICAL FAMILY N.A. (Not N.A. ITRADENAMEANDSYNONYMS Applicable) N.A. I FORMULA N.J<. SECTION II . HAZAROOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS % TLV (Units) PIGMENTS BASE METAL CATALYST I VEHICLE SOLVENTS ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX ADDITIVES OTHERS c:'{\'i\ ,....."....... "::.J'..v:':: -." .;..~;';" OTHERS .,..~ . . ;'-/':~ HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % ,TLV (Units) Phenylene diamine color developinq aqent Annr~Y *No TLV Established. Oral toxicity to rats is moderate. DOT CORROSIVE. Contains small amount of free Sulfuric Acid. 45 * SECTION 111- PHYSICAL DATA I BOILING POINT tF.) 1 VAPOR PRESSURE (mm Hg.) I VAPOR DENSITY (AIR=l) I SOLUBILITY IN WATER I APPEARANCE AND ODOR Approx. Approx. 2120F 15 rrun SPECIFIC GRAVITY (H20=1) '~omplete pH as is 1.19 55 1 2.1 PERCENT, VOLATILE BY VOLUME ('10) EVAPORATION RATE (Water = 1) 'Amber aqueous solution with odor of sulfur dioxide I FLASH POINT (Melhod Used) Not flarrunable I EXTINGUISHING MEDIA N.A. SPECIAL FIRE FIGHTING PROCEDURES None SECTION IV. FIRE AND EXPLOSION HAZARD DATA I FLAMMABLE LIMITS ILel N.A. I Uel \ ',--, I UNUSUAL FIRE AND EXPLOSION HAZARDS None I PAGE 1 01 2 JHC/mp 10-5-82 Form OSHA.20 Rev. May 72 , liCENSES AND X4XES · 91 . PHILIP A. HUNT CHEMICAL CORPORATION CATALOG NO. NAME OF PRODUCT KIS FILM KIT ~ DEVELOPER PART C c' SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None established EFFECTS OF OVEREXPOSURE ~k;n &-Mucous Membranes - irritant; can cause sensitization dermatitis EMERGENCY AND FIRST AID PROCEDURES Skin: Flush with water (Do not use soap at first) ~: Flush with water. Get medical attention immediately. Tnt-~rnrll! Tnc1uce vomitincr: Get medical attention immediately. SECTION VI - REACTIVITY DATA STABILITY I UNSTABLE I STABLE . ~ INCOMPATABILITY (Materials to avoid) CONDITIONS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS y None Sulfur dioxide in small amounts HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR :>< SECTION VII- SPill OR LEAK PROCEDURES c. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Fl~sh with water to drain. WASTE DISPOSAL METHOD ~lush with water to drain. in sewerinq. Biodeqradable -- no problen SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specif)' type) PROTECTIVE GLOVES Rubber gloves Not required. I SPECIAL Recommended I OTHER Recommended I EYE PROUC~IOl'l 1 ~arety gogg es or glasses VENTILATION ,LOCAL EXHAUST MECHANICAL (General) OTHER PROTECTIVE EQUIPMENT SECTION IX - SPECIAL PRECAUTIONS pRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Kppp r.ontgjners closed and plainly marked. r.Qnl. drv area. OTHER PRECAUTIONS - None Store in a .~ I J c PAGE 2 of 2 JMC/mp 10-5-82 Form OSHA-20 Rev. Mav 72 92 · liCENSES AND TAXES c' E2'"'''' ~ ," " '. , '::'~<~~~~~i~':~ /,- -;\.. \, .".'.~] . ~ ~,.~-.!... <..r" \1 PHIL.~, A. HUNT ,CHEMICAL d~RPORATION PRODUCT SAFETY DATA SHEET PALISADES PARK, NEW JERSEY 07650 CABLE ADDRESS, OCHAP NEW YORK TELEPHONE, 201 944-40'00.' <. '-', l~ ~.' ~ ,'.! ~""J,,, CATALOG NO. KIS FILH KIT BLEACH NAME OF PRODUCT PURPOSE OF PRODUCT Photographic Concentrate used to prepare a Working Solution and Replenisher for Bleaching Color Negatives. DESCRIPTION OF MATERIALS A proprietary aqueous solution containing inorganic salts and organic chelating agents. CERTIFIED BY: DR. M. J. KELLEY, Director of Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I CHEMICAL NAME AND SYNONYMS, N.A. I CHEMICAL FAMILY N.A. I TRADE NAME AND SYNONYMS ADDl~) I FORMULA (Not N.A. N.A. SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS TLV (Units) % TLV (Units) % ALLOYS AND METALLIC COATINGS PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS SOLVENTS I ADDITIVES I OTHERS I I I I I FILLER METAL PLUS COATING OR CORE FLUX OTHERS ;:~.:,.. "\' HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % TLV (Units) N.A. SECTION III- PHYSICAL DATA I BOILING POINT (oF.) I VAPOR PRESSURE (mmHg.) I VAPOR DENSITY (AIR=l) I SOLUBILITY IN WATER I APPEARANCE AND ~R I SPECIFIC GRAVITY (H20=l) PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE (Water = 1) pH (diluted l:l) Approx. 2120F. Approx.' 15 nun 1.32 50 :::omplete 6.0 Reddish-brown. aaueous liauid: little or no odor. SECTION IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method Used) I Uel I FLAMMABLE LIMITS ILel N.A. Not Flanunal)l~ N.A. I EXTINGUISHING MEDIA I SPECIAL FIRE FIGHTING PROCEDURES I N.A. UNUSUAL FIRE AND EXPLOSION HAZARDS N .A.. PAGE 1 of 2 JMC/mp 10-5-82 Form OSHA.2D Rev. May 72 L/CENSESAND TAXES'e 93 . PHILIP A. HUNT CHEMICAL CORPORATION CATALOG NO. NAME OF PRODUCT KIS FILM KIT - BLEACH h" \i? SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None established. EFFECTS OF OVEREXPOSURE Ammonia vapors may produce mild irritation to eyes and mucous membranes. Soills on Skin: Wash affected areas with water. EMERGENCY AND FIRST AID PROCEDURES In Eyes: Immediately flush eyes with water for 15 minutes. Get medical attention ~mmedi~~~lY: Accidental In~~~tion:Induce vomiting. Get medical attention immediately. SECTION VI . REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID X INCOMPATABILlTY (Malaials to avoid) Strong alkalies HAZARDOUS DECOMPOSITION PRODUCTS STABLE will release ammonia vapor. None, HAZARDOUS POL YMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR x SECTION VII - SPill OR LEAK PROCEDURES (, STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush to drain with water. WASTE DISPOSAL METHOD Dilution with water; flush to drain. Biodegradable; no problem in sewering. ,SECTION VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Sped!,v Ivpel Not normally required; avoid breathing any released ~onia vapors. VENTILATION LOCAL EXHAUST SPECIAL No MECHANICAL (C,o.'/erall OTHER PROTECTIVE GLOVES I EYE PROTECTION Safety glasses or goggles Yes OTHER PROTECTIVE EQUIPMENT Liquid stains clothing, protect as needed SECTION IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep containers closed and Store in cool, dry area. plainly marked. OTHER PRECAUTIONS None PAGE 2012 JHC/mp (";,, ; .'0'" ~ 10-5-82 Form OSHA.20 Rev, May 72 94 · LICENSES AND X4XES . \ --......-- ~ . ".,t.;~1 :'-:.::l ::.~i;" ,.;;~ ':. "~S:';~":)'.:~.. ' (" . . '. .~:;:I PHILIP A. HUNT ,CHEMICAL CORPORATION PALISADES PARK, NEW JERSEY 07650 ".. """,'-P'RODUCT SAFETY DATA SHEET CABLE ADDRESS, OCHAP:N,EWYORK c . TELEPHONE, 20t 944.4000 CATALOG,NO, NAME OF PRODUCT KIS FILM KIT - STABILIZER PURPOSE OF PRODUCT To Stabilize Color Negatives against Dye Fading DESCRIPTION OF MATERIALS A proprietary aqueous solution of formalin and a wetting agent. CERTIFIED BV: DR. M. J.KELLEV, Director of Research EMERGENCV TELEPHONE: (201) 944.4000 SECTION I CHEMICAL FAMILV N.A. 1 ' 1) I TRADE NAME AND SYNONYMS (Not App J.cab e I FORMULA N.A. N.A. CHEMICAL NAME AND SVNONYMSN . A. SECTION II. HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS I PIGMENTS I CATALYST % TLV (Units) ALLOYS AND METALLIC,COATINGS % TLV (Units) BASE METAL ALLOYS VEHICLE METALLIC COATINGS (';"" ........ '. SOLVENTS ~L\J~ECRO~~T~~ OR CORE FLUX I ADDITIVES I OTHERS I OTHERS ',-'J' I . '" I DOT CORROSIVE HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES INote Formaldehyde Solution can contain 0 - 13% Methanol I I I 1% ,TLV (Units) Formaldehyde At-'J:-'.Lv.<.llo 137 198 200 3 (*3 ppm acceptable continuoUsilO ppm acceptable maximum 30 min.) 37% soln. 3* I BOILING POINT tF.) I VAPOR PRESSURE (mm Hg.) I VAPOR DENSITV (AIR=1)' I SOLUBILITY IN WATER I APPEARANCE AND ODOR SECTION III . PHYSICAL DATA 210-21S"E 770F p.HCHO 1 mm p.Hz:() ?1 mm SPECIFIC GRAVITY (H20=1) PERCENT, VOLATILE BY VOLUME (%) at 4350F. 1. 09 100% Colorless 1. 03 ~omplete solution; strong, pungent, EVAPORATION RATE (Water = 1) faster than 1 I irritating odor. / \ ",--, I FLASH POINT (Method Used) l400F closed cup I EXTINGUISHING MEDIA , Water spray, C02 or-dry chemical. I SPECIAL FIRE FIGHTING PROCEDURES Use water spray to knock down irritating vapor. I I I UNUSUAL FI RE AND EXPLOSION HAZARDS I On heating, formaldehyde solution may release flammable methanol vapor. Iuse protectiv~ ~0~!pment OSHA Class 3A, Combustible Liquid. J PAGE 1 of 2 JMC 10 - 5 - 8 2 Form OSHA.20 Rev. May 72 SECTION IV. FIRE AND EXPLOSION HAZARD DATA I FLAMMABLE LIMITS ILel 7 I Uel 73 ,UCENSESAND TAXES. 95 _ ,PHILIP A. HUNT CHEMICAL CORPORATION ~LOG NO,' NAME OF PRODUCT KIS FILH KIT - STABILIZER (", SECTION V . HEALTH HAZARD DATA THRESHOLD LIMIT VALUE Formaldehyde: 3 ppm. for 8-hr. working day; 10 ppm. max., 30 minutes. EFFECTS OF OVEREXPOSURE vapor ~s very ~rr~tat~ng to eyes,nose and throat,and ma~ cause conjunctivis 0, r bronchitis on prolonged exposure. Contact causes, seve,re eye ~rritati1n~ hardening and irritation of skin, dermatitis in some individuals. Swallowing irritat s and inflam~:?_the mouth,throat and stomach,causing abdominal pain,nausea,vom~ting and ~,;~c'I>~~F'rR'sT AID PROCEDURES If inhaled, remove to fresh air ,give artificial respir- ation or oxygen if not breathing. In case of contact,wash sk~n immediately with plenty of water; remove contaminated clothing; flush ,eyes immediately with plenty of water for at least 15 minutes and call a physician. If swallowed, call a physician. Induce vomiting b~ finger down throat or with warm salt water (tablespoon salt per glass). Repeat t~ll vomit is clear, then give milk or white of egg beaten in water. SECTION VI.. REACTIVITY DATA STABLE x CONDITIONS TO AVOIDOSHA 'Class 3A Combustible Liquid. Keep away from sparks and open flames. Store at recommended temperature to avoid polymerization. STABILITY UNSTABLE INCOMPATABILlTY IMarrrials to avoid), Reacts with oxidants. phenols. HAZARDOUS DECOMPOSITION PRODUCtS Burning may produce irritating HAZARDOUS POL YMERIZATION MAY OCCUR amines. Acids and bases catalyze polymerization. formaldehyde vapor or carbon monoxide. I CONDITIONS TO AVOID Exposure to cold may X \CaUSe precipitation of polymers, which :reQj_<::SQlvt:"1.9wly on Dp.i'lti,na. WILL NOT OCCUR SECTION VII. SP1LL OR LEAK PROCEDURES ( I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate area. Cover with inert, absorbent material and remove to disposal container. Flush area with water. Wash with dilute ammonia to remove any residual odor. I VU..STEDlsPos-Ai. METHOO--- '" ,.., '------- Incinerate in a suitable furnace. or bury in an approved landfill. Observe local, state and federal regulations, and do not contaminate any streams, lakes or ponds. I I SECTION VIII .. SPECIAL PROTECTION INFORMATION RESPI RATORY PROTECTION ISpec-lfl' rvpel If concentration exceeds TLV, use air line respirator, .Q.I.:...ll""-P"ll' of ~ir>ps i'looroved c:artridae respirator for oraanic vapors. VENTILATION LOCAL EXHAUST SPECIAL For confined area None MECHANICAL (Gr'/el'al) I Acceptable for small volume I PROTECTIVE GLOVES Waterproof qloves to avoid skin contact I OT~ER PROTECTIVE E.QUIPMENT ,Wi;lsh contaminated eve wash founta~n. protect~ve hand c::ream. OTHER transfer None I EYE PROTECTION Splash proof qoqqles or clothing before re-use. face shield. Safety shower, SECTION IX.. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING' Keep containers closed and plainly marked. Istore in cool, dry place. OT'-iER PRECAUTIONS WARNING: Strong irritant. Avoid breathing vapors. Avoid contact en, PAGE 201 2 wi th eyes. skin or clothing.: JMC/mp 10-5-82 Fo,m OSHA.20 Rev. May 72 96 · liCENSES AND TAXES CATALOG NO. ~~ -"-.t.,y::-~'! ~ "~-..:: C''''-,J;,,-~! --~~; . ~%>':I'V .,}.,' ')''11'"''(, "r . ~. ,. PHILI~ A. HUNT 'CHEMICAL CbRPORATION PALlSADES PARK. NEW JERSEY 07650 T SHEET S OCHAP'NEW YORK ''''',. ',',; ,.",.."PRODUCT SAFETY DA A CABLE ADORES ,,;,' ','" TELEPHONE: 201 944-4000 NAME OF PRODUCT KIS FILM KIT - FIXER PURPOSE OF PRODUCT A Photographic Concentrate used to prepare a Working Solution for Processing Color Film and Paper. DESCRIPTION OF MATERIALS A proprietary I aqueous solution of inorganic salts and organic chelating agents CERTIFIED BY: DR. M. J. KELLEY, Director of Rese.rcn EMERGENCY TELEPHONE: (201) 944-4000 SECTION I { 7I7,-If- ITRADE NAME AND SYNONYMS 7\1"""\T'\l-:.-::)hlo\ -~ ~ or FORMULA 1\1 n CHEMICAL FAMILY CHEMICAL NAME AND SYNONYMS, , N n 1\1 n PAINTS, PRESERVATIVES AND SOLVENTS I PIGMENTS I CATALYST I VEHICLE I SOLVENTS I ADDITIVES , OTHERS I I N .A. I I I 1\1 n SECTION II . HAZARDOUS INGREDIENTS % TLV (Units) % , TLV (Units) ALLOYS AND METALLIC COATINGS BASE METAL ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX / OTHERS "':;.'" /',";;; HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES TLV (Units) % t;';~. SECTION III. PHYSICAL DATA ! BOILING POINT tF.) VAPOR PRESSURE (mmHg.) VAPOR DENSITY (AIR=1) Aprrn,,:_ J\pprQX. I SPECIFIC GRAVITY (H20=1) 1. 38 43 1 7.6 ?l?Op PERCENT, VOLATILE 15 BY VOLUME (%) EVAPORATION RATE ~ter = 1) ....,_Al'l-Jlete I :zI.pprny_ ADDrox _, pH I 25 0 C . SOLUBILITY IN WATER I APPEARANCE AND ODOR I FLASH POINT (Metnod Used) Not Flanunable I EXTINGUISHING, MEDIA , N.A. I SPECIAL FIRE FIGHTING PROCEDURES None I Colorless liquid; sliqht odor of anunonia. SECTION IV. FIRE AND EXPLOSION HAZARD DATA 1, FLAMMABLE'UMITS - , ILel , N.A. I Uel / i \ '~, I UNUSUAL FIRE AND EXPLOSION HAZARDS I None PAGE 1 of 2 JMC/mp 10-5-82 Form OSHA.20 Rey. May 72 , liCENSES AND 1)tXE8~" 97 . PHILIP A. HUNT CMEMICAL CORPORATION CATALOG NO. NAME OF PRODUCT KIS FILM KIT - FIXER SECTION V - HEALTH HAZARD DATA r.......' ~:...'~.:., THRESHOLD LIMIT VALUE None established EFFECTS OF OVEREXPOSURE Ammonia vanors mav nroduce mild irritation to eves and mucous membranes. -Snills on Skin: Wash affected areas with water until irritation is relieved. EMERGENCY AND FIRST AID PROCEDURES In Eyes: Immediately flush eyes with water for 15 minutes. ~et medical attention immediatelv. LArrirlentallnQ:estion: Drink a glass of water. Induce vaniting. Get medical attention. SECTION VI- REACTIVITY DATA I STABILITY UNSTABLE CONDITIONS TO AVOID STABLE v: INCOMPATABILITY (MaTerials To avoid) Stronq acids or alkalies HAZARDOUS DECOMPOSITION PRODUCTS Sulfur dioxide if acidified. h'I'1U1J.a if made alkaline I HAZARDOUS POL YMERIZATION MAY OCCUR I WILL NOT OCCUR CONDITIONS TO AVOID x STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ~r;llQ should be promptly cleaned up. to drain. Wash down with water; flush I G...... I . .j'. I SECTION VII- SPill OR lEAK PROCEDURES WASTE DISPOSAL METHOD Flush with water to drain. Biodegradable; no problem in sewering. SECTION VIII- SPECIAL PROTECTION INFORMATION -j 1 I RESPIRATORY PROTECTION (Sped!.\' Type) Nnr nO"QQQ~T": avoid breathing traces of sulfur dioxide vapors. VENTILATION r LOCAL EXHAUST SPECIAL Recommended I MECHANICAL (General) OTHER Recommended PROTECTIVE GLOVES I EYE PROTECTION Plastic or rubber gloves Safety glasses or goggles. OTHER PROTECTIVE EQUIPMENT Rubber aprons SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE. TAKEN IN HANDLING AND STORING Keep containers closed. Store in roo1.. rlTv oceas. \ OTHER'PRECAUT"ONS--- I ~~ills should be promptly cleaned u~. c~_. PAGE 2 of 2 JMC/mp 10-5-82 Form OSHA.20 Rev. Mav 72 . 98 · LICENSES AND TAXES -.... --- -- ....."1'- -:-.,,' ?,,;:~'\:_"-.I,?1<-""": - ~ ,;..-.~,:~: ~--~'';., ~ ,~7~':';~1~ j.,: : ~... ~ -~ ." ('0 'PHILIP Ao HU~?; CHEMI~~L CORPORATION ::~~::~::E::R:~:A~:~:Ry:~: 07650 PRODUCT SAFETY DATA' SHEET ALoe I'WTELEPHONE, 201 , ~89: PRODUCT KIS PAPER KIT - DEVELOPER (Consists of 1 Parts) PURPOSE OF PRODUCT Photogra.phic Concentrates used to prepare a Working Solution for Developing Color Prints DESCRIPTION OF MATERIALS PART A - Aqueous solution containing Hydroxylamine SulfatE" CERTIFIED BY: DR. M. J. KELLEY. Director of Research EMERGENCY TELEPHONE, (201) 944.4000 SECTION I CHEMICAL FAMILY CHEMICAL NAME AND SYNONYMS, N.A. N.A. ITRADENAMEANDSYNONYMS (Not Applicable) I FORMULA N.A. N.A. SECTION II. HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS ,I 'Y. PIGMENTS TLV (Un lis) ALLOYS AND METALLIC COATINGS % TLV (Units) BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS SOLVENTS FILLER METAL PLUS COATING OR CORE FLUX OTHERS I I I I % I TLV (Units) Approx. 120 I * I IV below]1 V nel.owJ ADDITIVES OTHERS 'HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES t,., Hydroxylamine Sulfate *No TLV Established. Toxicity is moderate. Main hazards are explosibility at 26SoF.[See.Section and corrOSlveness to the bOdy L~ee ~ectlon SECTION III. PHYSICAL DATA 212 OF. I SPECIFIC GRAVITY (H20=1) lS mm. ~~R,Jgmi.)~~~fTILE EVAPORATlo"N RATE (' l.Va -t<=>r =1) Approx. 1.21 70 1 3.2 o BOILING POINT ( F.) Approx. Approx. VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR=I) SOLUBILITY IN WATER Completel Clear, water-white, mobile liquid. pH APPEARANCE AND ODOR No odor. FLASH POINT"(Method USed) Not Flammable I EXTINGUISHING MEDIA , . Solution is not a hazardr but crystals from dried liquid I SPECIAL FIRE FIGHTING PROCEDURES could be, especially under disaster ~onditions.Explosion Hazard for I such crystals exists when exposed to heat - e.g. 2650F. This danger UNUSUAL FIRE AND EXPLOSION HAZARDS would be increased in the presence of excess of alkalies which could , liberate free fydroxylamine. PAGElof2 JMC/mp lO-5-82 SECTION IV. FIRE AND EXPLOSION HAZARD DATA I FLAMMABLE LIMITS ILel N.A. I Uel Form OSHA.20 Rev. May 72 , LICENSES AND TAXES · 99 Q" PHIUPA. HUNT CHEMICAL CORPORATION ' ATALOGNO. '" NAME OF PRODUCT KIS PAPER KIT - DEVELOPER PART A c SECTIONV-HEAl TH HAZARD DATA 'THRESHOLD LIMIT VALUE N.A. EFFECTS OFDVEREXPOSURE Liquid 'is corrosive to skin, eyes and mucous membranes. It can cause irritation and burns wherever it comes in contact with the body. EMERGENCY AND FIRST AID PROCEDURES Affected body areas should be washed with copious quantities of soap and'warm water. In Eyes: Immediately flus~ with clean warm water for 15 min. and get medical attention. SECTION VI . REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID X Heat and excess of alkalies. Crystals [drie<< ,lIP liquid spill] can explode at 265 of. STABLE INCOMPATABILITY (MarerialS ro avoid) HAZARDOUS DECOMPOSITION PRODUCTS CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR X SECTION VII . SPill OR LEAK PROCEDURES 1(, I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush to drain with copious amounts of water. I WASTE DISPOSAL METHOD Flush to 9rain with copious amounts of water. SECTION VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify rype) Not normallv needed VENTILATION LOCAL EXHAUST SPECIAL Recommended MECHANICAL (General) , Recommended I PROTECTIVE GLOVES I EYE PROTECTION Dry rubber gloves Safety glasses, I OTHER PROTECTIVE EQUIPMENT I OTHER goggles or face shield. SECTION IX . SPECIAL PRECAUTIONS PRECAUTIONS TO filE TAKEN IN HANDLING AND STORIN~ Keep conta1ners closed. Store 1n a cool, ventilated place. OTHER PRECAUTIONS Personnel should be cautioned regarding its handling and required to use protective clothing. PAGE20f2 JMC/mp 10-5-82 (- Form OSHA-20 Re.. May 72 '. 100 . LICENSES AND TAXES ~..... ;,: :..:-.;::....;,.1~.' c.'.'..',,', 'Z'" PHILIP A. HUNT CHEMICAL CORPORATION PALISADES PARK. NEWJERS,EY 07650 '"., ,y. -"<'PRODUCT SAFETY DATA SHEET CABLE ADDRESS, OCHAP NEW YORK TELEPHONE, 201 944.4000 CATALOG NO. NAME OF PRODUCT KIS PAPER KIT - DEVELOPER (Consists of 3 Parts) PURPOSE OF PRODUCT Photographic Concen tra tes used to prepare a Working Solution for Developing Color Prints DESCRIPTION OF MATERIALS PART B - A proprietary mixture of high boiling organic solvents of low toxicity, and a color developing agent CERTIFIED BY: DR. M. J. KELLEY, Director of,Research EMERGENCY TELEPHONE: (201) 944.4000 SECTION I CHEMICAL NAME AND SYNONYMS, , N .A. CHEMICAL FAMILY N.A. (Not Applicable >1 TRADE NAME AND SYNONYMS I FORMULA N.A. N.A. SECTION II . HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS % TLV (Units) PIGMENTS BASE METAL I I I I I 1% jl6 none I L ~glutibn I r TLV (Unitsl CATALYST I VEHICLE I SOLVENTS ADDITIVES ALLOYS METALLIC COATINGS I FILLER METAL PLUS COATING OR CORE FLUX Q- -',,7. OTHERS ~~~r OTHERS HAZARDOUS MIXTURES OF 01""ER LIQUIDS, SOLIDS, OR GASES ~ ' . . Phosphate salt of p-phenylenediamine developing agent SECTION III. PHYSICAL DATA o BOILING POINT ( F.) I VAPOR PRESSURE (mm Hg.) VAPOR DENSITY IAIR=l) Approx. 400 of. SPECIFIC GRAVITY (H2o=1) loll 95 1 2 SOLUBILITY IN WATER Approx. l5 mIn. ~~R8gt'JM~~!;.fTILE Approx. I E;.~APORATION RATE 2.5 1,W;,h=>r =1) ICompletel pH at 20oC. Approx.1 Clear, pale yellow; with a mild aromatic odor. I APPEARANCE AND ODOR SECTION IV - FIRE AND EXPLOSION HAZARD DATA I FLASH'POINT (Method Used) 230oF. I EXTINGUISHING MEDIA .Water, I SPECIAL FIRE FIGHTING PROCEDURES I I FLAMMABLE LIMITS (C.C.> foam, dry chemical, C02. None ILel N.A. I Uel UNUSUAL FI RE AND EXPLOSION HAZARDS Fir~ ha2ard slight. PAGE 1 Of 2 JMC/mp lO-5-82 Form OSHA.20 Rev. May 72 - liCENSES AND TAXES-.'-tO 1 . PHILIP A. HUNT CHEMICAL CORPORATION CATALOG NO. NAME OF. PRODUCT KIS PAPER KIT - DEVELOPER PART B OJ I I THRESHOLD LIMIT VALUE I SECTION V . HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE Skin and Mucous Membranes - irritant. can cause sensitization dermatitis. Accidental Ingestion: can cause headache, nausea, vomiting or diarrhea. None established - hazard considered slight. EMERGENCY AND FI RST AID PROCEDURES On Skin: Immediately flush skin I In Eyes: Immediately flush eyes I attention immediately. Accidental InQ:estion: Ind1.H:r- vorn.;!. t in~" I with water for at least 15 min. with water for at least 15 min. Get medical G~t medical ~~~~ntion immedi~~ely. , SECTION VI . REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE x IINCOMPATABILlTY (Materials to Qvoid) Avoid oxidant such as chromic acid. liouid chlorine and concentrated oxygen. HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR x SECTION VII. SPIll OR lEAK PROCEDURES E STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush with water t.o drnin - liberates sulfur dioxide. - ..- --~~ I WASTE DISPOSAL METHOD D' 1 t . th It. t. f 1 U e W1 arge quan 1 y 0 Ito sewer. All materials are biode~radable. I I I water before sending SECTION VIII'. SPECIAL PROTECTION INFORMATION VENTILATION RESPIRATORY PROTECTION (Specify type) Not necessary - Do not breathe vapors directly LOCAL EXHAUST SPECIAL Recommended MECHANICAL (General) Recommended I EYE PROTECTION Safetv alasses. aoaales or face shield. OTHER PROTECTIVE GLOVES Drv rubber qloves I OTHER PROTECTIVE EQUIPMENT SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in cool area away fro~ 0~idants - liberates sulfur dioxide. Do not expose to high heat or flame. OTHER PRECAUT10NS l , PAGE 2 of 2 JMC/mp lO-5-82 Form OsHA.20 ,Rev. May 72 102 · LICENSES AND TAXES -.....~- (. TELEPHONE, 201 944.4000 CABLE ADDRESS, OCHAP NEW YORK PALISADES PARK. NEW JERSEY 07650 CATALOG NO. NAME OF PRODUCT KIS PAPER KIT - DEVELOPER (Consists of 3 Parts) PURPOSE OF PRODUCT Photographic Concentrates used to prepare a Working Soluton for Developing Color Prints DESCRIPTION OF MATERIALS PART C - An aqueous, alkaline solution containing 1norganic salts and organic chelating agents CERTIFIED BY, DR. M. J. KELLEY, DIrector of Research CHEMICAL NAME AND SYNONYMS, N.A. N.A. CHEMICAL FAMILY EMERGENCY TELEPHONE: (201) 944.4000 SECTION I ITRADENAMEANDSYNONYMS (Not Applicable) N.A. I FORMULA N.A. SECTION II. HAZARDOUS INGREDIENTS c.., PAINTS, PRESERVATIVES AND SOLVENTS I PIGMENTS I CATALYST I VEHICLE I SOL VENTS I ADDITIVES I OTHERS I I I I I % TLV (Units) TLV (Units) ALLOYS AND METALLIC COATINGS % BASE METAL ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS % TLV (Units) HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES o BOILING POINT ( F.) Approx. Approx. VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR=1) I SOLUBILITY IN WATER I APPEARANCE AND ODOR Colorless, potassium hydroxide 4 none in solutLon SECTION III. PHYSICAL DATA 2l2OF. SPECIFIC GRAVITY (H2o=l) 1.50 l5 mm. PERCENT, VOLATILE Approx. _48 BY VOLUME ('10) fVAW~PJ,I{;!N RA=W 1 Complet~ pH Approx. l4 odorless, aqueous liquid. SECTION IV. FIRE AND EXPLOSION HAZARD DATA I FLASH POINT (Method Used) Not Flammable I EXTINGUISHING MEDIA N.A. SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS PAGE 1 of 2 JHC/mp lO-5-82 I FLAMMABLE LIMITS N.A. Ii...el I Uel N.A. N.A. Form OSHA.20 Rev. MIY 72 LICENSES AND TAXES . 103 ~. PHILIP A. HUNT CHEMICAL CORPORATION \~ALOG NO. , NAME OF PRODUCT KIS P~PER KIT - DEVELOPER (Consists of 3 Parts SECTION V. HEALTH HAZARD DATA I?r) \2:'::.,. THRESHOLD LIMIT VALUE None established - hazard considered slight. EFFECTS OF OVEREXPOSURE On Skin: Wash affected area thoroughly with water. Use acid-type hand clean,r EMERGENCY AND FIRST AID PROCEDURES {pH.:;;:; c;,<;:::.LILl} .i.1 Civa..i.lctLl . In Eyes: Irrigate immediately with copious amounts of water for a minimum of 15 min. Get medical, attention. Accidental Ingestion: Do not induce vomiting. Give large quantities of water and - , ar lpast 1 oz. vinegar in equal amount of water. Call physician. SECTION VI . REACTIVITY DATA STABILITY UNSTABLE II> CONDITIONS TO AVOID STABLE x IINCOMPATABILlTY (Materials to avo oid) Strong acids will c~~~~ II'iAZARDOUS DECOMPOSITION PRODUCTS ~"ol~rion of carbon dioxide. None HAZARDOUS POL YMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR x SECTION VII. SPill OR lEAK PROCEDURES r. \:' STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Wash down with water. WASTE DISPOSAL METHOD Dilution with water. SECTION VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) VENTILATION LOCAL EXHAUST N.A. N.A. N.A. SPECIAL N.A. MECHANICAL (General) OTHER PROTECTIVE GLOVES Plastic or rubber I EYE ~cPf~CiyONgoggles or glasses. OTHER PROTECTIVE EQUIPMENT Rubber or plastic aprons. SECTION IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Store in cool area. Keep containers closed. OTHER PRECAUTIONS (. PAGE 2 of 2 JMC/mp lO-5-82 Form OsHA.20 Rev. May 72 104-,. LICENSES AND . TAXES -...--- . ::: ~ >;:.~ 0'."?.., .'...:-. : -:.. PALISADES PARK. NEW JERSEY 07650 ;?;..;;; . OCHAP NEW YORK 944-4000 NAME OF PRODUCT KIS PAPER KIT - BLEACH FIX (Consists of 2 Parts) PURPOSE OF PRODUCT 'Photographic Concentrate used to prepare a Working " Solution for Bleaching and Fixing Color Prints DESCRIPTION.OF MATERIALS PART A - A proprietary aqueous, almost neutral Solution containing inorganic salts and organic chelating agent~ CERTI FI ED BY: DR. M. J. KELLEY, Director of Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I CHEMICAL NAME AND SYNONYMsN . A. CHEMICAL FAMILY N.A. (Not Applicable) I TRADE NAME AND SYNONYMS I FORMULA N.A. N.A. SECTION 11- HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES AND SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS 'II. TL.V (Units) PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE I SOLVENTS I ADDITIVES, I OTHERS I I N.A. I I I METALLIC COATINGS ,\., .: FILLER METAL PLUS COATING OR CORE FLUX I OTHERS I'" HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES 'II. TLV (Units) I BOILING POINT tF.) I VAPOR PRESSURE (mm Hg.) I VAPOR DENSITY (AIR=l) I SOLUBILITY IN WATER J APPEARANCE AND ODOR SECTION 111- PHYSICAL DATA Approx. Approx. 2l20F. 15 mm. SPECIFIC GRAVITY (H20=1) PERCENT, VOLATILE BY VOLUME (%) EVAfj;RATION RATE ( ;,d-"".,.. =1) 1.3 50 1 8.0 ICompletE; pH, As Is Reddish-brown; aqueous liquid: with a mild ammonia odor. I FLASH POINT (Method Used) I EXTINGUISHING MEDIA I SPECIAL FIRE FIGHTING PROCEDURES I SECTION IV. FIRE AND EXPLOSION HAZARD' DATA Not Flammable I FLAMMABLE LIMITS ILel N.A. I Uel N.A. N.A~ I UNUSUAL FIRE AND,EXPLOSION HAZARDS I 'N.A. ,PAGE 1 of 2 JMC/mp ll-U-82 Form OsHA.ZO Rev. MIll' 72 , LICENSES AND TAXES - 105 . PHIUP.... HUNT CHEMICAL CORPORATION CATALOG NO. NAME OF PRODUCT KIS PAPER KIT - BLEACH FIX PART B (\ SECTION V . HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None established. I EFFECTS OF OVEREXPOSURE Ammonia vapors may produce mild irritation to eyes and mucous membranes of nose. I Spills on Skin: Wash affected areas with water until irritation is relieved. EMERGENCY AND FIRST AID PROCEDURES In Eyes: Immediately flush eyes,with water for 15 minutes. Get medical attention immediately. Accidental Ingestion: Drink a glass of water. Induce vomiting. I Get medical attentio~. SECTION VI. REACTIVITY DATA STABILITY I UNSTABLE I STABLE INCOMPAT ABILITY (Materials to avoid) CONDITIONS TO AVOID X None HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR x SECTION VII - SPIll OR lEAK PROCEDURES c STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush to drain wi th water. Ammonia fumes are evolved if made strongly alkaline. with strong alkalies. WASTE DISPOSAL METHOD Dilution with water: Do not contact flush to drain. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specifv type) Not normally requ1red; avoid breathing of ammonia vapors. VENTILATION LOCAL EXHAUST Recommended SPECIAL RecvlLu"ended PROTECTIVE GLOVES I EYE PROTECTION Plastic or rubber qloves Safety qlasses or qoqqles OTHER PROTECTIVE EQUIPMENT Plastic or rubber aprons MECHANICAL (General) OTHER SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING OTHER PRECAUTIONS Keep containers closed. None Store in cool area. (' PAGE 2 of 2 JMC/mp ll-ll-82 Form OSHA-20 Rev. May 72 106 · LICENSES AND TAXES -...~--_._- '. ::;:~ ~\'"... . ("''''.'.'''' " ,':".'" :~. ":'":.,"~~,; """:," , PHILIP A. HUNT CHEMICAL CORPORATION , " " ',.'. .'1"" l.. r ::BL~::~::E::R~:A~V:~:Ry:~: 07650 PRODUCT SAFETY OAT A SHEET 20t J~~t~~OpRODUCT KIS PAPER KIT - BLEACH FIX (Consists of 2 Parts) Photographic Concentrate used to prepare a Working Solution for Bleaching and Fixing Color Prints PART B - A proprietary aqueous solution of inorganic salts PURPOSE OF PRODUCT O<oSCRIPTION OF MATERIALS CERTIFIED BY: DR. M. J. KELLEY, Director 01 Research EMERGENCY TELEPHONE: (201) 944-4000 SECTION I CHEMICAL NAME AND SYNONYMS, N.A. N.A. (Not JTRADENAMEANDSYNONYMS Applicable~ I FORMULA N.A. N.A. CHEMICAL FAMILY SECTION 11- HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES AND SOLVENTS I PIGMENTS I CATALYST 'II. TLV (Uni15) ALLOYS AND METALLIC COATINGS 'II. I TLV (Units) BASE METAL ALLOYS VEHICLE METALLIC COATINGS SOLVENTS FILLER METAL PLUS COATING OR CORE FLUX ADDITIVES OTHERS OTHERS HAZARDOUS MIXTURES OF C)THER LIQUIDS. SOLIDS. OR GASES 'II. TLV (Units) N.A. I I, I SECTION 111- PHYSICAL DATA o BOILING POINT I F.) Approx. Approx. 2l2OF. SPECIFIC GRAVITY (H20=l) 1.32 15 mm. PERCENT, VOLATILE 50 BY VOLUME ('11.) fv~<t'W'pON RA';W 1 CompletE pH, As Is 5.6 VAPOR PRESSURE (mm Hg.) I VAPOR DENSITY (,AIR=l) I SOLUBILITY IN WATER I APPEARANCE AND ODOR Clear, colorless, aqueous liquid; with a very mild ammonia odor. , l\ " I FLASH POINT (Method Used) Not Flammable I EXTINGUISHING MEDIA, N.A. I SPECIAL FI,RE FIGHTING PROCEDURES N'.A. I I UNUSUAL FIRE AND EXPLOSION HAZARDS N.A. I SECTION IV - FIRE ANDEXPlOSuiN HAZARD DATA I FLAMMABLE LIMITS ILel N.A. I Uel PAGE 1 012 JMC/mp ll-ll-82 Form OsHA-20 Rev. May 72 , liCENSES AND TAXES · 107 . PHIUP A. HUNT CHEMICAL CORPORATiON CATALQG>NO. NAME OF PRODUCT KIS PAPER KIT ~ BLEACH FIX PART A c.> SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE None established. EFFECTS OF OVEREXPOSURE , Ammonia vapors may produce mild irritation to eyes and mucous membranes. Spills on Skin: Wash affected areas with water until irritation is relieved. EMERGENCY AND FIRST AID PROCEDURES In Eyes: Immediately flush eyes with water for 15 minutes. Get medical attention immediately. Accidental Ingestion: Drink a Rlass of water. Incuce vomitin~. Get medical attentioI SECTION VI. REACTIVITY D~TA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE INCOMPATABILITY {MareriDJs to tWoid} x None HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POL VMERIZATION MAVOCCUR CONDITIONS TO AVOID WILL NOT OCCUR x SECTION VII- SPILL OR LEAK PROCEDURES C.">' , ' STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush to drain with water. WASTE DISPOSAL METHOD , Dilution with water; flush to drain. SECTION VIII- SPECIAL PROTECTION INFORMATION REsPIRATORY PROTECTION (Specify type) . Not normally requ1red; avo1d breathing of VENTILATION LOCAL EXHAUST ammonia vapors. I SPECIAL I OTHER Recu......ended > PROTECTIVE GLOVES I EVE PROTECTION Plastic or rubber qloves Safety qlasses or qoqqles OTHER PROTECTIVE EQUIPMENT 1 . P ast1c or rubber aprons. Recu......ended MECHANICAL (Gene,,") SECTION IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep conta1ners closed. Store in cool area. OTHER PRECAUTIONS None PAGE 2 of 2 JMC/mp 11-11-82 c. Form OsHA.20 Rev. May 72 108 · LICENSES AND TAXES (" -~ C'" " l PALISADES PARK. NEW JERSEY D76~O PHILIP A. HUNT CHEMICAL CORPORATION PRODUCT SAFETY DATA SHEET CABLE ADDRESS: OCHAP NEW YORK TELEPHONE: 201 e....OOO SECTION I MATERIAL DESCRIPTION .. ' Name: KIS PAPER KIT 3X PRESS BLEACH-FIX (consists of 2 parts) Chemical Name or Synonyms: Not applicable (N.A.) Use: Photographic concentrate used to prepare a working solution for bleaching and fixing of color prints. - A proprietary aqueous, almost neutral solution containing inorganic salts and organic che1ating aqents. INGREDIENTS Description: Part-A ~ECTION II - HAZARDOUS Ammoium thiosulfate Sodium bisulfite SECTION III - PHYSICAL DATA Boiling Point (OF): Aprox~ 2l20F Specific Gravity: 1.3 Vapor Density: Vapor Pressure: Approx. 15 mm .... b HAZARD DATA TLV 45 - 50 3 - 5 Solubility in Water: Percent Volatile by VoL.(%): Evaporation Rate: (Water = 1) pH as is: Complete Aprox. 50 1 8.0 Appearance and Odor: Reddish-brown: aqueous liquid, with mild ammonia odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Not Flammable Extinquishing Media: Not App'licable. Lowe,r Uppe r N.A. N.A. Unusual Fire and Explosion Hazards~ Not Applicable~ SECTION V - HEALTH HAZARD DATA TLV: None established. Skin and Mucous ~1embranes: Ammonia vapors may produce mild irritation to eyes and mucous membranes of nose. Accidental Inqestion: Drink a glass of water. Induce vomiting. Ge mectical attention. Page 1 cont'd l liCENSES AND TAXt.f~l 09 . PHILIP A. HUNT CHEMICAL CORPORATION NAME: KIS PAPER KIT 3X PRESS - BLEACH-FIX, P'ART A SECTION V - HEALTH HAZARDS, cont'd First Aid: Skin: Wash affected areas with water until irritation is relieved. Eyes: Immediately flush eyes with water for at least 15 minutes. Get medical att~ntion immediately. ~ECTION VI - REACTIVITY DATA Stablity: Material is stable. Incompatibility: None. Hazardous Polymerization: Will not occur. ~ECTION VII - SPILL, LEAK, AND DISPOSAL PROCEDURES Spill or Leak: FLush to drain with water. Disposal: Dilution with water, flush to drain. S,ECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required, avoid breathing ammonia vapors. Recommended Recommended Plastic or rubber gloves Safety glasses, goggles or face'shield Local Exhaust: Mechanical: Protective Gloves: Eye Protection: SECT10N IX - SPECIAL PRECAUTIUNS AND COMMENTS Handlina & Storing: Keep containers closed. Store in cool crea. Page 2 " Approved by Mr. E. 'C. Saunders/njc 4-24-84 no . LICENSES AND TAXES c (: l -....~--- ~,'~"""'"' ,'co:-,:,:.:.;~:...;, "~:J~:~J~~~'t7 (:; ~" PALISADES PARK. NEW JERSEY 071550 CAGI.E ADDRESS: OCHAP NEW YORK TELEPHONE: 201 114.0&..0&000 SECTION I - MATERIAL DESCRIPTION Name: .~. 1; '.\f~ ~~ KIS PAPER KIT 3X PRESS BLEACH-FIX (consists of 2 parts) Chemical Name or Synonyms: Not applicable (N.A.) Use: Photographic concentrate used to prepare a working solution for bleaching and fixing of color prints. SECTION II - HAZARDOUSH INGREDI;~N'IS Description: Part~B ~ A proprietary aqueous solution of inorganic salts. Ferric EDTA Derivative SECTION III - PHYSICAL DATA Boiling Point (OF): Specific Gravity: Vapor Density: Vapor Pressure: Aprox. 2l20F 1.32 , . Approx. 15 ITUr, % HAZARD DATA TLV 45 - 50 Solubility in Water: Percent Volatile by Vol.(%): Evaporation Rate: (Water = 1) pH as is: Complete Aprox. 50 1 5.6 Appearance and Odor-: C1e4r, .colorless aqueous liquid, with very mild ammonia odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower Uoper Not Flammable Extinquishinq Media: N.A~ N.A. Not Applicable. Unusual Fire and Explosion Hazards: Not Applicable. SECTION V - HEALTH HAZARD DATA TLV: None established. Skin and Mucous Membranes: Am~onia vapors may produce mild irritation to eyes and mucous ~emhranes of nose. ' Accid~ntal Lnqestion: Drink a glass of water. Induce vomiting. Ge medical attention. Page 1 cont1d , liCENSES ANDTAXEs~~-lll ~ i:i ~ \,~ PHILIP A. HUNT CHEMICAL CORPORATION c> NAt-1E: KIS PAPER KIT3X PRESS - BLEACH-FIX, PART-B SECTION V - HEALTH HAZARDS,cont'd First Aid: Skin: Wash affected areas with wate~ until irritation is relieved. Eyes: Immediately flush eyes with water for at least 15 minutes. Get medical attention immediately. SECTION VI - REACTIVITY DATA Stablity: Material is stable. Incompatibility: None. Hazardous Polymerization: Will not occur. SECTION VII - SPILL, LEAK, AND DISPOSAL PROCEDURES Spill or Leak: Flush with water to drain. ~-mmonia fumes are evolved if made strongly alkaline. Do not contact with strong alkalies. [" '"-' Disposal: 'Dilution with water, flush to drain. SECTION VIII - SPE:IAL PROTECTION INFORHATION Respiratory Protecti.on,:. Not normally required, avoid breathing ammonia vapors. RecOIllItlended Recommended Plastic or rubber gloves Safety glasses, goggles or face shield Local Exhaust: Mechanical: Protec..t..ive Gloves,: Eye Protection: SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handlira & Storina~ Keep containers closed. Store in cool area. Page 2 Approved by Mr. E. C. Saunders/njc 4-24-84 c. 112 . LICENSES AND TAXES .....;..;:;......', .; !. PHILIP A. HUNT CHE~I~AL CORPORATION PRODUCT SAFETY DATA SHEET PALISADES PARK. NEW JERSEY 07650 CABLE ADDRESS: OCHAP NEW YORK TELEPHONE: 201 944.4000 SECTION I - MATERIAL DESCRIPTION Name: KIS TANK CLEANER Chemical Name or Synonyms: , Not Applicable (N.A.) Use: Cleaner for KIS processing equipment Description: Strongly acidic aqueous solution. SECTION II - HAZARDOUS INGREDIENTS % HAZARD DATA Composition: TLV Sulfuric acid Potassium dichromate l4 lO SECTION III - PHYSICAL DATA Boiling Point (OF): Specific Gravity: Vapor Density: (Air = 1) Vapor ,Pressure: 15 mm 200 1. 175 N.A. SOlubil},ty in Water: Complete Percent Volatile by Vol.(%): 80 Evaporation Rat.e,: Water = 1 N.A. Appearance and Odor: Orange liquid; essentially odorless. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method Flammability Limits Lower Upper None N.A. N.A. Extinguishing Media: Cool fire-exposed containers with water spray. SECTION V - HEALTH HAZARD DATA TLV: Not Applicable. Effects of Overexposure: Cbrrosive; contact may cause moderate to severe irritation. ./ i \ " cont'd Page 1 . liCENSES AND TAXEr'- 113 (iI' PHILIP A. HUNT CHEMICAL CORPOR'ATION ~NAME: KIS TANK CLEANER SECTION V - HEALTH HAZARDS, cont'd First Aid: On Skin: Rinse thoroughly; wash with mild soap. In Eyes: Rinse copiously with cold water for at least 15 minutes: seek medical attention. SECTION VI - REACTIVITY DATA Stability: Stable Hazardous Polymerization: Will not occur. SECTION VII - SPILL; LEAKr AND DISPOSAL PROCEDURES Spill or Leak: Collect spills; collect in a container for disposal. Disposal: Sroa1l quantities may be flushed to drain; for large quantities Consult local regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: Local Exhaust: Mechanical: Protective Gloves: Eye Protection: Other: Not normally needed Recommended Dry rubber gloves Safety glasses, goggles or face shield SECTION IX - SPECIAL PRECAUTIONS AND COMMENTS Handlinq & Storinq~ Store in cool, dry area. and tightly closed. Keep containers well marked Other Precautions: None Page 2 Approved by Mr. E.C. Saunders/njc January 4, 1984 114 . liCENSES AND TAXES .--.~--- ( ( ( ..,......,"1. PALISADES PARK ",r::.W JERSEY 07650 ' 'UNT CHEMICAL COF :>RATION PRODUCT SAFETY DATA SHEET PHILIP A, @;:<>;~ '. ~".,'."'..'.~ :-."~. :!:~:.~. CAIlL.E AOORESS: OCHAP NEW YORK TEL.EPHONE: 201 11,,"-"000 SECTION I MATERIAL DESCRIPTION Name: KIS PAPER KIT 3X PRESS DEVELOPER (consists of 3 parts) Chemical Name or Synonyms: Not applicable (N.A.) Use: Photogr~phic concentrates used to prepare a working solution for developing color prints. Description: 'Part A - An aqueous solution containing Hydroxylamine sulfate SECTION II - HAZARDOUS INGREDIENTS % HAZARD DATA Composition: Hydroxylamine sulfate Lithium Chloride TLV Approx. 15 - 20 10 - 15 ,. *No TLV established. Toxicity is moderate. Main hazards are exposibility at 2650F. [See Section IV below] and corrosiveness to the body [See Section V below]. SECTION III - PHYSICAL DATA Boiling'Point ( of ) : Approx. 2120 Solubility in Water: Specific Gravity: 1. 21 Percent Volatile by ( Vapor Density: Evaporation Rate: Vapor Pressure: 'Approx. 15 mm (Water = 1 ) Complete Vol.(%): Aprox. 70 1 pH: 2.5 Appearance and Odor: Clear, water-white, mobile liquid. No odor. ~ECTION IV - FIRE AND EXPLOSION HAZARD DATA flash Point and Method flammability Li~its Lower Upper Not Flammable N.A. N.A. Extinguishinq Medial Solution is not a hazard, but crystals from dried liquid could be, especially under disaster conditions. Unusual Fire and Explosion--H'a'z-ards,: EXPLOSION HAZARD for such crystals exists when exposed to heat - e.g. 2650F. This danger would be increased in the presence of excess alkalies which could liberate free hydroxylamine. SECTION V - HEALTH HAZARD DATA TLV~ N.A. Effects of Overexposure: Liquid is corrosive to skin, eyes and mucous membranes. It can cause irritation and burns wherever it comes in contact with the body. cont'd Page 1 liCENSES AND 'E4XES · 115 ~ PHIUP A. HUNT CHEMICAL CORPORATION r ~~;, NAME: KIS PAPER:KIT3X PRESS -PART A . SECTION V - HEALTH HAZARDS, cont'd First Aid: Skin: Affected body areas should be washed with copious amounts of soap and warm \ola ter . Eyes: Immediately flush with clean warm water for 15 minutes and'get medical attention. SECTION VI - REACTIVITY,DATA Stablitv: Material is unstable. Conditions to Avoid: Heat and excess of alkalies. Crystals (dried up liquid spill) can explode at 2650F. SECTION VII - SPILL, LEAK, AND DISPOSAL PROCEDurt~~ Spill or Leak: Flush to drain with copious amounts of water~ (",. , , Disoosal: Fltish to drain with copious amounts of water~ SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: Local Exhaust: Mechanical: Protective Gloves: Eye Protection: Not normally needed Recommended Recommended Dry rubber gloves Safety glasses, goggles or face shield SECTION .l.X - SPECIAL PRECAUTIONS AND COMMENTS Handl~na & Storina: Keep containers closed. Store in a cool, ventilated place. Other Precautions: Persbnnel should be cautioned regarding its handling and required to use protective clothing. Page 2 Approved by Mr. E. C. Saunders/mat 4-24-84 l, . 116 · LICENSES AND TAXES , '. _ " ','"~,'; t.,c' , " PALISADES PARK. NEW .JERSEY 07650 IUNT CHEMICAL CO~"VRATION ~-:-..{..:;~'::. PRODUCT SAFETY DATA SHEET PHILIP .A CASU ADDRESS: OCHAP NEW YORK TEUPHONE: 201 1144.4000 . i." _J".. C,," ;.'.>" .... ,.." . -......-. . - ~...:' . ~;:.-;;: . SECTION I - MATERIAL DESCRIPTION '"t Name: KIS PAPER KIT 3X PRESS DEVELOPER (consists of,3 parts) Chemical Name or Synonyms: Not applicable (N.A.) Use: Photographic concentrates used to prepare a working solution for developing color prints. Description: Part B -A proprietary mixture of high boiling organic' , Solvents of low toxicity, and a color develooin9 aaent SECTION II - HAZARDOUS INGREDIENTS % I HAZARD DATA Phosphate salt of p~phenYlen~iamine TLV developing agent 15 - 20 . , Benzyl Alcohol 16 - 21 Ethylene glycol 35 - 40 Whitening Agent (Stilbene derivative) 0.5 - 1.0 Sodium sulfite 1 - 2 *None in solution. SECTION III - PHYSICAL DATA Boiling Point (OF): Aprox. 4000F Specific Gravity: Vapor Density: Vapor Pressure: Aprox. 1.15 2.5 l5~'mm Solubility in Water: Percent Volatile by Vol.(%): Evaporation Rate: Watet.: 1 pH @ 20oC: Complete Aprox., 95 1 2 Appearance and Odor: Clear, pale yellow; with a mild aromatic odor. .~ECTION IV - FIRE AND EXPLOSION HAZARD DATA .t'lasR Point and Method J t'.lammability Limits Lower Upper 2300F. (C.C.) R.A. R.A. Extinauishinq Media: Water, foam, dry chemical, C02 Unusual Fire and Explosion Hazards: Fire hazard slight. SECTION V - HEALTH HAZARD DATA TLV: None established - hazard considered slight Skin and Mucous Memnranes: Irritant, can cause sensitization dermati~is Accidental Inqestion~ Can cause headache, nausea, vomiting or diarrhea LICENSES AND TAiEf~'-117 ~. , / I I I \ .,~ PHILIP A.. HUNT CHEMICAL CORPORATION c NAME: KIS PAPER KIT 3X PRESS - PART B SECTION V - HEALTH HAZARDS, cont1d First Aid: Skin: Immediately flush skin with water for at least 15 minutes. Eyes: Immediately flush eyes with water for at least 15 minutes. Get medical attention immediately. Inaestion: Induce vomitin9. Get medical attention immediately. SECTION VI - REACTIVITY DATA Stablitv: Material is unstable. Incornoatibilit~: Avoid oxidant such as chromic acid, liquid chlorine and Concentrated oxygen. Hazardous Polymerization: Will not occur. SECTION VII - SPILL, LEAK, AND DISPOSAL PROCEDURES Spill or Leak: Flush with water to drain - liberates sulfur dioxide. ( Disposal: Dilute with large quantity of water before sending to sewer. All materials are biodegradable. SECTION--VIII - SPECIAL PROTECTION INFORMATION Respiratory ProtectIon: Local Exhaust: Mechanical: Protective Gloves: Eye Protection: Not necessary - do not breath vapors directly, Recommended Recommended Dry rubber gloves Safety glasses,. goggles or face shield SECTION IX - SPECIAL PRECAUTIONS AND Cm1MENTS ffa-n'dttncr & Storinq: Store in a cool area away from oxidants - liberates sulfur dioxide. Do not expose to high heat or flame. Page 2' l. Approved by Mr. E. C. Saunders/mat 4-24-84 118 · LICENSES AND TAXES _....__or--- > - '.. ,."- ~. , , " , PHILIP A. .1UNT CHEMICAL CORf-'ORATION ~RpDUCT SAFETY DATA SHEET PALISADES PARK. NEW JERSEY 07650 CABLE ADDRESS: OCHAP NEW YORK TELEPHONE: 201 9","'."'000 SECTION I - MATERIAL DESCRIPTION Name: KIS PAPER KIT 3X PRESS DEVELOPER (consists of 3 parts) Chemical Name or Synonyms: Not applicahle (N.A.) Use: Photographic concentrates used to prepare a working solution for developing color prints. Description: Part C - An aqueous, alkaline solution containing inorganic salts and oraanic chelatino aqents SECTION II - HAZARDOUS~INGREDIENTS I' HAZARD DATA Potassium hydroxide EDTA derivatives Potassium carbonate Sodium sulfite TLV 5 - 8 2 - 4 35 - 40 1 - 2 SECTION III - PHYSICAL DATA Boiling Point (OF): Specific Gravity: Vapor Density: Vapor Pressure: Aprox. 2120F Solubility in Water: 1.50 Percent Volatile by Vol.(%): Evaporation Rate: Approx. 15 mm Water =1 pH : Complete Aprox. 48 1 Aprox. 14 Appearance and Odor: Colorless, odorless, aqueous liquid. SECTION IV - FIRE Flash Point and Not flammable AND EXPLOSION HAZARD DATA Method I -Fl'ammabi 1i tv Limi ts I N.A. Lower Upper N.A. Extinouishinq Media: N.A. Unu-sua1 F'ire and Explos ion 'Hazards: N .A. SECTION V . - HEALTH HAZARD DATA TLV: None established - hazard considered slight LICENSES AND TAXES · 119 e PHILIP A. HUNT CHEMICAL CORPORATION G,'.",'..',.... '<1f:'~': NAME: KIS PAPER KIT 3X PRESS - DEVELOPER, PART C SECTION V - HEALTH HAZARDS, cont~d first Aid: Skin: Wash affected area thoroughly with water. Use acid-type hand cleaner if available. (pH. SO derm) Eyes: Irrigate immediately with copious amounts of water for a minimum of 15 minutes. Get medical attention. Ingestion: Do not induce vomiting. Give large quantities of water and at least 1 oz. vinegar in equal amount of water. Call physician. SECTION VI - REACTIVITY DATA Stablitv: Material is unstable. Incomoatibility: Strong acids will cause evolution of carbon dioxide. Hazardous Polymerization: Will not occur. SECTION VII - SPILL, LEAK, AND DISPOSAL ~rtUL~uURES ,G.'."",'..'. ,. - ',,".', '.';-.,--' Spill or Leak: Wash down with water. Disposal: Dilution with water. SECTION VIII - SPECIAL PROTECTION.INFORMATION Respiratory Protection: Local Exhaust: Mechanical: Protective Gloves: Eye Protection: Other: Ventilation: N. A. N. 'A. N. A. Plastic or rubber Safety goggles or glasses Rubber or plastic aprons N. A. . SECTiON LX - SPECIAL PRECAUT.lONSAND COMMENTS Handlin~ & StorinQ? Store in a cool area. Keep containers closed. Page 2 Approved by Mr. E. C. Saunders/mat 4-24-84 l~ 120 · LICENSES AND TAXES -.... --,- G".". ,'... ,H.. . ",;'r.. ". ;;~.'.:'.' . ,,'.,:U , ....'C.,. ;:.'!' ('..,,:....,',. ~ - ',- " .... ,""'; -' _-_'Sl'~ , [ \ ,~. '~:,~;{..:.t PHILIP A.HUNT CHEMICAL CORPORATION July lB, 19B3 Mr. Richard Novak Video Cinema, Inc. 51 Ethan Allen Highway Ridgefield, CT 06B77 , Dear Mr. Novak: Mr. J.Bergeron has indicated that you wish to be informed of any hazards to the septic disposal system, that might occur as the result of putting the wash water from your KIS minilab processors down the drain. The effluents from the photoprocessing of color films and paper are environmentally inocuous. The color processing solutions of today are formulated to have a minimum impact on the waste disposal systems. The components are readily biodegradable, and have no inhibiting effect on the bacterial activity of the treatment facility. Those salts which are present in any significant concentrations are phosphates, carbonates and sulfates, the same as those used in,-household laundry detergents. Inasmuch as the wash waters from the processor{s) are mixed together the dissolved solids concentration is low, the pH is essentially neutral to mildly alkaline, ranging between 7.0 and B.5, and the temperature seldom reaches B50F., lower than bath water. Kis formulations for film and paper contain no heavy metals such as lead, zinc, copper, nickel or mercury. The waste does not contain any cyanide. Suspended solids are considerably less than those present in the sanitary sewer effluents. Trace quantities of silver are not unusual, coming from the fixing-out of film and paper. Good housekeeping and proper monitoring of the silver recovery system should hold this to a low continued..... PALISADES PARK. NEW JERSEY 07650.2011944-4000 .2011592.7000. TELEX 7101991.9783 LICENSES AND TAXES . 121 ~lr. Richard Novak -2- July 18, 1983 ( acceptable level of a few parts per million. Any dissolved silver in the waste is present as thiosulfate complex, in which the silver is tightly bonded. This species of silver at these low ' concentrations has no toxic effects, as distinct from the greater toxicity of the free silver ion. I trust that the foregoing will be sufficient for your purpose. However, if further information is needed, do not hesitate to call on us. Very truly yours, A. HUNT CHEMICAL CORPORATION uane, Ph.D. Director, Research Administrat{j" JJD/njc cc: r~. J. Bergeron Mr. R. W. McConnell Mr. H. T. Viehmeyer l 122 · LICENSES AND TAXES -......-,- 0:'" (;;;~:i,S;; t. \:~ ( '~, ,.::;.' PHILIP A.HUNT CHEMICAL CORPORATION BIOLOGICAL OXYGEN DEMAND OF PHOTOGRAPHIC CHEMICALS The decomposition of waste in a municipal sewage secondary treatment plant depends on aerobic bacterial activity; oxygen is consumed during the biodegradation processes. A septic tank, on the other hand, is a closed anerobic system; bio- degradation occurs in the absence of oxygen. Over 99 percent of photofinishers discharge waste water to sewage treatment piants. The latter are concerned with the load of biodegradable constituents that enter their works, therefore, they often request information on the biological oxygen demand (BOD) or chemical oxygen demand (COD) of the effluent passing into the sewer. An explanation of this terminology and the ' arithmetic of using the data is contained in Kodak Publication J-4l, "BODS & COD of Kodak Photographic Chemicals." The BODS and COD values for Hunt packaged chemistry kits have been determined. These are given in the attached table, express- ed either as pounds per gallon of replenisher or grams per liter. LICENSES AND TAXES -123 c PHIUP AHUNT CHEMICAL CORPORATION SILVER IN PHOTOGRAPHIC .r.tr".n..uuuS It is a fact that almost all photofinishers discharge waste to a publically-owned (municipal).sewage treatment plant. Therefore, it is the local sewer code that determines what is or is not acceptable going to the sewer. Federal EPA effluent guide lines on the other hand apply specifically for control of discharges to open waters or ground water. The three most closely controlled ionic species emanating from photo- .',' processing plants are cyanide, chromate, and silver. It is extremely (~ unlikely that cyanide would ever appear except under exceptional cir- ' cumstances involving ferricyanide bleaches. Chromate occurs only in a few motion picture fi1m processes. However, silver is a1most always present in measurable amounts 'in photoprocessing effluents. Since most sewer codes do require a statement regarding silver, we will attempt to address this point. Silver content is usually expressed as a concentration, i.e., 5 milli- grams per liter (5 mg/L) or, less often, troy ounces per gallon (1.0 troy oz/gal = 8.2 mg/L). The sewage treatment plant is more concerned. with the quantity of silver it has to deal. with so it also requires that the total volume of effluent discharged per day (or week, or year) also be given. Most large treatment facilities are not unduly concern- ed about a reasonable quantity of silver going to drain because 1) the photographic effluent will be greatly diluted with other sewage by the time it reaches the plant, and 2) silver from photoprocessing waste is no longer regulated as a hazardous waste. l 124 . LICENSESAND TAXES -.~-- c l To get a feeling for what constitutes a "reasonable" concentration of silver, the table following gives some rough approximations as guide- posts. NORMAL STANDARD Max. permissible concentration in drinking water. A low level in wash water. Fixer exiting from a steel wool bucket in good working order. Prepare to change the steel wool bucket. Recirculating fixer in electrolytic silver recovery unit. Nominal silver content of working fixer or bleach. IJCENSES AND TAXES . 125